RU2010145022A - METHOD OF WORK OF GAS-TURBINE INSTALLATION - Google Patents

METHOD OF WORK OF GAS-TURBINE INSTALLATION Download PDF

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RU2010145022A
RU2010145022A RU2010145022/06A RU2010145022A RU2010145022A RU 2010145022 A RU2010145022 A RU 2010145022A RU 2010145022/06 A RU2010145022/06 A RU 2010145022/06A RU 2010145022 A RU2010145022 A RU 2010145022A RU 2010145022 A RU2010145022 A RU 2010145022A
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Russia
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methane
catalytic reactor
gas
pressure steam
gas mixture
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RU2010145022/06A
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Russian (ru)
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RU2467187C2 (en
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Анатолий Яковлевич Столяревский (RU)
Анатолий Яковлевич Столяревский
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ООО "Центр КОРТЭС" (RU)
ООО "Центр КОРТЭС"
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Priority to RU2010145022/06A priority Critical patent/RU2467187C2/en
Priority to PCT/RU2011/000844 priority patent/WO2012060739A1/en
Publication of RU2010145022A publication Critical patent/RU2010145022A/en
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Publication of RU2467187C2 publication Critical patent/RU2467187C2/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/34Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/18Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84Energy production

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1. Способ работы газотурбинной установки, включающий подачу в камеру сгорания сжатых воздуха и метансодержащей парогазовой смеси, расширение продуктов их сгорания в газовой турбине, охлаждение продуктов сгорания путем испарения или перегрева водяного пара высокого давления, конденсацию водяного пара низкого давления, содержащегося в продуктах сгорания, испарение и перегрев конденсата с образованием водяного пара высокого давления, направляемого в газотурбинную установку, отличающийся тем, что природный газ последовательно смешивают с водяным паром высокого давления, нагревают в первом теплообменнике продуктами сгорания метансодержащей парогазовой смеси, пропускают через каталитический реактор с образованием метансодержащей парогазовой смеси, которую нагревают во втором теплообменнике, пропускают через второй каталитический реактор и подают в камеру сгорания. ! 2. Способ по п.1, отличающийся тем, что нагрев природного газа с водяным паром высокого давления, подаваемым в каталитический реактор, ведут до температуры в диапазоне 350°С-530°С. ! 3. Способ по п.1, отличающийся тем, что нагрев метансодержащей парогазовой смеси, подаваемой во второй каталитический реактор, ведут до температуры в диапазоне 620-680°С. ! 4. Способ по п.1, отличающийся тем, что давление водяного пара высокого давления выбирают в диапазоне ориентировочно от 2,0 до 9,0 МПа. !5. Способ по п.1, отличающийся тем, что реакцию смеси природного газа с водяным паром высокого давления в каталитическом реакторе ведут без подвода тепловой энергии на катализаторе, содержащем металлы из ряда: никель, железо, платина, палладий, иридий или их соединения, с обра 1. The method of operation of a gas turbine installation, comprising supplying compressed air and a methane-containing gas mixture to the combustion chamber, expanding their combustion products in a gas turbine, cooling the combustion products by evaporation or overheating of high pressure steam, condensation of low pressure steam contained in the combustion products, evaporation and overheating of the condensate with the formation of high-pressure water vapor sent to a gas turbine installation, characterized in that the natural gas is sequentially mixed with high-pressure steam, they are heated in the first heat exchanger with the products of combustion of a methane-containing gas mixture, passed through a catalytic reactor to form a methane-containing gas mixture, which is heated in a second heat exchanger, passed through a second catalytic reactor and fed into the combustion chamber. ! 2. The method according to claim 1, characterized in that the heating of natural gas with high-pressure steam supplied to the catalytic reactor is carried out to a temperature in the range of 350 ° C-530 ° C. ! 3. The method according to claim 1, characterized in that the heating of the methane-containing vapor-gas mixture supplied to the second catalytic reactor is carried out to a temperature in the range of 620-680 ° C. ! 4. The method according to claim 1, characterized in that the pressure of high pressure water vapor is selected in the range of approximately from 2.0 to 9.0 MPa. !5. The method according to claim 1, characterized in that the reaction of a mixture of natural gas with high pressure steam in a catalytic reactor is carried out without supplying thermal energy to a catalyst containing metals from the series: nickel, iron, platinum, palladium, iridium or their compounds, with

Claims (8)

1. Способ работы газотурбинной установки, включающий подачу в камеру сгорания сжатых воздуха и метансодержащей парогазовой смеси, расширение продуктов их сгорания в газовой турбине, охлаждение продуктов сгорания путем испарения или перегрева водяного пара высокого давления, конденсацию водяного пара низкого давления, содержащегося в продуктах сгорания, испарение и перегрев конденсата с образованием водяного пара высокого давления, направляемого в газотурбинную установку, отличающийся тем, что природный газ последовательно смешивают с водяным паром высокого давления, нагревают в первом теплообменнике продуктами сгорания метансодержащей парогазовой смеси, пропускают через каталитический реактор с образованием метансодержащей парогазовой смеси, которую нагревают во втором теплообменнике, пропускают через второй каталитический реактор и подают в камеру сгорания.1. The method of operation of a gas turbine installation, comprising supplying compressed air and a methane-containing gas mixture to the combustion chamber, expanding their combustion products in a gas turbine, cooling the combustion products by evaporation or overheating of high pressure steam, condensation of low pressure steam contained in the combustion products, evaporation and overheating of the condensate with the formation of high-pressure water vapor sent to a gas turbine installation, characterized in that the natural gas is sequentially mixed with high-pressure steam, they are heated in the first heat exchanger with the products of combustion of a methane-containing gas mixture, passed through a catalytic reactor to form a methane-containing gas mixture, which is heated in a second heat exchanger, passed through a second catalytic reactor and fed into the combustion chamber. 2. Способ по п.1, отличающийся тем, что нагрев природного газа с водяным паром высокого давления, подаваемым в каталитический реактор, ведут до температуры в диапазоне 350°С-530°С.2. The method according to claim 1, characterized in that the heating of natural gas with high-pressure steam supplied to the catalytic reactor is carried out to a temperature in the range of 350 ° C-530 ° C. 3. Способ по п.1, отличающийся тем, что нагрев метансодержащей парогазовой смеси, подаваемой во второй каталитический реактор, ведут до температуры в диапазоне 620-680°С.3. The method according to claim 1, characterized in that the heating of the methane-containing vapor-gas mixture supplied to the second catalytic reactor is carried out to a temperature in the range of 620-680 ° C. 4. Способ по п.1, отличающийся тем, что давление водяного пара высокого давления выбирают в диапазоне ориентировочно от 2,0 до 9,0 МПа.4. The method according to claim 1, characterized in that the pressure of high pressure water vapor is selected in the range of approximately from 2.0 to 9.0 MPa. 5. Способ по п.1, отличающийся тем, что реакцию смеси природного газа с водяным паром высокого давления в каталитическом реакторе ведут без подвода тепловой энергии на катализаторе, содержащем металлы из ряда: никель, железо, платина, палладий, иридий или их соединения, с образованием метансодержащего газа с концентрацией водорода от 1 до 5%.5. The method according to claim 1, characterized in that the reaction of a mixture of natural gas with high pressure water vapor in a catalytic reactor is carried out without supplying thermal energy to a catalyst containing metals from the series: nickel, iron, platinum, palladium, iridium, or their compounds, with the formation of methane-containing gas with a hydrogen concentration of from 1 to 5%. 6. Способ по п.1, отличающийся тем, что реакцию метансодержащей парогазовой смеси во втором каталитическом реакторе ведут без подвода тепловой энергии на катализаторе, содержащем металлы из ряда: никель, железо, платина, палладий, иридий или их соединения, с образованием метансодержащего газа с концентрацией водорода свыше 20%.6. The method according to claim 1, characterized in that the reaction of the methane-containing vapor-gas mixture in the second catalytic reactor is carried out without supplying thermal energy to a catalyst containing metals from the series: nickel, iron, platinum, palladium, iridium or their compounds, with the formation of methane-containing gas with a hydrogen concentration of over 20%. 7. Способ по п.1, отличающийся тем, что перед смешением природного газа с водяным паром проводят очистку природного газа от соединений серы.7. The method according to claim 1, characterized in that before mixing the natural gas with water vapor, the natural gas is purified from sulfur compounds. 8. Способ по п.1, отличающийся тем, что в качестве греющей среды первого и второго теплообменника используют продукты сгорания метансодержащей парогазовой смеси. 8. The method according to claim 1, characterized in that the combustion products of the methane-containing vapor-gas mixture are used as the heating medium of the first and second heat exchanger.
RU2010145022/06A 2010-11-03 2010-11-03 Method of operating gas turbine unit RU2467187C2 (en)

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PCT/RU2011/000844 WO2012060739A1 (en) 2010-11-03 2011-11-01 Method for operating a gas turbine unit

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US9377202B2 (en) 2013-03-15 2016-06-28 General Electric Company System and method for fuel blending and control in gas turbines
US9382850B2 (en) 2013-03-21 2016-07-05 General Electric Company System and method for controlled fuel blending in gas turbines
RU2561755C2 (en) 2013-11-07 2015-09-10 Открытое акционерное общество "Газпром" Operating method and system of gas-turbine plant
RU2626291C2 (en) * 2015-11-13 2017-07-25 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Energy conversion method
RU2648478C2 (en) * 2015-11-18 2018-03-26 федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" Maneuvered regenerative steam gas thermal power plant operating method and device for its implementation
RU2639397C1 (en) * 2016-12-29 2017-12-21 Общество с ограниченной ответственностью "Газпром трансгаз Самара" Mode of gas turbine plant operation on methane-contained steam-gas mixture and its actualization device
RU2647013C1 (en) * 2017-02-27 2018-03-13 Федеральное государственное бюджетное образовательное учреждение высшего образования "Саратовский государственный технический университет имени Гагарина Ю.А." (СГТУ имени Гагарина Ю.А.) Method of operation of the compressed-air power station
RU2643878C1 (en) * 2017-02-27 2018-02-06 Федеральное государственное бюджетное образовательное учреждение высшего образования "Саратовский государственный технический университет имени Гагарина Ю.А." (СГТУ имени Гагарина Ю.А.) Method of operation of the compressed-air power station with an absorption lithium bromide refrigerating system (lbrs)
RU2665745C1 (en) * 2017-07-25 2018-09-04 Андрей Владиславович Курочкин Gas turbine installation
RU2689483C2 (en) * 2017-10-30 2019-05-28 федеральное государственное автономное образовательное учреждение высшего образования "Самарский национальный исследовательский университет имени академика С.П. Королёва" Energy plant with high-temperature steam-gas condensate turbine
RU2672416C1 (en) * 2018-03-12 2018-11-14 Андрей Владиславович Курочкин Hydrogen recovery plant (options)
RU2679241C1 (en) * 2018-03-12 2019-02-06 Андрей Владиславович Курочкин Hydrogen recovery plant

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RU2467187C2 (en) 2012-11-20

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