PL422386A1 - New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materials - Google Patents
New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materialsInfo
- Publication number
- PL422386A1 PL422386A1 PL422386A PL42238617A PL422386A1 PL 422386 A1 PL422386 A1 PL 422386A1 PL 422386 A PL422386 A PL 422386A PL 42238617 A PL42238617 A PL 42238617A PL 422386 A1 PL422386 A1 PL 422386A1
- Authority
- PL
- Poland
- Prior art keywords
- new
- group
- europium
- iii
- complex compounds
- Prior art date
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
Abstract
Zgłoszenie dotyczy nowych systemów fotoinicjujących do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej, nowych związków kompleksowych europu(III), oraz sposobu ich wytwarzania, zastosowań związków kompleksowych europu(III), nowych luminescencyjnych sond molekularnych do monitorowania procesów polimeryzacji oraz nowych luminescencyjnych sensorów molekularnych do badań materiałów powłokowych. Nowe systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej, zawierające sole oniowe i ko-inicjator, charakteryzują się tym, że zawierają a) co najmniej jedną sól oniową wybraną spośród następujących: sole jodoniowe wybrane spośród heksafluorofosforanu difenylojodoniowego, heksafluoroantymonianu difenylojodoniowego, heksafluorofosforanu 4-metylo-4'-izopropylodifenylojodoniowego, heksafluorofosforanu 4,4'-dimetylodifenylo-jodoniowego, tetrakis pentafluorofenyloboranu 4-metylo-4'-izopropylodifenylo-jodoniowego; sole sulfoniowe wybrane spośród heksafluorofosforanu trifenylo-sulfoniowego i heksafluoroantymonianu trifenylosulfoniowego; oraz b) co najmniej jeden ko-inicjator wybrany z grupy związków kompleksowych europu(III) o wzorze ogólnym (1), w którym: A1 oznacza ugrupowanie o wzorze ogólnym (2), w którym podstawnik R1 wybrany jest spośród następujących: grupa fenylowa, grupa 4-fluorofenylowa, grupa 4-chlorofenylowa, grupa 4-metylofenylowa, grupa 4-metoksyfenylowa, grupa 4-cyjanofenylowa, grupa 4-nitrofenylowa, grupa 2-naftylowa, grupa 2-tienylowa, grupa 2-furylowa; A2 oznacza ugrupowanie o wzorze ogólnym (3), w którym podstawnik R2 oznacza atom wodoru lub grupę metylową, albo A2 oznacza ugrupowanie o wzorze (4), albo A2 oznacza ugrupowanie o wzorze (5), albo A2 oznacza ugrupowanie o wzorze (6).The application concerns new photoinitiation systems for the processes of photoinitiated cationic, radical, thiol-hybrid and hybrid polymerization, new europium (III) complex compounds and their production method, applications of europium (III) complex compounds, new luminescent molecular probes for monitoring polymerization processes and new luminescent molecular sensors for testing coating materials. The new photoinitiation systems for photoinitiated cationic, radical, thiol-hybrid and hybrid polymerization processes, containing onium salts and a co-initiator, are characterized by containing a) at least one onium salt selected from the following: iodonium salts selected from diphenyldionium hexafluorophosphate, hexafluoroanthonate diphenyl iodonium, 4-methyl-4'-isopropyl diphenyl iodonium hexafluorophosphate, 4,4'-dimethyldiphenyl iodonium hexafluorophosphate, 4-methyl-4'-isopropyl diphenyl iodonium pentafluorophenyl borate tetrakis; sulfonium salts selected from triphenyl sulfonium hexafluorophosphate and triphenyl sulfonium hexafluoroantimonate; and b) at least one co-initiator selected from the group of europium (III) complex compounds of general formula (1), wherein: A1 is a moiety of general formula (2), wherein R1 is selected from the following: phenyl group, 4-fluorophenyl group, 4-chlorophenyl group, 4-methylphenyl group, 4-methoxyphenyl group, 4-cyano-phenyl group, 4-nitrophenyl group, 2-naphthyl group, 2-thienyl group, 2-furyl group; A2 is a moiety of general formula (3), wherein R2 is a hydrogen atom or a methyl group, or A2 is a moiety of formula (4), or A2 is a moiety of formula (5), or A2 is a moiety of formula (6) .
Priority Applications (1)
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PL422386A PL244892B1 (en) | 2017-07-28 | 2017-07-28 | New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materials |
Applications Claiming Priority (1)
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PL422386A PL244892B1 (en) | 2017-07-28 | 2017-07-28 | New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materials |
Publications (2)
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PL422386A1 true PL422386A1 (en) | 2019-02-11 |
PL244892B1 PL244892B1 (en) | 2024-03-25 |
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PL422386A PL244892B1 (en) | 2017-07-28 | 2017-07-28 | New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materials |
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Citations (3)
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CN102093628A (en) * | 2010-12-31 | 2011-06-15 | 南京大学 | Ethylene vinyl acetate (EVA) adhesive film for light conversion |
WO2015113114A1 (en) * | 2014-01-31 | 2015-08-06 | Newsouth Innovations Pty Limited | Process for preparing a polymer |
WO2015157149A1 (en) * | 2014-04-07 | 2015-10-15 | Dow Global Technologies Llc | Regulation of a controlled radical polymerization of acrylates by light |
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2017
- 2017-07-28 PL PL422386A patent/PL244892B1/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102093628A (en) * | 2010-12-31 | 2011-06-15 | 南京大学 | Ethylene vinyl acetate (EVA) adhesive film for light conversion |
WO2015113114A1 (en) * | 2014-01-31 | 2015-08-06 | Newsouth Innovations Pty Limited | Process for preparing a polymer |
WO2015157149A1 (en) * | 2014-04-07 | 2015-10-15 | Dow Global Technologies Llc | Regulation of a controlled radical polymerization of acrylates by light |
Non-Patent Citations (6)
Title |
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DAN WANG ET AL., SYNTHESIS AND PHOTOLUMINESCENT PROPERTIES OF EU (III) COMPLEXES WITH FLUORINATED B-DIKETONE AND NITROGEN HETEROCYCLIC LIGANDS, September 2016 (2016-09-01) * |
I.V. KALINOVSKAYA ET AL., MECHANOCHEMICAL SYNTHESIS OF MIXED-LIGAND EUROPIUM B-DIKETONATES WITH NITROGEN-CONTAINING NEUTRAL LIGANDS, April 2007 (2007-04-01) * |
JI-HUA GAO ET AL., A COMPARATIVE STUDY OF THE OPTICAL AND ELECTROLUMINESCENT PROPERTIES OF EU(III) COMPLEXES WITH TTA AND 2-(2'-PYRIDYL)AZOLES: THE CRYSTAL STRUCTURE OF [EU(TTA)3(PBO)], 2006 * |
JING WU ET AL., SYNTHESIS AND PHOTOLUMINESCENT PROPERTIES OF SERIES TERNARY LANTHANIDE (EU(III), SM(III), ND(III), ER(III), YB(III)) COMPLEXES CONTAINING 4,4,4-TRI FLUORO-1-(2-NAPHTHYL)-1 ,3-BUTANEDIONATE AND CARBAZOLE-FUNCTIONALIZED LIGAND, 10 August 2010 (2010-08-10) * |
L.C THOMPSON, ISOMERISM IN THE ADDUCT OF TRIS (4,4,4,-TRIFLUORO-1-(2-NAPHTHYL)-1,3-BUTANEDIONATO) EUROPIUM(III) WITH DIPYRIDYL, 24 July 1998 (1998-07-24) * |
ZHIQIANG LI ET AL., ORGANIC-INORGANIC HIERARCHICAL SELF-ASSEMBLY INTO ROBUST LUMINESCENT SUPRAMOLECULAR HYDROGEL, 12 January 2017 (2017-01-12) * |
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