RU2015154756A - COMPLEX OF TITANIUM TETRACHLORIDE WITH N-METHYLFORMANANILIDE AND METHOD OF ITS PRODUCTION - Google Patents

COMPLEX OF TITANIUM TETRACHLORIDE WITH N-METHYLFORMANANILIDE AND METHOD OF ITS PRODUCTION Download PDF

Info

Publication number
RU2015154756A
RU2015154756A RU2015154756A RU2015154756A RU2015154756A RU 2015154756 A RU2015154756 A RU 2015154756A RU 2015154756 A RU2015154756 A RU 2015154756A RU 2015154756 A RU2015154756 A RU 2015154756A RU 2015154756 A RU2015154756 A RU 2015154756A
Authority
RU
Russia
Prior art keywords
titanium tetrachloride
complex
methylformaniline
methylformanilide
methylformananilide
Prior art date
Application number
RU2015154756A
Other languages
Russian (ru)
Other versions
RU2646224C2 (en
Inventor
Алексей Михайлович Немерюк
Марина Михайловна Лылина
Original Assignee
Федеральное Государственное Унитарное Предприятие "Государственный Ордена Трудового Красного Знамени Научно-Исследовательский Институт Химических Реактивов И Особо Чистых Химических Веществ"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Федеральное Государственное Унитарное Предприятие "Государственный Ордена Трудового Красного Знамени Научно-Исследовательский Институт Химических Реактивов И Особо Чистых Химических Веществ" filed Critical Федеральное Государственное Унитарное Предприятие "Государственный Ордена Трудового Красного Знамени Научно-Исследовательский Институт Химических Реактивов И Особо Чистых Химических Веществ"
Priority to RU2015154756A priority Critical patent/RU2646224C2/en
Publication of RU2015154756A publication Critical patent/RU2015154756A/en
Application granted granted Critical
Publication of RU2646224C2 publication Critical patent/RU2646224C2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C01G23/047—Titanium dioxide
    • C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/04—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C233/07—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)

Claims (5)

1. Комплекс тетрахлорида титана с N-метилформанилидом формулы:1. The complex of titanium tetrachloride with N-methylformanilide of the formula:
Figure 00000001
Figure 00000001
 в качестве исходного продукта при сольвотермальном синтезе титаноксидных соединений.as a starting product in the solvothermal synthesis of titanoxide compounds. 2. Способ получения комплекса тетрахлорида титана с N-метилформанилидом структурной формулы:
Figure 00000002
взаимодействием N-метилформанилина с тетрахлоридом титана, используемыми в виде их растворов в насыщенных галоидуглеводородах в количествах, соответствующих 2,5 кратному мольному избытку N-метилформанилида по отношению к тетрахлориду титана, который осуществляют прикапыванием при интенсивном перемешивании раствора тетрахлорида титана к раствору N-метилформанилина, с последующим интенсивным перемешиванием кипящей реакционной массы, охлаждением и выделением выпавшего осадка фильтрацией, промывкой растворителем и вакуумной сушкой.2. A method of obtaining a complex of titanium tetrachloride with N-methylformanilide of the structural formula:
Figure 00000002
the interaction of N-methylformaniline with titanium tetrachloride, used in the form of their solutions in saturated halocarbons in quantities corresponding to a 2.5-fold molar excess of N-methylformanilide with respect to titanium tetrachloride, which is carried out by dropping with vigorous stirring a solution of titanium tetrachloride to a solution of N-methylformaniline, followed by vigorous stirring of the boiling reaction mass, cooling and separation of the precipitated precipitate by filtration, washing with a solvent and vacuum drying. 3. Способ по п. 2, осуществляемый взаимодействием N-метилформанилина с тетрахлоридом титана в виде их растворов в растворителях, предпочтительно, выбранных из группы следующих соединений: четыреххлористый углерод, дихлорметан, трихлорметан.3. The method according to p. 2, carried out by the interaction of N-methylformaniline with titanium tetrachloride in the form of their solutions in solvents, preferably selected from the group of the following compounds: carbon tetrachloride, dichloromethane, trichloromethane.
RU2015154756A 2015-12-21 2015-12-21 Titane tetrahloride complex with n-methylformanilide and method of its production RU2646224C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2015154756A RU2646224C2 (en) 2015-12-21 2015-12-21 Titane tetrahloride complex with n-methylformanilide and method of its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2015154756A RU2646224C2 (en) 2015-12-21 2015-12-21 Titane tetrahloride complex with n-methylformanilide and method of its production

Publications (2)

Publication Number Publication Date
RU2015154756A true RU2015154756A (en) 2017-06-22
RU2646224C2 RU2646224C2 (en) 2018-03-02

Family

ID=59240301

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015154756A RU2646224C2 (en) 2015-12-21 2015-12-21 Titane tetrahloride complex with n-methylformanilide and method of its production

Country Status (1)

Country Link
RU (1) RU2646224C2 (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD3535G2 (en) * 2007-03-21 2008-10-31 Государственный Университет Молд0 Process for nanodispersed titanium dioxide obtaining

Also Published As

Publication number Publication date
RU2646224C2 (en) 2018-03-02

Similar Documents

Publication Publication Date Title
RU2017102355A (en) METHOD FOR PRODUCING A CONDENSED HETEROCYCLIC COMPOUND
JP2015063536A5 (en)
RU2017126724A (en) PICOLINAMIDES AS FUNGICIDES
JP2015506943A5 (en)
HRP20171167T1 (en) Preparation of pyrimidine intermediates useful for the manufacture of macitentan
EA201790916A1 (en) NEW RIG-I LIGANDS AND METHODS OF THEIR RECEPTION
WO2016038628A3 (en) A process for preparing olodaterol and intermediates thereof
JP2014510043A5 (en)
RU2017102307A (en) METHOD FOR PRODUCING SYNTHETIC PENTAPEPTIDE
JP2016539168A5 (en)
PH12019500435A1 (en) Method for producing scandium compound, and scandium compound
RU2015154756A (en) COMPLEX OF TITANIUM TETRACHLORIDE WITH N-METHYLFORMANANILIDE AND METHOD OF ITS PRODUCTION
RU2015113741A (en) METHOD FOR PRODUCING VORICONAZOLE AND ITS ANALOGUES
RU2011143166A (en) NEW CRYSTAL FORMS OF ADEFOVIR DIPIVOXIL AND METHODS OF ITS PRODUCTION
EA201990236A1 (en) NEW METHODS FOR PRODUCING STIMULANTS OF SOLUBLE GUANILATICYCLASE
JP2020502280A5 (en)
RU2013122374A (en) THE PRODUCT HAS ANTITOXIC ACTIVITY AND CONTAINS THE COMPLEX COMPOUND OF THE DERIVATED METHYLURACYL WITH ORGANIC ACID, AND THE METHOD FOR PRODUCING IT
RU2015135184A (en) METHOD FOR PRODUCING COMPOUND OF PYRIDAZINONE AND INTERMEDIATE PRODUCTS FOR ITS PRODUCTION
JP2015524456A5 (en)
CL2013001882A1 (en) Industrial synthesis process of the compound of formula (i) agomelatine, from allyl cyanide; intermediary compounds
JP2016525094A5 (en)
RU2017128217A (en) METHOD FOR PRODUCING THIAZOLE DERIVATIVE
RU2613976C1 (en) Method for production of lanthanum organometallic frame compound of three-dimensional structures based on terephthalic acid
CN105601640B (en) A kind of N- tertbutyloxycarbonyls -7-（Amine methyl）The synthetic method of -6- oxa- -2- spiral shells [4.5] decane
RU2016134724A (en) METHOD FOR PRODUCING PURIFIED COMPOUND

Legal Events

Date Code Title Description
HZ9A Changing address for correspondence with an applicant
QB4A Licence on use of patent

Free format text: LICENCE FORMERLY AGREED ON 20180910

Effective date: 20180910