RU2015117225A - METHOD FOR CLEANING GAS EMISSIONS USING GRANULATED GLAUCONITE SORBENT - Google Patents

METHOD FOR CLEANING GAS EMISSIONS USING GRANULATED GLAUCONITE SORBENT Download PDF

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RU2015117225A
RU2015117225A RU2015117225A RU2015117225A RU2015117225A RU 2015117225 A RU2015117225 A RU 2015117225A RU 2015117225 A RU2015117225 A RU 2015117225A RU 2015117225 A RU2015117225 A RU 2015117225A RU 2015117225 A RU2015117225 A RU 2015117225A
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Prior art keywords
glauconite
enriched
mixture
intercalated graphite
finely dispersed
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RU2015117225A
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Russian (ru)
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RU2617504C2 (en
Inventor
Сергей Борисович Вениг
Римма Кузьминична Чернова
Виктор Геннадиевич Сержантов
Екатерина Игоревна Селифонова
Наталия Николаевна Щербакова
Владимир Петрович Сплюхин
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Федеральное государственное бюджетное образовательное учреждение высшего образования "Саратовский национальный исследовательский государственный университет имени Н.Г. Чернышевского"
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Priority to RU2015117225A priority Critical patent/RU2617504C2/en
Publication of RU2015117225A publication Critical patent/RU2015117225A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

1. Способ очистки газовых выбросов, заключающийся в сорбции и совместном одновременном окислении-восстановлении газов путем последовательного пропускания их через слой сорбционного катализатора на основе глауконита, отличающийся тем, что в качестве глауконита используют обогащенный мелкодисперсный глауконит, который предварительно смешивают с интеркалированным графитом, полученную смесь модифицируют раствором гальваношламов, содержащего соединения тяжелых металлов, после чего полученную массу гранулируют и обжигают при температуре 600-700°C в течение 1-1,5 ч.2. Способ по п. 1, отличающийся тем, что после модифицирования смесь обогащенного мелкодисперсного глауконита и интеркалированного графита подвергают высокотемпературному обжигу.3. Способ по любому из пп. 1 и 2, отличающийся тем, что смесь обогащенного мелкодисперсного глауконита и интеркалированного графита содержит в своем составе сорбированные окислы тяжелых металлов, являющиеся катализаторами, в том числе и смесевые, окисления-восстановления токсичных и вредных продуктов.1. The method of purification of gas emissions, which consists in sorption and simultaneous simultaneous oxidation-reduction of gases by sequentially passing them through a layer of sorption catalyst based on glauconite, characterized in that enriched finely dispersed glauconite is used as glauconite, which is pre-mixed with intercalated graphite, the resulting mixture modify with a solution of galvanic sludge containing compounds of heavy metals, after which the resulting mass is granulated and fired at a temperature D 600-700 ° C for 1-1.5 p.2. The method according to claim 1, characterized in that, after modification, the mixture of enriched finely divided glauconite and intercalated graphite is subjected to high-temperature firing. The method according to any one of paragraphs. 1 and 2, characterized in that the mixture of enriched finely dispersed glauconite and intercalated graphite contains sorbed oxides of heavy metals, which are catalysts, including mixed, oxidation-reduction of toxic and harmful products.

Claims (3)

1. Способ очистки газовых выбросов, заключающийся в сорбции и совместном одновременном окислении-восстановлении газов путем последовательного пропускания их через слой сорбционного катализатора на основе глауконита, отличающийся тем, что в качестве глауконита используют обогащенный мелкодисперсный глауконит, который предварительно смешивают с интеркалированным графитом, полученную смесь модифицируют раствором гальваношламов, содержащего соединения тяжелых металлов, после чего полученную массу гранулируют и обжигают при температуре 600-700°C в течение 1-1,5 ч.1. The method of purification of gas emissions, which consists in sorption and simultaneous simultaneous oxidation-reduction of gases by sequentially passing them through a layer of sorption catalyst based on glauconite, characterized in that enriched finely dispersed glauconite is used as glauconite, which is pre-mixed with intercalated graphite, the resulting mixture modify with a solution of galvanic sludge containing compounds of heavy metals, after which the resulting mass is granulated and fired at a temperature D 600-700 ° C for 1-1.5 hours. 2. Способ по п. 1, отличающийся тем, что после модифицирования смесь обогащенного мелкодисперсного глауконита и интеркалированного графита подвергают высокотемпературному обжигу.2. The method according to p. 1, characterized in that after modifying the mixture of enriched finely dispersed glauconite and intercalated graphite is subjected to high temperature firing. 3. Способ по любому из пп. 1 и 2, отличающийся тем, что смесь обогащенного мелкодисперсного глауконита и интеркалированного графита содержит в своем составе сорбированные окислы тяжелых металлов, являющиеся катализаторами, в том числе и смесевые, окисления-восстановления токсичных и вредных продуктов. 3. The method according to any one of paragraphs. 1 and 2, characterized in that the mixture of enriched finely dispersed glauconite and intercalated graphite contains sorbed oxides of heavy metals, which are catalysts, including mixed, oxidation-reduction of toxic and harmful products.
RU2015117225A 2015-05-06 2015-05-06 Method for cleaning gas emissions by means of granulated glauconite sorbent RU2617504C2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2761211C1 (en) * 2021-02-20 2021-12-06 федеральное государственное бюджетное образовательное учреждение высшего образования «Санкт-Петербургский горный университет» Method for purification of exhaust gases of metallurgical plants from hydrogen sulfide

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX4509E (en) * 1975-08-27 1982-06-02 Engelhard Min & Chem IMPROVED CATALYTIC COMPOSITION FOR SIMULTANEOUS OXIDATION GASCOUS HYDROCARBONS AND CARBON MONOXIDE AND REDUCE NITROGEN OXIDES
RU2048175C1 (en) * 1992-02-10 1995-11-20 Заворин Виктор Анатольевич Method of cleaning gas effluents from nitric oxide
RU2041737C1 (en) * 1992-10-16 1995-08-20 Промышленно-финансовая группа "Ассоциация Внедрения" Catalyst of multiple cleaning of exhaust gases from nitrogen oxides and carbon
RU2323769C1 (en) * 2006-08-04 2008-05-10 Андрей Аронович Золотушкин Method of gas emission filtering and device for its realization

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