RU2012118494A - ADSORBENT WITH A LOWERER REACTIVITY AND HIGHER CAPACITY OF OXYGEN CONTAINING COMPOUNDS FOR REMOVING OXYGEN CONTAINING COMPOUNDS FROM OLEFIN FLOWS - Google Patents

ADSORBENT WITH A LOWERER REACTIVITY AND HIGHER CAPACITY OF OXYGEN CONTAINING COMPOUNDS FOR REMOVING OXYGEN CONTAINING COMPOUNDS FROM OLEFIN FLOWS Download PDF

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RU2012118494A
RU2012118494A RU2012118494/05A RU2012118494A RU2012118494A RU 2012118494 A RU2012118494 A RU 2012118494A RU 2012118494/05 A RU2012118494/05 A RU 2012118494/05A RU 2012118494 A RU2012118494 A RU 2012118494A RU 2012118494 A RU2012118494 A RU 2012118494A
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zeolite
component
adsorbent
metal
additional
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RU2560360C2 (en
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Уилльям ДОЛАН
Барри СПЕРОНЕЛЛО
Альфонсе МАГЛИО
Деннис РЕЙНЕРСТЕН
Дейна РЕМС-МУНИ
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Басф Корпорейшн
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
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    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
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    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
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    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent

Abstract

1. Твердый адсорбент для очистки потоков углеводородов, содержащий компонент оксида алюминия, компонент цеолита и добавочный компонент металла, добавочный компонент металла присутствует в количестве от приблизительно 0,0075 до 0,0135 моль металла в виде оксида на 100 г адсорбента, и где оксид алюминия присутствует в количестве от приблизительно 40 до приблизительно 90 мас.% адсорбента.2. Адсорбент по п.1, где цеолит выбран из группы, включающей цеолит X, цеолит Y, цеолит A, ZSM-5, цеолит бета и их смеси.3. Адсорбент по п.1, где добавочный компонент металла является щелочным металлом, выбранным из группы, включающей натрий, калий, литий, рубидий, цезий и их смеси.4. Адсорбент по п.3, в котором добавочным компонентом металла является натрий.5. Адсорбент по п.1, в котором добавочный компонент металла сначала добавляют, прежде всего, к цеолиту так, что добавочный металл присутствует в компоненте цеолита в количествах больших, чем, если бы такое же количество исходного металла было добавлено к смеси цеолита и оксида алюминия.6. Адсорбент по п.5 в виде твердой формы, содержащей смесь частиц цеолита и оксида алюминия.7. Твердый адсорбент для очистки потоков углеводородов, включающий компонент оксида алюминия, компонент цеолита и добавочный компонент металла, добавочный компонент металла сначала добавляют, прежде всего, к цеолиту так, что добавочный металл присутствует в компоненте цеолита в количествах больших, чем, если бы такое же количество исходного металла было добавлено к смеси цеолита и оксида алюминия.8. Адсорбент по п.7, где цеолит выбран из группы, включающей цеолит X, цеолит Y, цеолит A, ZSM-5, цеолит бета и их смеси.9. Адсорбент по п.8, где цео1. A solid adsorbent for cleaning hydrocarbon streams containing an alumina component, a zeolite component and an additional metal component, an additional metal component is present in an amount of from about 0.0075 to 0.0135 mol of metal in the form of oxide per 100 g of adsorbent, and where aluminum oxide present in an amount of from about 40 to about 90 wt.% adsorbent. 2. The adsorbent according to claim 1, wherein the zeolite is selected from the group consisting of zeolite X, zeolite Y, zeolite A, ZSM-5, zeolite beta, and mixtures thereof. The adsorbent according to claim 1, where the additional component of the metal is an alkali metal selected from the group comprising sodium, potassium, lithium, rubidium, cesium and mixtures thereof. The adsorbent according to claim 3, in which the additional metal component is sodium. The adsorbent according to claim 1, in which the additional metal component is first added primarily to the zeolite so that the additional metal is present in the zeolite component in amounts greater than if the same amount of the starting metal was added to the mixture of zeolite and alumina. 6. The adsorbent according to claim 5 in the form of a solid form containing a mixture of particles of zeolite and alumina. A solid adsorbent for cleaning hydrocarbon streams, including an alumina component, a zeolite component and an additional metal component, an additional metal component is first added, first of all, to the zeolite so that the additional metal is present in the zeolite component in quantities greater than if the same amount the starting metal was added to a mixture of zeolite and alumina. 8. The adsorbent according to claim 7, wherein the zeolite is selected from the group consisting of zeolite X, zeolite Y, zeolite A, ZSM-5, zeolite beta, and mixtures thereof. The adsorbent of claim 8, where ceo

Claims (20)

1. Твердый адсорбент для очистки потоков углеводородов, содержащий компонент оксида алюминия, компонент цеолита и добавочный компонент металла, добавочный компонент металла присутствует в количестве от приблизительно 0,0075 до 0,0135 моль металла в виде оксида на 100 г адсорбента, и где оксид алюминия присутствует в количестве от приблизительно 40 до приблизительно 90 мас.% адсорбента.1. A solid adsorbent for cleaning hydrocarbon streams containing an alumina component, a zeolite component and an additional metal component, an additional metal component is present in an amount of from about 0.0075 to 0.0135 mol of metal in the form of oxide per 100 g of adsorbent, and where aluminum oxide present in an amount of from about 40 to about 90 wt.% adsorbent. 2. Адсорбент по п.1, где цеолит выбран из группы, включающей цеолит X, цеолит Y, цеолит A, ZSM-5, цеолит бета и их смеси.2. The adsorbent according to claim 1, where the zeolite is selected from the group comprising zeolite X, zeolite Y, zeolite A, ZSM-5, zeolite beta and mixtures thereof. 3. Адсорбент по п.1, где добавочный компонент металла является щелочным металлом, выбранным из группы, включающей натрий, калий, литий, рубидий, цезий и их смеси.3. The adsorbent according to claim 1, where the additional component of the metal is an alkali metal selected from the group comprising sodium, potassium, lithium, rubidium, cesium and mixtures thereof. 4. Адсорбент по п.3, в котором добавочным компонентом металла является натрий.4. The adsorbent according to claim 3, in which the additional metal component is sodium. 5. Адсорбент по п.1, в котором добавочный компонент металла сначала добавляют, прежде всего, к цеолиту так, что добавочный металл присутствует в компоненте цеолита в количествах больших, чем, если бы такое же количество исходного металла было добавлено к смеси цеолита и оксида алюминия.5. The adsorbent according to claim 1, in which the additional metal component is first added primarily to the zeolite so that the additional metal is present in the zeolite component in quantities greater than if the same amount of the starting metal was added to the mixture of zeolite and oxide aluminum. 6. Адсорбент по п.5 в виде твердой формы, содержащей смесь частиц цеолита и оксида алюминия.6. The adsorbent according to claim 5 in the form of a solid form containing a mixture of particles of zeolite and alumina. 7. Твердый адсорбент для очистки потоков углеводородов, включающий компонент оксида алюминия, компонент цеолита и добавочный компонент металла, добавочный компонент металла сначала добавляют, прежде всего, к цеолиту так, что добавочный металл присутствует в компоненте цеолита в количествах больших, чем, если бы такое же количество исходного металла было добавлено к смеси цеолита и оксида алюминия.7. A solid adsorbent for cleaning hydrocarbon streams, including an alumina component, a zeolite component and an additional metal component, the additional metal component is first added, first of all, to the zeolite so that the additional metal is present in the zeolite component in quantities greater than if such the same amount of the starting metal was added to the mixture of zeolite and alumina. 8. Адсорбент по п.7, где цеолит выбран из группы, включающей цеолит X, цеолит Y, цеолит A, ZSM-5, цеолит бета и их смеси.8. The adsorbent according to claim 7, where the zeolite is selected from the group comprising zeolite X, zeolite Y, zeolite A, ZSM-5, zeolite beta and mixtures thereof. 9. Адсорбент по п.8, где цеолитом является цеолит Y.9. The adsorbent of claim 8, where the zeolite is zeolite Y. 10. Адсорбент по п.7, где добавочным компонентом металла является щелочной металл, выбранный из группы, включающей натрий, калий, литий, рубидий, цезий и их смеси.10. The adsorbent according to claim 7, where the additional component of the metal is an alkali metal selected from the group comprising sodium, potassium, lithium, rubidium, cesium and mixtures thereof. 11. Адсорбент по п.10, где компонентом металла является натрий.11. The adsorbent of claim 10, where the metal component is sodium. 12. Адсорбент по п.7, в котором добавочный компонент металла присутствует в количестве от приблизительно 0,0075 до 0,05 моль металла в виде оксида на 100 г адсорбента.12. The adsorbent according to claim 7, in which the additional component of the metal is present in an amount of from about 0.0075 to 0.05 mol of metal in the form of oxide per 100 g of adsorbent. 13. Способ получения твердого адсорбента для очистки потоков углеводородов, включающий компонент оксида алюминия, компонент цеолита и добавочный компонент металла, где оксид алюминия присутствует в количестве от приблизительно 40 до приблизительно 90 мас.% адсорбента; способ включает комбинирование компонента цеолита с предшествующим веществом добавочного компонента металла, чтобы образовать насыщенный цеолит, комбинирование насыщенного цеолита и оксида алюминия, чтобы образовать формованное изделие и активацию изделия в условиях активации, чтобы получить твердый адсорбент.13. A method of producing a solid adsorbent for cleaning hydrocarbon streams, comprising an alumina component, a zeolite component and an additional metal component, where alumina is present in an amount of from about 40 to about 90 wt.% Adsorbent; the method includes combining a zeolite component with a precursor of an additional metal component to form a saturated zeolite, combining saturated zeolite and alumina to form a molded article and product activation under activation conditions to obtain a solid adsorbent. 14. Способ по п.13, где компонент цеолита выбирают из группы, включающей цеолит X, цеолит Y, цеолит А, ZSM-5, цеолит бета и их смеси.14. The method of claim 13, wherein the zeolite component is selected from the group consisting of zeolite X, zeolite Y, zeolite A, ZSM-5, zeolite beta, and mixtures thereof. 15. Способ по п.13, где предшествующее вещество добавочного компонента металла выбирают из карбоксилатного, карбонатного, алюминатного и гидроксильного соединения компонента металла.15. The method according to item 13, where the preceding substance of the additive metal component is selected from a carboxylate, carbonate, aluminate and hydroxyl compound of the metal component. 16. Способ по п.13, где добавочным компонентом металла является щелочной металл.16. The method according to item 13, where the additional component of the metal is an alkali metal. 17. Способ по п.13, включающий выдерживание указанного формованного изделия, предшествующее активации при температуре приблизительно окружающей среды до приблизительно 200°С и время от приблизительно 5 мин до приблизительно 25 ч.17. The method according to item 13, including maintaining the specified molded product, prior activation at a temperature of approximately ambient temperature to about 200 ° C and a time of from about 5 minutes to about 25 hours 18. Способ по п.13, где условия активации включают температуру от приблизительно 275°С до приблизительно 600°С и время от приблизительно 5 до приблизительно 70 мин.18. The method of claim 13, wherein the activation conditions include a temperature of from about 275 ° C. to about 600 ° C. and a time of from about 5 to about 70 minutes. 19. Способ удаления примесей из потока углеводородов, включающий контакт потока углеводородов с адсорбентом по п.1.19. The method of removing impurities from a hydrocarbon stream, comprising contacting the hydrocarbon stream with an adsorbent according to claim 1. 20. Способ удаления примесей из потока углеводородов, включающий контакт потока углеводородов с адсорбентом по п.7. 20. A method for removing impurities from a hydrocarbon stream, comprising contacting the hydrocarbon stream with an adsorbent according to claim 7.
RU2012118494/05A 2009-10-06 2010-09-30 Adsorbent with lower reactivity and higher capacity for oxygen-containing compounds for removing oxygen-containing compounds from olefin streams RU2560360C2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/573,927 US8147588B2 (en) 2009-10-06 2009-10-06 Lower reactivity adsorbent and higher oxygenate capacity for removal of oxygenates from olefin streams
US12/573,927 2009-10-06
PCT/US2010/050806 WO2011043974A2 (en) 2009-10-06 2010-09-30 Lower reactivity adsorbent and higher oxygenate capacity for removal of oxygenates from olefin streams

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