NZ335732A - Polyolefin compounds with balanced sealant properties and improved modulus and method for same - Google Patents

Polyolefin compounds with balanced sealant properties and improved modulus and method for same

Info

Publication number
NZ335732A
NZ335732A NZ335732A NZ33573297A NZ335732A NZ 335732 A NZ335732 A NZ 335732A NZ 335732 A NZ335732 A NZ 335732A NZ 33573297 A NZ33573297 A NZ 33573297A NZ 335732 A NZ335732 A NZ 335732A
Authority
NZ
New Zealand
Prior art keywords
ethylene polymer
composition
polymer
astm
measured
Prior art date
Application number
NZ335732A
Inventor
Luc Bosiers
Jacquelyn A Degroot
Lawrence T Kale
Pak-Wing Steve Chum
Staci A Dekunder
Dun Jozef J Van
Thomas T Oswald
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/748,321 external-priority patent/US5874139A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of NZ335732A publication Critical patent/NZ335732A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B32B2307/734—Dimensional stability
    • B32B2307/736—Shrinkable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/10—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Sealing Material Composition (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The specification describes a sealant film composition comprising at least two ethylene polymer components. The sealant film composition comprises: from 5 to 95 weight percent, based on the total weight of the composition, of at least one first ethylene polymer which is a homogeneously branched substantially linear ethylene polymer or a homogeneously branched linear ethylene polymer. The first ethylene polymer is characterized as having: i. Melt flow ratio, I10/I2, of greater than 5.63, ii. an I2 melt index in the range of from 0.001g/10 minutes to 2 g/10 minutes, as measured by ASTM D-1238 Condition 190 C/2.16 kg, iii. a density in the range of from 0.85 to 0.92g/cc, as measured in accordance with ASTM D 792, iv. a molecular weight distribution, MW/Mn as determined by gel permeation chromatography of less than 3.5, v. a short chain branching distribution index (SCBDI) greater than 50 percent, as determined using temperature rising elutionfractionation, and from 5 to 95 weight percent, based on the total weight of the composition, of at least one second ethylene polymer which is a homogeneously branched ethylene polymer or a heterogeneously branched linear ethylene polymer. The second ethylene polymer is characterized as having a density less than 0.97 g/cc. The composition is characterized as having a composition density of from 0.89 g/cc to 0.95 g/cc, as measured in accordance with ASTM D-792, and the I2 melt index of the at least one first polymer is lower than the I2 melt index of the at least one second polymer.
NZ335732A 1996-11-13 1997-11-13 Polyolefin compounds with balanced sealant properties and improved modulus and method for same NZ335732A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/748,321 US5874139A (en) 1994-10-21 1996-11-13 Multilayer polyolefin with balanced sealant properties
US88000697A 1997-06-20 1997-06-20
PCT/US1997/020574 WO1998021274A1 (en) 1996-11-13 1997-11-13 Polyolefin compositions with balanced sealant properties and improved modulus and method for same

Publications (1)

Publication Number Publication Date
NZ335732A true NZ335732A (en) 2000-12-22

Family

ID=27114920

Family Applications (1)

Application Number Title Priority Date Filing Date
NZ335732A NZ335732A (en) 1996-11-13 1997-11-13 Polyolefin compounds with balanced sealant properties and improved modulus and method for same

Country Status (9)

Country Link
EP (1) EP0938520A1 (en)
JP (1) JP2000507645A (en)
KR (1) KR20000053255A (en)
AU (1) AU739746B2 (en)
BR (1) BR9713051A (en)
CA (1) CA2271482A1 (en)
NO (1) NO992304L (en)
NZ (1) NZ335732A (en)
WO (1) WO1998021274A1 (en)

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ZA986434B (en) 1997-07-21 2000-01-20 Dow Chemical Co Broad mwd, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom.
TR200000691T2 (en) 1997-09-19 2002-04-22 The Dow Chemical Company Narrow MWD, composition-optimized ethylene interpolymer composition, process to achieve this, and the product manufactured therefrom.
BR0013220A (en) * 1999-09-07 2002-06-18 Du Pont Process for lowering the thermosealing temperature of a thermoplastic, process for preparing an article and article
US7125933B2 (en) 2000-06-22 2006-10-24 Univation Technologies, Llc Very low density polyethylene blends
ES2290159T3 (en) * 2000-06-22 2008-02-16 Univation Technologies, Llc VERY LOW DENSITY POLYETHYLENE MIXTURES AND HIGH DENSITY POLYETHYLENE.
US20020160167A1 (en) 2001-02-23 2002-10-31 Bader Michael J. Multi-layer hermetically sealable film
US6686005B2 (en) * 2001-10-11 2004-02-03 Pactiv Corporation End termination materials for reclosable polymeric bags
JP4028206B2 (en) * 2001-10-19 2007-12-26 大日本印刷株式会社 Bag with zipper tape
US7846552B2 (en) * 2002-09-23 2010-12-07 Dow Global Technologies Inc. Polymer compositions for extrusion coating
CN1806004B (en) 2003-06-10 2010-06-16 陶氏环球技术公司 Film layers made from ethylene polymer blends
EP1721739A1 (en) * 2005-05-09 2006-11-15 Total Petrochemicals Research Feluy Bi-layer rotomoulding applications
US8617717B2 (en) 2006-06-09 2013-12-31 Exxonmobil Chemical Patents Inc. Heat sealable films from propylene and α-olefin units
ES2615802T3 (en) * 2006-12-21 2017-06-08 Dow Global Technologies Llc Films of layers, packages prepared from them, and methods to produce them
EP1995058B1 (en) * 2007-05-25 2015-12-09 Flexopack S A Multilayer heat shrinkable cook-in film
EP2077297B1 (en) 2008-01-02 2012-04-04 Flexopack S A PVDC formulation and heat shrinkable film
KR100901632B1 (en) * 2008-04-01 2009-06-08 호남석유화학 주식회사 Polyethlene resin composition for preparing container closure
RU2475362C2 (en) 2008-10-17 2013-02-20 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Biaxially oriented film
MX2011008226A (en) * 2009-02-06 2011-08-17 Dow Global Technologies Llc Ethylene-based polymers and compositions, methods of making the same, and articles prepared therefrom.
US20100221528A1 (en) * 2009-02-27 2010-09-02 Schwab Thomas J Extrusion coated article
ES2589766T3 (en) 2009-07-01 2016-11-16 Dow Global Technologies Llc Ethylene polymer and its use
EP2483334B1 (en) * 2009-09-28 2016-08-24 ExxonMobil Chemical Patents Inc. Polyolefin compositions and products made therefrom
DE202011110798U1 (en) 2011-05-03 2016-08-09 Flexopack S.A. Waste packaging system and foil
EP2535279B1 (en) 2011-06-16 2016-11-16 Flexopack S.A. Waste packaging system and film
US9604430B2 (en) 2012-02-08 2017-03-28 Flexopack S.A. Thin film for waste packing cassettes
US9181369B2 (en) 2013-03-11 2015-11-10 Chevron Phillips Chemical Company Lp Polymer films having improved heat sealing properties
US9815975B2 (en) * 2013-03-25 2017-11-14 Dow Global Technologies Llc Film having good barrier properties together with good physical characteristics
EP2813362B1 (en) 2013-06-14 2019-05-22 Flexopack S.A. Heat shrinkable film
US20170152377A1 (en) 2014-06-26 2017-06-01 Dow Global Technologies Llc Breathable films and articles incorporating same
AU2015258191B2 (en) 2014-11-19 2020-02-27 Flexopack S.A. Oven skin packaging process
JP6398841B2 (en) * 2015-03-31 2018-10-03 日本ポリエチレン株式会社 Packaging film
WO2018045559A1 (en) 2016-09-09 2018-03-15 Dow Global Technologies Llc Multilayer films and laminates and articles comprising the same
EP3501822A1 (en) 2017-12-22 2019-06-26 Flexopack S.A. Fibc liner film
WO2020064349A1 (en) * 2018-09-25 2020-04-02 Sabic Global Technologies B.V. Polyethylene film for heat sealing.
US20220025135A1 (en) * 2018-11-13 2022-01-27 Exxonmobil Chemical Patents Inc. Polyethylene Films
EP3880738A1 (en) * 2018-11-13 2021-09-22 ExxonMobil Chemical Patents Inc. Polyethylene blends and films
US11046843B2 (en) * 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties
WO2024097008A1 (en) * 2022-11-03 2024-05-10 Dow Global Technologies Llc Polyethylene composition
WO2024097006A1 (en) * 2022-11-03 2024-05-10 Dow Global Technologies Llc Polyethylene composition

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RO116409B1 (en) * 1993-04-28 2001-01-30 Dow Chemical Co Ehylene polymer composition
US5773106A (en) * 1994-10-21 1998-06-30 The Dow Chemical Company Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus

Also Published As

Publication number Publication date
KR20000053255A (en) 2000-08-25
NO992304L (en) 1999-07-13
AU739746B2 (en) 2001-10-18
BR9713051A (en) 2002-01-15
EP0938520A1 (en) 1999-09-01
WO1998021274A1 (en) 1998-05-22
AU5507598A (en) 1998-06-03
NO992304D0 (en) 1999-05-12
JP2000507645A (en) 2000-06-20
CA2271482A1 (en) 1998-05-22

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