RU2012150425A - ZEOLITE COMPOSITION UZM-35, METHOD FOR PRODUCING AND METHODS OF APPLICATION - Google Patents

ZEOLITE COMPOSITION UZM-35, METHOD FOR PRODUCING AND METHODS OF APPLICATION Download PDF

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RU2012150425A
RU2012150425A RU2012150425/05A RU2012150425A RU2012150425A RU 2012150425 A RU2012150425 A RU 2012150425A RU 2012150425/05 A RU2012150425/05 A RU 2012150425/05A RU 2012150425 A RU2012150425 A RU 2012150425A RU 2012150425 A RU2012150425 A RU 2012150425A
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Джейми Дж. МОСКОСО
Дэн-Ян ДЖЭН
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Юоп Ллк
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Abstract

1. Композиция UZM-35, содержащая цеолит MFI, цеолит ERI, и цеолит MSE, которая обладает трехмерным каркасом, состоящим, по меньшей мере, из тетраэдров AlOи SiOи имеет эмпирический состав свежесинтезированной безводной основы, выражаемый эмпирической формулой:M RAlESiOгде М представляет собой сочетание ионообменных катионов калия и натрия, «m» является мольным отношением М к (Al+Е) и изменяется от около 0,05 до примерно 3, R представляет собой однозарядный катион диметилдипропиламмония, «r» является мольным отношением R к (Al+E) и имеет значение от около 0,25 до примерно 2,0; Е представляет собой элемент, выбранный из группы, состоящей из галлия, железа, бора и их смесей, «х» является мольной долей Е и имеет значение от 0 до примерно 1,0; «y» представляет собой мольное отношение Si к (Al+Е) и изменяется от больше 2 до примерно 12 и «z» является мольным отношением О к (Al+Е) и имеет значение, определяемое уравнением:z=(m+r+3+4·y)/2,отличающаяся тем, что она характеризуется рентгеновской дифрактограммой, включающей, по меньшей мере, d-расстояния и интенсивности, приведенные в таблице А:и является термически стабильной до температуры, равной, по меньшей мере, 400°С.2. Композиция по п.1, в которой «х» равен нулю.3. Композиция по п.1, в которой количество цеолита MSE изменяется от около 55% масс. до примерно 90% масс. в расчете на массу смеси, количество цеолита MFI изменяется от около 10% масс. до примерно 35% масс. в расчете на массу смеси и количество цеолита ERI изменяется от около 3% масс. до примерно 10% масс. в расчете на массу смеси.4. Способ получения композиции UZM-35, содержащей цеолит MFI, цеолит ERI и цеолит MSE, которая обладает трехмерным каркасом, по меньшей мере, из тетраэдров AlOи SiO�1. The composition UZM-35, containing zeolite MFI, zeolite ERI, and zeolite MSE, which has a three-dimensional skeleton, consisting of at least tetrahedra AlO and SiO and has the empirical composition of a freshly synthesized anhydrous base, expressed by the empirical formula: M RAlESiO where M is a combination ion exchange cations of potassium and sodium, “m” is the molar ratio of M to (Al + E) and varies from about 0.05 to about 3, R is the singly charged dimethyldipropylammonium cation, “r” is the molar ratio of R to (Al + E) and has a value of from about 0.25 to at measured 2.0; E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof, “x” is the mole fraction of E and has a value from 0 to about 1.0; “Y” is the molar ratio of Si to (Al + E) and varies from more than 2 to about 12 and “z” is the molar ratio of O to (Al + E) and has the value defined by the equation: z = (m + r + 3 + 4 · y) / 2, characterized in that it is characterized by an X-ray diffraction pattern including at least the d-distances and intensities shown in Table A: and is thermally stable to a temperature of at least 400 ° C.2. The composition of claim 1, wherein “x” is zero. 3. The composition according to claim 1, in which the amount of zeolite MSE varies from about 55% of the mass. up to about 90% of the mass. based on the weight of the mixture, the amount of zeolite MFI varies from about 10% of the mass. up to about 35% of the mass. based on the weight of the mixture and the amount of zeolite ERI varies from about 3% of the mass. up to about 10% of the mass. based on the weight of the mixture. 4. A method of obtaining a UZM-35 composition containing MFI zeolite, ERI zeolite and MSE zeolite, which has a three-dimensional skeleton of at least AlO and SiO� tetrahedra

Claims (9)

1. Композиция UZM-35, содержащая цеолит MFI, цеолит ERI, и цеолит MSE, которая обладает трехмерным каркасом, состоящим, по меньшей мере, из тетраэдров AlO2 и SiO2 и имеет эмпирический состав свежесинтезированной безводной основы, выражаемый эмпирической формулой:1. The composition UZM-35 containing zeolite MFI, zeolite ERI, and zeolite MSE, which has a three-dimensional skeleton, consisting of at least tetrahedra AlO 2 and SiO 2 and has the empirical composition of a freshly synthesized anhydrous base, expressed by the empirical formula: Mm +RrAl1-xExSiyOz, M m + R r Al 1-x E x Si y O z, где М представляет собой сочетание ионообменных катионов калия и натрия, «m» является мольным отношением М к (Al+Е) и изменяется от около 0,05 до примерно 3, R представляет собой однозарядный катион диметилдипропиламмония, «r» является мольным отношением R к (Al+E) и имеет значение от около 0,25 до примерно 2,0; Е представляет собой элемент, выбранный из группы, состоящей из галлия, железа, бора и их смесей, «х» является мольной долей Е и имеет значение от 0 до примерно 1,0; «y» представляет собой мольное отношение Si к (Al+Е) и изменяется от больше 2 до примерно 12 и «z» является мольным отношением О к (Al+Е) и имеет значение, определяемое уравнением:where M is a combination of ion exchange cations of potassium and sodium, “m” is the molar ratio of M to (Al + E) and varies from about 0.05 to about 3, R is the singly charged dimethyldipropylammonium cation, “r” is the molar ratio of R to (Al + E) and has a value of from about 0.25 to about 2.0; E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof, “x” is the mole fraction of E and has a value from 0 to about 1.0; "Y" is the molar ratio of Si to (Al + E) and varies from greater than 2 to about 12 and "z" is the molar ratio of O to (Al + E) and has the value given by the equation: z=(m+r+3+4·y)/2,z = (m + r + 3 + 4 · y) / 2, отличающаяся тем, что она характеризуется рентгеновской дифрактограммой, включающей, по меньшей мере, d-расстояния и интенсивности, приведенные в таблице А:characterized in that it is characterized by an x-ray diffraction pattern including at least d-distances and intensities shown in table A: Таблица АTable a 2θ2θ d(Å)d (Å) I/Io %I / Io% 6,48-6,516.48-6.51 13,32-13,5813.32-13.58 cpcp 6,78-6,836.78-6.83 12,91-13,0212.91-13.02 cp-ccp-c 7,79-7,967.79-7.96 11,09-11,3211.09-11.32 cpcp 8,05-8,078.05-8.07 10,93-10,9610.93-10.96 cpcp 8,71-8,758.71-8.75 10,08-10,1310.08-10.13 cpcp 9,61-9,659.61-9.65 9,15-9,189.15-9.18 cp-ccp-c 10,75-10,7910.75-10.79 8,18-8,218.18-8.21 слcl 13,61-13,6513.61-13.65 6,47-6,496.47-6.49 слcl 14,74-14,7914.74-14.79 5,98-65.98-6 слcl 15,56-15,5915.56-15.59 5,67-5,695.67-5.69 слcl 15,86-15,8615.86-15.86 5,58-5,585.58-5.58 слcl 19,46-19,519.46-19.5 4,54-4,554.54-4.55 cpcp 19,89-19,9219.89-19.92 4,45-4,454.45-4.45 cpcp 20,48-20,5120.48-20.51 4,32-4,334.32-4.33 cpcp 20,94-20,9620.94-20.96 4,23-4,234.23-4.23 cpcp 21,61-21,6421.61-21.64 4,1-4,14.1-4.1 осos 21,79-21,8121.79-21.81 4,07-4,074.07-4.07 сfrom 22,39-22,4522.39-22.45 3,95-3,963.95-3.96 cpcp 22,93-22,9822.93-22.98 3,86-3,873.86-3.87 c-occ-oc 23,29-23,3123.29-23.31 3,81-3,813.81-3.81 cpcp 23,5-23,523.5-23.5 3,78-3,783.78-3.78 cpcp 23,78-23,8623.78-23.86 3,72-3,733.72-3.73 cpcp
2θ2θ d(Å)d (Å) I/Io %I / Io% 24,39-24,4124.39-24.41 3,64-3,643.64-3.64 слcl 24,82-24,8224.82-24.82 3,58-3,583,58-3,58 слcl 25,76-25,7925.76-25.79 3,45-3,453.45-3.45 сл-срwed 26,09-26,1226.09-26.12 3,4-3,413.4-3.41 срwed 26,74-26,8126.74-26.81 3,32-3,333.32-3.33 срwed 27,14-27,1427.14-27.14 3,28-3,283.28-3.28 срwed 27,42-27,4627.42-27.46 3,24-3,2493.24-3.249 срwed 27,69-27,6927.69-27.69 3,21-3,213.21-3.21 срwed 28,02-28,0628.02-28.06 3,17-3,183.17-3.18 срwed 29,1-29,1529.1-29.15 3,06-3,063.06-3.06 срwed 29,54-29,6129.54-29.61 3,01-3,023.01-3.02 слcl 29,75-29,8629.75-29.86 2,98-2,992.98-2.99 слcl 30,12-30,1430.12-30.14 2,96-2,962.96-2.96 срwed 30,73-30,7930.73-30.79 2,9-2,92.9-2.9 срwed 31,26-31,2731.26-31.27 2,85-2,852.85-2.85 слcl 31,47-31,4731.47-31.47 2,83-2,832.83-2.83 слcl 33,19-33,2533.19-33.25 2,69-2,692.69-2.69 слcl 34,34-34,4834.34-34.48 2,59-2,62.59-2.6 слcl 34,76-34,7634.76-34.76 2,57-2,572.57-2.57 слcl 35,18-35,235.18-35.2 2,54-2,542.54-2.54 слcl 35,57-35,5935.57-35.59 2,51-2,522.51-2.52 слcl 36,02-36,0436.02-36.04 2,48-2,492.48-2.49 слcl 41,65-41,7141.65-41.71 2,16-2,162.16-2.16 слcl 44,57-44,6144.57-44.61 2,02-2,032.02-2.03 слcl 47,48-47,5847.48-47.58 1,9-1,911.9-1.91 слcl 49,53-49,5949.53-49.59 1,83-1,831.83-1.83 слcl
и является термически стабильной до температуры, равной, по меньшей мере, 400°С.and is thermally stable to a temperature of at least 400 ° C. 2. Композиция по п.1, в которой «х» равен нулю.2. The composition according to claim 1, in which "x" is zero. 3. Композиция по п.1, в которой количество цеолита MSE изменяется от около 55% масс. до примерно 90% масс. в расчете на массу смеси, количество цеолита MFI изменяется от около 10% масс. до примерно 35% масс. в расчете на массу смеси и количество цеолита ERI изменяется от около 3% масс. до примерно 10% масс. в расчете на массу смеси.3. The composition according to claim 1, in which the amount of zeolite MSE varies from about 55% of the mass. up to about 90% of the mass. based on the weight of the mixture, the amount of zeolite MFI varies from about 10% of the mass. up to about 35% of the mass. based on the weight of the mixture and the amount of zeolite ERI varies from about 3% of the mass. up to about 10% of the mass. based on the weight of the mixture. 4. Способ получения композиции UZM-35, содержащей цеолит MFI, цеолит ERI и цеолит MSE, которая обладает трехмерным каркасом, по меньшей мере, из тетраэдров AlO2 и SiO2 и имеет эмпирический состав свежесинтезированной безводной основы, выражаемый эмпирической формулой:4. A method of obtaining a composition UZM-35 containing zeolite MFI, zeolite ERI and zeolite MSE, which has a three-dimensional skeleton of at least tetrahedra AlO 2 and SiO 2 and has the empirical composition of a freshly synthesized anhydrous base, expressed by the empirical formula: Mm +RrAl1-xExSiyOz, M m + R r Al 1-x E x Si y O z, где М представляет собой сочетание ионообменных катионов калия и натрия, «m» является мольным отношением М к (Al+Е) и изменяется от около 0,05 до примерно 3, R представляет собой однозарядный катион диметилдипропиламмония, «r» является мольным отношением R к (Al+E) и имеет значение от около 0,25 до примерно 2,0; Е представляет собой элемент, выбранный из группы, состоящей из галлия, железа, бора и их смесей, «х» является мольной долей Е и имеет значение от 0 до примерно 1,0; «y» представляет собой мольное отношение Si к (Al+Е) и изменяется от больше 2 до примерно 12 и «z» является мольным отношением О к (Al+Е) и имеет значение, определяемое уравнением:where M is a combination of ion exchange cations of potassium and sodium, “m” is the molar ratio of M to (Al + E) and varies from about 0.05 to about 3, R is the singly charged dimethyldipropylammonium cation, “r” is the molar ratio of R to (Al + E) and has a value of from about 0.25 to about 2.0; E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof, “x” is the mole fraction of E and has a value from 0 to about 1.0; "Y" is the molar ratio of Si to (Al + E) and varies from greater than 2 to about 12 and "z" is the molar ratio of O to (Al + E) and has the value given by the equation: z=(m+r+3+4·у)/2,z = (m + r + 3 + 4 · y) / 2, причем композиция характеризуется рентгеновской дифрактограммой, включающей, по меньшей мере, d-расстояния и интенсивности, приведенные в таблице А:moreover, the composition is characterized by x-ray diffraction pattern, including at least d-distances and intensities shown in table A: Таблица АTable a 2θ2θ d(Å)d (Å) I/I0 %I / I 0 % 6,48-6,516.48-6.51 13,32-13,5813.32-13.58 cpcp 6,78-6,836.78-6.83 12,91-13,0212.91-13.02 cp-ccp-c 7,79-7,967.79-7.96 11,09-11,3211.09-11.32 cpcp 8,05-8,078.05-8.07 10,93-10,9610.93-10.96 cpcp 8,71-8,758.71-8.75 10,08-10,1310.08-10.13 cpcp 9,61-9,659.61-9.65 9,15-9,189.15-9.18 cp-ccp-c 10,75-10,7910.75-10.79 8,18-8,218.18-8.21 слcl 13,61-13,6513.61-13.65 6,47-6,496.47-6.49 слcl 14,74-14,7914.74-14.79 5,98-65.98-6 слcl 15,56-15,5915.56-15.59 5,67-5,695.67-5.69 слcl 15,86-15,8615.86-15.86 5,58-5,585.58-5.58 слcl 19,46-19,519.46-19.5 4,54-4,554.54-4.55 cpcp 19,89-19,9219.89-19.92 4,45-4,454.45-4.45 cpcp 20,48-20,5120.48-20.51 4,32-4,334.32-4.33 cpcp 20,94-20,9620.94-20.96 4,23-4,234.23-4.23 cpcp 21,61-21,6421.61-21.64 4,1-4,14.1-4.1 осos 21,79-21,8121.79-21.81 4,07-4,074.07-4.07 сfrom 22,39-22,4522.39-22.45 3,95-3,963.95-3.96 cpcp 22,93-22,9822.93-22.98 3,86-3,873.86-3.87 c-occ-oc 23,29-23,3123.29-23.31 3,81-3,813.81-3.81 cpcp 23,5-23,523.5-23.5 3,78-3,783.78-3.78 cpcp 23,78-23,8623.78-23.86 3,72-3,733.72-3.73 cpcp 24,39-24,4124.39-24.41 3,64-3,643.64-3.64 слcl 24,82-24,8224.82-24.82 3,58-3,583,58-3,58 слcl 25,76-25,7925.76-25.79 3,45-3,453.45-3.45 сл-срwed 26,09-26,1226.09-26.12 3.4-3,413.4-3.41 cpcp 26,74-26,8126.74-26.81 3,32-3,333.32-3.33 cpcp 27,14-27,1427.14-27.14 3,28-3,283.28-3.28 cpcp 27,42-27,4627.42-27.46 3,24-3,2493.24-3.249 cpcp 27,69-27,6927.69-27.69 3,21-3,213.21-3.21 cpcp 28,02-28,0628.02-28.06 3,17-3,183.17-3.18 cpcp 29,1-29,1529.1-29.15 3,06-3,063.06-3.06 cpcp 29,54-29,6129.54-29.61 3,01-3,023.01-3.02 слcl 29,75-29,8629.75-29.86 2,98-2,992.98-2.99 слcl 30,12-30,1430.12-30.14 2,96-2,962.96-2.96 cpcp 30,73-30,7930.73-30.79 2,9-2,92.9-2.9 cpcp
2θ2θ d(Å)d (Å) I/I0 %I / I 0 % 31,26-31,2731.26-31.27 2,85-2,852.85-2.85 слcl 31,47-31,4731.47-31.47 2,83-2,832.83-2.83 слcl 33,19-33,2533.19-33.25 2,69-2,692.69-2.69 слcl 34,34-34,4834.34-34.48 2,59-2,62.59-2.6 слcl 34,76-34,7634.76-34.76 2,57-2,572.57-2.57 слcl 35,18-35,235.18-35.2 2,54-2,542.54-2.54 слcl 35,57-35,5935.57-35.59 2,51-2,522.51-2.52 слcl 36,02-36,0436.02-36.04 2,48-2,492.48-2.49 слcl 41,65-41,7141.65-41.71 2,16-2,162.16-2.16 слcl 44,57-44,6144.57-44.61 2,02-2,032.02-2.03 слcl 47,48-47,5847.48-47.58 1,9-1.911.9-1.91 слcl 49,53-49,5949.53-49.59 1,83-1,831.83-1.83 слcl
является термически стабильной до температуры, равной, по меньшей мере, 400°С;is thermally stable to a temperature of at least 400 ° C; при этом способ включает в себя формирование реакционной смеси, содержащей реакционноспособные источники М, R, Al, Si и необязательно Е, и нагревание реакционной смеси при температуре от около 150°С до примерно 200°С, в течение периода времени, достаточного для формирования цеолитной композиции, причем реакционная смесь имеет следующий состав, выражаемый в виде мольных отношений оксидов:the method includes forming a reaction mixture containing reactive sources of M, R, Al, Si and optionally E, and heating the reaction mixture at a temperature of from about 150 ° C to about 200 ° C for a period of time sufficient to form a zeolite composition, and the reaction mixture has the following composition, expressed as molar ratios of oxides: аМ2О:bR2/pO:1-cAl2O3:cE2O3:dSiO2:eH2O,AM 2 O: bR 2 / p O: 1-cAl 2 O 3 : cE 2 O 3 : dSiO 2 : eH 2 O, где «а» имеет значение от около 0,05 до примерно 1,25; «b» имеет значение от около 1,5 до примерно 40, «р» является средневзвешенной валентностью R и изменяется от 1 до примерно 2, «с» имеет значение от 0 до примерно 1,0; «d» имеет значение от около 4 до примерно 40, «е» имеет значение от около 25 до примерно 4000.where "a" has a value from about 0.05 to about 1.25; “B” has a value from about 1.5 to about 40, “p” is a weighted average valency R and varies from 1 to about 2, “c” has a value from 0 to about 1.0; “D” has a value of from about 4 to about 40, “e” has a value of from about 25 to about 4000. 5. Способ по п.4, в котором источник М выбирают из группы, состоящей из галогенидов, нитратов, ацетатов, гидроксидов, сульфатов и их смесей; источник Е выбирают из группы, состоящей из щелочных боратов, борной кислоты, осажденного оксигидроксида галлия, сульфата галлия, сульфата железа(III), хлорида железа(III) и их смесей; источник алюминия выбирают из группы, состоящей из изопропоксида алюминия, втор-бутоксида алюминия, осажденного оксида алюминия, Al(ОН)3, металлического алюминия и солей алюминия; и источник кремния выбирают из группы, состоящей из тетраэтилортосиликата, пирогенного диоксида кремния, коллоидного диоксида кремния и осажденного диоксида кремния.5. The method according to claim 4, in which the source M is selected from the group consisting of halides, nitrates, acetates, hydroxides, sulfates and mixtures thereof; source E is selected from the group consisting of alkaline borates, boric acid, precipitated gallium oxyhydroxide, gallium sulfate, iron (III) sulfate, iron (III) chloride and mixtures thereof; the aluminum source is selected from the group consisting of isopropoxide aluminum, sec-butoxide aluminum, precipitated aluminum oxide, Al (OH) 3 , aluminum metal and aluminum salts; and the silicon source is selected from the group consisting of tetraethylorthosilicate, fumed silica, colloidal silicon dioxide, and precipitated silica. 6. Способ по п.4, в котором реакционную смесь подвергают взаимодействию при температуре от около 150°С до примерно 185°С в течение примерно от 1 дня до около 3 недель.6. The method according to claim 4, in which the reaction mixture is subjected to interaction at a temperature of from about 150 ° to about 185 ° C for about 1 day to about 3 weeks. 7. Способ по п.4, в котором R представляет собой сочетание гидроксида диметилдипропиламмония и, по меньшей мере, одного однозарядного аммонийорганического катиона, выбранного из группы, состоящей из TEA, ТРА, ЕТМА, DEDMA, триметилпропиламмония, диметилдиизопропиламмония, триметилбутиламмония, диметилдиэтаноламмония или метилтрипропиламмония.7. The method according to claim 4, in which R is a combination of dimethyldipropylammonium hydroxide and at least one singly charged organo-ammonium cation selected from the group consisting of TEA, TPA, ETMA, DEDMA, trimethylpropylammonium, dimethyldiopropylammonium, trimethylbutylammonium ammonium dimethylammonium, . 8. Способ превращения углеводородов, включающий в себя контактирование углеводородного потока с катализатором на основе композиции UZM-35 в условиях превращения углеводородов с целью получения превращенного продукта, при этом катализатор на основе композиции UZM-35 содержит цеолит MFI, цеолит ERI и цеолит MSE, причем композиция UZM-35 обладает трехмерным каркасом, по меньшей мере, из тетраэдров AlO2 и SiO2 и имеет эмпирический состав свежесинтезированной безводной основы, выражаемый эмпирической формулой:8. A method of converting hydrocarbons, comprising contacting a hydrocarbon stream with a catalyst based on the UZM-35 composition under conditions of hydrocarbon conversion to obtain a converted product, the catalyst based on the UZM-35 composition contains MFI zeolite, ERI zeolite and MSE zeolite, wherein composition UZM-35 has a three-dimensional framework of at least AlO 2 and SiO 2 tetrahedra and has the empirical composition of a freshly synthesized anhydrous base, expressed by the empirical formula: Mm +RrAl1-xExSiyOz, M m + R r Al 1-x E x Si y O z, где М представляет собой сочетание ионообменных катионов калия и натрия, «m» является мольным отношением М к (Al+Е) и изменяется от около 0,05 до примерно 3, R представляет собой однозарядный аммонийорганический катион диметилдипропиламмония, «r» является мольным отношением R к (Al+E) и имеет значение от около 0,25 до примерно 2,0; Е представляет собой элемент, выбранный из группы, состоящей из галлия, железа, бора и их смесей, «х» является мольной долей Е и имеет значение от 0 до примерно 1,0; «y» представляет собой мольное отношение Si к (Al+Е) и изменяется от больше 2 до примерно 12 и «z» является мольным отношением О к (Al+Е) и имеет значение, определяемое уравнением:where M is a combination of ion exchange cations of potassium and sodium, “m” is the molar ratio of M to (Al + E) and varies from about 0.05 to about 3, R is the singly charged organomonium dimethyldipropylammonium cation, “r” is the molar ratio of R to (Al + E) and has a value of from about 0.25 to about 2.0; E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof, “x” is the mole fraction of E and has a value from 0 to about 1.0; "Y" is the molar ratio of Si to (Al + E) and varies from greater than 2 to about 12 and "z" is the molar ratio of O to (Al + E) and has the value given by the equation: z=(m+r+3+4·y)/2,z = (m + r + 3 + 4 · y) / 2, композиция характеризуется рентгеновской дифрактограммой, включающей, по меньшей мере, d-расстояния и интенсивности, приведенные в таблице А:the composition is characterized by an x-ray diffraction pattern including at least d-distances and intensities shown in table A: Таблица АTable a 2θ2θ d(Å)d (Å) I/I0 %I / I 0 % 6,48-6,516.48-6.51 13,32-13,5813.32-13.58 cpcp 6,78-6,836.78-6.83 12,91-13,0212.91-13.02 cp-ccp-c 7,79-7,967.79-7.96 11,09-11,3211.09-11.32 cpcp 8,05-8,078.05-8.07 10,93-10,9610.93-10.96 cpcp 8,71-8,758.71-8.75 10,08-10,1310.08-10.13 cpcp 9,61-9,659.61-9.65 9,15-9,189.15-9.18 cp-ccp-c 10,75-10,7910.75-10.79 8,18-8,218.18-8.21 слcl 13,61-13,6513.61-13.65 6,47-6,496.47-6.49 слcl 14,74-14,7914.74-14.79 5,98-65.98-6 слcl 15,56-15,5915.56-15.59 5,67-5,695.67-5.69 слcl 15,86-15,8615.86-15.86 5,58-5,585.58-5.58 слcl 19,46-19,519.46-19.5 4,54-4,554.54-4.55 cpcp 19,89-19,9219.89-19.92 4,45-4,454.45-4.45 cpcp 20,48-20,5120.48-20.51 4,32-4,334.32-4.33 cpcp 20,94-20,9620.94-20.96 4,23-4,234.23-4.23 cpcp
2θ2θ d(Å)d (Å) I/I0 %I / I 0 % 21,61-21,6421.61-21.64 4,1-4,14.1-4.1 осos 21,79-21,8121.79-21.81 4,07-4,074.07-4.07 сfrom 22,39-22,4522.39-22.45 3,95-3,963.95-3.96 срwed 22,93-22,9822.93-22.98 3,86-3,873.86-3.87 с-осSOS 23,29-23,3123.29-23.31 3,81-3,813.81-3.81 срwed 23,5-23,523.5-23.5 3,78-3,783.78-3.78 срwed 23,78-23,8623.78-23.86 3,72-3,733.72-3.73 срwed 24,39-24,4124.39-24.41 3,64-3,643.64-3.64 слcl 24,82-24,8224.82-24.82 3,58-3,583,58-3,58 слcl 25,76-25,7925.76-25.79 3,45-3,453.45-3.45 сл-срwed 26,09-26,1226.09-26.12 3,4-3,413.4-3.41 срwed 26,74-26,8126.74-26.81 3,32-3.333.32-3.33 срwed 27,14-27,1427.14-27.14 3,28-3,283.28-3.28 срwed 27,42-27,4627.42-27.46 3,24-3,2493.24-3.249 срwed 27,69-27,6927.69-27.69 3,21-3,213.21-3.21 срwed 28,02-28,0628.02-28.06 3,17-3,183.17-3.18 срwed 29,1-29,1529.1-29.15 3,06-3,063.06-3.06 срwed 29,54-29,6129.54-29.61 3,01-3,023.01-3.02 слcl 29,75-29,8629.75-29.86 2,98-2,992.98-2.99 слcl 30,12-30,1430.12-30.14 2,96-2,962.96-2.96 срwed 30,73-30,7930.73-30.79 2,9-2,92.9-2.9 срwed 31,26-31,2731.26-31.27 2,85-2,852.85-2.85 слcl 31,47-31,4731.47-31.47 2,83-2,832.83-2.83 слcl 33,19-33,2533.19-33.25 2,69-2,692.69-2.69 слcl 34,34-34,4834.34-34.48 2,59-2,62.59-2.6 слcl 34,76-34,7634.76-34.76 2,57-2,572.57-2.57 слcl 35,18-35,235.18-35.2 2,54-2,542.54-2.54 слcl 35,57-35,5935.57-35.59 2,51-2,522.51-2.52 слcl 36,02-36,0436.02-36.04 2,48-2,492.48-2.49 слcl 41,65-41,7141.65-41.71 2,16-2,162.16-2.16 слcl 44,57-44,6144.57-44.61 2,02-2,032.02-2.03 слcl 47,48-47,5847.48-47.58 1,9-1,911.9-1.91 слcl 49,53-49,5949.53-49.59 1,83-1,831.83-1.83 слcl
и является термически стабильной до температуры, равной, по меньшей мере, 400°С.and is thermally stable to a temperature of at least 400 ° C. 9. Способ по п.8, в котором процесс превращения углеводородов выбран из группы, состоящей из алкилирования, трансалкилирования, изомеризации, димеризации олефинов, олигомеризации олефинов и депарафинизации. 9. The method of claim 8, wherein the hydrocarbon conversion process is selected from the group consisting of alkylation, transalkylation, isomerization, dimerization of olefins, oligomerization of olefins and dewaxing.
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