NZ703757B2 - Laser-welded shaped steel - Google Patents
Laser-welded shaped steel Download PDFInfo
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- NZ703757B2 NZ703757B2 NZ703757A NZ70375712A NZ703757B2 NZ 703757 B2 NZ703757 B2 NZ 703757B2 NZ 703757 A NZ703757 A NZ 703757A NZ 70375712 A NZ70375712 A NZ 70375712A NZ 703757 B2 NZ703757 B2 NZ 703757B2
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- flange
- web material
- denotes
- welded
- laser beam
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 46
- 239000010959 steel Substances 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 108
- 238000002844 melting Methods 0.000 claims abstract description 34
- 230000035515 penetration Effects 0.000 claims description 17
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 8
- 239000008397 galvanized steel Substances 0.000 claims description 8
- 238000003466 welding Methods 0.000 abstract description 31
- 238000005260 corrosion Methods 0.000 abstract description 10
- 239000002184 metal Substances 0.000 description 9
- 238000007747 plating Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 235000020127 ayran Nutrition 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 241000719332 Cephaleuros virescens Species 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000001678 irradiating Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 230000000534 elicitor Effects 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000001771 impaired Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001681 protective Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Abstract
provide a laser welded shaped steel having a T-joint part which secures desired bonding strength and desired corrosion resistance by making a formed melting part in an appropriate shape. In the shaped steel, the T-joint part is formed by vertically pressing an end of a web material made of a steel plate to a flange material also made of a steel plate and is subjected to fusion-welding by one-pass irradiation of a laser beam from one side. The vertical cross section of the shape of the welded part in the longitudinal direction of the shaped steel is set to satisfy the following: a>0 mm; b>0 mm; c?0.14Tw; d?0 mm; e?0 mm; a+d?2 mm; and b+e?2 mm, where a denotes a front melting width of the web material (welding side), b denotes a back melting width of the web material (non-welding side), c denotes a maximum melt-in depth in the plate thickness direction of the flange material, d denotes a front melting width of the flange material (welding side), e denotes a back melting width of the flange material (non-welded side), and Tw denotes the thickness of the web material. l plate to a flange material also made of a steel plate and is subjected to fusion-welding by one-pass irradiation of a laser beam from one side. The vertical cross section of the shape of the welded part in the longitudinal direction of the shaped steel is set to satisfy the following: a>0 mm; b>0 mm; c?0.14Tw; d?0 mm; e?0 mm; a+d?2 mm; and b+e?2 mm, where a denotes a front melting width of the web material (welding side), b denotes a back melting width of the web material (non-welding side), c denotes a maximum melt-in depth in the plate thickness direction of the flange material, d denotes a front melting width of the flange material (welding side), e denotes a back melting width of the flange material (non-welded side), and Tw denotes the thickness of the web material.
Description
DESCRIPTION
LASER WELDED SHAPED STEEL
TECHNICAL FIELD
The present invention relates to welded shaped steel, in
which a T-shaped welded joint is formed by laser welding,
using laser beam as a heat source.
BACKGROUND ART
Laser welding methods that involve irradiating laser beam
onto a T-shaped joint between a flange material and a web
material, have been studied as methods for producing shaped
steel such as T-shaped steel or H-shaped steel, which is used
for instance in beams that make up building frames of
buildings.
As illustrated in Patent literature 1, for instance, two
metal plates are butted perpendicularly to each other, and two
laser beams are irradiated simultaneously, along the butting
section, onto opposing positions, from both the front and rear
faces of the butting metal plates.
In such a method, laser beam is irradiated onto the
butting section from the directions of both sides of the web
material, which is not necessarily efficient in terms of
enhancing productivity.
Therefore, the applicants proposed a method that involves
irradiating laser onto the butting section only from the
direction of one face of the web material. See, for instance,
Patent literature 2.
To produce a building member in which a T-shaped welded
joint is formed by pressing of edge section of a second metal
plate perpendicularly to a first metal plate, this method
involves relying on laser welding through irradiation of laser
beam, as the welding method, with laser beam being irradiated
at an inclination angle of 30 degrees or less with respect to
the first metal plate, in such a manner that the second metal
plate melts, over the entire thickness thereof, at the end
section at which the second metal plate is pressed.
Patent literature 1: Japanese Patent Application
Publication No. 2005-21912
Patent literature 2: Japanese Patent Application
Publication No. 2007-307591
DISCLOSURE OF THE INVENTION
In the welding method proposed in Patent literature 2,
laser beam is irradiated in such a manner that the web
material melts over the entire thickness thereof at the edge
section of the web material, on the pressed side. The melting
region can accordingly be made narrow and deep. As a result,
this allows not only weld-joining with good shape precision,
but allows also a damaged region, at which a plating layer
evaporates, to be made as narrow as possible, when the flange
material and the web material (steel plate to be welded) are
plated steel plates. It becomes possible as a result to
reduce the coating amount of refinish coating after welding.
Since the melting region can be made thus deep, profiles of
required welding strength can be produced in a simple manner,
even with welding from just one side.
In the welding method of Patent literature 2, however,
the portion to be welded melts, upon being irradiated with
laser beam, over the entire thickness of the plate. In some
instances, therefore, the shape conditions of the melted
section can vary and the desired joint strength may fail to be
achieved, depending on differences in the incidence angle of
laser beam with respect to the flange material, the aim
position of laser beam with respect to the edge section of the
web material, and the energy of the laser beam itself. When
the shape conditions of the melted section vary, the corrosion
resistance of the produced welded shaped steel may in some
instances be impaired, due to changes in the evaporation
conditions of the plated layer, in cases where a plated steel
plate, in particular a galvanized steel plate, is used as the
material.
It is thus an object of the present invention, which has
been devised to solve such problems, to provide laser-welded
shaped steel, comprising a T-shaped joint, and in which
desired joint strength and desired corrosion resistance are
secured, by prescribing a suitable shape of melted sections
that are formed in the laser-welded shaped steel.
In order to attain the above goal, the laser-welded
shaped steel of the present invention is shaped steel in which
a T-shaped joint, formed by pressing of an edge section of a
web material perpendicularly against a flange material, is
fusion-joined on the basis of one-pass irradiation of laser
beam that is irradiated from a face on one side of the web
material, wherein both the flange material and the web
material comprise a steel plate, and a welded portion shape of
a cross-section along the longitudinal direction of the shaped
steel satisfies a>0, b>0, c 0.14Tw, d 0 and e 0.
When both the flange material and the web material
comprise a galvanized steel plate, there hold preferably a>0,
b>0, c 0.14Tw, d 0, e 0, a+d 2 and b+e 2.
Herein, a is a front melting width of the web material
(on the laser beam irradiation side), b is a rear melting
width of the web material (on the laser beam non-irradiation
side), c is a maximum weld penetration depth, in the plate
thickness direction, into the flange material, d is a front
melting width of the flange material (on the laser beam
irradiation side), e is a rear melting width of the flange
material (on the laser beam non-irradiation side), and Tw is
the plate thickness of the web material, with all the units
thereof being mm.
Preferably, a ratio Sf/Su satisfies Sf/Su<0.75, Sf being
a surface area of weld penetration into the flange material
and Su being a surface area of weld penetration into the web
material, of the welded portion.
The following approximations Sf=(d+Tw+e) c/2 and
Su=(a+b) Tw/2 apply herein.
In the laser-welded shaped steel according to the present
invention, a T-shaped joint, formed by pressing of an edge
section of a web material perpendicularly against a flange
material, is fusion-joined on the basis of one-pass
irradiation of laser beam from one side onto the joint, such
that the melted welded portion that is formed at the joint has
a prescribed shape.
As a result, the laser-welded shaped steel provided by
the present invention has stable joint strength, and exhibits
no drop in welded portion corrosion resistance even when, in
particular, the laser-welded shaped steel is welded shaped
steel in which a galvanized steel plate is used. Therefore,
it becomes possible to produce, at a low cost, welded shaped
steel of high strength and high corrosion resistance.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a diagram for explaining a method for laser
welding a T-shaped joint through one-pass irradiation from one
side;
Fig. 2 is a diagram for explaining a melted welded
portion shape of a T-shaped joint in a cross-section along the
longitudinal direction of shaped steel; and
Fig. 3 is a diagram for explaining a relationship between
a laser beam irradiation angle and an irradiation position
with respect to an edge section of the web material, during
laser welding of a T-shaped joint through one-pass irradiation
from one side.
BEST MODE FOR CARRYING OUT THE INVENTION
Upon welding of a T-shaped joint formed by pressing of an
edge section of a web material perpendicularly against a
flange material on the basis of one-pass laser beam
irradiation of the T-shaped joint from one side (front or rear
side of the web material), a desired joint strength fails to
be obtained unless the irradiation angle of laser beam with
respect to the flange material and the irradiation position of
laser beam with respect to edge section of the web material,
illustrated in Fig. 1, are set properly. In a case where a
plated steel plate is used as the material, the plating layer
of the flange material at the face that abuts the web material
may be damaged unless the irradiation angle and the
irradiation position are set properly.
For instance, when the irradiation angle of the laser
beam is reduced, there increase the flange front melting width
d and the flange rear melting width e at positions above and
below the intersection point (abutting position) of the web
material and the flange material, illustrated in Fig. 2, and
impairment of the corrosion resistance of the welded portion
becomes a concern.
When by contrast the irradiation angle is increased,
the flange melting widths d and e decrease, but the weld
penetration at the web end face decreases as well.
Accordingly, an unmelted section is prone to occur, and it is
no longer possible to secure sufficient strength. When the
irradiation angle is increased, moreover, the weld
penetration depth c into the flange material increases as
well. As a result, thermal deformation increases in a case
where the flange material is thin, and the width of the
plating damage on the surface facing the web material
increases, in the case of a plated steel plate.
Accordingly, the inventors found optimal sizes of the
various sites, illustrated in Fig. 2, that result in desired
characteristics, by finely adjusting the irradiation angle
of laser beam with respect to the flange material and the
irradiation position of laser beam with respect to the edge
section of the web material.
The detailed particulars will be explained below.
Firstly, a preliminary experiment (Fig. 1) was performed
that involved modifying, in various ways, the irradiation
angle of laser beam and irradiation position, in order to
assess the influence exerted on the flange material by the
irradiation angle and the distance from the abutting
position of the web material and the flange material up to the
irradiation position of the laser beam. The irradiation
position is represented by the coordinates, with respect to
the abutting position as the origin, of the irradiation
position on the laser beam irradiation surface of the web
material, in the direction of moving away from the abutting
position.
Herein, T-shaped shaped steel was obtained by laser
welding under the conditions given in The above 1, using a
hot-dipped steel plate, cut to a width of 200 mm and a length
of 2000 mm, in which a Zn-6%Al-3%Mg alloy plating layer was
deposited, to a deposition amount of 90 g/m per side, on a
steel plate having a plate thickness of 2.3 mm and a tensile
strength of 400 N/mm . Herein Ar was used as a shield gas, and
as a side gas that was blown onto the laser beam irradiation
point from an oblique transversal direction.
Table 1: Welding conditions
Laser welder Fiber laser welder
Beam spot diameter (mm)
Focal distance (mm) 600
Output (kW) 4.0
Welding speed (m/min) 5.0
Shield gas (l/min) Ar/20 (side gas)
to 20
Irradiation angle ( )
Irradiation position (mm) 0 to +1.0
Thereafter, the sizes of the sites illustrated in Fig. 2
were measured on the basis of cross-section observation of the
welded portion of the obtained T-shaped laser-welded shaped
steel, and the joint strength of the welded portions was
likewise measured. The welds were visually observed from the
non-abutting surface side of the web material of the flange
material.
A tensile test according to JIS G 3353 was carried out.
Joint strength was determined to be good if the tensile
strength at the load of breakage was 400 N/mm or higher, in
case of breakage of the base material of the web. Joint
strength was determined to be good if the value resulting from
dividing the breaking load by the actual cross-sectional area
of the web was 400 N/mm or higher, in the case of breakage of
the welded portion. In the observation from the non-abutting
surface side of the flange material, instances of observable
damage due to re-melting of plating were deemed as instances
of damage, and the corresponding damage width was measured.
The results are given Tables 2 to 12.
In Tables 2 to 12, underlined numerical values denote
instances of insufficient strength in the tensile test. The
units of the numerical values in the tables are mm.
Table 2: Welded portion shape: a
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
0.73 0.76 1.18 1.45
0.95 0.73 0.87 1.35 1.57
0.74 0.61 1.09 1.21 1.67
0.80 0.70 0.75 1.00 1.60 1.77
Table 3: Welded portion shape: b
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
0.45 0.45 0.78 1.28
0.58 0.64 0.55 1.04 1.18
0 0.54 0.74 0.82 0.85
0 0 0.37 0.43 0.91 0.81
Table 4: Welded portion shape: c
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
0.42 0.42 0.46 0.23
0.59 0.65 0.60 0.43 0.21
0.91 0.86 0.63 0.51 0.20
0.95 1.00 1.02 0.86 0.33 0.28
Table 5: Welded portion shape: d
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
1.63 0.52 0.20 0
1.82 1.19 0.83 0.25 0
1.50 1.01 0.31 0 0
1.55 1.20 0.52 0.31 0 0
Table 6: Welded portion shape: e
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
0.84 1.29 0.35 0.12
0.33 0.53 0.85 0 0
0 0.35 0.48 0.54 0
0 0 0.22 0.25 0.28 0
Table 7: Welded portion shape: a+d
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
2.36 1.28 1.38 1.45
2.77 1.92 1.70 1.60 1.57
2.24 1.62 1.40 1.21 1.67
2.35 1.90 1.27 1.31 1.60 1.77
Table 8: Welded portion shape: b+e
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
1.29 1.74 1.13 1.40
0.91 1.17 1.40 1.04 1.18
0 0.89 1.22 1.36 0.85
0 0 0.59 0.68 1.19 0.81
Table 9: Welded portion shape: Su
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
1.36 1.39 2.25 3.14
1.76 1.58 1.63 2.75 3.16
0.85 1.32 2.10 2.33 2.90
0.92 0.81 1.29 1.64 2.89 2.97
Table 10: Welded portion shape: Sf
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
0.98 0.86 0.66 0.28
1.31 1.31 1.19 0.55 0.24
1.73 1.57 0.97 0.72 0.23
1.83 1.75 1.55 1.23 0.43 0.32
Table 11: Welded portion shape: Sf/Su
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
0.72 0.62 0.29 0.09
0.75 0.83 0.73 0.20 0.08
2.03 1.19 0.46 0.31 0.08
1.99 2.17 1.20 0.75 0.15 0.11
Table 12: flange damage width
Irradiation position (mm)
Irradiation angle ( )
0 0.2 0.4 0.6 0.8 1.0
1.50 1.47 0.84 0
3.30 2.73 1.74 0.86 0
3.48 2.75 1.90 1.18 0
3.50 3.30 3.26 2.50 0.62 0
In order to secure the welding strength in the T-shaped
joint that comprises a combination of the web material and the
flange material, the foregoing materials must be integrated
together through melting in the vicinity of the mutual
abutting surfaces of the flange material and the web material.
In a case where welding is performed by one-pass laser welding
from one side, specifically, a front melting width and rear
melting width of the web material (front and rear beads of the
flange material) must be present (a>0, b>0), and the flange
must exhibit weld penetration. The results in Table 4
indicate that the weld penetration depth c into the flange
must be equal to or greater than 0.33 mm. Table 4 gives test
results for steel plates having a plate thickness of 2.3 mm.
Accordingly, the weld penetration width c in a flange must
ordinarily be equal to or greater than 0.14 Tw (mm), since
c/Tw=0.33/2.3=0.14.
Laser beam is incident obliquely from the top face of the
flange. Accordingly, when the incidence angle is excessively
large, or when the irradiation position is too far removed
from the abutting position of the flange material and the web
material, strength tends to drop since there is no front
melting width or rear melting width of the web material, and
an unmelted section arises between the web end face and the
flange. Specifically, the front and rear melting widths d and
e of the flange material must satisfy d 0 (mm) and e 0 (mm).
If the flange material is a thin plated steel plate, the
flange material exhibits substantial plating damage and
undergoes thermal deformation at the face opposing the web
material when the weld penetration amount in the flange
material is large. Accordingly, the weld penetration amount
into the flange material should not be excessively large.
The melting surface area in the vicinity of the
intersection point between the web material and the flange
material should be as small as possible. The sacrificial
protection action at a cut end face of the galvanized steel
plate is reported to extend ordinarily only to about 2.3 mm.
Taking into consideration evaporation of plating around the
welded portion in the laser welded portion, good corrosion
resistance can then be secured, even without repair-coating of
the welded portion, by keeping the melting width by laser
welding up to about 2 mm. Accordingly, the melting region is
best kept within 2 mm.
In a case where a galvanized steel plate is used as the
material, specifically, there must hold a+d 2 mm and b+e 2 mm
in order to suppress impairment of corrosion resistance in the
vicinity of the intersection point of the web material and the
flange material.
Preferably, the damage width of the flange is 2 mm or
smaller, from the viewpoint of sacrificial protection of the
plated steel plate. However, although in Table 7 a+d is 2 or
smaller when the irradiation angle is 10 or 15 , if the aim
position is 0.2 mm, the flange damage width in Table 12
exceeds nevertheless 2 mm, under identical conditions.
The flange damaged section is not irradiated by laser
beam, and therefore, does not disappear completely through
evaporation of plating; accordingly, the damage width need not
necessarily be 2 mm or smaller. However, good corrosion
resistance is elicited, even without application of a repair
coating, through the sacrificial protective action of the
galvanized steel plate. Therefore, the width of the flange
damaged section is preferably set to be 2 mm or smaller, and
there is prescribed Sf/Su<0.75, in order to suppress thermal
deformation of the flange. Herein, Sf is the surface area of
weld penetration into the flange material, and Su is the
surface area of weld penetration into the web material of the
welded portion. The surface area of weld penetration into the
flange material denotes the surface area of a region in which
the metal has melted once and that appears within the flange
material, at a cross-section along the longitudinal direction
of the shaped steel. The surface area of weld penetration
into the web material is the surface area of a region in which
the metal has melted once, and which appears within the web
material, at a cross-section along the longitudinal direction
of the shaped steel.
More preferably, there holds Sf/Su 0.15, from the
viewpoint of the strength of the welded portion.
The following approximations Sf=(d+Tw+e) c/2 and
Su=(a+b) Tw/2 apply herein.
In a case where a galvanized steel plate is used as the
material, there must hold a+d 2 mm and b+e 2 mm. Preferably,
here holds also Sf/Su<0.75, as confirmed in a repetition test
(CCT test) of salt spraying drying moistening, widely
used in the art as an accelerated test for corrosion
resistance evaluation. (In this case the repeat conditions
that were resorted to included two-hour spraying of 5%NaCl at
C four-hour drying at 60 C and 30%RH (relative humidity)
two-hour moistening at 50 C and 95%RH.)
The test was performed over 200 cycles. The results
revealed that in a laser welded portion of a T-shaped joint
with a+d 2 mm and b+e 2 mm, the welded portion became covered
with white rust, from an early stage, while no occurrence of
red rust was observed. The plating damaged section in the
heat-affected zone of the flange was also covered with white
rust, but no occurrence of red rust was observed. No thermal
deformation was observed, either, in the flange section.
The entire web end face must be melted efficiently in
order to obtain a melted section of narrowness such as the
above-described one. In order to achieve a narrow melted
section, it is therefore best, with geometry in mind, to aim
at an intersection point of the flange and the web, on the web
rear face side, than to aim at an intersection point of the
flange and the web on the web front face side, upon welding of
the T-shaped joint by one-pass laser welding from one side.
The aim position X from the flange on the web front face
is worked out from “X=Tw·tan ” (where Tw: web plate thickness,
: laser incidence angle with respect to the flange). An
unmelted section arises when the aim position X is set to be
equal to or greater than the laser beam radius (D/2), since
the laser does not pass through the intersection point of the
web front face and the flange, taking geometry into account.
In actuality, however, also the periphery of the laser
beam diameter is thermally affected (through heat conduction),
and thus melting occurs within a range equal to or greater
than the beam diameter. The area over which melting occurs
ranges from about 1.1 to 2.5 times the beam diameter,
depending on the conditions. Accordingly, the upper limit
value of the aim position X is “2.5 (D/2)”
(Tw·tan <X 2.5 (D/2)). The irradiation angle can be obtained
from the above expression as 0< tan ((2.5 D/2)/Tw).
A welded portion of prescribed shape can be obtained by
welding the T-shaped joint, through one-pass laser welding,
from one side, according to the irradiation angle and the
aim position X.
Claims (3)
1. Laser-welded shaped steel, in which a T-shaped joint, formed by pressing of an edge section of a web material perpendicularly against a flange material, is fusion-joined on the basis of one-pass irradiation of laser beam that is irradiated from a face on one side of the web material, wherein both the flange material and the web material comprise a steel plate; and a welded portion shape of a cross-section perpendicular to the longitudinal direction of said shaped steel satisfies a>0, b>0, c 0.14Tw, d 0, e 0, where a is a front melting width of the web material (on the laser beam irradiation side), b is a rear melting width of the web material (on the laser beam non-irradiation side), c is a maximum weld penetration depth, in the plate thickness direction, into the flange material, d is a front melting width of the flange material (on the laser beam irradiation side), e is a rear melting width of the flange material (on the laser beam non-irradiation side), and Tw is the plate thickness of the web material, with all units thereof being mm.
2. The Laser-welded shaped steel according to claim 1, wherein the steel plates are galvanized steel plates; and the welded portion shape further satisfies a+d≤2 and b+e≤2.
3. The laser-welded shaped steel according to claim 1 or 2, wherein when, in said welded portion, a surface area of weld penetration into the flange material is Sf and a surface area of weld penetration into the web material is Su, a ratio Sf/Su satisfies Sf/Su<0.75.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2012/068951 WO2014016935A1 (en) | 2012-07-26 | 2012-07-26 | Laser-welded shaped steel |
Publications (2)
Publication Number | Publication Date |
---|---|
NZ703757A NZ703757A (en) | 2016-05-27 |
NZ703757B2 true NZ703757B2 (en) | 2016-08-30 |
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