RU2009122702A - SELF-ADHESIVE CLEANING BLOCK FOR SOLID SURFACES - Google Patents

SELF-ADHESIVE CLEANING BLOCK FOR SOLID SURFACES Download PDF

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Publication number
RU2009122702A
RU2009122702A RU2009122702/04A RU2009122702A RU2009122702A RU 2009122702 A RU2009122702 A RU 2009122702A RU 2009122702/04 A RU2009122702/04 A RU 2009122702/04A RU 2009122702 A RU2009122702 A RU 2009122702A RU 2009122702 A RU2009122702 A RU 2009122702A
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RU
Russia
Prior art keywords
block according
phase
adhesive
detergent
adhesive material
Prior art date
Application number
RU2009122702/04A
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Russian (ru)
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RU2443770C2 (en
Inventor
Джузеппе Винченцо БОЛЬЦОНИ (IT)
Джузеппе Винченцо БОЛЬЦОНИ
Иван ВАЛЬКАРЕНГИ (IT)
Иван Валькаренги
ФЬОЛЬ Даниэле ДЕЛЬ (IT)
Фьоль Даниэле Дель
Original Assignee
Юнилевер Н.В. (Nl)
Юнилевер Н.В.
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Publication date
Application filed by Юнилевер Н.В. (Nl), Юнилевер Н.В. filed Critical Юнилевер Н.В. (Nl)
Publication of RU2009122702A publication Critical patent/RU2009122702A/en
Application granted granted Critical
Publication of RU2443770C2 publication Critical patent/RU2443770C2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0091—Dishwashing tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

1. Самоклеящийся чистящий блок для твердой поверхности, включающий ! а. фазу моющего средства, ! b. адгезионную фазу; ! в котором адгезионная фаза включает гидрофобный адгезивный материал, содержащий: ! i. 25-60 мас.%, по меньшей мере, одного гидрофобного соединения с совокупной точкой плавления 30-60°С; и !ii. 5-75 мас.% полимера, ! в котором адгезионная фаза подходит для прикрепления фазы моющего средства к твердой поверхности. ! 2. Блок по п.1, в котором сила адгезии, прикрепляющая фазу моющего средства к твердой поверхности, составляет, по меньшей мере, 0,3 Н. ! 3. Блок по п.1, в котором гидрофобное соединение выбрано из природного или минерального масла, петролатума, загущенных масел, частично гидрированных масел или жиров, силиконовых масел и производных, загущенного неполярного растворителя или неионно-генного поверхностно-активного вещества с низким HLB и их комбинаций. ! 4. Блок по п.1 или 2, в котором полимер выбран из природных и синтетических полимеров целлюлозы, полиакрилатов, поливинилпирролидона, малеинового/винилового сополимеров, полимеров на основе кремния и их смесей. ! 5. Блок по п.1, в котором адгезионная фаза дополнительно включает гидрофильный адгезивный материал. ! 6. Блок по п.4, в котором гидрофильный адгезивный материал выбран из адгезивов на основе крахмала и/или адгезивных гидрофильных полимеров и/или их комбинаций. ! 7. Блок по п.1, в котором гидрофобный адгезивный материал дополнительно включает реологический модификатор. ! 8. Блок по п.1, в котором гидрофильный адгезивный материал дополнительно включает реологический модификатор. ! 9. Блок по п.1, в котором адгезионная фаза дополнительно включает поверхностно- 1. Self-adhesive cleaning block for hard surfaces, including! but. detergent phase! b. adhesive phase; ! in which the adhesive phase includes a hydrophobic adhesive material containing:! i. 25-60 wt.%, At least one hydrophobic compound with a total melting point of 30-60 ° C; and! ii. 5-75 wt.% Polymer,! in which the adhesive phase is suitable for attaching the phase of the detergent to a solid surface. ! 2. The block according to claim 1, in which the adhesion force, attaching the phase of the detergent to a solid surface, is at least 0.3 N.! 3. The block according to claim 1, in which the hydrophobic compound is selected from natural or mineral oil, petrolatum, thickened oils, partially hydrogenated oils or fats, silicone oils and derivatives, thickened non-polar solvent or non-ionic surfactant with low HLB and their combinations. ! 4. The block according to claim 1 or 2, in which the polymer is selected from natural and synthetic polymers of cellulose, polyacrylates, polyvinylpyrrolidone, maleic / vinyl copolymers, polymers based on silicon and mixtures thereof. ! 5. The block according to claim 1, in which the adhesive phase further comprises a hydrophilic adhesive material. ! 6. The block according to claim 4, in which the hydrophilic adhesive material is selected from adhesives based on starch and / or adhesive hydrophilic polymers and / or combinations thereof. ! 7. The block according to claim 1, in which the hydrophobic adhesive material further includes a rheological modifier. ! 8. The block according to claim 1, in which the hydrophilic adhesive material further includes a rheological modifier. ! 9. The block according to claim 1, in which the adhesive phase further includes a surface

Claims (14)

1. Самоклеящийся чистящий блок для твердой поверхности, включающий1. Self-adhesive cleaning block for a hard surface, including а. фазу моющего средства,but. detergent phase b. адгезионную фазу;b. adhesive phase; в котором адгезионная фаза включает гидрофобный адгезивный материал, содержащий:in which the adhesive phase includes a hydrophobic adhesive material containing: i. 25-60 мас.%, по меньшей мере, одного гидрофобного соединения с совокупной точкой плавления 30-60°С; иi. 25-60 wt.%, At least one hydrophobic compound with a total melting point of 30-60 ° C; and ii. 5-75 мас.% полимера,ii. 5-75 wt.% Polymer, в котором адгезионная фаза подходит для прикрепления фазы моющего средства к твердой поверхности.in which the adhesive phase is suitable for attaching the phase of the detergent to a solid surface. 2. Блок по п.1, в котором сила адгезии, прикрепляющая фазу моющего средства к твердой поверхности, составляет, по меньшей мере, 0,3 Н.2. The block according to claim 1, in which the adhesion force, attaching the phase of the detergent to a solid surface, is at least 0.3 N. 3. Блок по п.1, в котором гидрофобное соединение выбрано из природного или минерального масла, петролатума, загущенных масел, частично гидрированных масел или жиров, силиконовых масел и производных, загущенного неполярного растворителя или неионно-генного поверхностно-активного вещества с низким HLB и их комбинаций.3. The block according to claim 1, in which the hydrophobic compound is selected from natural or mineral oil, petrolatum, thickened oils, partially hydrogenated oils or fats, silicone oils and derivatives, thickened non-polar solvent or non-ionic surfactant with low HLB and their combinations. 4. Блок по п.1 или 2, в котором полимер выбран из природных и синтетических полимеров целлюлозы, полиакрилатов, поливинилпирролидона, малеинового/винилового сополимеров, полимеров на основе кремния и их смесей.4. The block according to claim 1 or 2, in which the polymer is selected from natural and synthetic polymers of cellulose, polyacrylates, polyvinylpyrrolidone, maleic / vinyl copolymers, polymers based on silicon and mixtures thereof. 5. Блок по п.1, в котором адгезионная фаза дополнительно включает гидрофильный адгезивный материал.5. The block according to claim 1, in which the adhesive phase further comprises a hydrophilic adhesive material. 6. Блок по п.4, в котором гидрофильный адгезивный материал выбран из адгезивов на основе крахмала и/или адгезивных гидрофильных полимеров и/или их комбинаций.6. The block according to claim 4, in which the hydrophilic adhesive material is selected from adhesives based on starch and / or adhesive hydrophilic polymers and / or combinations thereof. 7. Блок по п.1, в котором гидрофобный адгезивный материал дополнительно включает реологический модификатор.7. The block according to claim 1, in which the hydrophobic adhesive material further includes a rheological modifier. 8. Блок по п.1, в котором гидрофильный адгезивный материал дополнительно включает реологический модификатор.8. The block according to claim 1, in which the hydrophilic adhesive material further includes a rheological modifier. 9. Блок по п.1, в котором адгезионная фаза дополнительно включает поверхностно-активное вещество.9. The block according to claim 1, in which the adhesive phase further comprises a surfactant. 10. Блок по п.1, который дополнительно включает промежуточную фазу между фазой моющего средства и адгезионной фазой.10. The block according to claim 1, which further comprises an intermediate phase between the detergent phase and the adhesive phase. 11. Способ обеспечения гигиены в туалете, включающий стадию нанесения блока по пп.1-9 на поверхность туалета.11. A method of providing hygiene in the toilet, comprising the step of applying the block according to claims 1 to 9 on the surface of the toilet. 12. Способ по п.11, в котором остатки адгезионной фазы легко счищаются или смываются после использования фазы моющего средства.12. The method according to claim 11, in which the residual adhesive phase is easily cleaned or washed off after using the detergent phase. 13. Способ мытья посуды, включающий стадии нанесения блока, заявленного в пп.1-9, на кухонную раковину и заполнения раковины водой.13. A method of washing dishes, including the stage of applying the block, as claimed in claims 1 to 9, on the kitchen sink and filling the sink with water. 14. Способ мытья посуды, включающий стадию нанесения блока, заявленного в пп.1-9, на внутреннюю часть посудомоечной машины. 14. A method of washing dishes, including the step of applying the block, as claimed in claims 1 to 9, on the inside of the dishwasher.
RU2009122702/04A 2006-11-16 2007-11-02 Self-adhesive cleaning unit for solid surfaces RU2443770C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06124234 2006-11-16
EP06124234.3 2006-11-16

Publications (2)

Publication Number Publication Date
RU2009122702A true RU2009122702A (en) 2010-12-27
RU2443770C2 RU2443770C2 (en) 2012-02-27

Family

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Country Status (14)

Country Link
EP (1) EP2082020B1 (en)
CN (1) CN101535463B (en)
AR (1) AR063824A1 (en)
AU (1) AU2007321362B2 (en)
BR (1) BRPI0718778B1 (en)
CL (1) CL2007003287A1 (en)
HK (1) HK1134517A1 (en)
MX (1) MX2009005178A (en)
MY (1) MY153644A (en)
PL (1) PL2082020T3 (en)
RU (1) RU2443770C2 (en)
UA (1) UA97967C2 (en)
WO (1) WO2008058853A1 (en)
ZA (1) ZA200902458B (en)

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Also Published As

Publication number Publication date
HK1134517A1 (en) 2010-04-30
AU2007321362A1 (en) 2008-05-22
UA97967C2 (en) 2012-04-10
EP2082020B1 (en) 2012-08-22
AU2007321362B2 (en) 2010-09-02
WO2008058853A1 (en) 2008-05-22
CN101535463A (en) 2009-09-16
RU2443770C2 (en) 2012-02-27
BRPI0718778B1 (en) 2017-11-21
AR063824A1 (en) 2009-02-18
PL2082020T3 (en) 2012-11-30
MX2009005178A (en) 2009-05-25
BRPI0718778A2 (en) 2015-01-06
CL2007003287A1 (en) 2008-06-20
CN101535463B (en) 2013-07-17
EP2082020A1 (en) 2009-07-29
MY153644A (en) 2015-03-13
ZA200902458B (en) 2010-07-28

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