RU2004136585A - Секция установки и способ разложения и очистки синтез-газа - Google Patents
Секция установки и способ разложения и очистки синтез-газа Download PDFInfo
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
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- F25J3/0276—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of H2/N2 mixtures, i.e. of ammonia synthesis gas
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- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
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- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0223—H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0261—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0271—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of H2/CO mixtures, i.e. of synthesis gas
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/70—Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
- F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/30—Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/42—Nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
- F25J2270/904—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration by liquid or gaseous cryogen in an open loop
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/92—Carbon monoxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/931—Recovery of hydrogen
- Y10S62/934—From nitrogen
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Claims (14)
1. Секция установки для разложения и очистки синтез-газа, отличающаяся тем, что она имеет устройство для парциальной конденсации синтез-газа и устройство для промывки азота, причем устройство для промывки азота примыкает к устройству для парциальной конденсации.
2. Секция установки по п.1, отличающаяся тем, что она включает в себя следующие соединенные друг с другом устройства:
теплообменник А для охлаждения синтез-газа, подаваемого в секцию установки;
соединенный с теплообменником А сепаратор В для разделения синтез-газа 2 на газовую фракцию 4, состоящую в основном из водорода и моноксида углерода, и жидкую фракцию 5, состоящую в основном из моноксида углерода и метана;
выпарной аппарат С для дальнейшего разделения газовой фракции 4, направляемой из сепаратора В, на газовую фракцию 6, состоящую главным образом из водорода, и жидкость 7, состоящую главным образом из моноксида углерода;
выпарной аппарат D, в котором происходит испарение абсорбированного в жидкости 7 водорода и из которого остаточная, содержащая в основном моноксид углерода жидкость 8 может быть направлена в дистилляционную колонну F;
еще один выпарной аппарат Е, в котором остатки водорода, абсорбированные в жидкой фракции 5 сепаратора В, удаляется путем испарения и из которого содержащая в основном моноксид углерода и метан жидкость 9 может быть направлена в дистилляционную колонну F;
дистилляционную колонну F для отделения газообразного моноксида углерода и получения метана в виде жидкости, отбираемой из нижней части колонны; и
промывную колонну G для отделения жидким азотом примесей из содержащей в основном водород газовой фракции 6 выпарного аппарата С и утилизации примесей в виде горючего газа 12.
3. Секция установки по п.1 или 2, отличающаяся тем, что теплообменник А может иметь множество подводящих линий для газа и жидкости и охлаждать или нагревать их до заданных температур.
4. Секция установки по п.1 или 2, отличающаяся тем, что выпарные аппараты С, D и Е представляют собой выпарные аппараты мгновенного испарения, с помощью которых возможно удаление растворенного в жидкости газа.
5. Секция установки по п.1 или 2, отличающаяся тем, что дистилляционная колонна F имеет теплообменник, через который пропускается синтез-газ произвольного состава, или предусмотренный в нижней части колонны отвод для собирающейся в ней жидкости, которая после прохождения через теплообменник А может быть возвращена в дистилляционную колонну.
6. Секция установки по п.1или 2, отличающаяся тем, что промывная колонна G имеет подводящие линии для газообразного и жидкого азота.
7. Способ разложения и очистки синтез-газа в секции установки по одному из пп.1-6, отличающийся тем, что вначале проводят парциальную конденсацию синтез-газа и затем его промывку жидким азотом.
8. Способ по п.7, отличающийся тем, что в сепараторе В синтез-газ 2 разделяется на газовую фракцию 4, состоящую в основном из водорода и моноксида углерода, и жидкую фракцию 5, состоящую в основном из моноксида углерода и метана, при давлении около 78 бар и температуре -171±10°С.
9. Способ по п.7 или 8, отличающийся тем, что в выпарном аппарате С газовая фракция 4 разделяется на состоящую преимущественно из водорода газовую фракцию 6 и на состоящую преимущественно из моноксида углерода жидкость 7 при давлении около 78 бар и температуре -195±10°С.
10. Способ по п.7, отличающийся тем, что в выпарном аппарате D абсорбированный в жидкости 7 водород испаряется при давлении 6 бар и температуре -195±10°С.
11. Способ по п.7, отличающийся тем, что в выпарном аппарате Е абсорбированный в жидкости 5 водород испаряется при давлении 6 бар и температуре -171±10°С.
12. Способ по п.7, отличающийся тем, что дистилляционная колонна F для отделения моноксида углерода работает при давлении около 5 бар и температуре в верхней части колонны около -175°С и в нижней части колонны около -155°С.
13. Способ по п.7, отличающийся тем, что промывная колонна G для отделения жидким азотом примесей из содержащей в основном водород газовой фракции 6 работает при давлении около 77 бар и температуре -185°С±10°.
14. Способ по п.7, отличающийся тем, что молярное отношение водорода к азоту в газовой смеси, отводимой из верхней части промывной колонны, устанавливают равным приблизительно 3:1 путем подвода газообразного азота.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10226210A DE10226210A1 (de) | 2002-06-13 | 2002-06-13 | Anlagenteil zur Zerlegung und Reinigung von Synthesegas |
DE10226210.1 | 2002-06-13 |
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RU2004136585A true RU2004136585A (ru) | 2005-07-10 |
RU2296704C2 RU2296704C2 (ru) | 2007-04-10 |
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RU2004136585/15A RU2296704C2 (ru) | 2002-06-13 | 2003-03-22 | Секция установки и способ для разделения и очистки синтез-газа |
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US (1) | US7269972B2 (ru) |
EP (1) | EP1490295B2 (ru) |
JP (1) | JP4708017B2 (ru) |
AU (1) | AU2003214251A1 (ru) |
DE (2) | DE10226210A1 (ru) |
RU (1) | RU2296704C2 (ru) |
WO (1) | WO2003106331A1 (ru) |
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DE102006056642A1 (de) * | 2006-11-30 | 2008-06-05 | Linde Ag | Verfahren und Vorrichtung zur Gewinnung von Produkten aus Synthesegas |
US9243842B2 (en) * | 2008-02-15 | 2016-01-26 | Black & Veatch Corporation | Combined synthesis gas separation and LNG production method and system |
US8640495B2 (en) * | 2009-03-03 | 2014-02-04 | Ait Products and Chemicals, Inc. | Separation of carbon monoxide from gaseous mixtures containing carbon monoxide |
CN102153109B (zh) * | 2010-11-10 | 2012-09-19 | 天脊煤化工集团股份有限公司 | 鲁奇煤制氨液氮洗尾气馏份循环利用方法 |
CN103328375B (zh) * | 2011-01-17 | 2016-02-10 | 乔治洛德方法研究和开发液化空气有限公司 | 使用低温分离生产氨合成气和纯甲烷的方法和装置 |
WO2013078606A1 (en) * | 2011-11-29 | 2013-06-06 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process and apparatus for the purification of hydrogen by cryogenic nitrogen wash and co-production of liquid methane |
FR3011069B1 (fr) * | 2013-09-24 | 2015-09-11 | Air Liquide | Procede et appareil de separation cryogenique d'un melange contenant au moins du monoxyde de carbone, de l'hydrogene et de l'azote |
US10436505B2 (en) * | 2014-02-17 | 2019-10-08 | Black & Veatch Holding Company | LNG recovery from syngas using a mixed refrigerant |
US20210254891A1 (en) * | 2020-02-14 | 2021-08-19 | Joseph Michael Schwartz | Method for an improved partial condensation carbon monoxide cold box operation |
RU2751758C1 (ru) * | 2020-11-03 | 2021-07-16 | Юрий Иванович Духанин | Водородная криогенная система с колонной низкотемпературной ректификации газовой смеси |
US20230249970A1 (en) * | 2022-02-08 | 2023-08-10 | Air Products And Chemicals, Inc. | Method for producing high purity hydrogen |
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US3186145A (en) * | 1963-01-28 | 1965-06-01 | Chemical Construction Corp | Absorption of impurities from hydrogencarbon monoxide synthesis gas |
US3872025A (en) * | 1969-10-31 | 1975-03-18 | Bethlehem Steel Corp | Production and utilization of synthesis gas |
DE2624857A1 (de) * | 1975-06-05 | 1976-12-16 | Bamag Verfahrenstechnik Gmbh | Verfahren zur vergasung von kohlenstoffhaltigem material |
JPS57122026A (en) * | 1980-09-04 | 1982-07-29 | Ici Ltd | Manufacture of carbon compound from carbon monoxide and hydrogen |
US4338107A (en) * | 1980-10-30 | 1982-07-06 | Union Carbide Corporation | Wash system gas separation |
DE3201776A1 (de) * | 1982-01-21 | 1983-09-08 | Krupp-Koppers Gmbh, 4300 Essen | Verfahren zur gleichzeitigen erzeugung von methanol- und ammoniak-synthesegas. |
IN160585B (ru) * | 1983-02-14 | 1987-07-18 | Exxon Research Engineering Co | |
US5180570A (en) * | 1992-01-23 | 1993-01-19 | Lee Jing M | Integrated process for making methanol and ammonia |
IT1275404B1 (it) * | 1994-02-07 | 1997-08-05 | Spherilene Srl | Composizioni poliolefiniche utilizzabili per la preparazione di articoli per uso biomedicale |
JP3415748B2 (ja) * | 1996-07-15 | 2003-06-09 | 株式会社荏原製作所 | 有機性廃棄物の二段ガス化方法及び装置 |
EP0905127B1 (en) * | 1997-09-20 | 2001-11-28 | Urea Casale S.A. | Process for combined production of ammonia and urea |
GB9800692D0 (en) * | 1998-01-13 | 1998-03-11 | Air Prod & Chem | Separation of carbon monoxide from nitrogen-contaminated gaseous mixtures also containing hydrogen and methane |
FR2775276B1 (fr) * | 1998-02-20 | 2002-05-24 | Air Liquide | Procede et installation de production de monoxyde de carbone et d'hydrogene |
FR2775275B1 (fr) * | 1998-02-20 | 2000-05-19 | Air Liquide | Procede et installation pour la production combinee d'un melange de synthese d'ammoniac et de monoxyde de carbone |
DE69835357T2 (de) * | 1998-11-03 | 2007-08-23 | Ammonia Casale S.A. | Verfahren zur Herstellung von Synthesegas |
-
2002
- 2002-06-13 DE DE10226210A patent/DE10226210A1/de not_active Ceased
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2003
- 2003-03-22 DE DE50300917T patent/DE50300917D1/de not_active Expired - Lifetime
- 2003-03-22 AU AU2003214251A patent/AU2003214251A1/en not_active Abandoned
- 2003-03-22 WO PCT/EP2003/003010 patent/WO2003106331A1/de active IP Right Grant
- 2003-03-22 EP EP03709810A patent/EP1490295B2/de not_active Expired - Lifetime
- 2003-03-22 RU RU2004136585/15A patent/RU2296704C2/ru not_active IP Right Cessation
- 2003-03-22 US US10/503,484 patent/US7269972B2/en not_active Expired - Fee Related
- 2003-03-22 JP JP2004513170A patent/JP4708017B2/ja not_active Expired - Fee Related
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DE50300917D1 (de) | 2005-09-08 |
RU2296704C2 (ru) | 2007-04-10 |
US7269972B2 (en) | 2007-09-18 |
AU2003214251A1 (en) | 2003-12-31 |
JP4708017B2 (ja) | 2011-06-22 |
EP1490295A1 (de) | 2004-12-29 |
WO2003106331A1 (de) | 2003-12-24 |
EP1490295B2 (de) | 2009-11-04 |
DE10226210A1 (de) | 2004-01-08 |
US20050076672A1 (en) | 2005-04-14 |
JP2005529222A (ja) | 2005-09-29 |
EP1490295B1 (de) | 2005-08-03 |
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