PL410875A1 - Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them - Google Patents

Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them

Info

Publication number
PL410875A1
PL410875A1 PL410875A PL41087515A PL410875A1 PL 410875 A1 PL410875 A1 PL 410875A1 PL 410875 A PL410875 A PL 410875A PL 41087515 A PL41087515 A PL 41087515A PL 410875 A1 PL410875 A1 PL 410875A1
Authority
PL
Poland
Prior art keywords
difuran
benzo
producing
dssc
dye ligand
Prior art date
Application number
PL410875A
Other languages
Polish (pl)
Other versions
PL238407B1 (en
Inventor
Mariusz Jan Bosiak
Andrzej Jan Wolan
Marcin Rakowiecki
Marcin Pakulski
Original Assignee
Synthex Technologies Spółka Z Ograniczoną Odpowiedzialnością
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Synthex Technologies Spółka Z Ograniczoną Odpowiedzialnością filed Critical Synthex Technologies Spółka Z Ograniczoną Odpowiedzialnością
Priority to PL410875A priority Critical patent/PL238407B1/en
Priority to PCT/PL2015/000206 priority patent/WO2016111636A1/en
Publication of PL410875A1 publication Critical patent/PL410875A1/en
Publication of PL238407B1 publication Critical patent/PL238407B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • C07F15/0053Ruthenium compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D519/00Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyridine Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

Przedmiotem wynalazku są nowe ligandy do syntezy fotouczulających kompleksów rutenowych do zastosowań DSSC, zawierające układ benzodifuranu połączony bezpośrednio lub przez wiązanie wielokrotne z układem 2,2'bipirydylu w pozycjach 4,4' lub układem fluorenu oraz sposoby ich wytwarzania. Ujawniono także nowe symetryczne i niesymetryczne fotouczulające kompleksy rutenowe do zastosowań DSSC, otrzymane z tych ligandów i sposoby ich wytwarzania. Otrzymane kompleksy charakteryzują się wysokimi współczynnikami molowymi ekstynkcji w zakresie światła widzialnego, są trwałe na powietrzu i po ekspozycji na światło słoneczne i mogą zostać użyte do budowy barwnikowych ogniw słonecznych DSSC.The present invention relates to new ligands for the synthesis of photosensitizing ruthenium complexes for DSSC applications, comprising a benzodifuran system connected directly or by multiple bonding to the 2,2'-bipyridyl system at 4,4 'positions or a fluorene system and methods for their preparation. New symmetric and asymmetric photosensitizing ruthenium complexes for DSSC applications, obtained from these ligands, and methods for their preparation have also been disclosed. The resulting complexes are characterized by high molar coefficients of extinction in the visible light range, are stable in air and after exposure to sunlight and can be used to build DSSC dye solar cells.

PL410875A 2015-01-05 2015-01-05 Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them PL238407B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL410875A PL238407B1 (en) 2015-01-05 2015-01-05 Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them
PCT/PL2015/000206 WO2016111636A1 (en) 2015-01-05 2015-12-23 Benzo[1,2-b:4,5-b]furan derivatives as ligands of ruthenium dyes and methods for obtaining thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL410875A PL238407B1 (en) 2015-01-05 2015-01-05 Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them

Publications (2)

Publication Number Publication Date
PL410875A1 true PL410875A1 (en) 2016-07-18
PL238407B1 PL238407B1 (en) 2021-08-16

Family

ID=55275140

Family Applications (1)

Application Number Title Priority Date Filing Date
PL410875A PL238407B1 (en) 2015-01-05 2015-01-05 Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them

Country Status (2)

Country Link
PL (1) PL238407B1 (en)
WO (1) WO2016111636A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018208712A1 (en) * 2017-05-09 2018-11-15 Warner Babcock Insitute For Green Chemistry, Llc Stilbene and fused stilbene derivatives as solar cell dyes
JP2021532173A (en) 2018-07-10 2021-11-25 アンビエント フォトニクス, インコーポレイテッド Solar cell dyes for copper redox dye-sensitized solar cells and their combinations

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9217811D0 (en) 1992-08-21 1992-10-07 Graetzel Michael Organic compounds
WO2012017869A1 (en) * 2010-08-03 2012-02-09 富士フイルム株式会社 Metal complex dye, photoelectric conversion element and photoelectrochemical cell

Also Published As

Publication number Publication date
PL238407B1 (en) 2021-08-16
WO2016111636A1 (en) 2016-07-14

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