PT89423A - Processo para a preparacao de resinas epoxi avancadas modificadas - Google Patents

Processo para a preparacao de resinas epoxi avancadas modificadas Download PDF

Info

Publication number
PT89423A
PT89423A PT89423A PT8942389A PT89423A PT 89423 A PT89423 A PT 89423A PT 89423 A PT89423 A PT 89423A PT 8942389 A PT8942389 A PT 8942389A PT 89423 A PT89423 A PT 89423A
Authority
PT
Portugal
Prior art keywords
γχχ
formula
quot
compound
epoxy resins
Prior art date
Application number
PT89423A
Other languages
English (en)
Other versions
PT89423B (pt
Inventor
John L Massingill Jr
Raul A Pabon Jr
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of PT89423A publication Critical patent/PT89423A/pt
Publication of PT89423B publication Critical patent/PT89423B/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C08G59/1422—Polycondensates modified by chemical after-treatment with inorganic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1488—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/226—Mixtures of di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

ο DESCRIÇÃO DA PATENTE DE INVENÇÃO N-° 89 423
REQUERENTE: THE DOW CHEMICAL COMPANY, norte-americana, com sede em 20 30 Dow Center, Abbott Road, Midland, Michigan 48640 Estados Unidos da América do Norte. EPÍGRAFE: ·· PROCESSO PARA A PREPARAÇAO DE RESINAS EPOXI AVANÇADAS MODIFICADAS INVENTORES: John L.Massingill, Jr. e Raul A Pabon, Jr.
Reivindicação do direito de prioridade ao abrigo do artigo 4.° da Convenção de Paris de 20 de Março de 1883. Estados Unidos da América do Norte,em 13 de Janeiro de 1988, sob ο ηδ . 143,558. INP1. MOO. 113 RF 16732
Λ r ο d»:
•·γ ιΛ μ - z ρδ Γ' t: z ο-: ?' 1:9 15 O O que ϊ;:! 9:’9po ·.·:£-· . :' L·* r-: ...· c·. * om-itico 5 -7- - * :-7-:7.7.--:9: .. Λ-.:::.. 7 7 9 I ~ -1 9 I 9 z-.-ij z. s r £ z L; ' z -o • ; .. q - :è ^ .- r - · v 1 Υ ΟΖ 7 λ. Τ.Ο I !-·'ΟΓ .37-779.:- • c: - · òy i ·.: 0 ou L-<7i ;J S -- rr r > :-3 1 7’9 73 199 5 ppo: < i .-7-:.7 .9 v z μ ·';· i .· Z'„- p : ;"·: = π··μ *; Άο Ρ 7: T. 9 9:-:77 7- •p r 1 i. μ-1 i. 1 pí Zp· z : ao-.r Z-.-i , 7’ e £71. s ι ·! 1 1 · ’ : ρ μ q-O i*·:· L V-:--1 t-p: . I Π'Γ íí I i Z ‘*r:-l ·.- · * . · - ··· 7.3 T — ; 7 £ j- £ 7 ' : 1' 9 9 .. Π 7 '7-· C I -.Τ'·-. *5 7- 9 i C -7- 77 ;77 ; ' 77 L 77 Ϊ. 7 L ' 7 9 Ο 9 5. 1 '.7 7 -.-3 L £ -' 9 7 ' .7 ·. ‘7.7 7- 7' - I .7- ‘ 7 . ' 7 ' 77 77 ' * T-P 9. t 1 V 77 7'' "77 ' I 1 '71 77 7 7 *~ Γ 77 7 . ; 7 ‘ ’’ ‘1' ' ‘Vi -77 7 - 7 7 1 97 5 .J 7
7 -.- 'l 7 7-7 - 7 Γ '77* 3 ‘7 7 77 7:^7)7. 7 9 1 I T P. 7- I L 9. '5 '-7. 7-' .7 P .£ ^ ,7 7 -7 £7 .7 :£. - £ 7, C 0' 9) · :'£ 37 I 1 ; ’ 7 -7-7 7. 7· 9 .7£' 77· 777 7 77.777 777 V 7 5COS 1 0! 9. C:‘9 75 O '7 77.· I 7' 3 : i ‘7 7-09 :P7‘ 77 l'1 7 0‘ '-7 £ O- - 7·' i. 7- 77 7 7 : 77 .7.' ’ '77 .7 I 7.7 7- 77 Γ:7 I d 7*1 9 1 O -77. 77 7 -7“*. 9 77 77 7 : 77 I V 77 7 O 7' -- w 7 7- --7 p '·' O .' 7 7 £ -£- : - 0- i .! 7 o 5 . -γ·7-·'·'£ ·...... v--1. t-ο.’r resmoí -pPO-p : 7-- 7^-:007: 9 : .opo-o : ^ 5 7 - --7-.-7- 7 .7' 7-77-7- . _ - i -- 7 - ’ -7 0 d -77- 7777 '73 9 V i SC 7- - I - 7--7-.7--7 ·. 7- - I ’ - - 7 77 — · 7' ' --77 9 0 7 7 -’ 7- ·£ : ·: : u··· ·5.£ΡρΡ9: cP- · :.··-- apropriado, ·.··_·pío-icoí io-po, -* 7 -· 7 res i sc-íp: ip 77 sou: o produtos qu 1 m 1 cos o soi v inta= . o--- asp*c to 00 presente i nven to o 12. o·:--:-; to o:
1 : 777' -7- 7 ·. 7. -7-7. V-i-,: 7 v 77 O 77 Tif >_'0 1 f I 7 9 O - 9. 9 7 -5 1 Γ - _ - . - i £ .-7 O - 7’ -77 P -.£ -£ τ- O i A.- uma o-.- s i! £ p. epox i svsricsdo puo re»u i :· 5 o·?, r* 5.; c-.-. o · 1: 099 composição resina epo·<i c-:--99--ee,--:-7.7:;:· ' 7- 7 P 7"7 7 O* MienOS 7-:- -7 :*-::- i 7*7-77 7 — 1 - -. - - rP: 7 9 -7:-:777-. :9777 p;7pi e.romàt l iço ; ; ϊ ^ -j o p * i p -9..9 7::-:-7.- ΠΡΟ ΓίίΡΙΡ 07-9 c; 7..:.9 doii 9 !'7--9··7;'9 7:9-“.--: V L 7' 7 97*--9 9 9.. -77 -7.7 i. 77 -.; I, £ .7. p e pop c on '-ip.v* 9.,91.:: 777977.:9 99 ριρρ 1 a i pui i eno ou 07-7:191-9:91 79-:1-: :-7.1-77.1 7 :.7-79 7- -: :: 79 Ϊ. p ·.-: i .9. · è
X : j . : :..p---0 r.-r.-O'; ·. qxx ce ·*«:<?* rr 1 ' 0: ;·:·.· l x q * 3. x x. ; .·- i': ·. - : q 1 qx arn P 1' ^-q.: t-í; X ^Π> qo-o-oo-: 00 - ο 5 a I 0 0- eqo4 i v aieró-ee ν : -_ -.- -_- —,' o vo.-J-.-b αό · ·.--···- o-·-:.,· x va ianies por cent- ·.·· - Γ : - - r-Oo-O GO *0 οο,ροηοπ t- ' 1 Pr,' ο,·: i -2. .---.-10 OÔP03 o«m coiiiposio i 0--:3.: qrapoa πιο-:·-; ; -:-"θΓ·-ϊί.: rri·; por -TíO i õc o 1 ο ; vp qo-o -.-.- -:..--0 v 1 a 02,- 5 ào Of.ipragados O-Oi q..---P O t- I Ο .Η-·;.--;. -íu for 00-..-0-,7, -'.ov-ã i OOCPJ ·. : ‘ V ·'·: 03 Ç-rO-rpõO o 1 O Γ -:-:-. .·: · -.· r 0 0-cr qro-ip·.:· ê?ox : ds C·1.OuS 1 1 a 2oo; ; 1 ; cor : O··· C ÕO-PÕ··.-to contendo fooforo S-O-C-OOO,;:;:; porro c 1 ·: x o o f co o fòr i c o ; • 22) o·: ido- i-Or-cO ·’ f o-afór i ; .0 - ' t_- 0 -r -' -- ' O b 7 ã. 0 ·_ , - ·'· -OJ-O i -L-í r COilÇDÍir-iÇõO 0-0; C 0-:--0-.0 O -:-0.- -. - : - - c·'- 2..' -..-0- : 2- — -! , O-0--O 0-0 ·: ·........t C- ·;'· t A '} Õ ' ·;, - τ * · - 0 T C-O 0: 00:,---0 ‘0,0- .0 1 T. ; — o- a coiocoo ae mo 1 es do compon-e-po-a· · 2- ) poro -oo prop-oa •0 : 1 C 0-0 0 1 Gõ-i C ΟΡΡΌPõP Í-G Ó õ: J ô G0 0- ; i , X -o. ô 1 . ? 1 o! ·ι·;ο q qq ooo-i o- r c· sop-ic ío do presence ρνο,ο : :·:·,p c-o, i ; 2 -o c o- r a ve i -a ρο-ia 2 corirproero-r 0 x ) ’ I 'M-o-T. Γ; I 1' ' JIO 2 I Ή-rl I -rò V roí ' — 'ôoT o;'o -r.: v 1 I :.-:···q q'.· ·:· n t· i dqqq dx ci-q q;.ropr 1 q.o-;- pq >'a ocori-qoqen^q? < I ) . r'j:? ; 'j-ipOT? i c ΰ-i-s c!o ρ ·' -f: V I 1 '._ó q 'Π: órr \ 1 X-r». } } dr
: ίν·ϊ X :;· ·' V.·-'-' 1 X i , i ·:; i “ X x ;-‘;í t ve :: í- -- •VT z ; ·*·-..· X XpOX i X. V P-- X X-. Ο por Γ ãftC -. A XX 0; c OX t- O t-ã X 7·\ 1 tu pa aã lã :-o·' a-:· i a ·: x a . oora ae iãií c ..9.,:--0-:----. ·: -a ·:- ·'·:·.— i aOa—aa to 0 · C a 3000C; ··-.· i - a----i'i a Γ 1- -J i ; .·! Γ a ·; : ISO! C , e a laioa nva i s e.propr i adamen te ae 6v ·' 0 a. taapa -a ’x : x 9- to - · coapiãta" a ra-a aí·:·, --r-:- : -x Oã 1 o. £ . xxi i o r f O!’ a Xã-i-p- r for ã tãr;:p.-?a . .. -.1 aínte íj ;·’ }" t.í J^· -a i a ae X a. o, a ?·"·:χ aax -:--- n · : aa a-v-a·’ : -a i ._i ... a ·_·; 1 _· _> -aa · - ·.·. - -s - a. I α r 1 -a n a -.9---a - -- ·, -. - - - ’ ·_ · ·.-·:-· - ρ -.- ·' -a - : v a-a ··.·-.·····. :···λ· ·'· xa e r ec t-yíaa — a pre -99-:a a-· -saia. -a.’!·-' ’’ TJri X X •'.'z -j Ό j P r.: X X1 ; X/fif J ft t I X' of p ''' oo ί ·. ro zo ·Χ:.·: Xr X z.· ..-.:-;.c--;'.-r-a-;:..:!.:.-a a:-- a-· .···'·: · ;.--:-as t-ã i a qpy a ;aa.c-o 99:.19 ·. · · 9'':-9 •lã-·'.;.:· 1 1 a a a; -g»po epO;aOO a 3 ·' OP 1 ã ::·,. 99a O X 9.99 -r- ..-.00, i , ; a -· - ·: i .--lãOãnt -a · :·: 0.3: i -:· a: i , -·- i --a - ·.: .1 v- -.-:--. !-'·' i aa 9iã9 aa d . 5 ; I a 1 i .
rz Γ τ:;3: I 1 *X X j—1 ·...· .3. 1 U cr.' X '7*. V -z*.z· 0.: X 0 XX 0 r x ; Γ· ij X ΧιΙΧΓΟ li a r Ι-ΡΟ x-x c os tem à? r op- r i ·? c· Ο-.-Γ: 1 ã a-:- i 1 ; ': -. i X pi' op i xcixrop nt-ã ao 10 a 100, seis sprupr pie ainaa 23 0 1 XX P xr ·: X ·- ·:- -:· nos orupos epox i der i vaoos ..lã .· a r -a s i na. οροί o a I I- ·: c··'· t χ-Γν 9 ··.·- -:· s ·.>:: -> 1 --vj i 1 ene· os o a. i e : oJ 1 o: ;··:· i-: to ι ·:μ· a p - =·.Ρ'' -F 1 aa-S.-.-ã 'lã Oã OãPO ã. 3O’; fé ã ± a 1-.F: -A 1- p i Χ'.:χ·χ ani-ã Oã O a 3a, XX 1 r> ep"ãp;' i èoèsenie de zero â 73 p:-- c ãt-:· ·--·> at-o; ao O X i’ I r- - J ·..' ase i'ís i na epox i a qual ã n i ã ." ã ã : -a a- asna ορο ,, 1 X ·. I Γ,. ,ã nenx i r;a sioao epoxi ipiOpaeras :,a X Γ' ·- - · ·-' z.' a;:.. — :'rX; P aa naaaia de rna is ao -a:e ·ρρ· , a: nio X - 1 Z XX a;,:ã oo*^ 9 x i : x .: 1 ρ··ο; ·· OiéCUia e 9 _ .: 1 :..3-: 0, 2. X 0 : a : ,;χ ‘Λ Ο/ \ h2c — c-ch2
R
Ο/ \ (0-Z'-)m-0-Z-0-((Z*-0-)m'—ch2 — c —ch2 I R -sis pret t-3 rapre ο ρ
1 -íím 9ΓΪ---ΡΟ » m-5is ap \
-CH-CH-
I I
R2 RI -a-:-: c: au-a- -: a aja * -a ~ 5 -a- ·. · . ’· a ·'. -·-. a. a: a i -ρν.:.,p : : : :: -:- .- " i o ' - a:- a : ou r; a .:·' o-: a r b i 1 ox a tendo ap ropr L a-J-P.::-:. :-a a oa 1 a r-aa. a-Up-:' xa uao.ic r a 1 a a-a- a s a- P rr.p : a -osao a ·._ 1 a-a í·-a.roono ου aana -g>'aa;-:-a--·-!.- T.r :· - i.i-Μ d .1 C P -a-a. o a 1 a-ano-a apropriadâMianta aa I a 12 Ml Λ 1 5 aproa Γ 1 ο· μ]·:-' ΓτΙ :· Ú; ; ^ -a a a ãp;’opi' i ãoarnenta ai nd·:· • -· i r >"· :· a -:-··--:· a li ~I- C 1· *"ΐο ; r- ·: a-.ja f :i a o ' i noapena-entamsnia te fu Ur·'. ''•' τ'··. ,L Γ a- p rop P 1 rd 'J :' I i r- ; ff-?, i s apropr iadamente de 1 a 1 0 , Γμ-:· ι ·:· próp r a acuai- õ 11·:"a-c- niarocarbi i coníopíu-í. axoa ..... :·· ~ :-o·:- .....i ’ -.5 ;· ·;ροί i tico, cic 1 o a í aá :1 : , a r -.-0- : i : o . a 1 i i a : i ·: ou a i ·.: Ϊ ·.·:; 1 i ·" a a .1 c o -:· · ι 1 ao o si- i t a-1 do, •.-a- a ; a i .·· a : ·: o a-a- c i : i. a-a i a - a a - : o arooatico uaao5. Os grupas a 1 a ia : a c a:-s -c-::-r - u--u sa aa-a- a-oa a-a: ; ii-ao a ao'oaíoa . a gua I π; £? - a ta ; o ivOOa- c l a:—pc-. .· a-a r oi a aiguo. - a ·; uo --grupo hicaocaròi 1 tenao urna 1 igaa ?-:- οχ · ge:" ι o arara eie a o a-Cijai; a;a ao aa-al está 1 iga'do. ôpoxi pârt-icula:'fi;er)t-e eps -:·.-·!· i- te o uo a-ao a a ' · o: :··. ct do -ga r-a ui! nua S Γ: a-a rna a £i 1] ο -ι·.. · -a-:-: a grupce V I Z 1 ! " “fl- 3 - a- ’-:a- a a O POi-á 1- •ziTiO 1 cua anel cr Γ Oft) m· ·.- '· c P- ΜΜχΙΊ,χί 1 ti ρ·£ 1 1 !Υ·£- mi :: : ;:r- o · ι -· i - ι -i i i eno gr:..ip o O x iai gaa a ie xo aa -a- ·: a -:a; ι cia - -..- r ÍV-O 1 -r Cola i nc J. L···: p.p. i. : - -r:; , p: i . ‘1' ; O -r? ·:: t€: P a-a g 1 i ο ι a. 1 aip :· a a a-oo a -.-a cu.-:.· !- -:-1-. -: ía- -;u.a a 1 : aua :-:up _/ -J ·.. ar ornati Γ 0 tendo aao a £. \-z-r r 1 O ' -1-;I 1 a r - r. i — poc r-aa-a r;-al- a-ar aístura :: ta a a copp-;-ar· a; Uã J. idos p-í \ Λ
i j. A , ; i n 0/ \ h2c c-ch2 - t° R \
0/ \
ο/ \ h2c — c-ch2o I R
(-CH-CH-0) m -CH2I I R2 RI O/ \c —ch2
R ia 1qu11eno suòãti
a r a ♦ -CH-CH-0-R2 R1 -0-CH-CH-
I I R2 R1 - CO:rJ Ο C 1 Ρ:Ρ· C:r:'· I ·'· L G Ο £· H :r> P £ £ 1 ' "· 3. £ e por ci ί a 15 F-a.r crcoi?c ã'·’ c a ? ap r i ··..· õ ^ -C-0 Γ-- L.-;'-P: í'-:c:cí o! d r ! · r; -r·. 1 ο do qoo O::· Cão C: C...C : - 0,0·.: o. ·-·' - _ - : —* oi ' : I V I :: i r-pio a a pelo γηenos up ane 1 a roo o iic o por o. r c. 1 o -:P·-.·.· £dP‘ I Í V P Pr £ d'£ propos ox :i a. 1 qo i 1 erso i r-o i oor , po r ext/nçp' 1 PP ; dl'. ·:!·.: il di£ c aiechol, "c = or : i no 1 , h loroqu nona. . b 1 Γ r^'P! •Ό 1 . ;r OiOjl ·-'; c> i s f Pr P: ·_ l l··. ; o · L 'o.‘ 7 c.r ; · ;d ]; o. qua. Iqu Pr Ϊ' a lo: *~·i' cr’ cr ·. · Per - cr p1 .·. 1 :—j L- cr; oc4·-* j—: P cr P -'J* ;_.· o ’_r P’-'-4 ; i P '."Ο ·_ rr los lendo írupcõ hxdroxi i ai i fazi cos que reaqi r =>p. coo ur.-a epirtí-i ·ΐ'···;'J 'i i ^oooo -si"·' prepa.rsdos por qualquer ooa rcxq.odoo coméí idos para preparação de resmas epcx i a .1 i f a i i c a s cai c omo c oroçicáo cr !'accçío c?a presença oe o?·· e.c i do ·„οριο ca] coro; por exemp i o , c ioreto escarico, ir i í iuore oo de coro - sua o cor-.oina- ocãoi c;o po;‘ oes i ο>Όgena.çSo cor·! um coniposio ocÇocoo... copo oo ;a tai oooío um π i q r ox x ao de retal alcalino. r;a i s ρχίοπνοιοοχο, estas I ‘ ' a · .·. 1 a Ό ' J 0.'- ' i_-: a :0 *' a *_.í S per I '_· 0 · 0: L a ,1.0 ·_} ·. O O : :-í O·.'·.' ’"·.· 0’· . l _· ' 0 = c a ia 1 i nadores apropr iaoos que pooeni ser empreqaGC-s : -rc* P p1 < ‘ cr P ‘ t' cõ c? i *r Oo Pf P' 4_'éá I cr·. V '.· : · v 'c? 1 ; c a P-* o;;; r ; p: ·_> P v_: cr ! r; f—; i _4 ; 1 'PP·. 3 P *Ρ P C I ·--·. P ]. r-, £· j T Oa 7 I IP P*. 'zt ·, *_ zj £'_-· P*. Γ* - PP ι 1 ·._> L 4,_· ΓΓ’ p‘ P.· cr o i \
- ·!· ·ι ·' · =1. ~ · .·. 1 ί r: ) ’ i. ·_' } 1 · _' .v.r ο· ./ '.ί οτ '_· .· ·: : ν te so ο ο ο s ι 1 :· γ· : τ ; ‘ ι —:· oirsoosii f os r Οη ί ο , ο· r ο · -τ c ο c-1 1 ί os r όπ ; ·:corno ι οοο ο·. οο : ύ 11 c ο / e so -. s c omo ι η a. · r : é ·:-’ :'·” ό'-“ .·0 ΓΡ·ΡΟ. ί· 1 '.Ir Γ-SOS S Si O S qj?Vi t K}-·.] í OOS : 1 op· r i soa·;i-.·.·rs te ‘li·? 0 . Oõe a C . 0/. = 1 ·?-. 0 . U t , moles oe ·: ? t-s 1 i zao· l sc- .-moo - · ..· .:.· ·.; l O· · SO ’:·_' α-'ΓΟΡ')' I '.vj O pO'-O.; · · r? O -... O... ' -i.. /-·-.'·-· r -. · ‘ -r·' - v i’ ·_· O -.-·. "' ί' ; - I 1 '· a r? S F1 ·—1:·. 1 -·. V S. í '· C S. O -S I i 1 ._ c S; ·.: · i O j ‘icoói s, e;í.o"íi, éteres g í i c o 1 , h i a ;'·:? a rosne t·:· ο ι I : i :· t; ·: oí , : oro·: a ‘Όοο s sos .··. i : f·-tuos ha 1 ogen ases , η i <:: r·.:··: s r o·:·/s so - a r om.-. s i — ·.· ? ?v i? .·.: .......; ·: ac óc-s Solventes ps r t· i ·: u 1 s r me'· se .v;”opí' i;·;:·:··; .·'··: /··:·"; f-o r sei-iO, solueno, xiieno ore:' eis 9:1101 s : : i ; cS-o” p 1 1 s-n·;· giicol 1011 1 , Sis-' prop : i no ;s . o í o ~ 2-ou tóx1e ta noi • e v ί i ^r-·:· } l 1 : ·: I ;:· v 1 í ·“ ivente pooe s e ·' rr “ :1! ~ ’ 1' -r- ·:;·.. -.‘Ρ'Όρ ·': ir·:;·.··'·;·^;'· v-:; c1. 'Z' 1 } f Γ:^ rt 1 =j c-1. -"Opr I 'V: e·''· Scr oe 0 a I-.o e 1 nda de S a 2' 0 por cent ·:·:·-·· c-op es1 na epox1 e •j·:· coííípOoi 0 -snn: í?·1 !Opi‘ i ac;o 3 ·: c-ntenoo fo so···:· soo PO:? ser reagir com ir. Ξ1 Γ -ir I >' s 1PO - os Γ: ; 7. .J-- s SCI CÍO f C‘S for 1 oco È-::o·, OS- ,·:Γ t ·.· / 1 0 r 1 c C‘, :er nón·ι··::η·ί t: 1 , eser r.eo coooiíscíoi. 0
pa 1 a fôrrns··la XII 1 · · 1 Far ;';c i υο- ο.··._·, :' ensep] :r seres rosfsro e soas comoí nações . ssseres ros i :· 10 r.propr 1. ;'··:! lof os ‘Ό-··νοί-'ί iocíos peila t ons 1 a X 1 I siosnXe .
Ο
, II
R3-0-P-0H ΟΗ ορρ ' é ο ο um grupo η ι i. —ρο··:· ο·.ρ rog : α:ι - - γ. η r ^ ,;:ρ t =¾ Σ'·.-, ''·. S I S Α.ΡΓΟΡΓ ί ΑΟ =>.Ρ!θη ÍO 1 '· , ih Γ ,.-1-1- ppropr I Ρ ~ :.· ρρ,η ί ο ο α ηοο ο ο I ο 4 á t-omos de c ,τ· ” oo np Σ ·.·::: oo . oορr>. Γ 11 cu 2 armen te e-prc-pi s ooo s cu·- o ore:o pp oro -- Γ· ' ' c.- p ί : ;p ·,' :_ÍOP PO. P Ο. Γ·-! L Γ I L :* · 'Γ P ' ’ . 1 ; · ί- _ ir P ·- : 1 ’* - ~ ·, ~ C?.S p r* Γ p pipj-^r1. Γ.ϊ i’ MS Γ SS ± Παΐ OP 1 r.Vrr!1. :Op p P ~ rj r: · · Cp 1 : V P P C .· I Ρ C í ·.-· ·. '·· i P ‘ r: C ρ I :J , cC 1 d1-1 f O P T Ο Ρ I C O C 1 ...; r? ’ .· ’—''·,· ‘' Γ P j.· " O ' I _ ·_: ; Pô>·· tõ»· icjo fcãforoão, estep bu 11 i tospco ótpp ou ο1 I ue sstsr o ti leno íi 1 i c c· í ·' os t θ z-o e syss c oo-o i no ç c. :Ρ . :j C OP'ipO 5 t-Ο contendo fosfOiO O TTÍ|·:"·'OPOOC> n:.·!,··· :·. quent ioeoe qoo ío":oo: or··-;- roiocso rnolar entro o : orp-··.· o : o ·:: or> í-on :;; ' o i f , cov.ponente ('S > , o o; grupos epo-< i cor,·: 100·= ·η >. e;uo spc·:··. 1 'Cf. V -J? ’ I 'T 'L· ; L :‘ : '- ' ' ! O '·. r ; dC* p’ r"* ' 1 ^ : ·.··' : 1 ί i Ό : X ; ' ' 1 op ropr i oo ροπίο de OfÍ!l a i , 5: 1 , o í-o prop-i-Orsrp sirds. Oo 0 ; I : 1 o 1 : 1 hs o·.;x; · .· „ οροχα o'-· ·.ρ· :..;ο i ' ο -ι-ο-α ο ·;;·α: p-1 : ooηΐ e ii-v.onto pooo;r ssr curaoas co n-, gus i qa-so r -.gsnac o-vV -..ργο»γ isco ρ-ι-Ό cp, ipoinp:· ríc;:a ine luinoo, ?-':· ^ .· ·μ· , ρ.·η·:·:ρ,·ο ρ·.· Γ I ·7. ΐ> ογ '.ρ ÕÒ C '1 Ο 1 ; ·* λ C I C γ*. Γ !~ί1_· 1 i i. ο- ο - l - - ^ 1 οό *_ I ί-' Ο* 'ο: tos renoixoco· contondo hadroxalo, goona ·; ρ· .·_ ; c-1 go r - r o:· o ; ;-o a :ac-õ •ay a i o -p l op a oo , rpinas ;·>ο I arr· a no.--·?, a oo i oo , ..a o ·=·-. . "oíp a t :o <i ia~ occivcioo; rcspo'., nieiâfiuro ο I c :·:·. i t:>,;·-·-ο- α c:o i go, ' · .·; ·'··/ -
5 Ο Γ
G ΓΟΧ 1 CV-3 L t· 2 VO :« Sc*.Ο --:,-:1 v^iem-es e.g., i g<?nte
,;1 .-- .. .··.·· · ·. |Γ_ ; j . ; j_ '._j ‘ »_ -j, ; , . >. · .... ; s_ ·. ; ’.· O r .·* ... ; <.· - , ·. ί ·: i-·: : ~ e L c i or i naaos e sííí-ϊ : er,- ι I p-:- - t1 c··.:· i e r'·*’··: r.;· ap^o-p r i :··;': — ·_ 11·.--·· , - ; . r i Leno, 1 et i i c ·r · · ·· r-1-e- :: ; i. i ,e til, è ter d i ρ· r ορ· ι 1 ei . g 1 i ; o i r:o, : i i , e ter ο ,-ορ i I ano g 1 i c o i ee ΐ ι 1 , 1 , 1 , ite·-t o,-.-. ri :·£’i c :·; a 11 laçais to ; èíe;' ρ-'ορο l J ^ , -i ·τ z: . - OO ·£ i -tpa n te- o · :· · enr h i der. to ορ-όρ: ’ i eJo , ri *' — g i,' „ i; eí'. ip1 o r e.xeriíp i. r, o i o _ r i e ; 1 λ r,p : s pl ^st-l s:as ê -· roer 1 o , i r r rã . ·. .: v ·; r -.· a de enchipemo proa- €,-· ar.ípÍ'..r-i,-.oce • ' ·. I *, ; eg:P I —,.j. Γ, e! 1 P·è Oa 1 o. eo1 r1, ··· · 1 — ,.*p lP j. ·. _ : * _ ..-: e rri 5 --íOPírroiPanta ainde oe õo e 'ee- ,-··.··' r - - .:· ·.-; - e e -:ec eo poío o lerír; 1 i ge.. o PO p. i ·; oas resines · o or r ãiipragão-io ivr p-, I ’ ' Ρ ; O θΓ|.ρΌ3 1 v O S ; :: " ·. i c ·._ êter dliclrj.il do -'''.•'.'d'·.·'·.·
6.-.ido r/e PropileriQ rorc tor equipado cop -j;··'•iper-p. rir' p : oroonppoor ; e tamp-So de azo to- - ;' £ £·0; - ί / o 1 r . d i abví VèiViO.e , e 1 /-P· r . i 9 i l· >.·: j·;· ; ·_ or; v ; ό Io· ;;õ ri r.o CO-Í d!lOO :f'-7. ; ; ^,cr j i v :_:r- i
r.. : ; ·. .! ·;·y i i ·:. i d í 1 de b i e ··. - ··
SpOX 1 ··-: ·'. i J 4 n Ό -·. t Vr O 'B J. i i c.
; ---:..:--:0 : ·.' L · ' -:ή o.· ot - r* \' 1 íl·1 A p -ν.·.·;;::· vr d ,-· ·. ‘· ή O - ·' ·" ’· Τ·: • -o 'iv:; . A i':·^ ·. --o d ; ; v d ; - 0 /1- : -/iii -: 1 -.·- -. -3 -: - - -.-1’ I T T 0 Moiro -.-‘οχ ι A v α liCao p ·~· d-3 g 10,0S2 equiv.> da p... 1; 1 papi :-.p 0-3. ΟΓ,·: 1:3/ ι-.γ< ·: ™ r 1 c- r o is turaffios I U., 3 g dr p--í r - 1 1 dii·:. -5 1 p " 0 ; n-fOn·d-dp-; t 1 1 rr-j ···: ·’ r ο·ρ-;ο ·ο·:.· racíonao 0 f: 3-1 p IO L -.-1-- t : τ .- -. :-/-.-0-.1-0 i p c '.;·Λ· i p g i tador mecânico c-n v r r '--r: . ' :-· -d ri 1 Γ· : op-Amaao!:- p- Γ.’ ‘ ·~! p- · *_· O c.; ct JT. —* P· ·_* . H . p-L; í1' õ· :'θ: -d -•-.Ο 1 . -: .- /. : .' 3 ; COf-ί -Γ.9Ι i^.c · para •-j 1 zl* i 0 )' Γr tC1 '£í cr* roa ma. .'uni-ai-o I · ' - 0-V-P 0-:-/0 i l-·-; *:·ο p- 01 na u-i:a mistura do 0 ; 3.-..3. O ·, 1 ... O,. :--ρ L:--pp-a m 1 : -5 ''£·-ϊ ι'·' κ ορο, - avsncsoa) ο··.? a-::oo -ο- m ρ m m . .'·;- £ ό: ·: : 1 - 1::0-.1 :·: 1 1 ·- C- ί ΟΟ ΡΟίΓιΟ t ί 1 Η τ.· : -:-/1-. --1.. -ο _· 1 1 1 1 ν. .... 3-.---. . Α :'· ι ν ι-.-τ :·. · ·. · ·· ι*.· τ' ο ι agi ·£·.: · .· a -ι·:.·;··-·· . · .;· ·-.·" ι a : £ -- Ο οι-ο 30 -κΐ'νΟι.ρ. Jyr;tpp-;p ο··0·.-·;- .3 .· -. ι ··;.·. ·ι·: : ι ο-: ι ο ·_ ο :- ' ι ο ··..- I ι. ο: οι- e t-r 1--53 c-eres -ρρ 3-:.- .·.. a . -· post-ma ι- ;ο ο ο ·ρ·ο λ ?' ps: tscií ò ;-qop κρ .- '/.mO o...o^U: ---:-10 f . .'Ο ΠΤ· :-:0.10 i *1' O - IP - O / P -”· 1 _ - - 0 ' ol -.0-10 1 1 -.1 -1- 1
----.-- ------./ -_ 1 . ; / - - ’ .- O 5' ::: 01- ΟΓ::O :r.· 1 U :r /- 1 - . · - - ‘ — - O - ' I -. - Γ I 0--.--.1 Ο V — : 1 lr —1 - Ο -Ο. Γ Γ: O OIT 1 -_ Ο. Ο Ο ΊΟΠ -ΡΙΊΟΟ -- - - - - - — 1 Ο -.- Ο Ο Γ- - ’ Ί
-Ό ι Ρ Γ.Ο I ~ ι οΡο ρ ο ι : ι οι_rurmul <aÇc>o tose 1-::-.-. : -.- - - -.. - 1 O / c C.Jc*. Oír T o a. soiucáo r-aoma de C anterior C-O 3 o-a agente dõ C-ieriimal -Spec ia. 1t ies . ρΐ'ίρο " o:-:·
Ofi O 0030 1 I O cura Methylon / r- i. 1 Γ 1- t
4- .-. f Ο 1 Γi'i 1 S ·.· L-í Γ -rVj A formulação cont- ιπί: ’ ·. ' 1 Γ O ! O cr Λ P i l C -Ά V Ã r-:'..•••j.-j * » cir; + r · 1
:·:ο οι- ρ a ο: o oo ·- :r-o:·: -_-. -.- :-op: - ---5-5 1Γ:·-ír· to re-o-p .·. -.-5-5::.- - _Γ·.·'..~-: :. ' 1 ..5~ί___'- 1..-___l- ·-’ ·— -- -- * .. ' - Γ -:05- 1-5, Γ- · 5 Γ 0 ·3 1 Ο GÕ ΌΟ 1 5 ' - .5 - - 0 -: : -: : -ο·:- :·:ρ ρ ο -:- ί ο ί r e vea t: oa ο-:··'·· -5:-::-..- . .1 -:0-.0--5 ν .· Ke-tsí-io; ο 5.5-,-:5-:- ·:---ο ο--.— !-: o . ·.· · . ·; ; .··- -. ;··!'· :-ev·.'.·.·..·· - ,:--.- 1 pa-joc. T Oi oe-P! 1 O "· ρ··· ι o : r-: - r i1··-:/-·! c -:-:- A-i-Tri l>323 1 ~3~ oo t-, .5-·. : í-;! Η·’-' -~ Koo L : Ao o Lr:: 0.00.5ter-O·:- :.--- -:--:--:-1 esfc-rcscio (circ: de 2' -i vapor 00 1 - , 5 ps:g ( Í00 kra) dur.-.nl* :·ο 5.---:-::- :· -op:·.-;--::-1:--:--::0-:-5 d 5 5---too I a va 3-sco3 c ·;···(> : -:--1---:-5 ce papel . Oo rsvri 11.--5-.-1 ; d i '_A-.1; - ; d 1 ' '; ô* 1 S Gc: ri^OC1*' C GIrO τ: V 1 · oiGoG νΐ-!··ίηιο . . g ·.:· r -õ'. < · Γ:: ·:
£ =·. I PGI '·· .r ·.- i --l-íi-P: -'·:·ι o oegoir te -a r. λ t .:-5 PÕ·' 51-5 0 o-v. ,·. Γ·-:> 'd ·' τ orçada . £·35όρρρο: a segui r f i tí*. de C -fr 1 C- r f-.pe , O , 05 - 51 o, c o.oo. O"· a-:-: X '5 e removeroos c om GiVi p-o - 5 - p :-p-1 Ata- qysiqusr ;·=νΐ·::ι:-:π:ο perdido. 5 5 5 ---:-5---15-05055 S'é.O 3P're.‘S5!l ·. 5.0
m:0-::0 - -J p-o--‘o -.55 ; iv-J :- : i 5::· o c-ρρο “sí-i voo , p- - op .· . - 35-,00 i - : 5 PO -:1-:-0 1 T I C-5.05. -O-tr i C- :515-:-0-.- no íiiPorópi o Ir . f-·:-·:-
Design do Ex. ou Exp. Comp. Esfre gões Duplos Perda da margem dobrada Curva T Autoclave Rubor a Adesão 1E 100+ 51 T2 nenhum b passa 1F 50 13 T2 nenhum passa A* 30 24 T2 fraco passa ί ! y cri ι v·-1 τ? p Z*.

Claims (1)

  1. \
    V
    Ο -Ο ΡΟΊ'· o. 1 - i ; f ι c ?.ο ?· carac r,er iza.do por sa proc soar - raac ·; 5 o \ ··’: · ΟΡΡΟ :'ã;SÍ0 f i'J Ρ;ρ·:_,*:. 1 V'.’ ;_;v d'J'? pOS; C S“ S U i. PP ã: 0- S a S C CS·-1 U-; 1 uma. co^poíícso o a rsiiri? apoxi compr eanaanoo (a; paio manos,· uma rasinã epoxi ta· οό·:· uma Χ:·:!.;ί Pa pai a pua um, pas náo rnais ao pua dois prupass apa· · . i vizinooa iiiO ί èc 1 s a pua contas1 paio manos; uu çri-^o o - a lS:j Isno ou oa- i quiruno íuosiiouaio por mo 1 âc u I a ; a > ,:d; psi o manos um c *1‘SV-p*o»'ís to tanoo oois ρη'ορ·ο..· ·" o ore· .· .i ^ ._· aro-· o : por moiaculs; a 0··!· PUS: OS c oppOnan o a;· : i: ' £ *. j.5 z? ·:.4 c · ’ d; ; ::·.·_· a··: · a.:. ":: i *: v;u f ·;· r na c ao o a si a rala â a. o o a 3 r upos h i o ·’ aso i i ·.:· -1 Γ . d · ' Í r : 0-0 ΡΟΓ 'li vp·· ca- o o a d ; . ; ;i 1 .a : i; c om 1 a-o ·. o '.· um costposto contando fósforo seiacc lonaco --nora f 1 - a c i cio f oo f 6r i co ; a- acioo supar fosfórico, - . : s· ·. so '' :: . .. * a1 ata v C1, o U ; .o o cua 1 quar combina·; So óa camparo an o ao fo— li, '·. b_u) ou ·. 5* o·s ; am pua os c omponan ·: as (A) a < S > estão pre santas raia --uant xo lai pua a raι açSc· oa mo 1 es oa componan ta - ο·. ; p-a ra 3ropOS ap contidos no componente (A) é óa 0, i:1 a 5:1.
    2ê . - Processo da acordo com a rai v i no i cc-, r i. z: - o Ρ'_·Γ os c a· i ; i;-: ο ί ί a n o- a ·. h í i c vO - ρ· .u:- ρ. sp ·, · s _· · o - pcí-Oj ursa rasina epo.xi a qual tem uma ;··ό=·ό i os: ao; n r. — i a Ό ... pua a r <_ a. Oa CO 1 s pr uia-a-s -, 1 o· l 0 1 )’ 1 s; pua d . r iapo f a oa resina ap··.· i de ·. A-l-a· : ···· o tos ad-o: a r á-; .-o as t«o presentes --o qu-no mame o a ·::''· a·.· s:m aqo i va i trPvC s ca·;. \
    ο/ \ H2C ç CH2 R Ο/ \ ch2 -C —CH2 I R
    DO J. 1
    \ -CH-CH- R2 R1 XX *—· X τ,: L ,ρ X ·:.* Γ" 'Γ.Γ Χ\ SciO 1 ΠΟΟΡ'Χ1 Π ;ΐί*~ \~· ν XX ;Χ XX X ; ‘ r I ·’: -' ;Χ ·ρ ·Χ X 1 X 0'X X : : X χ 10 χχ·: χ 'χ ι , χ- ·:·χ χ x:xxxcaro: ioxi txx-I - 1,1 ao a caxo:: xx ':)Xrv “ x-x —x ~ a·'·'· x a fc~ á χχ -Γν.'^ρο χ ι x x ·. I ·: ί χχχχ· χχ-- ~ -- ,. X · X X ' X ; a ί. 9. ϋΐΛ Γί; X ·:! : 7·.'··!: 1 XX·;. X X X 'X X; - - -ν: , X X X V ο .· χ ·: χχρ·χχχπ χχ < Α·~·1~χ> sa r χχχ ra·.-.-? : χ a τ.:χ··_·.· ι χ·χ -'.ixtx—x ' -τΧ λ X .--. ζ: :. ί Γ Xi"1 X a ! "ί I-ΟΟ pc? ί * Ο '1' ΓΧΧ I -Χ X 'X X: X XX X X X V., | , V X | ϊ ’· χ·χ χ ·*χ χ χ;··χ· ι · - χ όχχ ·
    Formula VIII
    0 / \ C — C«2 I R Formula IX O / \ ch2 - c —ch2 I R O / \ HoC - C-CH20 -(-CH-CH-0)m I I I R R2 RI orrriu i
    Formula V
    Formula VI
    η τ_. r .¾ ·) Γ·? η ·}. χ _·*
    RUA VlCTCil CC-nCOM. 10-A. ΚΙ 200 USSOA
PT89423A 1988-01-13 1989-01-11 Processo para a preparacao de resinas epoxi avancadas modificadas PT89423B (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/143,558 US4820784A (en) 1988-01-13 1988-01-13 Modified advanced epoxy resins

Publications (2)

Publication Number Publication Date
PT89423A true PT89423A (pt) 1990-02-08
PT89423B PT89423B (pt) 1993-09-30

Family

ID=22504585

Family Applications (1)

Application Number Title Priority Date Filing Date
PT89423A PT89423B (pt) 1988-01-13 1989-01-11 Processo para a preparacao de resinas epoxi avancadas modificadas

Country Status (12)

Country Link
US (1) US4820784A (pt)
EP (1) EP0324389A3 (pt)
JP (1) JP2670160B2 (pt)
KR (1) KR900700517A (pt)
AU (1) AU2945489A (pt)
BR (1) BR8807419A (pt)
CA (1) CA1299804C (pt)
MY (1) MY104947A (pt)
NO (1) NO173392C (pt)
PT (1) PT89423B (pt)
WO (1) WO1989006661A1 (pt)
ZA (1) ZA89291B (pt)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5248741A (en) * 1987-07-16 1993-09-28 The Dow Chemical Company Cationic, advanced epoxy resin compositions incorporating glycidyl ethers of oxyalkylated aromatic or cycloaliphatic diols
US5021470A (en) * 1987-07-24 1991-06-04 Basf Corporation Flexible aryl alkyl epoxy resins, their amine resin derivatives and their use in electrodeposition coatings
CA1336029C (en) * 1987-11-06 1995-06-20 Michiharu Kitabatake Coating resin composition containing an epoxy-polyamine resin
US5360838A (en) * 1987-12-03 1994-11-01 The Dow Chemical Company Cationic, capped advanced epoxy resin compositions from glycidyl ethers of oxyalkylated aromatic or cycloaliphatic diols
AU612794B2 (en) * 1988-01-13 1991-07-18 Dow Chemical Company, The Modified advanced epoxy resins
EP0358096A3 (en) * 1988-09-07 1990-09-26 The Dow Chemical Company Organic solvent solutions of phosphate esters of epoxy resins
US5086094A (en) * 1988-09-07 1992-02-04 The Dow Chemical Company Organic solvent solutions of phosphate esters of epoxy resins
US4952646A (en) * 1989-07-20 1990-08-28 Akzo America Inc. Epoxy resin compositions containing a polyphosphoric/polyphosphonic anhydride curing agent
FR2650794B1 (fr) * 1989-08-08 1991-11-29 Bennes Marrel Dispositif de bennage a bras modulaires
US5244998A (en) * 1990-05-15 1993-09-14 The Dow Chemical Company Advanced and unadvanced compositions, nucleophilic derivatives thereof and curable coating compositions thereof
MY106546A (en) * 1990-05-15 1995-06-30 Dow Chemical Co Advanced and unadvanced compositions, nucleophilic derivatives thereof curable and coating compositions thereof
US5095050A (en) * 1990-11-21 1992-03-10 The Dow Chemical Company Advanced epoxy compositions, curable compositions and cured products
GB9027406D0 (en) * 1990-12-18 1991-02-06 Ciba Geigy Ag Production of compounds
JPH04268319A (ja) * 1991-02-22 1992-09-24 Dow Chem Nippon Kk 水分散可能なエポキシ樹脂及びその製造方法
JPH07503491A (ja) * 1992-01-28 1995-04-13 ザ　ダウ　ケミカル　カンパニー エポキシ樹脂，エポキシ樹脂のホスホネートエステルのブレンド
JPH07179728A (ja) * 1993-12-21 1995-07-18 Yuka Shell Epoxy Kk 半導体封止用難燃化エポキシ樹脂組成物
JP3308397B2 (ja) * 1994-07-07 2002-07-29 住友ベークライト株式会社 半導体封止用エポキシ樹脂組成物
GB9421405D0 (en) * 1994-10-21 1994-12-07 Dow Chemical Co Low voc laminating formulations
US5993787A (en) * 1996-09-13 1999-11-30 Johnson & Johnson Consumer Products, Inc. Composition base for topical therapeutic and cosmetic preparations
US5811498A (en) * 1997-04-16 1998-09-22 The Dexter Corporation α-glycol endcapped resins, their method of manufacture, and compositions containing the same
KR100740895B1 (ko) * 2005-12-30 2007-07-19 제일모직주식회사 재작업이 가능한 고신뢰성 반도체 사이드필용 액상 에폭시수지 조성물 및 이를 이용한 반도체 소자
CN112480370A (zh) 2015-03-19 2021-03-12 泽费罗斯股份有限公司 用于高分子材料的酯化酸
EP3348621A1 (en) * 2017-01-16 2018-07-18 ALLNEX AUSTRIA GmbH Aqueous coating composition for corrosion protection
JP6854661B2 (ja) * 2017-02-10 2021-04-07 株式会社Adeka 樹脂組成物及び硬化物

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3937679A (en) * 1968-10-31 1976-02-10 Ppg Industries, Inc. Electrodepositable compositions
US3842037A (en) * 1972-06-08 1974-10-15 Shell Oil Co Process for preparing higher molecular weight polyepoxide products by condensing lower molecular weight polyepoxide with polyhydric phenols
US4164487A (en) * 1976-12-23 1979-08-14 The Dow Chemical Company Water-thinnable mixtures of base-neutralized products of reaction of H3 PO4 with polyether epoxides and with other type epoxides
US4256844A (en) * 1976-12-23 1981-03-17 The Dow Chemical Company Fire retardant, thermosetting, resinous reaction products of phosphoric acid and methyol- or alkoxymethyl-substituted epoxides
US4289812A (en) * 1977-11-21 1981-09-15 The Dow Chemical Company Method of water-solubilizing high performance polyether epoxide resins, the solubilized resins and thermoset, hydrophobic coatings derived therefrom
US4316922A (en) * 1980-10-23 1982-02-23 The Dow Chemical Company Aqueous epoxy phosphate dispersions comprising n-butanol, n-hexanol and ethylene glycol monobutyl ether
US4360613A (en) * 1981-05-18 1982-11-23 Celanese Corporation Ether-ester water reducible coating compositions
US4397970A (en) * 1981-06-24 1983-08-09 The Dow Chemical Company Process for epoxy phosphate coating resins
US4608313A (en) * 1982-06-10 1986-08-26 The Dow Chemical Company Advanced epoxy resins crosslinked with polyisocyanates
AU571499B2 (en) * 1983-04-01 1988-04-21 Dow Chemical Company, The Preparing epoxy resins
US4452929A (en) * 1983-09-09 1984-06-05 Celanese Corporation Water reducible epoxy based coating compositions
US4507461A (en) * 1983-10-14 1985-03-26 Wilmington Chemical Corporation Low viscosity epoxy resins
US4481347A (en) * 1983-10-24 1984-11-06 The Dow Chemical Company Epoxy resins containing phosphorus
GB2158074B (en) * 1984-05-01 1987-09-16 Asahi Denka Kogyo Kk Coating composition
CA1262794A (en) * 1984-09-10 1989-11-07 Terence J. Hart Blends of phosphated epoxy and acrylic resins and the use thereof in coating compositions
US4613661A (en) * 1985-05-28 1986-09-23 The Dow Chemical Company Epoxy phosphate compositions
DE3601560A1 (de) * 1986-01-21 1987-07-23 Herberts Gmbh Waessriges, hitzehaertbares ueberzugsmittel, dessen verwendung und damit beschichtete gegenstaende
US4692382A (en) * 1986-07-21 1987-09-08 Ppg Industries, Inc. Elastomeric coating compositions
GB8712121D0 (en) * 1987-05-22 1987-06-24 Dow Chemical Rheinwerk Gmbh Film-forming resin compositions

Also Published As

Publication number Publication date
JP2670160B2 (ja) 1997-10-29
AU2945489A (en) 1989-08-11
ZA89291B (en) 1990-09-26
MY104947A (en) 1994-07-30
WO1989006661A1 (en) 1989-07-27
EP0324389A3 (en) 1990-09-26
US4820784A (en) 1989-04-11
PT89423B (pt) 1993-09-30
EP0324389A2 (en) 1989-07-19
CA1299804C (en) 1992-04-28
NO893641L (no) 1989-09-12
BR8807419A (pt) 1990-05-15
NO893641D0 (no) 1989-09-12
NO173392C (no) 1993-12-08
NO173392B (no) 1993-08-30
JPH02502927A (ja) 1990-09-13
KR900700517A (ko) 1990-08-13

Similar Documents

Publication Publication Date Title
PT89423A (pt) Processo para a preparacao de resinas epoxi avancadas modificadas
MX2021011394A (es) Compuestos de carbamoilpiridona triciclica puenteada y su uso farmaceutico.
BRPI0208811B8 (pt) derivados de pirazol, seu uso e processo de preparação, bem como composição farmacêutica compreendendo os mesmos
MX9403380A (es) Inhibidores de proteasa de vih utiles para el tratamiento de sida.
DK0730594T3 (da) 9-hydroxy-pyrido{1,2-a}pyrimidin-4-on-ether-derivater
AR011101A1 (es) Compuesto derivado de acidos arilsulfonilaminohidroxiamicos y composicion farmaceutica que lo contiene
AR018042A1 (es) Uso de compuestos de quinolina para la preparacion de medicamentos para el tratamiento de infecciones bacterianas en mamiferos, particularmenteen el hombre, composiciones farmaceuticas formuladas con dichos compuestos y procedimiento de preparacion de dichos compuestos de quinolina
BR0015056A (pt) Composto, uso de um composto, composição farmacêutica, método de tratamento de infecções por hiv e kit farmacêutico
UY26799A1 (es) Método para preparar un compuesto
AR017377A1 (es) Polieteraminas termicamente estables, proceso para obtener dichas polieteraminas, estructuras laminares que comprenden una o mas capas de dichasestructuras y solventes y composiciones de recubrimiento que comprenden dichas polieteraminas
MX9401388A (es) Compuestos que inhiben la proteasa retroviral y composiciones farmaceuticas que los incluyen.
DK326785D0 (da) Terapeutisk middel til paavisning og/eller behandling af tumorer og fremgangsmaade til fremstilling af et saadant middel
BR0111263A (pt) Derivados de 2-aminocarbonil-9h-purina
ES2001152A4 (es) Preparados cosmeticos a base de n - hidroxibutil - quitosanas, nuevasn - hidroxibutil - quitosanas, asi como el procedimiento para su obtencion.
PE20230410A1 (es) Compuestos de sulfonimidamida como moduladores de nlrp3
PT93160A (pt) Processo para a preparacao de benzenossulfonamidas e de composicoes farmaceuticas que as contem
MX9308005A (es) Compuestos inhibidores de la proteasa del virus de la inmunodeficiencia humana, procedimiento para su preparacion y formulacion farmaceutica que los contiene.
ES2046671T3 (es) Un procedimiento para la preparacion de tetrahidroimidazo(1,4)benzodiazepin-2-tionas.
MX9303572A (es) Inhibidores de proteasa del sindrome de inmunodeficiencia humana, procedimiento para su preparacion y formualcion farmaceutica que los contiene.
DK1455800T3 (da) Fremgangsmåde til fremstilling af glucosaminsalte
BG93114A (bg) Производни на бензонафтиридин-1,8 ,методи за получаването им и състави които ги съдържат
MX9401171A (es) Forma purificada de estreptograminas, procedimiento para su preparacion y composiciones farmaceuticas que las contienen.
BR0106129A (pt) Compostos de amino-pirazinona bicìclicos, processo para sua preparação e composições farmacêuticas contendo-os
CY1106711T1 (el) Υποκατεστημενα παραγωγα προπανο-1,3-διαμινης και η φαρμακευτικη χρηση τους
AR005323A1 (es) Composicion para mejorar la resistencia al impacto y la flexibilidad de una resina fenolica endurecible en acido, metodos para prepararla y articulosformados con la misma.

Legal Events

Date Code Title Description
FG3A Patent granted, date of granting

Effective date: 19930323

MM3A Annulment or lapse

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 19950930