RU2011153777A - Катализатор и способ - Google Patents
Катализатор и способ Download PDFInfo
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- RU2011153777A RU2011153777A RU2011153777/04A RU2011153777A RU2011153777A RU 2011153777 A RU2011153777 A RU 2011153777A RU 2011153777/04 A RU2011153777/04 A RU 2011153777/04A RU 2011153777 A RU2011153777 A RU 2011153777A RU 2011153777 A RU2011153777 A RU 2011153777A
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- Prior art keywords
- catalyst
- metal compound
- hydrocarbon
- alkane
- dehydrogenation
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- 238000000034 method Methods 0.000 title claims abstract 30
- 239000003054 catalyst Substances 0.000 title claims abstract 10
- 150000002736 metal compounds Chemical class 0.000 claims abstract 13
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 12
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 12
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 12
- 239000012018 catalyst precursor Substances 0.000 claims abstract 10
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract 9
- 238000006356 dehydrogenation reaction Methods 0.000 claims abstract 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract 5
- 239000002184 metal Substances 0.000 claims abstract 5
- 229910052751 metal Inorganic materials 0.000 claims abstract 5
- 239000007789 gas Substances 0.000 claims abstract 4
- 150000001336 alkenes Chemical class 0.000 claims abstract 3
- 239000002134 carbon nanofiber Substances 0.000 claims abstract 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract 3
- 229910052742 iron Inorganic materials 0.000 claims abstract 3
- 229910052748 manganese Inorganic materials 0.000 claims abstract 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract 3
- 229910052763 palladium Inorganic materials 0.000 claims abstract 3
- 229910052697 platinum Inorganic materials 0.000 claims abstract 3
- 229910052703 rhodium Inorganic materials 0.000 claims abstract 3
- 229910052720 vanadium Inorganic materials 0.000 claims abstract 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract 2
- 229910002651 NO3 Inorganic materials 0.000 claims abstract 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract 2
- 239000000463 material Substances 0.000 claims abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract 2
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 2
- 239000001301 oxygen Substances 0.000 claims abstract 2
- 238000011065 in-situ storage Methods 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 239000002086 nanomaterial Substances 0.000 claims 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
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Abstract
1. Способ дегидрирования углеводорода, содержащий стадию подачи потока сырья, содержащего по меньшей мере один углеводород, над катализатором, содержащим каталитически активную углеродную фазу, где упомянутый катализатор образуют путем пропускания углеводородсодержащего газа над предшественником катализатора при повышенной температуре в течение времени, достаточного для образования активной углеродной фазы.2. Способ по п.1, где упомянутый предшественник катализатора содержит соединение металла.3. Способ по п.2, где упомянутое соединение металла представляет собой соединение металла, выбранного из V, Cr, Mn, Fe, Co, Ni, Pt, Pd, Ru, Au, Mo и Rh.4. Способ по любому из пп.2 и 3, где данное соединение металла содержит металл в элементарной форме или оксид, карбонат, нитрат, сульфат, сульфид или гидроксид данного металла.5. Способ по любому из пп.2 и 3 где упомянутое соединение металла наносят на пористый носитель.6. Способ по п.1, где упомянутый предшественник катализатора содержит предварительно сформированный углеродный нановолокнистый материал.7. Способ по п.1, где упомянутый углеводород содержит алкан, имеющий от 2 до 24 атомов углерода, который дегидрируют с образованием алкена.8. Способ по п.7, где упомянутое дегидрирование выполняют по существу в отсутствие кислорода.9. Способ по п.1, где упомянутая повышенная температура находится в интервале 650-750°С.10. Способ по п.1, где упомянутый углеводородсодержащий газ пропускают над упомянутым предшественником катализатора при упомянутой повышенной температуре в течение по меньшей мере одного часа.11. Способ формирования катализатора дегидрирования алканов, содержащий стадию контактировани�
Claims (17)
1. Способ дегидрирования углеводорода, содержащий стадию подачи потока сырья, содержащего по меньшей мере один углеводород, над катализатором, содержащим каталитически активную углеродную фазу, где упомянутый катализатор образуют путем пропускания углеводородсодержащего газа над предшественником катализатора при повышенной температуре в течение времени, достаточного для образования активной углеродной фазы.
2. Способ по п.1, где упомянутый предшественник катализатора содержит соединение металла.
3. Способ по п.2, где упомянутое соединение металла представляет собой соединение металла, выбранного из V, Cr, Mn, Fe, Co, Ni, Pt, Pd, Ru, Au, Mo и Rh.
4. Способ по любому из пп.2 и 3, где данное соединение металла содержит металл в элементарной форме или оксид, карбонат, нитрат, сульфат, сульфид или гидроксид данного металла.
5. Способ по любому из пп.2 и 3 где упомянутое соединение металла наносят на пористый носитель.
6. Способ по п.1, где упомянутый предшественник катализатора содержит предварительно сформированный углеродный нановолокнистый материал.
7. Способ по п.1, где упомянутый углеводород содержит алкан, имеющий от 2 до 24 атомов углерода, который дегидрируют с образованием алкена.
8. Способ по п.7, где упомянутое дегидрирование выполняют по существу в отсутствие кислорода.
9. Способ по п.1, где упомянутая повышенная температура находится в интервале 650-750°С.
10. Способ по п.1, где упомянутый углеводородсодержащий газ пропускают над упомянутым предшественником катализатора при упомянутой повышенной температуре в течение по меньшей мере одного часа.
11. Способ формирования катализатора дегидрирования алканов, содержащий стадию контактирования предшественника катализатора с углеводородом при температуре больше чем 650°С.
12. Способ по п.11, где упомянутый предшественник катализатора содержит соединение металла или предварительно сформированное углеродное нановолокно.
13. Способ по п.12, где упомянутый металл выбирают из V, Cr, Mn, Fe, Co, Ni, Pt, Pd, Ru и Rh.
14. Способ по п.12, где упомянутое соединение металла содержит оксид металла.
15. Способ по любому из пп.12-14, где упомянутое соединение металла наносят на пористый носитель.
16. Способ по любому из пп.11-14, где упомянутый углеводород содержит алкан, и катализатор формируют in-situ в реакторе, подходящем для проведения неокислительного дегидрирования упомянутого алкана, и способ дополнительно включает стадию использования катализатора для катализа дегидрирования упомянутого алкана в упомянутом реакторе.
17. Способ неокислительного дегидрирования алкана с образованием алкена, содержащий стадию контактирования потока сырья, содержащего по меньшей мере один алкан, с катализатором, содержащим углерод в форме наноструктуры.
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| GB0909694A GB0909694D0 (en) | 2009-06-05 | 2009-06-05 | Catalyst and process |
| GB0913579A GB0913579D0 (en) | 2009-08-05 | 2009-08-05 | Catalst and process |
| GB0913579.9 | 2009-08-05 | ||
| PCT/GB2010/050944 WO2010140005A2 (en) | 2009-06-05 | 2010-06-04 | Catalyst and process |
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| RU2011153777A true RU2011153777A (ru) | 2013-07-20 |
| RU2565757C2 RU2565757C2 (ru) | 2015-10-20 |
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| GB (1) | GB2485686A (ru) |
| RU (1) | RU2565757C2 (ru) |
| WO (1) | WO2010140005A2 (ru) |
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| GB201020501D0 (en) * | 2010-12-03 | 2011-01-19 | Johnson Matthey Plc | Dehydrogenation process |
| CN103143385A (zh) * | 2013-02-07 | 2013-06-12 | 大连理工大学 | 一种改性分子筛催化剂用于丙烷催化裂解的方法 |
| WO2017052860A1 (en) | 2015-09-25 | 2017-03-30 | Exxonmobil Chemical Patents Inc. | Hydrocarbon dehydrocyclization |
| US9796643B2 (en) | 2015-09-25 | 2017-10-24 | Exxonmobil Chemical Patents Inc. | Hydrocarbon dehydrocyclization in the presence of carbon dioxide |
| US9963406B2 (en) | 2015-09-25 | 2018-05-08 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion |
| US10273196B2 (en) | 2015-09-25 | 2019-04-30 | Exxonmobil Chemical Patents Inc. | Hydrocarbon dehydrocyclization |
| US9988325B2 (en) | 2015-09-25 | 2018-06-05 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion |
| US10202318B2 (en) | 2015-09-25 | 2019-02-12 | Exxonmobil Chemical Patents Inc. | Catalyst and its use in hydrocarbon conversion process |
| US9845272B2 (en) | 2015-09-25 | 2017-12-19 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion |
| WO2017052858A1 (en) | 2015-09-25 | 2017-03-30 | Exxonmobile Chemical Patents Inc. | Conversion of non-aromatic hydrocarbon |
| EP3361781B1 (en) * | 2015-10-30 | 2019-06-26 | Huawei Technologies Co., Ltd. | Resident cell determination method, user equipment and network device |
| CA3022086A1 (en) | 2016-04-25 | 2017-11-02 | Exxonmobil Chemical Patents Inc. | Catalytic aromatization |
| CN108155020B (zh) * | 2016-12-02 | 2019-10-25 | 中国石油化工股份有限公司 | 石墨烯复合材料及其制备方法和应用 |
| WO2018151900A1 (en) | 2017-02-16 | 2018-08-23 | Exxonmobil Research And Engineering Company | Fixed bed radial flow reactor for light paraffin conversion |
| WO2021095782A1 (ja) * | 2019-11-14 | 2021-05-20 | 三菱ケミカル株式会社 | 触媒及びその製造方法、並びに不飽和炭化水素の製造方法 |
| US11920078B2 (en) * | 2019-11-20 | 2024-03-05 | Lummus Technology Llc | Heat storage in chemical reactors |
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| BE571350A (ru) | 1957-09-20 | |||
| US3758625A (en) * | 1971-04-30 | 1973-09-11 | Exxon Research Engineering Co | Dehydrogenation catalyst |
| US4067924A (en) * | 1975-01-13 | 1978-01-10 | Petro-Tex Chemical Corporation | Dehydrogenation process |
| US5087792A (en) | 1991-01-09 | 1992-02-11 | Uop | Process for the dehydrogenation of hydrocarbons |
| GB9113686D0 (en) * | 1991-06-25 | 1991-08-14 | Shell Int Research | Process for the preparation of alkenes |
| EP0556489A1 (en) | 1992-02-19 | 1993-08-25 | Shell Internationale Researchmaatschappij B.V. | Process for the dehydrogenation of hydrocarbons |
| IT1254988B (it) * | 1992-06-23 | 1995-10-11 | Eniricerche Spa | Procedimento per la deidrogenazione di paraffine leggere in un reattore a letto fluido |
| FI100584B (fi) * | 1996-02-16 | 1998-01-15 | Neste Oy | Menetelmä alkaanien dehydraamiseksi ja siinä käytettävä katalyytti |
| US6756339B1 (en) * | 1998-04-01 | 2004-06-29 | Sud-Chemie Inc. | Dehydrogenation catalysts |
| US6485858B1 (en) * | 1999-08-23 | 2002-11-26 | Catalytic Materials | Graphite nanofiber catalyst systems for use in fuel cell electrodes |
| US6756340B2 (en) | 2002-04-08 | 2004-06-29 | Uop Llc | Dehydrogenation catalyst composition |
| US7012038B2 (en) * | 2002-06-12 | 2006-03-14 | Engelhard Corporation | Paraffin dehydrogenation catalyst |
| AU2003294286A1 (en) * | 2002-11-14 | 2004-06-15 | Catalytic Materials, Llc | Novel graphite nanocatalysts |
| MXPA06008965A (es) * | 2004-02-09 | 2007-02-20 | Down Chemical Company | Proceso para la preparacion de compuestos de hidrocarburos deshidrogenados. |
| EP1589131A1 (en) * | 2004-04-21 | 2005-10-26 | Stichting Voor De Technische Wetenschappen | Carbon nanofibre composites, preparation and use |
| CN101014412A (zh) | 2004-07-16 | 2007-08-08 | 那诺克有限公司 | 用于制备不饱和烃的包含纳米碳结构的催化剂 |
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- 2010-06-04 RU RU2011153777/04A patent/RU2565757C2/ru not_active IP Right Cessation
- 2010-06-04 CN CN201080028328.4A patent/CN102459135B/zh not_active Expired - Fee Related
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- 2010-06-04 US US13/376,301 patent/US20120136191A1/en not_active Abandoned
- 2010-06-04 CA CA2763706A patent/CA2763706A1/en not_active Abandoned
- 2010-06-04 EP EP10724118A patent/EP2438032A1/en not_active Withdrawn
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| WO2010140005A9 (en) | 2011-09-01 |
| US20120136191A1 (en) | 2012-05-31 |
| GB2485686A (en) | 2012-05-23 |
| RU2565757C2 (ru) | 2015-10-20 |
| CN102459135A (zh) | 2012-05-16 |
| GB201122246D0 (en) | 2012-02-01 |
| CN102459135B (zh) | 2016-01-20 |
| CA2763706A1 (en) | 2010-12-09 |
| EP2438032A1 (en) | 2012-04-11 |
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