RU2005129117A - Способ получения "живых" радикальных полимеров и полимеры - Google Patents
Способ получения "живых" радикальных полимеров и полимеры Download PDFInfo
- Publication number
- RU2005129117A RU2005129117A RU2005129117/04A RU2005129117A RU2005129117A RU 2005129117 A RU2005129117 A RU 2005129117A RU 2005129117/04 A RU2005129117/04 A RU 2005129117/04A RU 2005129117 A RU2005129117 A RU 2005129117A RU 2005129117 A RU2005129117 A RU 2005129117A
- Authority
- RU
- Russia
- Prior art keywords
- polymers
- aryl
- radical polymer
- living radical
- alkyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C395/00—Compounds containing tellurium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/04—Azo-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (5)
1. Способ получения "живого" радикального полимера, отличающийся тем, что виниловый мономер полимеризуют с использованием теллурорганического соединения, представленного формулой (1), и инициатора полимеризации азо-типа
где R1 означает C1-C8-алкил, арил, замещенный арил или ароматическую гетероциклическую группу, каждый из R2 и R3 означает атом водорода или C1-C8-алкил и R4 означает арил, замещенный арил, ароматическую гетероциклическую группу, ацил, оксикарбонил или циано.
2. Способ получения "живого" радикального полимера по п.1, где температура полимеризации составляет от 40 до 100°C и время полимеризации изменяется в пределах от 1 до 15 ч.
3. Способ получения "живого" радикального полимера по п.2, где температура полимеризации составляет от 40 до 80°C и время полимеризации изменяется в пределах от 1 до 5 ч.
4. "Живой" радикальный полимер, полученный путем полимеризации винилового мономера с использованием теллурорганического соединения, представленного формулой (1), и инициатора полимеризации азо-типа.
5. Смесь теллурорганического соединения, представленного формулой (1), и инициатора полимеризации азо-типа.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003-38590 | 2003-02-17 | ||
| JP2003038590 | 2003-02-17 | ||
| JP2003331544 | 2003-09-24 | ||
| JP2003-331544 | 2003-09-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005129117A true RU2005129117A (ru) | 2006-01-27 |
| RU2315775C2 RU2315775C2 (ru) | 2008-01-27 |
Family
ID=32871202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005129117/04A RU2315775C2 (ru) | 2003-02-17 | 2004-02-17 | Способ получения "живых" радикальных полимеров и полимеры |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20060135711A1 (ru) |
| EP (1) | EP1595894B1 (ru) |
| JP (1) | JP3845108B2 (ru) |
| KR (1) | KR100633200B1 (ru) |
| CN (1) | CN1820030B (ru) |
| AT (1) | ATE528323T1 (ru) |
| AU (1) | AU2004210796B2 (ru) |
| CA (1) | CA2523112C (ru) |
| RU (1) | RU2315775C2 (ru) |
| TW (1) | TWI276641B (ru) |
| WO (1) | WO2004072126A1 (ru) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4107996B2 (ja) * | 2003-04-25 | 2008-06-25 | 大塚化学株式会社 | リビングラジカルポリマーの製造方法及びポリマー |
| TWI288139B (en) * | 2003-04-25 | 2007-10-11 | Otsuka Chemical Co Ltd | Living radical polymer, manufacturing method thereof and mixture therefor |
| JP2005126459A (ja) * | 2003-10-21 | 2005-05-19 | Jsr Corp | 酸解離性基含有樹脂およびその製造方法 |
| JP2005344009A (ja) * | 2004-06-03 | 2005-12-15 | Shin Etsu Chem Co Ltd | レジスト材料用高分子化合物及びその製造方法並びに化学増幅ポジ型レジスト材料 |
| JP4539843B2 (ja) * | 2005-02-17 | 2010-09-08 | 国立大学法人神戸大学 | 有機テルル化合物を用いた水性液の製造方法 |
| ES2336473T5 (es) * | 2005-09-26 | 2014-01-07 | Nippon Shokubai Co., Ltd. | Polímero, procedimiento para su preparación y mezcla de cemento que lo contiene |
| TWI347337B (en) * | 2006-04-14 | 2011-08-21 | Otsuka Chemical Co Ltd | Resin composition and heat resistant adhesive |
| JP5417600B2 (ja) * | 2008-02-15 | 2014-02-19 | 大塚化学株式会社 | 水性顔料分散体及びコーティング剤 |
| JP2009270105A (ja) * | 2008-04-11 | 2009-11-19 | Otsuka Chem Co Ltd | ポリマーアロイ用相溶化剤およびポリマーアロイ調製用マスターバッチ |
| CN103113278A (zh) * | 2013-02-03 | 2013-05-22 | 北京化工大学 | 有机碲化合物链转移剂的合成方法及其在活性自由基聚合的应用 |
| US10676575B2 (en) | 2016-10-06 | 2020-06-09 | Johnson & Johnson Vision Care, Inc. | Tri-block prepolymers and their use in silicone hydrogels |
| CN110418806B (zh) * | 2017-03-09 | 2022-02-22 | Ａｇｃ株式会社 | 聚合物的制造方法 |
| KR102549951B1 (ko) | 2017-04-28 | 2023-06-29 | 고쿠리츠 다이가쿠 호진 교토 다이가쿠 | 유기 텔루륨 화합물 및 그의 제조 방법, 리빙 라디칼 중합 개시제, 비닐 중합체의 제조 방법, 그리고 비닐 중합체 |
| US10996491B2 (en) | 2018-03-23 | 2021-05-04 | Johnson & Johnson Vision Care, Inc. | Ink composition for cosmetic contact lenses |
| US11891526B2 (en) | 2019-09-12 | 2024-02-06 | Johnson & Johnson Vision Care, Inc. | Ink composition for cosmetic contact lenses |
| EP4190868A1 (en) | 2020-07-30 | 2023-06-07 | Nippon Kayaku Kabushiki Kaisha | Colored dispersion for inkjet, inkjet recording ink, and inkjet recording method |
| US20230312974A1 (en) | 2020-09-09 | 2023-10-05 | Nippon Paint Automotive Coatings Co., Ltd. | Composition for coating materials |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4124633A (en) * | 1977-08-01 | 1978-11-07 | Atlantic Richfield Company | Tellurium catalyzed decomposition of peroxide intermediates resulting from the autoxidation of unsaturated aldehydes |
| US6518364B2 (en) * | 2000-09-28 | 2003-02-11 | Symyx Technologies, Inc. | Emulsion living-type free radical polymerization, methods and products of same |
| US7276569B2 (en) * | 2002-08-06 | 2007-10-02 | Otsuka Chemical Co., Ltd. | Organic tellurium compound, process for producing the same, living radical polymerization initiator, process for producing polymer with the same, and polymer |
| RU2285010C2 (ru) * | 2002-08-08 | 2006-10-10 | Оцука Кемикал Ко., Лтд. | Способ получения полимеров "живой" радикальной полимеризацией и соответствующие полимеры |
| JP4360829B2 (ja) * | 2003-04-25 | 2009-11-11 | 大塚化学株式会社 | 有機テルル化合物の製造方法 |
-
2004
- 2004-02-17 WO PCT/JP2004/001707 patent/WO2004072126A1/ja active IP Right Grant
- 2004-02-17 RU RU2005129117/04A patent/RU2315775C2/ru not_active IP Right Cessation
- 2004-02-17 EP EP04711754A patent/EP1595894B1/en not_active Expired - Lifetime
- 2004-02-17 AT AT04711754T patent/ATE528323T1/de not_active IP Right Cessation
- 2004-02-17 AU AU2004210796A patent/AU2004210796B2/en not_active Expired
- 2004-02-17 CN CN2004800043675A patent/CN1820030B/zh not_active Expired - Lifetime
- 2004-02-17 TW TW093103713A patent/TWI276641B/zh not_active IP Right Cessation
- 2004-02-17 US US10/545,310 patent/US20060135711A1/en not_active Abandoned
- 2004-02-17 KR KR1020057015028A patent/KR100633200B1/ko active IP Right Grant
- 2004-02-17 CA CA002523112A patent/CA2523112C/en not_active Expired - Fee Related
- 2004-02-17 JP JP2005505028A patent/JP3845108B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20060135711A1 (en) | 2006-06-22 |
| AU2004210796B2 (en) | 2007-07-19 |
| ATE528323T1 (de) | 2011-10-15 |
| EP1595894B1 (en) | 2011-10-12 |
| CA2523112A1 (en) | 2004-08-26 |
| CN1820030A (zh) | 2006-08-16 |
| CA2523112C (en) | 2009-11-10 |
| EP1595894A1 (en) | 2005-11-16 |
| AU2004210796A1 (en) | 2004-08-26 |
| JP3845108B2 (ja) | 2006-11-15 |
| TW200426158A (en) | 2004-12-01 |
| KR20050111325A (ko) | 2005-11-24 |
| TWI276641B (en) | 2007-03-21 |
| WO2004072126A1 (ja) | 2004-08-26 |
| KR100633200B1 (ko) | 2006-10-11 |
| JPWO2004072126A1 (ja) | 2006-06-01 |
| EP1595894A4 (en) | 2007-05-30 |
| CN1820030B (zh) | 2010-10-06 |
| RU2315775C2 (ru) | 2008-01-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20070119 |
|
| FZ9A | Application not withdrawn (correction of the notice of withdrawal) |
Effective date: 20070405 |
|
| FZ9A | Application not withdrawn (correction of the notice of withdrawal) |
Effective date: 20070405 |
|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200218 |