PL400714A1 - Propiconazole salts and processes for their preparation - Google Patents
Propiconazole salts and processes for their preparationInfo
- Publication number
- PL400714A1 PL400714A1 PL400714A PL40071412A PL400714A1 PL 400714 A1 PL400714 A1 PL 400714A1 PL 400714 A PL400714 A PL 400714A PL 40071412 A PL40071412 A PL 40071412A PL 400714 A1 PL400714 A1 PL 400714A1
- Authority
- PL
- Poland
- Prior art keywords
- propiconazole
- salts
- substituent
- preparation
- benzyl
- Prior art date
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem wynalazku sa sole propikonazolu majace zastosowanie jako srodki grzybobójcze i sposób ich wytwarzania. Sole propikonazolu stanowia czwartorzedowe sole propikonazolu o wzorze ogólnym 1, w których X oznacza anion chlorkowy, bramkowy lub jodkowy, a R oznacza podstawnik metylowy lub prostolancuchowy podstawnik alkilowy zawierajacy od 3 do 20 atomów wegla, lub podstawnik benzylowy, lub allilowy, lub cykloheksylowy. Sposób ich otrzymywania polega na tym, ze propikonazol poddaje sie reakcji z czynnikiem czwartorzedujacym o wzorze ogólnym R-X, w którym R oznacza podstawnik metylowy lub prostolancuchowy podstawnik alkilowy zawierajacy od 3 do 20 atomów wegla, lub podstawnik benzylowy lub allilowy, a X oznacza atom chloru lub bromu, lub jodu przy stosunku molowym propikonazolu do czynnika czwartorzedujacego wynoszacym od 1:1 do 1:3 w rozpuszczalniku organicznym I, w temperaturze od 273 do 363K, w czasie co najmniej 20 godzin, po czym odparowuje sie rozpuszczalnik, a mieszanine poreakcyjna przemywa sie rozpuszczalnikiem organicznym II do momentu usuniecia nieprzereagowanych substratów, a nastepnie produkt suszy sie pod zmniejszonym cisnieniem w temperaturze od 313 do 363K, przez co najmniej 8 godzin.The present invention relates to propiconazole salts for use as fungicides and the process for their preparation. Propiconazole salts are the quaternary salts of propiconazole of the general formula 1 in which X is a chloride, gate or iodide anion, and R is a methyl substituent or straight chain alkyl substituent containing from 3 to 20 carbon atoms, or a benzyl, or allyl or cyclohexyl substituent. The method of their preparation is that propiconazole is reacted with a quaternizing agent of the general formula RX, in which R is a methyl substituent or a straight chain alkyl substituent containing from 3 to 20 carbon atoms, or a benzyl or allyl substituent, and X is a chlorine atom or bromine or iodine at a molar ratio of propiconazole to quaternizing agent of 1: 1 to 1: 3 in organic solvent I, at a temperature of 273 to 363K, for at least 20 hours, after which the solvent is evaporated and the reaction mixture is washed organic solvent II until the removal of unreacted substrates, and then the product is dried under reduced pressure at a temperature from 313 to 363K, for at least 8 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL400714A PL219914B1 (en) | 2012-09-10 | 2012-09-10 | Propiconazole salts and processes for their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL400714A PL219914B1 (en) | 2012-09-10 | 2012-09-10 | Propiconazole salts and processes for their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL400714A1 true PL400714A1 (en) | 2014-03-17 |
| PL219914B1 PL219914B1 (en) | 2015-07-31 |
Family
ID=50240926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL400714A PL219914B1 (en) | 2012-09-10 | 2012-09-10 | Propiconazole salts and processes for their preparation |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL219914B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422979A1 (en) * | 2017-09-26 | 2019-04-08 | Instytut Ochrony Roślin - Państwowy Instytut Badawczy W Poznaniu | N-benzyltriticonazole salts, method for obtaining them and application as fungicides |
-
2012
- 2012-09-10 PL PL400714A patent/PL219914B1/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422979A1 (en) * | 2017-09-26 | 2019-04-08 | Instytut Ochrony Roślin - Państwowy Instytut Badawczy W Poznaniu | N-benzyltriticonazole salts, method for obtaining them and application as fungicides |
Also Published As
| Publication number | Publication date |
|---|---|
| PL219914B1 (en) | 2015-07-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PH12015501585A1 (en) | Manufacturing process for pyrimidine derivatives | |
| PH12014501711A1 (en) | Benzyl sulfonamide derivatives useful as mogat-2 inhibitors | |
| MX2017017022A (en) | Method for the synthesis of rapamycin derivatives. | |
| Sączewski et al. | Experimental and theoretical studies on the tautomerism and reactivity of isoxazolo [3, 4-b] quinolin-3 (1H)-ones | |
| MX2013007462A (en) | Process for preparing 3-alkylsulfinylbenzoyl derivatives. | |
| PL400714A1 (en) | Propiconazole salts and processes for their preparation | |
| PL400713A1 (en) | Tebuconazole salts and processes for their preparation | |
| PL431315A1 (en) | Alkyl(2-hydroxyethyl)dimethylammonium indole-3-butyrates, method of their preparation and use as rooting hormones | |
| Zhuravlev et al. | Effect of structure of nucleophile and substrate on the quaternization of heterocyclic amines | |
| MY160382A (en) | Process for preparing biphenyl imidazole compounds | |
| PL400413A1 (en) | Methyl-imidazolium ionic liquids with the theophylline anion and a method for their preparation | |
| PL400411A1 (en) | Methyl Cyclohexyl ammonium ionic liquids with the theophylline anion and a method for their preparation | |
| PL413493A1 (en) | Quaternary salts of diphenoconazol with inorganic anion, method for obtaining them and application as fungicides | |
| PL400412A1 (en) | 1-methylpiperidinium ionic liquids with the theophylline anion and a method for their preparation | |
| PL419451A1 (en) | Quaternary halides, containing a diphenoconasol cation, method for obtaining them and application as fungicides | |
| PL398562A1 (en) | Tetraalkylammonium cyclamates and their preparation | |
| PL410320A1 (en) | New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogens | |
| PL410319A1 (en) | New quaternary alkoxymethyl tebuconazole chlorides, method for producing them and their application as growth inhibitors of mycelium | |
| PL421243A1 (en) | New quaternary ammonium halides that contain 3-alkyl-1-(N-propyl-N-(2-(2,4,6-trichlorophenoxy)ethyl)carbamoyl)imidazolium cation, method for obtaining them and their application as a disinfectant | |
| PL411286A1 (en) | New alkoxymethyl di(2-hydroxyethyl)ethylammonium ionic liquids with sweet anions and method for producing them and application as a medium for the protection of surface against accumulation of electrostatic charges | |
| PL403782A1 (en) | Alkylcyclohexyldimethylammonium 4-chloro-2-methylphenoxyacetates and a method for their preparation | |
| PL412742A1 (en) | New di[2-(2,4-dichlorophenoxy)propionates] alkano-1,X-bis(decyl dimethylammonium) bis-ammonium ionic liquids, method for obtaining them and applications as plant protection products | |
| WO2014153337A3 (en) | Small molecule inhibitors of pi3-kinase signaling | |
| PL418627A1 (en) | Proton ionic liquids with 1-methyl-4-piperidinolium cation and alkylcarboxylate anions, method for obtaining them and application as washing and disinfecting agents | |
| PL417286A1 (en) | New ionic liquids with alkane-1,X-bis(decyldimethylammonium) cation and acetate anion, method for obtaining them and applications as bactericides |