NZ210168A

NZ210168A - Partial combustion of gasification of carbonaceous material

Info

Publication number: NZ210168A
Application number: NZ210168A
Authority: NZ
Inventors: S Santen; B Hammarskog
Original assignee: Skf Steel Eng Ab
Priority date: 1984-06-14
Filing date: 1984-11-09
Publication date: 1987-04-30
Also published as: SE453751B; ES538144A0; GB8427964D0; DE3441358C2; CN85101700A; AU568693B2; GB2160218A; CA1233431A; ES8607374A1; GB2160218B; KR860000355A; BE901159A; AT390074B; NO844800L; IT1177080B; FR2565992A1; IT8423373A0; AU3525684A; BR8406069A; JPS614789A

Description

<div class="application article clearfix" id="description"> 210168 .tent tfice • 9 NOV 1984 RECEIVED Priority Date(s): .... {{t.. . 5/5*. Complete Specification Filed: $■. //. Class: . £ I P. C. J'V."'.""' 3'5* APR 1987 Publication Date: P.O. Journal, No: PATENTS ACT 1953 PATENTS FORM NO. 5 COMPLETE SPECIFICATION "METHODS AND MEANS FOR PARTIAL COMBUSTION AND GASIFICATION OF CARBONACEOUS MATERIAL" WE, SKF STEEL ENGINEERING AB, a Swedish Company, (Sweden) r n Tim TOT S-813 00 HOFORS, Sweden, hereby declare the invention for which we pray that a patent may be granted to us and the method by which it is to be performed, to be particularly described in and by the following statement: - 1 - 210168 The present invention relates to a method of partially combusting and gasifying atomized carbonaceous material by introducing oxidizing agent and said carbonaceous material into a reaction chamber while at the same time supplying energy by means of a plasma generator, 5 and to a plasma generator therefor. It is already known to use oxygen burners for gasifying carbonaceous material, which burners are directed towards the centre of a chamber having a central gas and slag outlet. However, certain problems arise here in conjunction with the 10 burner design. The rate at which the oxygen is blown in determines the location of the flame front and in order to prevent reverse firing there must be a certain distance between the burner nozzle and the flame front. This considerably limits the control range. In order to protect 15 the walls of the chamber, a wall of water vapour is sometimes blown around the oxygen inlet, making the flow relatively undisturbed. Carbon powder is blown into the oxygen flow by lances and mixed in the burner. Due to the undisturbed flow and the high flow rate, mixing is extremely poor and a long 20 mixing distance is required for water in the carbon particles to be gasified and the particles themselves to be sufficiently heated. Furthermore, a relatively low reaction speed is achieved in known methods of heating the oxidizing agent and fuel to a temperature 25 at which reactions commence, this being primarily achieved through circulation of hot reaction products. It is also known per se to use plasma generators for the supply of thermal energy for combustion and gasification of carbonaceous fuel. Pulverized carbon is injected into a carrier gas heated by 30 a plasma generator. Oxygen, CO2» and/or water vapour are used as oxidizing agent and injected either in the hot carrier gas or used wholly or partially as carrier gas. - 2 - 210168 The object of the present invention is to effect a process for partial combustion and gasification of carbonaceous material permitting rapid, efficient mixing of the oxidizing agent and the carbon carrier, giving a short mixing distance and a large control range irrespective of the location of the flame front, and achieving a considerably higher reaction speed by the direct supply of thermal energy to the oxidizing agent and fuel used. Another object of the invention is to produce a combined burner for performing the process according to the invention In the method described in the introduction, the above objects are achieved according to the invention by generating a hot gas flow in a plasma generator and introducing the gas into a reaction chamber the pulverent carbonaceous material being introduced concentrically around said hot gas flow with the aid of a transport gas. The transport gas may consist of oxidizing agent, for instance, combustion products (C^, CC^, or recirculated gas. The plasma gas is given a rotary movement in the plasma generator, so that on leaving the plasma generator vigorous turbulence is achieved in the concentrically flowing carboraceous material, while at the same time the central flow of hot gas instantaneously heats the material mixture to reaction temperature. The oxidizing agent preferably consists of C^, water vapour, air or a mixture thereof, while the carbonaceous material consists Df coal dust, coke dust, charcoal dust, peat and/or shavings. The plasma generator for performing the process according to the invention is characterised in that it cortprises cylindrical electrodes between which an electric arc may be generated, a supply pipe for the introduction of carrier gas into the plasma generator, means for imparting a tangential velocity component to the hot gas flow generated in the plasma generator, an outer tube arranged around the plasma generator to form an annular space between the outside of the plasma generator and said outer tube, at least at the outlet end of the plasma generator, and means for the supply of carbon-carrying material to said annular space. - 3 - 210168 A pressure chamber may preferably be arranged in connnection with the inlet side of the annular space, in which lances are arranged for the supply of carbonaceous material to give the carbonaceous material a tangential speed component in order to effect uniform distribution of the material in the annular space. Alternatively> an inner protective pipe nay be arranged with outer guides, for Instance in the form of blades to provide a rotary movement, preferably in a direction opposite to that of the plasma gas. In this case the annular space for introduction of the pulverulent material is formed by said outer tube and said inner tube. Besides achieving quicker mixing, this arrangement causes less wear on the plasma generator. Additional advantages and features of the invention will be revealed in the following detailed description with reference to the accompanying drawings in which Fig.1 shows the plasma generator according to the invention, Fig.2 shows an alternative embodiment of the plasma generator according to Fig.l and Fig.3 shows a somewhat modified embodiment of the plasma generator according to Fig.2. Figure 1 thus shows a burner according to the invention, with a plasma generator generally designated 1. The plasma generator is of conventional type with cylindrical electrodes between which an arc is generated. Carrier gas is injected through a supply pipe 2 and is heated upon passage through the arc. Besides acquiring an axial speed component in the plasma generator, the carrier gas also acquires a tangential speed component, so that the plasma gas rotates vigorously when leaving the plasma generator. 2 10168 Arranged around the front portion of the plasma generator is an outer pipe sealed to the plasma generator at 5. In the embodiment shown the outer pipe is provided with a flange 6 for fitting to a combustion or gasification chamber. This indicates that the outer pipe may be permanently fixed to a wall, thus considerably facilitating removal and replacement Of the plasma generator. In this case the outer pipe is preferably water-cooled, and by allowing it to protrude slightly past the chamber wall, the outer pipe can also function as a tuyere. Dry, pulverulent fuel is introduced through a pipe 7 into the annular space 8 formed between the plasma generator and the outer pipe. According to the embodiment shown a pressure chamber 9 is arranged at the inlet side of the annular space, the orifice of the supply pipe 7 being in this chamber. This ensures more uniform distribution of the material in the annular space. Figure 2 shows an alternative embodiment of the plasma generator according to Figure 1. An inner protective pipe 10 is arranged around the free end 3 of the plasma generator, surrounded by the outer pipe Outside the inner protective pipe 10 are blades 11-1*4, designed to give the pulverulent material introduced a direction of rotation opposite to that of the plasma gas generated. This provides better and more rapid mixing as well as protecting the plasma generator from wear. Figure 3 shows yet another embodiment of the plasma generator according to Figure 2. The outer pipe, here designated 15, is water-cooled, the coolant being supplied at 16 to the space 17* In the embodiment shown the outer, water-cooled pipe is in the form of an extended tuyere, intended to replace a conventional tuyere. The procedure and function of the arrangement are described in more detail in the following. 210168 Carrier gas, preferably comprising a part of the oxidizing agent used, is heated in the plasma generator and leaves the plasma generator as a hot core of rotating plasma gas. This ignites and causes vigorous turbulence in the pulverulent, carbonaceous material introduced through the annular space 8, preferably by means of oxidizing agent such as water vapour, oxygen, air or a mixture thereof. Contrary to the case with an oil burner, for instance, where firing is effected by the flame front whose location is determined by the flow conditions, the high temperature of the plasma gas ensures stable firing irrespective of other conditions. This provides an extremely wide control range for the plasma generator and considerably quicker initiation of firing and consequently higher total reaction speed. The hot plasma gas also reduces the need for excess oxygen to achieve substantially complete combustion/gasification. Furthermore, an extremely high flame temperature is obtained, considerably higher than in conventional burners, resulting in a greatly reduced percentage of undesired constituents in the gas after combustion/gasification, such as uncombusted/ungasified carbon, alcohols, phenols, methane, tar, heavy hydrocarbons, etc. Yet another decisive advantage is that an excess of thermal energy independent from the combustion is supplied through the plasma generator. This offers considerably greater opportunities of controlling the composition of the reaction products while at the same time reducing the risk of soot deposits. The matter contained in each of the following claims is to be read as part of the general description of the present invention. </div>

Claims

<div class="application article clearfix printTableText" id="claims"> 210168 What we claim is:

1. A method of partially combusting and gasifying pulverulent carbonaceous material by introducing oxidizing agent and said carbonaceous material into a reaction chamber while at the same time supplying thermal energy by means of a plasma generator, wherein a hot gas flow containing oxidizing agent is generated in a plasma generator and introduced into said reaction chamber and the pulverulent carbonaceous material is introduced concentrically around said hot gas flow with the aid of a transport gas.

2. A method according to claim 1, wherein the oxidizing agent used is O^t COj, water vapour, air or a mixture of one or more of said components.

3. A method according to claim lor claim 2, wherein the oxidizing agent is utilized as.transport gas for the carbonaceous material.

4. A method according to any one of claims 1 to 3, wherein the oxidizing agent is partially or wholly heated in the plasma generator to generate said hot gas flow.

5. A method according to any one of claims 1 to 4, wherein coal dust, charcoal powder, peat or shavings are used as carbonaceous material.

6. A means designed for partial combustion and gasification of pulverulent carbonaceous material by introducing oxidizing agent and said carbonaceous material into a reaction chamber while at the same time supplying thermal energy by means of a plasma generator, for performing the method according to claim 1, wherein the plasma generator comprises cylindrical electrodes between which an electric arc is generated, a supply pipe for the introduction of carrier gas into the plasma generator v,, s, C \ If.. |*2 7 FEB 1987 210168 means for imparting a tangential velocity component to the hot gas flow generated in the plasma generator, an outer tube arranged around the plasma generator to form an annular space between the outside of the plasma generator and said outer tube, at least at the outlet end of the plasma generator, and members for the supply of carbonaceous material to said annular space.

7. A means according to claim 6, wherein a pressure chamber is arranged in connection with the inlet side of the annular space, to effect uniform distribution of the carbonaceous material supplied.

8. A means according to claim 7, wherein the supply pipe for the carbonaceous material is arranged to open tangentially into said pressure chamber.

9. A means according to claim 6, wherein an inner, protective pipe is provided, having obliquely arranged blades to provide a rotary movement and to protect the plasma generator from wear.

10. A means according to any one of claims 6 to 9, wherein the outer pipe is water-cooled.

11. A means according to claim 10, wherein the water-cooled outer pipe is in the form of an extended tuyere.

12. A method of partially combusting and gasifying pulverulent carbonaceous material according to claim 1 and substantially as herein described with reference to any one of the embodiments illustrated in the accompanying drawings.

13. A means .for partial combustion and gasification of pulverulent carbonaceous material according to claim 6 and substantially as herein described with reference to any one of the embodiments illustrated in the accompanying drawings. 8 2 1 01 6

14. A mixture of gases comprising at least carbon monoxide and hydrogen and optionally comprising carbon dioxide and/or water whenever produced by a method according to any one of claims 1 to 5 and 12. SKF STEEL ENGINEERING AB By Their Attorneys </div>