PL410875A1 - Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them - Google Patents
Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing themInfo
- Publication number
- PL410875A1 PL410875A1 PL410875A PL41087515A PL410875A1 PL 410875 A1 PL410875 A1 PL 410875A1 PL 410875 A PL410875 A PL 410875A PL 41087515 A PL41087515 A PL 41087515A PL 410875 A1 PL410875 A1 PL 410875A1
- Authority
- PL
- Poland
- Prior art keywords
- difuran
- benzo
- producing
- dssc
- dye ligand
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title 1
- 125000005605 benzo group Chemical group 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052707 ruthenium Inorganic materials 0.000 title 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 230000002165 photosensitisation Effects 0.000 abstract 2
- 239000003504 photosensitizing agent Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 150000003303 ruthenium Chemical class 0.000 abstract 2
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 abstract 1
- 230000008033 biological extinction Effects 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D519/00—Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Przedmiotem wynalazku są nowe ligandy do syntezy fotouczulających kompleksów rutenowych do zastosowań DSSC, zawierające układ benzodifuranu połączony bezpośrednio lub przez wiązanie wielokrotne z układem 2,2'bipirydylu w pozycjach 4,4' lub układem fluorenu oraz sposoby ich wytwarzania. Ujawniono także nowe symetryczne i niesymetryczne fotouczulające kompleksy rutenowe do zastosowań DSSC, otrzymane z tych ligandów i sposoby ich wytwarzania. Otrzymane kompleksy charakteryzują się wysokimi współczynnikami molowymi ekstynkcji w zakresie światła widzialnego, są trwałe na powietrzu i po ekspozycji na światło słoneczne i mogą zostać użyte do budowy barwnikowych ogniw słonecznych DSSC.The present invention relates to new ligands for the synthesis of photosensitizing ruthenium complexes for DSSC applications, comprising a benzodifuran system connected directly or by multiple bonding to the 2,2'-bipyridyl system at 4,4 'positions or a fluorene system and methods for their preparation. New symmetric and asymmetric photosensitizing ruthenium complexes for DSSC applications, obtained from these ligands, and methods for their preparation have also been disclosed. The resulting complexes are characterized by high molar coefficients of extinction in the visible light range, are stable in air and after exposure to sunlight and can be used to build DSSC dye solar cells.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL410875A PL238407B1 (en) | 2015-01-05 | 2015-01-05 | Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them |
PCT/PL2015/000206 WO2016111636A1 (en) | 2015-01-05 | 2015-12-23 | Benzo[1,2-b:4,5-b]furan derivatives as ligands of ruthenium dyes and methods for obtaining thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL410875A PL238407B1 (en) | 2015-01-05 | 2015-01-05 | Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them |
Publications (2)
Publication Number | Publication Date |
---|---|
PL410875A1 true PL410875A1 (en) | 2016-07-18 |
PL238407B1 PL238407B1 (en) | 2021-08-16 |
Family
ID=55275140
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL410875A PL238407B1 (en) | 2015-01-05 | 2015-01-05 | Benzo[1,2-b:4,5-b]difuran ruthenium dye ligand derivatives and method for producing them |
Country Status (2)
Country | Link |
---|---|
PL (1) | PL238407B1 (en) |
WO (1) | WO2016111636A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018208712A1 (en) * | 2017-05-09 | 2018-11-15 | Warner Babcock Insitute For Green Chemistry, Llc | Stilbene and fused stilbene derivatives as solar cell dyes |
JP2021532173A (en) | 2018-07-10 | 2021-11-25 | アンビエント フォトニクス, インコーポレイテッド | Solar cell dyes for copper redox dye-sensitized solar cells and their combinations |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9217811D0 (en) | 1992-08-21 | 1992-10-07 | Graetzel Michael | Organic compounds |
WO2012017869A1 (en) * | 2010-08-03 | 2012-02-09 | 富士フイルム株式会社 | Metal complex dye, photoelectric conversion element and photoelectrochemical cell |
-
2015
- 2015-01-05 PL PL410875A patent/PL238407B1/en unknown
- 2015-12-23 WO PCT/PL2015/000206 patent/WO2016111636A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
PL238407B1 (en) | 2021-08-16 |
WO2016111636A1 (en) | 2016-07-14 |
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