NO994414L - Katalysatorsystem pÕ bærer for polymerisering av alk-1-ener - Google Patents

Katalysatorsystem pÕ bærer for polymerisering av alk-1-ener

Info

Publication number
NO994414L
NO994414L NO994414A NO994414A NO994414L NO 994414 L NO994414 L NO 994414L NO 994414 A NO994414 A NO 994414A NO 994414 A NO994414 A NO 994414A NO 994414 L NO994414 L NO 994414L
Authority
NO
Norway
Prior art keywords
groups
substituents
alkyl
halogen atoms
group
Prior art date
Application number
NO994414A
Other languages
English (en)
Other versions
NO994414D0 (no
Inventor
Marc Oliver Kristen
David Fischer
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of NO994414D0 publication Critical patent/NO994414D0/no
Publication of NO994414L publication Critical patent/NO994414L/no

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Et katalysatorsystem omfattende A) en organisk eller uorganisk bærer, B) minst ett metallocenkompleks, C) oligomere aluminiumoksydforbindelser og D) minst en borforbindelse med formel l -OR' R'-B eller en cyklisk borforbindelse med formel II B ^ \ o o II eller blandinger av borforbindelser l og II, hvor substituentene i formlene l og II har de følgende betydninger: R1 til R* er hver en Ci-C2o-alkylgruppe som kar: bæ- re halogenatomer, Ce-Cia-arylgrupper og/eller Ci-C-io-alkoksygrupper som sub- stituenter; en C4-C7-cykloalkylgruppe som kan bære halogenatomer, Ci-Cio-alkyl- grupper og/eller Ci-Cio-alkoksygrupper som substituenter; en Ci-Cio-alkoksy- el- ler alkylsulfidgruppe som kan bære halogenatomer, Ci-Cio-alkylgrupper og/eller Ce-Cis-arylgrupper som substituenter; en Cs-C-is-arylgruppe som kan bære halo- genatomer, Ci-Cio-alkylgrupper, Ci-Cto-halogenalkylgrupper, C4-Cio-cykloalkyl- grupper, Cs-C-is-arylgrupper, Ci-Cio-alkenylgnjpper, aminogrupper, monoalkyl- amino eller dialkylaminogrupper, nitrogrupper, formylgrupper, acetamidogrupper og/eller Ci-Cio-alkoksygrupper som substituenter; eller en mettet eller umettet Cs- Ci5-heterocyklisk gruppe som inneholder fra ett til tre oksygen-, svovel- og/eller nitrogenatomer i ringsystemet og som kan bære halogenatomer, Ce-Cis-arylgrup- per, ytterligere Cs-Cis-heterocykliske grupper og/eller Ci-Cio-alkylgrupper som substituenter; videre er R1 til R4 som definert ovenfor og bærer i tillegg fra en til tre ytterligere B(OR')(OR")-grupper eller, hvis R1 til R4 inneholder en aromatisk ring, er denne del av et metallocensystem; R' og R" er identiske eller forskjellige og er hver hydrogen eller en Ci-Cio-alkylgruppe, anvendes for polymerisering av C2-C12-alk-l-ener.
NO994414A 1997-03-11 1999-09-10 Katalysatorsystem pÕ bærer for polymerisering av alk-1-ener NO994414L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19709866A DE19709866A1 (de) 1997-03-11 1997-03-11 Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen
PCT/EP1998/000929 WO1998040418A1 (de) 1997-03-11 1998-02-18 Geträgertes katalysatorsystem zur polymerisation von alk-1-enen

Publications (2)

Publication Number Publication Date
NO994414D0 NO994414D0 (no) 1999-09-10
NO994414L true NO994414L (no) 1999-11-09

Family

ID=7822893

Family Applications (1)

Application Number Title Priority Date Filing Date
NO994414A NO994414L (no) 1997-03-11 1999-09-10 Katalysatorsystem pÕ bærer for polymerisering av alk-1-ener

Country Status (8)

Country Link
US (1) US6444764B1 (no)
EP (1) EP0968234B1 (no)
JP (1) JP4245667B2 (no)
KR (1) KR20000076121A (no)
CA (1) CA2283437A1 (no)
DE (2) DE19709866A1 (no)
NO (1) NO994414L (no)
WO (1) WO1998040418A1 (no)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10163154A1 (de) * 2001-12-20 2003-07-03 Basell Polyolefine Gmbh Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation
DE102004058578A1 (de) * 2004-12-03 2006-06-08 Basell Polyolefine Gmbh Verfahren zur Herstellung von Katalysatorsystemen später Übergangsmetalle
US8058200B2 (en) * 2007-05-17 2011-11-15 Chevron Phillips Chemical Company, L.P. Catalysts for olefin polymerization
US20130267407A1 (en) * 2010-12-15 2013-10-10 Basell Polyolefine Gmbh Method of preparing metallocene catalysts
EP2722344B1 (en) 2012-10-18 2017-03-22 Borealis AG Polymerisation process
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
EP2829558B1 (en) 2013-07-24 2016-12-14 Borealis AG Process
EP2829556B1 (en) 2013-07-24 2016-11-16 Borealis AG Process
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
WO2016171808A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
EP3274380B1 (en) 2015-04-20 2020-08-19 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
WO1987003889A1 (en) 1985-12-24 1987-07-02 Mitsui Petrochemical Industries, Ltd. Process for polymerization of alpha-olefins
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
ES2082745T3 (es) 1987-04-03 1996-04-01 Fina Technology Sistemas cataliticos metalocenos para la polimerizacion de las olefinas presentando un puente de hidrocarburo de silicio.
US5001244A (en) 1988-06-22 1991-03-19 Exxon Chemical Patents Inc. Metallocene, hydrocarbylaluminum and hydrocarbylboroxine olefin polymerization catalyst
US5411925A (en) 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
US5594078A (en) 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
DE4203753A1 (de) * 1992-02-10 1993-08-12 Basf Ag Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5391793A (en) 1992-11-02 1995-02-21 Akzo Nobel N.V. Aryloxyaluminoxanes
US5449650A (en) 1992-12-08 1995-09-12 Mitsubishi Petrochemical Company Limited Catalyst components for polymerization of olefins and use thereof
US5391529A (en) 1993-02-01 1995-02-21 Albemarle Corporation Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene
US5354721A (en) 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
US5412131A (en) 1993-07-09 1995-05-02 Albemarle Corporation Teritary amino-aluminoxane halides
US5414180A (en) 1993-07-14 1995-05-09 Phillips Petroleum Company Organo-aluminoxy product and use
ES2160634T3 (es) 1993-09-17 2001-11-16 Exxonmobil Chem Patents Inc Sistemas catalizadores de polimerizacion, su produccion y uso.
US5496781A (en) * 1994-05-16 1996-03-05 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators

Also Published As

Publication number Publication date
DE59813534D1 (de) 2006-06-14
CA2283437A1 (en) 1998-09-17
KR20000076121A (ko) 2000-12-26
EP0968234B1 (de) 2006-05-10
EP0968234A1 (de) 2000-01-05
JP2001514686A (ja) 2001-09-11
NO994414D0 (no) 1999-09-10
US6444764B1 (en) 2002-09-03
DE19709866A1 (de) 1998-09-17
WO1998040418A1 (de) 1998-09-17
JP4245667B2 (ja) 2009-03-25

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