RU2016140366A - Микроструктурированные многослойные эластичные слоистые материалы с повышенной прочностью и эластичностью и способы их получения - Google Patents
Микроструктурированные многослойные эластичные слоистые материалы с повышенной прочностью и эластичностью и способы их получения Download PDFInfo
- Publication number
- RU2016140366A RU2016140366A RU2016140366A RU2016140366A RU2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A RU 2016140366 A RU2016140366 A RU 2016140366A
- Authority
- RU
- Russia
- Prior art keywords
- styrene
- ethylene
- elastic laminate
- weight
- layer
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 10
- 239000000463 material Substances 0.000 title claims 2
- 229920001169 thermoplastic Polymers 0.000 claims 16
- 239000004416 thermosoftening plastic Substances 0.000 claims 16
- 239000004033 plastic Substances 0.000 claims 13
- 229920003023 plastic Polymers 0.000 claims 13
- 229920000098 polyolefin Polymers 0.000 claims 10
- 229920006125 amorphous polymer Polymers 0.000 claims 6
- 230000002427 irreversible effect Effects 0.000 claims 6
- 229920006132 styrene block copolymer Polymers 0.000 claims 6
- -1 styrene-ethylene-propylene-styrene Chemical group 0.000 claims 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims 6
- 229920006126 semicrystalline polymer Polymers 0.000 claims 5
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims 4
- GJKZSOHUVOQISW-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene;styrene Chemical compound C=CC=C.CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 GJKZSOHUVOQISW-UHFFFAOYSA-N 0.000 claims 4
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- 229920001195 polyisoprene Polymers 0.000 claims 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 239000004793 Polystyrene Substances 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000004927 clay Substances 0.000 claims 2
- 230000002708 enhancing effect Effects 0.000 claims 2
- 238000001125 extrusion Methods 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- 229920000728 polyester Polymers 0.000 claims 2
- 229920002223 polystyrene Polymers 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 239000003623 enhancer Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/144—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
- B32B7/022—Mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2009/00—Use of rubber derived from conjugated dienes, as moulding material
- B29K2009/06—SB polymers, i.e. butadiene-styrene polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2274/00—Thermoplastic elastomer material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/702—Amorphous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/704—Crystalline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7244—Oxygen barrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2555/00—Personal care
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31931—Polyene monomer-containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Claims (25)
1. Эластичный слоистый материал, содержащий:
первый термопластичный эластомерный слой пленки, обладающий необратимой деформацией менее 40% после 150% удлинения, при этом термопластичная эластомерная пленка содержит термопластичный эластомер на основе полиолефинов и стирольный блок-сополимер; и
первый слой пластика, прикрепленный к первой поверхности термопластичного эластомерного слоя пленки, при этом слой пластика обладает необратимой деформацией, превышающей необратимую деформацию эластомерного слоя пленки, и где слой пластика содержит один из полукристаллического и аморфного полимера.
2. Эластичный слоистый материал по п. 1, где термопластичный эластомер на основе полиолефинов содержит гомополимер или сополимер б-олефина с 1—12 атомами углерода.
3. Эластичный слоистый материал по п. 1, где стирольный блок-сополимер выбран из группы, состоящей из стирол-этилен-пропилен-стирола (SEPS), стирол-этилен-пропилен-стирол-этилен-пропилена (SEPSEP), стирол-этилен-бутилен-стирола (SEBS), стирол-этилен-бутилен-стирол-этилен-бутилена (SEBSEB), стирол-бутадиен-стирола (SBS), стирол-изопрен-стирола (SIS), стирол-изопрен-бутадиен-стирола (SIBS), стирол-этилен-этилен-пропилен-стирола (SEEPS), гидрогенизированного винил-полиизопрена/гидрогенизированного полиизопрена/полистирола и их комбинаций.
4. Эластичный слоистый материал по п. 1, дополнительно содержащий средство, повышающее прочность, где средство, повышающее прочность, представляет собой неорганическую глину.
5. Эластичный слоистый материал по п. 4, где термопластичный эластомерный слой пленки содержит более 50% по весу термопластичного эластомера на основе полиолефинов, от приблизительно 15% по весу до приблизительно 40% по весу стирольного блок-сополимера и от приблизительно 2% по весу до приблизительно 10% по весу средства, повышающего прочность.
6. Эластичный слоистый материал по п. 1, где термопластичный эластомерный слой пленки практически не содержит карбонат кальция.
7. Эластичный слоистый материал по п. 1, где полукристаллический или аморфный полимер выбран из группы, состоящей из полиолефинов, coполимеров на основе полиолефинов, сложных полиэфиров и их комбинаций.
8. Эластичный слоистый материал по п. 1, где слой пластика содержит от приблизительно 5% по весу до приблизительно 50% по весу полукристаллического или аморфного полимера.
9. Эластичный слоистый материал по п. 1, где термопластичный эластомерный слой пленки является непроницаемым для воздуха.
10. Эластичный слоистый материал по п. 1, дополнительно содержащий второй слой пластика, прикрепленный ко второй поверхности термопластичного эластомерного слоя пленки.
11. Эластичный слоистый материал по п. 1, дополнительно содержащий второй термопластичный эластомерный слой пленки, где второй термопластичный эластомерный слой пленки прикреплен к первому слою пластика, противоположному первому термопластичному эластомерному слою пленки.
12. Способ получения эластичного слоистого материала, при этом способ включает:
совместную экструзию первого термопластичного эластомерного слоя пленки с первым слоем пластика с получением эластичного слоистого материала, при этом термопластичный слой пленки обладает необратимой деформацией менее 40% после 150% удлинения и содержит термопластичный эластомер на основе полиолефинов, стирольный блок-сополимер и средство, повышающее прочность, при этом слой пластика обладает необратимой деформацией, превышающей необратимую деформацию эластомерного слоя пленки, и где слой пластика содержит один из полукристаллического или аморфного полимера;
растяжение эластичного слоистого материала в одном или обоих из машинного направления или поперечного направления; и
расслабление растянутого эластичного слоистого материала.
13. Способ по п. 12, где термопластичный эластомер на основе полиолефинов содержит гомополимер или сополимер α-олефина с 1—12 атомами углерода.
14. Способ по п. 12, где стирольный блок-сополимер выбирают из группы, состоящей из стирол-этилен-пропилен-стирола (SEPS), стирол-этилен-пропилен-стирол-этилен-пропилена (SEPSEP), стирол-этилен-бутилен-стирола (SEBS), стирол-этилен-бутилен-стирол-этилен-бутилена (SEBSEB), стирол-бутадиен-стирола (SBS), стирол-изопрен-стирола (SIS), стирол-изопрен-бутадиен-стирола (SIBS), стирол-этилен-этилен-пропилен-стирола (SEEPS), гидрогенизированного винил-полиизопрена/гидрогенизированного полиизопрена/полистирола и их комбинаций.
15. Способ по п. 12, где средство, повышающее прочность, представляет собой неорганическую глину.
16. Способ по п. 12, где термопластичный эластомерный слой пленки содержит более 50% по весу термопластичного эластомера на основе полиолефинов, от приблизительно 15% по весу до приблизительно 40% по весу стирольного блок-сополимера и от приблизительно 2% по весу до приблизительно 10% по весу средства, повышающего прочность.
17. Способ по п. 12, где полукристаллический или аморфный полимер выбирают из группы, состоящей из полиолефинов, coполимеров на основе полиолефинов, сложных полиэфиров и их комбинаций.
18. Способ по п. 12, где эластомерный слоистый материал растягивают на от приблизительно 100% до приблизительно 600% в машинном направлении или поперечном направлении.
19. Способ по п. 12, дополнительно включающий совместную экструзию второго слоя пластика с первым термопластичным эластомерным слоем пленки, противоположным первому слою пластика, при этом второй слой пластика содержит один из полукристаллического или аморфного полимера.
20. Способ по п. 12, дополнительно включающий совместную экструзию второго термопластичного эластомерного слоя пленки с первым слоем пластика, противоположным первому термопластичному эластомерному слою пленки.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/230,741 | 2014-03-31 | ||
US14/230,741 US9802392B2 (en) | 2014-03-31 | 2014-03-31 | Microtextured multilayered elastic laminates with enhanced strength and elasticity and methods of making thereof |
PCT/IB2015/051661 WO2015150937A1 (en) | 2014-03-31 | 2015-03-06 | Microtextured multilayered elastic laminates with enhanced strength and elasticity and methods of making thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2016140366A true RU2016140366A (ru) | 2018-04-13 |
RU2661214C2 RU2661214C2 (ru) | 2018-07-13 |
Family
ID=54189101
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2016140366A RU2661214C2 (ru) | 2014-03-31 | 2015-03-06 | Микроструктурированные многослойные эластичные слоистые материалы с повышенной прочностью и эластичностью и способы их получения |
Country Status (9)
Country | Link |
---|---|
US (1) | US9802392B2 (ru) |
EP (1) | EP3126140B1 (ru) |
KR (1) | KR102356219B1 (ru) |
CN (1) | CN106103088B (ru) |
AU (1) | AU2015242310B2 (ru) |
BR (1) | BR112016021562B1 (ru) |
MX (1) | MX360519B (ru) |
RU (1) | RU2661214C2 (ru) |
WO (1) | WO2015150937A1 (ru) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11220085B2 (en) * | 2017-08-31 | 2022-01-11 | Kimberly-Clark Worldwide, Inc. | Apertured elastic film laminates |
US11707917B2 (en) | 2019-04-17 | 2023-07-25 | Nitto Denko Corporation | Multilayer co-extruded films and article containing same |
CN111605277A (zh) * | 2020-04-27 | 2020-09-01 | 温州市特康弹力科技股份有限公司 | 一种卫材 |
EP4032703A1 (en) * | 2021-01-21 | 2022-07-27 | Kuraray Europe GmbH | Thermoplastic elastomeric compositions comprising polyolefins and styrene b-ethylene-ethylene-propylene b-styrene block copolymers |
Family Cites Families (118)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2531396A (en) | 1947-03-29 | 1950-11-28 | Nat Lead Co | Elastomer reinforced with a modified clay |
BE534424A (ru) | 1953-12-24 | |||
US3953638A (en) | 1973-11-26 | 1976-04-27 | The Procter & Gamble Company | Multi-ply absorbent wiping product having relatively inextensible center ply bonded to highly extensible outer plies |
DE2449491B2 (de) | 1974-10-19 | 1979-09-20 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von homogenen band- oder granulatförmigen thermoplastischen Massen auf der Basis von Polymeren und Bitumen |
US4197377A (en) | 1977-06-13 | 1980-04-08 | The Firestone Tire & Rubber Company | Thermoplastic elastomer compositions |
DK144382C (da) | 1977-11-08 | 1982-07-26 | Kroyer K K K | Apparat til fremstilling af et baneformet fiberprodukt |
US4259220A (en) | 1978-12-06 | 1981-03-31 | H. B. Fuller Company | Hot melt adhesive for elastic banding |
US4375448A (en) | 1979-12-21 | 1983-03-01 | Kimberly-Clark Corporation | Method of forming a web of air-laid dry fibers |
US4525407A (en) | 1982-08-27 | 1985-06-25 | Chicopee | Elastic composites |
US4528239A (en) | 1983-08-23 | 1985-07-09 | The Procter & Gamble Company | Deflection member |
US4514345A (en) | 1983-08-23 | 1985-04-30 | The Procter & Gamble Company | Method of making a foraminous member |
US4640810A (en) | 1984-06-12 | 1987-02-03 | Scan Web Of North America, Inc. | System for producing an air laid web |
US4639949A (en) | 1985-01-10 | 1987-02-03 | Kimberly-Clark Corporation | Elastic form-fitting closure constructions for disposable garments |
US4657802A (en) | 1985-07-30 | 1987-04-14 | Kimberly-Clark Corporation | Composite nonwoven elastic web |
US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
US4652487A (en) | 1985-07-30 | 1987-03-24 | Kimberly-Clark Corporation | Gathered fibrous nonwoven elastic web |
US4606964A (en) | 1985-11-22 | 1986-08-19 | Kimberly-Clark Corporation | Bulked web composite and method of making the same |
US4789699A (en) | 1986-10-15 | 1988-12-06 | Kimberly-Clark Corporation | Ambient temperature bondable elastomeric nonwoven web |
US4939016A (en) | 1988-03-18 | 1990-07-03 | Kimberly-Clark Corporation | Hydraulically entangled nonwoven elastomeric web and method of forming the same |
US4880682A (en) | 1988-03-22 | 1989-11-14 | Exxon Chemical Patents Inc. | Low gloss film and process of manufacture (FP 1323) |
JP2974702B2 (ja) * | 1989-12-22 | 1999-11-10 | 三菱化学株式会社 | 熱可塑性エラストマー積層フィルム |
US5429856A (en) | 1990-03-30 | 1995-07-04 | Minnesota Mining And Manufacturing Company | Composite materials and process |
US5354597A (en) | 1990-03-30 | 1994-10-11 | Minnesota Mining And Manufacturing Company | Elastomeric tapes with microtextured skin layers |
US5344691A (en) | 1990-03-30 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Spatially modified elastic laminates |
JP3007414B2 (ja) | 1990-03-30 | 2000-02-07 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 微細模様付き皮層を有するエラストマー性テープ |
CA2155222C (en) | 1990-06-29 | 1997-11-11 | Paul Dennis Trokhan | Process for making absorbent paper web |
US5260171A (en) | 1990-06-29 | 1993-11-09 | The Procter & Gamble Company | Papermaking belt and method of making the same using a textured casting surface |
US5098522A (en) | 1990-06-29 | 1992-03-24 | The Procter & Gamble Company | Papermaking belt and method of making the same using a textured casting surface |
US5275700A (en) | 1990-06-29 | 1994-01-04 | The Procter & Gamble Company | Papermaking belt and method of making the same using a deformable casting surface |
CA2048905C (en) | 1990-12-21 | 1998-08-11 | Cherie H. Everhart | High pulp content nonwoven composite fabric |
US5628741A (en) | 1991-02-28 | 1997-05-13 | The Procter & Gamble Company | Absorbent article with elastic feature having a prestrained web portion and method for forming same |
CA2069193C (en) | 1991-06-19 | 1996-01-09 | David M. Rasch | Tissue paper having large scale aesthetically discernible patterns and apparatus for making the same |
US5334446A (en) | 1992-01-24 | 1994-08-02 | Fiberweb North America, Inc. | Composite elastic nonwoven fabric |
US5576090A (en) | 1992-02-13 | 1996-11-19 | Suzuki; Migaku | Sheet elastic complex used in sanitary products its manufacturing process, and its usages |
US5376430A (en) | 1992-06-19 | 1994-12-27 | Minnesota Mining And Manufacturing Company | Elastic film laminate |
ES2122038T3 (es) | 1992-08-26 | 1998-12-16 | Procter & Gamble | Correa para la fabricacion de papel con configuracion semicontinua y papel fabricado sobre ella. |
CA2097630A1 (en) | 1992-12-29 | 1994-06-30 | Ann Louise Mccormack | Stretch-pillowed, bulked laminate |
USH2096H1 (en) | 1993-02-03 | 2004-01-06 | Exxon Chemical Patents, I | Thermoplastic elastomer copolymer films |
KR100307699B1 (ko) | 1993-02-03 | 2001-11-30 | 엑손 케미칼 패턴츠 인코포레이티드 | 열가소성엘라스토머공중합체필름 |
DK168670B1 (da) | 1993-03-09 | 1994-05-16 | Niro Separation As | Apparat til fordeling af fibre |
US5422172A (en) | 1993-08-11 | 1995-06-06 | Clopay Plastic Products Company, Inc. | Elastic laminated sheet of an incrementally stretched nonwoven fibrous web and elastomeric film and method |
FR2717450B1 (fr) | 1994-03-21 | 1996-05-15 | Oreal | Conditionnement en matériau plastique composite présentant un effet doux au toucher. |
EP0757624B2 (en) | 1994-04-29 | 2002-08-28 | Kimberly-Clark Worldwide, Inc. | Slit elastic fibrous nonwoven laminates |
US5496624A (en) | 1994-06-02 | 1996-03-05 | The Procter & Gamble Company | Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby |
US5500277A (en) | 1994-06-02 | 1996-03-19 | The Procter & Gamble Company | Multiple layer, multiple opacity backside textured belt |
CA2150333A1 (en) | 1994-05-26 | 1995-11-27 | W. Andrew Coslett | Unidirectionally stretchable elastomeric trilaminate and method for its manufacture |
USH1808H (en) | 1994-11-17 | 1999-10-05 | Shell Oil Company | Extrudable styrenic block copolymer compositions containing a metallocene polyolefin |
USH1798H (en) | 1994-12-22 | 1999-07-06 | Shell Oil Company | Soft compounds containing elastomeric metallocene polyolefins and styrenic block copolymers |
JP3217630B2 (ja) | 1994-12-28 | 2001-10-09 | ユニ・チャーム株式会社 | 伸縮性の不織布およびその製造方法 |
US5814413A (en) | 1995-06-07 | 1998-09-29 | Huntsman United Films Corporation | Multilayer protective garment film |
CA2226485C (en) | 1995-07-10 | 2002-09-10 | Japan Absorbent Technology Institute | Porous composite sheet and process for the production thereof |
US5885908A (en) | 1996-10-04 | 1999-03-23 | Minnesota Mining And Manufacturing Co. | Anisotropic elastic films |
US5914184A (en) | 1996-12-30 | 1999-06-22 | Kimberly-Clark Worldwide, Inc. | Breathable laminate including filled film and continuous film |
US6436529B1 (en) | 1997-01-21 | 2002-08-20 | 3M Innovative Properties Company | Elatomeric laminates and composites |
US6909028B1 (en) | 1997-09-15 | 2005-06-21 | Kimberly-Clark Worldwide, Inc. | Stable breathable elastic garments |
US6057024A (en) | 1997-10-31 | 2000-05-02 | Kimberly-Clark Worldwide, Inc. | Composite elastic material with ribbon-shaped filaments |
WO1999025912A1 (en) | 1997-11-18 | 1999-05-27 | The University Of Tennessee Research Corporation | Stretchable, cotton-surfaced, nonwoven, laminated fabric |
US6503619B1 (en) * | 1998-08-07 | 2003-01-07 | Advanced Elastomer Systems, L.P. | Soft touch labels |
EP1173123A1 (en) * | 1999-04-26 | 2002-01-23 | Mary G. Lynch | Trabeculotomy device and method for treating glaucoma |
JP3524019B2 (ja) | 1999-07-05 | 2004-04-26 | ユニ・チャーム株式会社 | 弾性伸縮性複合シートの製造方法 |
JP3492245B2 (ja) | 1999-07-06 | 2004-02-03 | ユニ・チャーム株式会社 | 弾性複合シート製造装置および弾性複合シート製造方法 |
US6682803B2 (en) | 1999-08-27 | 2004-01-27 | Kimberly-Clark Worldwide, Inc. | Breathable multilayer films with breakable skin layers |
US6794024B1 (en) | 1999-11-01 | 2004-09-21 | Kimberly-Clark Worldwide, Inc. | Styrenic block copolymer breathable elastomeric films |
JP2003515619A (ja) | 1999-11-01 | 2003-05-07 | キンバリー クラーク ワールドワイド インコーポレイテッド | スチレン系ブロックコポリマーの通気性エラストマーフィルム |
US6830800B2 (en) | 1999-12-21 | 2004-12-14 | The Procter & Gamble Company | Elastic laminate web |
US20030017345A1 (en) | 2000-01-27 | 2003-01-23 | Tredegar Film Products Corporation | Tear-resistant low set elastic film and method of making |
MXPA02007287A (es) * | 2000-01-28 | 2003-01-28 | 3M Innovative Properties Co | Laminado elastico/no tejido unido por extrusion. |
US6384123B1 (en) | 2000-07-14 | 2002-05-07 | Rjf International Corporation | Thermoplastic elastomer film composition |
DE10158345B4 (de) * | 2001-11-28 | 2005-11-24 | Nordenia Deutschland Gronau Gmbh | Monoaxial elastische Laminatfolie |
DE10161276B4 (de) | 2001-12-14 | 2004-09-09 | Nordenia Deutschland Gronau Gmbh | Elastisches Folienlaminat aus drei verbundenen Kunstoff-Folien |
US7078089B2 (en) | 2001-12-28 | 2006-07-18 | Kimberly-Clark Worldwide, Inc. | Low-cost elastic laminate material |
US7674733B2 (en) | 2002-03-22 | 2010-03-09 | Clopay Plastic Products Company, Inc. | Breathable and elastic composite materials and methods |
US8034440B2 (en) | 2002-10-31 | 2011-10-11 | Kimberly-Clark Worldwide, Inc. | Elastomeric film and laminates thereof |
US7303642B2 (en) | 2002-11-12 | 2007-12-04 | Kimberly-Clark Worldwide, Inc. | Methods of making responsive film with corrugated microlayers having improved properties |
US20040121683A1 (en) | 2002-12-20 | 2004-06-24 | Joy Jordan | Composite elastic material |
US20040122409A1 (en) | 2002-12-23 | 2004-06-24 | Thomas Oomman Painumoottil | Enhanced elastomer blend |
US20040122408A1 (en) | 2002-12-24 | 2004-06-24 | Potnis Prasad S. | Dry-blend elastomer for elastic laminates |
WO2004063270A2 (en) | 2003-01-08 | 2004-07-29 | Exxonmobil Chemical Patents Inc. | Elastic articles and processes for their manufacture |
US7220478B2 (en) | 2003-08-22 | 2007-05-22 | Kimberly-Clark Worldwide, Inc. | Microporous breathable elastic films, methods of making same, and limited use or disposable product applications |
US7179952B2 (en) | 2003-08-25 | 2007-02-20 | Kimberly-Clark Worldwide, Inc. | Absorbent article formed with microlayered films |
US7247675B2 (en) | 2003-12-30 | 2007-07-24 | Kimberly-Clark Worldwide, Inc. | Elastomer compositions and method of making them |
US7648771B2 (en) | 2003-12-31 | 2010-01-19 | Kimberly-Clark Worldwide, Inc. | Thermal stabilization and processing behavior of block copolymer compositions by blending, applications thereof, and methods of making same |
DE102004029138A1 (de) | 2004-06-17 | 2005-12-29 | Basf Ag | Blends aus Styrol-Butadien-Blockcopolymeren und Polyolefinen für transparente, elastische Folien |
US20060036225A1 (en) | 2004-08-13 | 2006-02-16 | Middlesworth Jeffrey A | Multi-layer web with extensible and inextensible regions and methods of making same |
US7291382B2 (en) | 2004-09-24 | 2007-11-06 | Kimberly-Clark Worldwide, Inc. | Low density flexible resilient absorbent open-cell thermoplastic foam |
US7612001B2 (en) | 2004-12-22 | 2009-11-03 | Kimberly-Clark Worldwide, Inc. | High performance elastic materials made using styrene block copolymers and mixtures |
US20060172137A1 (en) | 2005-02-01 | 2006-08-03 | Champion William T | Transverse-direction, elastomeric, breathable film |
US7910658B2 (en) | 2005-03-17 | 2011-03-22 | Dow Global Technologies Llc | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
US7737215B2 (en) | 2005-03-17 | 2010-06-15 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
AR053192A1 (es) | 2005-03-24 | 2007-04-25 | Clopay Plastic Prod Co | Metodos para producir laminados elastomericos multicapa y laminados |
TWI411528B (zh) | 2005-05-12 | 2013-10-11 | Clopay Plastic Prod Co | 具有脆而不結塊之表層的彈性膜 |
CA2609987A1 (en) | 2005-06-20 | 2007-01-04 | Pliant Corporation | Low cost multilayer elastomeric films having a low permanent set |
US20070049888A1 (en) | 2005-08-31 | 2007-03-01 | Soerens Dave A | Absorbent core comprising a multi-microlayer film |
AR058496A1 (es) | 2005-10-26 | 2008-02-06 | Dow Global Technologies Inc | Articulos elasticos de multiples capas |
KR101289591B1 (ko) | 2005-10-26 | 2013-07-26 | 다우 글로벌 테크놀로지스 엘엘씨 | 다층 사전-연신된 탄성 물품 |
US20070141352A1 (en) | 2005-12-15 | 2007-06-21 | Calhoun Patricia H | Cross-directional elastic films with machine direction stiffness |
US20070141303A1 (en) | 2005-12-15 | 2007-06-21 | Steindorf Eric C | Sheet materials with zoned machine direction extensibility and methods of making |
US20070298262A1 (en) | 2006-06-22 | 2007-12-27 | Tredegar Film Products Corporation | Elastic film exhibiting low tensile force properties in the machine direction |
US7585382B2 (en) | 2006-06-30 | 2009-09-08 | Kimberly-Clark Worldwide, Inc. | Latent elastic nonwoven composite |
DK1878830T3 (da) | 2006-07-11 | 2010-01-11 | Procter & Gamble | Flerlagstissueartikel, som har en bestemt udformning af prægede fordybninger og indeholder en blödgörende lotion |
US7803244B2 (en) | 2006-08-31 | 2010-09-28 | Kimberly-Clark Worldwide, Inc. | Nonwoven composite containing an apertured elastic film |
US7582178B2 (en) | 2006-11-22 | 2009-09-01 | Kimberly-Clark Worldwide, Inc. | Nonwoven-film composite with latent elasticity |
US7713636B2 (en) | 2006-12-15 | 2010-05-11 | Exxonmobil Chemical Patents Inc. | Multi-layer films comprising propylene-based polymers |
TWI411532B (zh) | 2007-01-25 | 2013-10-11 | Clopay Plastic Prod Co | 不需機械活化之彈性積層材料 |
CN101903455B (zh) | 2007-12-21 | 2013-01-16 | 科腾聚合物美国有限责任公司 | 软质弹性体膜 |
JP5674475B2 (ja) | 2008-01-24 | 2015-02-25 | クロペイ・プラスティック・プロダクツ・カンパニー・インコーポレーテッド | エラストマー材料 |
US8168853B2 (en) | 2008-01-24 | 2012-05-01 | The Proctor & Gamble Company | Extrusion bonded laminates for absorbent articles |
KR100918290B1 (ko) | 2008-03-18 | 2009-09-18 | 금호석유화학 주식회사 | 유동성 및 내 충격성이 우수한 폴리프로필렌 수지 조성물및 이로부터 제조된 폴리프로필렌 성형품 |
US9949906B2 (en) | 2008-07-11 | 2018-04-24 | Kimberly-Clark Worldwide, Inc. | Substrates having formulations with improved transferability |
US20100267882A1 (en) | 2009-04-15 | 2010-10-21 | Advanced Composites, Inc. | Polyolefin Compositions |
US8167490B2 (en) | 2009-04-22 | 2012-05-01 | Reynolds Consumer Products Inc. | Multilayer stretchy drawstring |
KR101293785B1 (ko) | 2009-12-29 | 2013-08-06 | 제일모직주식회사 | 열가소성 고무 조성물 및 이를 이용한 성형품 |
US20110160687A1 (en) | 2009-12-30 | 2011-06-30 | Welch Howard M | Nonwoven composite including an apertured elastic film and method of making |
KR101454062B1 (ko) | 2011-04-12 | 2014-10-27 | 주식회사 엘지화학 | 올레핀계 열가소성 엘라스토머 조성물 |
US8764722B2 (en) | 2011-04-28 | 2014-07-01 | Kimberly-Clark Worldwide, Inc. | Absorbent article with cushioned waistband |
US20120291949A1 (en) | 2011-05-20 | 2012-11-22 | Oomman Painummoottil Thomas | Method and Apparatus for Manufacturing an Absorbent Article with Crosslinked Elastic Components |
EP3083247B1 (en) | 2013-12-20 | 2018-10-03 | Kimberly-Clark Worldwide, Inc. | Hydroentangled elastic film-based, stretch-bonded composites and methods of making same |
EP3084057A4 (en) | 2013-12-20 | 2017-08-09 | Kimberly-Clark Worldwide, Inc. | Hydroentangled elastic filament-based, stretch-bonded composites and methods of making same |
-
2014
- 2014-03-31 US US14/230,741 patent/US9802392B2/en active Active
-
2015
- 2015-03-06 WO PCT/IB2015/051661 patent/WO2015150937A1/en active Application Filing
- 2015-03-06 CN CN201580015045.9A patent/CN106103088B/zh active Active
- 2015-03-06 KR KR1020167028816A patent/KR102356219B1/ko active IP Right Grant
- 2015-03-06 RU RU2016140366A patent/RU2661214C2/ru active
- 2015-03-06 EP EP15773424.5A patent/EP3126140B1/en active Active
- 2015-03-06 MX MX2016012442A patent/MX360519B/es active IP Right Grant
- 2015-03-06 AU AU2015242310A patent/AU2015242310B2/en active Active
- 2015-03-06 BR BR112016021562-1A patent/BR112016021562B1/pt active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
BR112016021562A2 (ru) | 2017-08-15 |
BR112016021562B1 (pt) | 2021-09-08 |
CN106103088B (zh) | 2019-07-05 |
AU2015242310A1 (en) | 2016-10-27 |
WO2015150937A1 (en) | 2015-10-08 |
EP3126140A1 (en) | 2017-02-08 |
MX360519B (es) | 2018-11-05 |
RU2661214C2 (ru) | 2018-07-13 |
MX2016012442A (es) | 2016-12-20 |
AU2015242310B2 (en) | 2018-06-14 |
US20150273802A1 (en) | 2015-10-01 |
EP3126140B1 (en) | 2021-01-13 |
KR20160140741A (ko) | 2016-12-07 |
EP3126140A4 (en) | 2017-12-27 |
KR102356219B1 (ko) | 2022-01-28 |
CN106103088A (zh) | 2016-11-09 |
US9802392B2 (en) | 2017-10-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR102108157B1 (ko) | 통기성 미세다공성 열가소성 박막 | |
RU2016140366A (ru) | Микроструктурированные многослойные эластичные слоистые материалы с повышенной прочностью и эластичностью и способы их получения | |
WO2012033680A3 (en) | Method for producing thin film gloves using the cutting and sealing process and glove produced therefrom | |
JP2011514391A5 (ru) | ||
MX2017008589A (es) | Estructuras de espuma poliolefinica multicapa reticulada coextruida a partir de material poliolefinico reciclado y metodos para fabricar las mismas. | |
NZ586914A (en) | Permanent set elastomeric film and laminate for improving the fit and comfort of garments | |
JP2015120349A (ja) | 共押出フィルムおよび共押出フィルムの製造方法 | |
AR042010A4 (es) | Un laminado de pelicula elastico respirable, un articulo absorbente que comprende dicho laminado y el metodo para hacer dicho laminado | |
JP2012140006A (ja) | エラストマー性積層体およびその製造方法 | |
RU2013134750A (ru) | Сегментированные пленки с высокопрочными швами | |
JP2018508307A5 (ja) | 非透過層を含む化粧料組成物塗布具、およびその製造方法 | |
MX2011010054A (es) | Peliculas que no son pvc con capa de nucleo duro. | |
JP2007526935A5 (ja) | 熱可塑性エラストマーを含むポリマー組成物 | |
ATE405604T1 (de) | Blends aus styrol-butadien-blockcopolymeren und polyolefine für transparente, elastische folien | |
MX2019005490A (es) | Uso de copolimeros aleatorios de polipropileno a base de metaloceno en peliculas hinchadas. | |
PL1661693T3 (pl) | Folia do owijania z następnym skręcaniem końców i jej zastosowanie jako folii opakowaniowej | |
CO2021005990A2 (es) | Nueva película de múltiples capas para empaques resellables con resellado mejorado | |
US11690932B2 (en) | Elastomeric films having low tear propagation | |
JP2017065186A5 (ru) | ||
JP2016117536A (ja) | 流体供給クッションの前方壁としての穿孔された弾性フィルムの使用 | |
PL414214A1 (pl) | Wielowarstwowa folia rozciągliwa o podwyższonej odporności na przebicie i propagację przedarcia oraz sposób jej wytwarzania | |
BR112020026966A2 (pt) | Laminados polidimensionais estiráveis | |
RU2018124349A (ru) | Самоклеящееся напольное покрытие и способ его изготовления |