RU2012152519A - TRIPLE COPOLYMER AND ITS APPLICATION FOR IMPROVING THE LOW FLOW OF MEDIUM-DIFFERENT FUELS - Google Patents
TRIPLE COPOLYMER AND ITS APPLICATION FOR IMPROVING THE LOW FLOW OF MEDIUM-DIFFERENT FUELS Download PDFInfo
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- RU2012152519A RU2012152519A RU2012152519/04A RU2012152519A RU2012152519A RU 2012152519 A RU2012152519 A RU 2012152519A RU 2012152519/04 A RU2012152519/04 A RU 2012152519/04A RU 2012152519 A RU2012152519 A RU 2012152519A RU 2012152519 A RU2012152519 A RU 2012152519A
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- Prior art keywords
- mol
- copolymer according
- carbon atoms
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- ethylene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
- C10L1/1963—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
- C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1. Тройной сополимер из(A) от 70 до 94,95 мол.% этилена,(B) от 5 до 25 мол.% (i) сложного алкенилового эфира с 2-14 атомами углерода в алкениле на основе одной или нескольких алифатических монокарбоновых кислот с 1-20 атомами углерода, или (ii) одного или нескольких сложных алкиловых эфиров акриловой или метакриловой кислоты с 1-24 атомами углерода в алкиле,и(C) от 0,05 до 5 мол.% олефинненасыщенного углеводорода, выбранного из группы, включающей (iii) циклоалкены с числом членов от пяти до семи, которые могут содержать один или несколько кольцевых атомов азота, кислорода и/или серы и/или один или несколько алкильных заместителей с 1-6 атомами углерода, и (iv) α-олефины с 6-20 атомами углерода,причем суммарное количество всех мономерных компонентов составляет 100 мол.%.2. Тройной сополимер по п.1 из(A) от 80 до 91,95 мол.%, в частности от 85 до 89,93 мол.% этилена,(B) от 8 до 19 мол.%, в частности от 10 до 14,6 мол.% компонента (В), и(C) от 0,05 до 1 мол.%, в частности от 0,07 до 0,4 мол.% компонента (C).3. Тройной сополимер по п.1 или 2, который в качестве компонента (C) содержит мономерные звенья циклогексена или неразветвленного α-олефина с 12-16 атомами углерода.4. Тройной сополимер по п.1 или 2 из этилена, винилацетата в качестве компонента (B) и циклогексена, 1-додецена, 1-тетрадецена или 1-гексадецена в качестве компонента (C).5. Тройной сополимер по п.1 или 2 из(A) от 85 до 89,93 мол.% этилена,(B) от 10 до 14,6 мол.% инилацетата и(C) от 0,07 до 0,4 мол.% циклогексена, 1-додецена, 1-тетрадецена или 1-гексадецена.6. Тройной сополимер по п.1 или 2 со среднечисловой молекулярной массой от 1000 до 5000, в частности от 1500 до 2500, или со среднемассовой молекулярной массой от 2000 до 10000, в частности от 3500 до 5000.7. Среднедистиллятное топли�1. Ternary copolymer of (A) from 70 to 94.95 mol.% Ethylene, (B) from 5 to 25 mol.% (I) an alkenyl ester with 2-14 carbon atoms in alkenyl based on one or more aliphatic monocarboxylic acids with 1-20 carbon atoms, or (ii) one or more complex alkyl esters of acrylic or methacrylic acid with 1-24 carbon atoms in the alkyl, and (C) from 0.05 to 5 mol.% of an olefinically unsaturated hydrocarbon selected from the group comprising (iii) cycloalkenes with a number of members from five to seven, which may contain one or more ring nitrogen, oxygen and / or sulfur atoms and / or one or more alkyl substituents with 1-6 carbon atoms, and (iv) α- olefins with 6-20 carbon atoms, the total amount of all monomeric components being 100 mol%. Ternary copolymer according to claim 1 from (A) from 80 to 91.95 mol%, in particular from 85 to 89.93 mol% of ethylene, (B) from 8 to 19 mol%, in particular from 10 to 14 , 6 mol% of component (B), and (C) from 0.05 to 1 mol%, in particular from 0.07 to 0.4 mol% of component (C). 3. The ternary copolymer according to claim 1 or 2, which contains as component (C) monomer units of cyclohexene or unbranched α-olefin having 12-16 carbon atoms. The ternary copolymer according to claim 1 or 2 of ethylene, vinyl acetate as component (B) and cyclohexene, 1-dodecene, 1-tetradecene or 1-hexadecene as component (C). The ternary copolymer according to claim 1 or 2 from (A) 85 to 89.93 mol% of ethylene, (B) 10 to 14.6 mol% of inyl acetate and (C) 0.07 to 0.4 mol% of ethylene. % cyclohexene, 1-dodecene, 1-tetradecene or 1-hexadecene. 6. The ternary copolymer according to claim 1 or 2 with a number average molecular weight from 1000 to 5000, in particular from 1500 to 2500, or with a weight average molecular weight from 2000 to 10000, in particular from 3500 to 5000. Medium distillate fuel
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10162333 | 2010-05-07 | ||
EP10162333.8 | 2010-05-07 | ||
PCT/EP2011/057214 WO2011138400A1 (en) | 2010-05-07 | 2011-05-05 | Terpolymer and use thereof to improve the low-temperature flow properties of middle-distillate fuels |
Publications (1)
Publication Number | Publication Date |
---|---|
RU2012152519A true RU2012152519A (en) | 2014-06-20 |
Family
ID=44202153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2012152519/04A RU2012152519A (en) | 2010-05-07 | 2011-05-05 | TRIPLE COPOLYMER AND ITS APPLICATION FOR IMPROVING THE LOW FLOW OF MEDIUM-DIFFERENT FUELS |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP2566899A1 (en) |
KR (1) | KR20130062285A (en) |
CN (1) | CN102884095A (en) |
CA (1) | CA2795843A1 (en) |
RU (1) | RU2012152519A (en) |
WO (1) | WO2011138400A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8721744B2 (en) | 2010-07-06 | 2014-05-13 | Basf Se | Copolymer with high chemical homogeneity and use thereof for improving the cold flow properties of fuel oils |
US9006158B2 (en) | 2010-12-09 | 2015-04-14 | Basf Se | Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines and use thereof as a fuel additive or lubricant additive |
EP3112384B1 (en) * | 2015-06-30 | 2018-07-18 | SABIC Global Technologies B.V. | Ethylene polymers having high density |
US10494463B2 (en) * | 2015-06-30 | 2019-12-03 | Sabic Global Technologies B.V. | Ethylene polymers having high density |
WO2017032506A1 (en) * | 2015-08-26 | 2017-03-02 | Sabic Global Technologies B.V. | Process for the production of ethylene polymers |
CN105567353B (en) * | 2016-02-26 | 2017-05-31 | 王金明 | A kind of modified ethylene vinyl acetate copolymer pour-point depressant |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0007590B1 (en) | 1978-07-26 | 1981-02-18 | BASF Aktiengesellschaft | Middle distillates of petroleum, suitable as diesel fuel or as light heating oil, and with improved filtration properties |
DE3141507A1 (en) | 1981-10-20 | 1983-04-28 | Basf Ag, 6700 Ludwigshafen | Process for the preparation of ethylene polymers in a two-zone tubular reactor at pressures above 500 bar |
JPH0662964B2 (en) | 1986-10-31 | 1994-08-17 | 住友化学工業株式会社 | Fuel oil composition |
DE19620119C1 (en) | 1996-05-18 | 1997-10-23 | Hoechst Ag | Terpolymers of ethylene, their production and their use as additives for mineral oil distillates |
DE19802689A1 (en) * | 1998-01-24 | 1999-07-29 | Clariant Gmbh | Process for improving the cold flow properties of fuel oils |
DE10000649C2 (en) * | 2000-01-11 | 2001-11-29 | Clariant Gmbh | Multi-functional additive for fuel oils |
AU2002309037A1 (en) | 2001-05-08 | 2002-11-18 | Sanyo Chemical Industries, Ltd. | Fluidity improver and fuel oil composition |
DE10245737C5 (en) * | 2002-10-01 | 2011-12-08 | Clariant Produkte (Deutschland) Gmbh | Process for the preparation of additive mixtures for mineral oils and mineral oil distillates |
DE10322163A1 (en) * | 2003-05-16 | 2004-12-02 | Basf Ag | Fuel compositions containing terpolymers with improved cold flow properties |
BRPI0808949A2 (en) | 2007-03-22 | 2014-08-26 | Basf Se | USE OF A MIX, AND, FUEL. |
-
2011
- 2011-05-05 CN CN2011800228864A patent/CN102884095A/en active Pending
- 2011-05-05 WO PCT/EP2011/057214 patent/WO2011138400A1/en active Application Filing
- 2011-05-05 CA CA2795843A patent/CA2795843A1/en not_active Abandoned
- 2011-05-05 KR KR1020127031093A patent/KR20130062285A/en not_active Application Discontinuation
- 2011-05-05 RU RU2012152519/04A patent/RU2012152519A/en not_active Application Discontinuation
- 2011-05-05 EP EP11716967A patent/EP2566899A1/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
CN102884095A (en) | 2013-01-16 |
EP2566899A1 (en) | 2013-03-13 |
KR20130062285A (en) | 2013-06-12 |
WO2011138400A1 (en) | 2011-11-10 |
CA2795843A1 (en) | 2011-11-10 |
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Date | Code | Title | Description |
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FA94 | Acknowledgement of application withdrawn (non-payment of fees) |
Effective date: 20170202 |