RU2015131017A - Приготовление катализатора конверсии углеводородов - Google Patents
Приготовление катализатора конверсии углеводородов Download PDFInfo
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- RU2015131017A RU2015131017A RU2015131017A RU2015131017A RU2015131017A RU 2015131017 A RU2015131017 A RU 2015131017A RU 2015131017 A RU2015131017 A RU 2015131017A RU 2015131017 A RU2015131017 A RU 2015131017A RU 2015131017 A RU2015131017 A RU 2015131017A
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- mixture
- alkali metal
- aluminosilicate composition
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- 239000003054 catalyst Substances 0.000 title claims 4
- 238000006243 chemical reaction Methods 0.000 title claims 4
- 229930195733 hydrocarbon Natural products 0.000 title claims 4
- 150000002430 hydrocarbons Chemical class 0.000 title claims 4
- 239000004215 Carbon black (E152) Substances 0.000 title claims 3
- 238000002360 preparation method Methods 0.000 title claims 2
- 239000000203 mixture Substances 0.000 claims 30
- 238000000034 method Methods 0.000 claims 17
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 10
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 5
- 229910052783 alkali metal Inorganic materials 0.000 claims 4
- -1 alkali metal aluminate Chemical class 0.000 claims 4
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 150000002739 metals Chemical class 0.000 claims 2
- 239000002244 precipitate Substances 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000004115 Sodium Silicate Substances 0.000 claims 1
- 239000012670 alkaline solution Substances 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical group [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 238000004517 catalytic hydrocracking Methods 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 150000002500 ions Chemical group 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 150000007522 mineralic acids Chemical class 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 229910001388 sodium aluminate Inorganic materials 0.000 claims 1
- 229910052911 sodium silicate Inorganic materials 0.000 claims 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/14—Inorganic carriers the catalyst containing platinum group metals or compounds thereof
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Claims (26)
1. Способ приготовления катализатора конверсии углеводородов, способ включает стадии, на которых:
(a) приготавливают водную смесь, содержащую сульфат алюминия и имеющую рН от 1,0 до 6,5,;
(b) добавляют в смесь, полученную на стадии (а), алюминат щелочного металла для повышения рН смеси от 7,1 до 12;
(c) добавляют в смесь, полученную на стадии (b), сульфат алюминия для понижения рН смеси от 1,5 до 6,5;
(d) добавляют в смесь, полученную на стадии (с), силикат щелочного металла для повышения рН смеси от 6,5 до 11,
причем на заключительных стадиях способа приготовления:
(v) добавляют сульфат алюминия в смесь, которая получена в процессе, состоящем из стадий (а)-(d), для понижения рН смеси от 2 до 8;
(w) добавляют в смесь, полученную на стадии (v), силикат щелочного металла для повышения рН смеси,
(х) добавляют в смесь, полученную на стадии (w), (i) алюминат щелочного металла для сдвига рН смеси от 7,8 до 12 и (ii) сульфат алюминия для сдвига рН смеси от 1,5 до 7,7, причем этап (i) может предшествовать этапу (ii) или же следовать за ним,
(у) обрабатывают полученную на стадии (х) смесь щелочным раствором, имеющим рН от 7,5 до 12, и
(z) извлекают из полученной на стадии (у) смеси твердый осадок, с получением алюмосиликатной композиции, содержащий от 30 до 70 вес.% диоксида кремния и от 70 до 30 вес.% оксида алюминия,
после чего полученную алюмосиликатную композицию формуют и добавляют к формованной алюмосиликатной композиции один или более металлов или соединений металлов, выбираемых из металлов групп VIB и VIII для получения катализатора конверсии углеводородов.
2. Способ по п. 1, в котором способ дополнительно включает стадии, на которых:
(е) добавляют в смесь, полученную на стадии (d), сульфат алюминия для понижения рН смеси от 1,5 до 7,0 и
(f) добавляют в смесь, полученную на стадии (е), алюминат щелочного металла для повышения рН смеси от 7,5 до 12.
3. Способ по п. 1 или 2, в котором алюминат щелочного металла является алюминатом натрия.
4. Способ по п. 1 или 2, в котором силикат щелочного металла является силикатом натрия.
5. Способ по п. 1 или 2, в котором на стадии (z) извлеченный твердый осадок дополнительно промывают и/или подвергают ионному обмену.
6. Способ по п. 1 или 2, в котором алюмосиликатную композицию, полученную на стадии (z), дополнительно сушат и/или обжигают.
7. Способ по п. 6, в котором алюмосиликатную композицию, полученную на стадии (z), сушат распылением.
8. Способ по п. 6, в котором высушенную алюмосиликатную композицию обжигают при температуре от 600 до 850°С.
9. Способ по п. 1 или 2, в котором алюмосиликат формуют, смешивая полученную алюмосиликатную композицию с водой и кислотой, с последующим экструдированием полученной смеси.
10. Способ по п. 9, в котором кислота является неорганической кислотой.
11. Способ по п. 1 или 2, в котором сформованную алюмосиликатную композицию дополнительно сушат и/или обжигают.
12. Способ по п. 11, в котором сформованную алюмосиликатную композицию обжигают при температуре от 600 до 850°С.
13. Способ гидрокрекинга углеводородного сырья, в котором газообразное сырье при температуре реакции от 250 до 500°С и полном давлении на входе реактора от 3⋅106 до 3⋅107 Па в присутствии водорода приводят в контакт с катализатором, приготовленным по способу по любому из пп. 1-12, при этом газообразное сырье содержит аммиак в количестве менее 150 вес.ч. на миллион.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261746203P | 2012-12-27 | 2012-12-27 | |
| US61/746,203 | 2012-12-27 | ||
| PCT/US2013/076016 WO2014105553A1 (en) | 2012-12-27 | 2013-12-18 | Preparation of a hydrocarbon conversion catalyst |
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| Publication Number | Publication Date |
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| RU2015131017A true RU2015131017A (ru) | 2017-01-31 |
| RU2656594C2 RU2656594C2 (ru) | 2018-06-06 |
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| RU2015131017A RU2656594C2 (ru) | 2012-12-27 | 2013-12-18 | Приготовление катализатора конверсии углеводородов |
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| Country | Link |
|---|---|
| US (2) | US9861963B2 (ru) |
| EP (1) | EP2938433B1 (ru) |
| KR (1) | KR102197525B1 (ru) |
| CN (1) | CN104884166B (ru) |
| BR (1) | BR112015015429A2 (ru) |
| DK (1) | DK2938433T3 (ru) |
| RU (1) | RU2656594C2 (ru) |
| WO (1) | WO2014105553A1 (ru) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2014105558A1 (en) * | 2012-12-27 | 2014-07-03 | Pq Corporation | Preparation of silica-alumina composition |
| US9861963B2 (en) * | 2012-12-27 | 2018-01-09 | Shell Oil Company | Preparation of catalyst |
| US10655074B2 (en) | 2017-02-12 | 2020-05-19 | Mag{hacek over (e)}m{hacek over (a)} Technology LLC | Multi-stage process and device for reducing environmental contaminates in heavy marine fuel oil |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| KR20200086983A (ko) * | 2019-01-10 | 2020-07-20 | 코아텍주식회사 | 대용량 과불화화합물 제거를 위한 금속산화물 촉매 및 그 제조 방법 |
| CN111632608B (zh) * | 2019-03-01 | 2023-06-30 | 中国石化扬子石油化工有限公司 | 一种核壳结构的二氧化硅负载硫酸铝催化剂及其制备方法和应用 |
| DE102019210217A1 (de) * | 2019-07-10 | 2021-01-14 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Aufbereitung und Reinigung von kohlenstoffhaltigen Materialien |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| PL142459B1 (en) * | 1984-05-18 | 1987-10-31 | Inst Chemii Przemyslowej | Method of obtaining amorphous aluminium silicates |
| US5208006A (en) * | 1990-05-28 | 1993-05-04 | Engelhard Corporation | Large-pored molecular sieves containing at least one octahedral site comprising titanium and at least silicon as a tetrahedral site |
| CN1096296C (zh) * | 1998-11-13 | 2002-12-18 | 中国石油化工集团公司 | 一种生产中间馏分油的加氢裂化催化剂及其制备 |
| EP2185278B1 (en) * | 2007-08-27 | 2021-02-17 | Shell International Research Maatschappij B.V. | An amorphous silica-alumina composition and a method of making and using such composition |
| RU2469789C2 (ru) * | 2007-08-27 | 2012-12-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Катализатор гидрирования ароматических углеводородов и способ получения и применения такого катализатора |
| FR2944027B1 (fr) * | 2009-04-03 | 2011-05-06 | Inst Francais Du Petrole | Procede de production de distillats moyens par hydroisomerisation et hydrocraquage d'une fraction lourde issue d'un effluent fischer-tropsch |
| US9187702B2 (en) * | 2009-07-01 | 2015-11-17 | Chevron U.S.A. Inc. | Hydroprocessing catalyst and method of making the same |
| CN102029192B (zh) * | 2009-09-28 | 2013-01-09 | 中国石油化工股份有限公司 | 一种含硅氧化铝及其制备方法 |
| US9861963B2 (en) * | 2012-12-27 | 2018-01-09 | Shell Oil Company | Preparation of catalyst |
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2013
- 2013-12-18 US US14/132,741 patent/US9861963B2/en active Active
- 2013-12-18 EP EP13817820.7A patent/EP2938433B1/en active Active
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- 2013-12-18 RU RU2015131017A patent/RU2656594C2/ru active
- 2013-12-18 BR BR112015015429A patent/BR112015015429A2/pt not_active Application Discontinuation
- 2013-12-18 KR KR1020157019411A patent/KR102197525B1/ko active IP Right Grant
- 2013-12-18 WO PCT/US2013/076016 patent/WO2014105553A1/en active Application Filing
- 2013-12-18 DK DK13817820.7T patent/DK2938433T3/da active
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2017
- 2017-12-27 US US15/856,026 patent/US10189012B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2938433B1 (en) | 2022-04-06 |
| US20180117568A1 (en) | 2018-05-03 |
| CN104884166B (zh) | 2017-11-17 |
| BR112015015429A2 (pt) | 2017-07-11 |
| US20140183098A1 (en) | 2014-07-03 |
| DK2938433T3 (da) | 2022-04-25 |
| EP2938433A1 (en) | 2015-11-04 |
| US9861963B2 (en) | 2018-01-09 |
| CN104884166A (zh) | 2015-09-02 |
| KR102197525B1 (ko) | 2021-01-04 |
| US10189012B2 (en) | 2019-01-29 |
| WO2014105553A1 (en) | 2014-07-03 |
| KR20150100768A (ko) | 2015-09-02 |
| RU2656594C2 (ru) | 2018-06-06 |
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