NO346349B1 - Method to create a turbulent and directional movement of expanded glass particles after entering a plastic state - Google Patents
Method to create a turbulent and directional movement of expanded glass particles after entering a plastic state Download PDFInfo
- Publication number
- NO346349B1 NO346349B1 NO20200660A NO20200660A NO346349B1 NO 346349 B1 NO346349 B1 NO 346349B1 NO 20200660 A NO20200660 A NO 20200660A NO 20200660 A NO20200660 A NO 20200660A NO 346349 B1 NO346349 B1 NO 346349B1
- Authority
- NO
- Norway
- Prior art keywords
- plate body
- glass particles
- glass
- powder
- particles
- Prior art date
Links
- 239000002245 particle Substances 0.000 title claims description 117
- 239000011521 glass Substances 0.000 title claims description 67
- 238000000034 method Methods 0.000 title claims description 61
- 230000026058 directional locomotion Effects 0.000 title claims description 14
- 239000000843 powder Substances 0.000 claims description 29
- 239000000945 filler Substances 0.000 claims description 23
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 15
- 230000001133 acceleration Effects 0.000 claims description 13
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 13
- 230000033001 locomotion Effects 0.000 claims description 11
- 235000019353 potassium silicate Nutrition 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 238000004078 waterproofing Methods 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000004567 concrete Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000004570 mortar (masonry) Substances 0.000 claims description 3
- 239000011378 shotcrete Substances 0.000 claims description 3
- 229910021487 silica fume Inorganic materials 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 229940032158 sodium silicate Drugs 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 235000019794 sodium silicate Nutrition 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000011505 plaster Substances 0.000 claims description 2
- 239000011178 precast concrete Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 1
- 239000008188 pellet Substances 0.000 description 12
- 239000004604 Blowing Agent Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/108—Forming porous, sintered or foamed beads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/28—Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/109—Glass-melting furnaces specially adapted for making beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
- C03C1/026—Pelletisation or prereacting of powdered raw materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Road Repair (AREA)
Description
Field of invention:
The present invention relates to the method of creating a high frequent, turbulent and directional movement of one or more expanded glass particles made from recycled glass and a blowing agent when entering a plastic state at high temperature to avoid sticking or merger of particles during the expansion phase. In the expansion phase the particles will move more than 85% of time in air.
Background:
There is an increasing demand for expanded glass pellets made from recycled glass to be used as insulants, lightweight aggregates in concrete, or fillers in epoxy, or other applications where low weight, low water absorption, flowability and high insulation capacity is needed.
Traditionally expanded glass pellets have been made from recycled glass powder, water glass, one or more additional blowing agents, and some time metakaolin, all mixed in order to form a slurry, then granulated into pellets and dried, to be foamed at temperature between 780<o>C and 950<o>C, preferably at temperatures below 850<o>C in a rotary kiln as mentioned in WO 2016/124428 A1.
Other prior art suggests the use of recycled glass powder and SiC as the blowing agent as part of a two-stage sintering process where foaming takes place at temperatures above 850<o>C, as mentioned in WO 2019/002561 A1.
To be able to produce an approximately spherical and expanded glass product at temperatures above 850<o>C with SiC as the blowing agent, the problem of sticking or merger of the particles when they enter a plastic state needs to be overcome, and especially when the production volume is large.
Prior art shows good results of using virgin kaolin powder as a release agent to overcome problem at process temperatures below 850<o>C.
On the other side, at temperatures above 850<o>C the release agent transforms into metakaolin and it loses some of its release agent properties. In addition, the metakaolin tends to melt into the surface of the expanded pellets in its plastic state due to the softening of the product, hence reducing the release properties of the agent. This problem increases as closer to the elastic state of the expanded glass pellets the foaming process needs to take place, and it increases with time at 3 operating temperature, and the amount of blowing agent used due to excess heat created from the exotherm reaction taking place inside the pellets that again reduces the viscosity of the expanded particle.
This invention overcomes the problem of prior art of sticking or merger of the expanded glass pellets at temperatures above 850<o>C and at all temperatures below the transition temperature where the expanded glass pellets enters an elastic state, making it possible to produce continuously large volume of expanded glass pellets and gaining economies of scale.
Summary of the invention:
The present invention provides a method of creating a high frequent, turbulent, and directional movement of glass particles that are applied to the surface of a horizontally angled plate body exposed to vertically angled g-forces at high temperature, the plate body being attached on top of a vibration table with a vibration engine attached under, where the frequency of the vibration engine is in the range from 25Hz to 75Hz.
Further embodiments of the method according to the present invention are described in the dependent patent claims.
The present invention has as one of its objectives to overcome the disadvantages of the prior art, by introducing a method to be able to make large volumes of approximately spherical expanded glass products at high temperature without any risk of sticking or merger of the expanded glass pellets before it has reached its solid state after cooling.
The present invention comprises a method to create a high frequent, turbulent and directional movement of one or more expanded glass particles at temperatures above 850<o>C and to avoid sticking or merger of the particles when entering a plastic state, but below the elastic state of the particle.
According to one aspect, the particles are added onto a horizontally angled vibrating plate body placed inside a furnace.
According to another aspect, the uniformly created and vertically angled g-force on top of the plate body, created by a vibration engine located under the plate body and outside the furnace, should be strong enough to create a turbulent movement in the particles, keep the particles in air more than 85% of the time, limit the time two particles are in direct contact with each other to not create any sticking or merger opportunities between them.
According to another aspect, the particles should move in one direction through the furnace to enable control of process time for each particle.
According to another aspect, different combinations of release agents are introduced to create a mineral on the surface of the particles and on the surface of the plate body, further reduce the risk of sticking or merger of particles or sticking to the plate body, when production volume is large.
According to another aspect, different combinations of water glass solutions are introduced to coat the particles to enhance strength or alter the surface of the particles or increase waterproofing of the particles or to bind dust.
According to another aspect, the expanded glass pellets can be used as filler in concrete, as filler in epoxy, as filler in artificial turf systems, or as filler in water filtration cartridges.
Brief description of the drawings:
The invention will now be described with reference to the attached figures, wherein:
Fig.1 shows particles (1) on top of a plate body (3) on top of a vibration engine (9) attached under a vibration table.
Fig.2 shows the surface of the plate body (3) and the g-force distribution (4)
Fig.3 shows the plate body (3) and the vibration engine (9) and the particle (1) movement from the side.
Fig.4 shows the result from example 1 of where particles move in an independent, turbulent, and directional movement over the plate body at a temperature of 850<o>C.
Fig.5 shows the result from example 2 of where particles move in an independent, turbulent, and directional movement over the plate body at a temperature of 25<o>C.
Fig.6 shows approximately spherical expanded glass pellets made according to example 1.
Detailed description:
The invention will now be described with reference to the drawings, which show sintered glass particles on top of a plate body under positive or negative acceleration and at high temperature.
The reference numeral 1 indicates a particle made from recycled glass and a blowing agent.
2 indicates the surface of a plate body
3 indicated the plate body
4 indicates a position on top of the plate body
5 indicated the directional movement of a particle
6 indicates the turbulent movement on one particle
7 indicated a projectile mode of one particle
8 indicates the free fall mode of one particle
9 indicates the vibration engine
10 indicates horizontally angle on the plate body
11 indicates the vertically stroke angle on the vibration engine
A detailed description of the method.
Fig.1 and fig.3 shows a plate body (3) being attached on top of a vibration table with a vibration engine (9) attached under. The vertically angle of the stroke from the vibration engine (11) can be adjusted to force the particles (1) to move in one direction (5). The length of the legs on the plate body (3) can be designed to give the desired horizontally angle (10) on the plate body (3).
Fig.2 shows that the vibration engine (9) must be designed so that it can deliver a force large enough to create a g-force from 3G to 8 G (4) on the surface (2) of the plate body (3) to keep the particles (1) in air more than 85% of the time and to operate at frequencies in the range of 25Hz to 75Hz. The difference in g-force on any point (4) on the surface (2) of the plate body (3) should be no more than 1.5G, preferably less than 1G to be able to create a directional movement (5) over the plate body (3).
The plate body (3) must be designed in a material that can withstand stress from vibration in the range of 25hz to 75hz, preferably 28hz to 50hz, and withstand cyclical oxidation, at a minimum temperature of 850<o>C and maximum 950<o>C.
The g-force created on top (2) of the plate body (3) must be large enough to create a turbulent (6) and directional (5) movement of a glass particle (1) of the desired size and density and to keep the particles(1) in air more than 85% of time.
The frequency of the vibrating engine (9) must be set high enough to limit the contact time between the particles (1) to no more than 40 milliseconds, preferably below 28 milliseconds. As smaller the particles (1) as higher the frequency is needed.
The plate body (3) is placed inside a furnace, while the vibration table and vibration engine (9) are placed outside the furnace to protect from the heat.
The vibration engine (9) should deliver a directional linear vibration energy, obtained by using two vibration motors there the rotational directions are opposite of each other.
Various aspects / details of the invention
According to one aspect of the invention, the vertically g-forces are formed by positive or negative acceleration of the plate body (3) indicated by (2πf)<2>A/G+1, where f=frequency, A=amplitude and G=gravitational constant.
According to another aspect of the invention, the positive and negative acceleration of the plate body (3) is greater than G.
According to another aspect of the invention, the positive and negative acceleration of the particle (1) is between 0 and the acceleration of the plate body (3).
According to another aspect of the invention, the direction of stroke of the vibration engine (9) has a vertical angle (11) from 0.1<o>to 25<o>.
According to another aspect of the invention, the particle (1) is either in a projectile mode (7) or in a free fall mode (8).
According to another aspect of the invention, the degree of turbulence (6) in the particle (1) is affected by the difference in g-force between the plate body (3) and the particle (1), the greater the difference in g-force, the greater the turbulent movement of particle (1).
According to another aspect of the invention, the particles (1) are in air more than 85% of the time. According to another aspect of the invention, the frequency of the vibration engine (9) is in the range from 25Hz to 75Hz, preferably from 28Hz to 50 Hz.
According to another aspect of the invention, the operating temperature in the furnace should be from 564<o>C to 950<o>C, preferably from 850<o>c to 920<o>C.
According to another aspect of the invention, the particles (1) contain a minimum of 65wt% SiO2, 10wt% Na2O and 5wt% CaO.
According to another aspect of the invention, the particles (1) have a particle size from 0.01mm to 60.0mm, preferably 0.2mm to 8.0mm.
According to another aspect of the invention, the particles (1) are approximately spherical.
According to another aspect of the invention, the particles (1) have a density from 0.5kg/l to 1.8kg/l. According to another aspect of the invention, the particles (1) have a directional speed above the plate body (3) from 0.005m/sec. to 0.5m/sec.
According to another aspect of the invention, the plate body (3) has a horizontal angle from 0.1 degrees to 25 degrees.
According to another aspect of the invention, the particles (1) are made from 80-99wt% recycled glass powder, 0.01-10wt% micro silica, and 1-10wt% SiC powder, sintered at temperature from 650<o>C to 850<o>C for a minimum of 10 min. and a maximum of 180 min., then crushed into desired particle size.
According to another aspect of the invention, the foaming agent consist of SiC particles with a fraction size of 0.1<10-6>m to 40<10-6>m, preferably 0.1<10-6>m to 2.0<10-6>m.
According to another aspect of the invention, the particles (1) are powder coated with 0.5-10wt% of virgin kaolin powder and 0.5-5wt% of talc power before the particle is heated up, to act as a release agent.
According to another aspect of the invention, the particles (1) can alternatively be made from a slurry of 80-90wt% recycled glass powder, 7-12wt% of water glass, 0-3wt% metakaolin powder, pelletized in a granulator pan, then dried.
According to another aspect of the invention, the particles (1) are coated with 0.1wt%-5wt% of a Sodium-silicate solution before coated with kaolin and talc.
According to another aspect of the invention, the expanded particles (1) can be treated with different water glass solutions at temperatures from 0.1<o>C to 200<o>C. for dust binding or strength enhancing or water proofing or for making the surface smoother.
According to another aspect of the invention, the excess kaolin powder and talc powder that fall off the particles (1) during movement, will sinter into a mineral on top of the surface of the plate body (3), where in contact with the moving particles (1).
According to another aspect of the invention, some of the kaolin and talc powder that stays on the surface of the particles (1) during expansion phase, will sinter into a mineral on the surface of the particle (1).
According to another aspect of the invention, the expanded particles (1) after cooling, can be used as filler in artificial turf systems or filler in shotcrete, or filler in mortar and plaster, or filler in precast concrete, or filler in epoxy or filler inside water filtration cartridges.
According to another aspect of the invention, the plate body (3) is made from a metal with high creep strength, very good resistance to isothermal and, particularly, cyclic oxidation, with good structural stability at temperatures up to 950<o>C, such as Sandvik 253MA, Nikrothal80 or similar alloys.
According to another aspect of the invention, the plate body (3) can be thermally coated on the surface to increase the resistance to cyclic oxidation.
Exemplary embodiments:
Example 1:
According to an example of operating modus where the following conditions where used:
1. Particles made from a sintered mixture of recycled glass powder and SiC as the blowing agent.
2. Particle Size: 1-2mm
3. Particle density: 1,2kg/l
4. Particles powder coated with 4% kaolin powder.
5. Temperature: 850<o>C
6. G-force: Not able to measure inside furnace at maximum temperature. Measured to 4.8-5.2G at ambient temperature.
7. Frequency: 43Hz
8. Vertical angle of vibration stroke: 5<0>
9. Horizontal angle of plate body: 3<o>
From example 1 we observed the following movement in the particle (Fig.4):
10. One directional speed over the plate body: 0.07m/s
11. Vertical jump of the particles above the surface of the plate body: 1-6mm
12. Observed a turbulent and independent movement of the particles
No sticking or merger of expanded glass particles was observed (fig.6).
Example 2:
According to an example of operating modus where the following conditions where used:
1. Particles made from a sintered mixture of recycled glass powder and SiC as the blowing agent.
2. Particle Size: 1-2mm
3. Particle density: 1,2kg/l
4. Particles were dry coated with 4% kaolin powder.
5. Temperature: 25<o>C
6. G-force: 4,8G - 5,2G measured on the surface of the plate body
7. Frequency: 43Hz
8. Vertical angle of vibration stroke: 5<0>
9. Horizontal angle of plate body: 3<o>
From example 2 we observed the following movement in the particle (Fig.5): 10. One directional speed over the plate body: 0.07m/s
11. Vertical jump of the particles above the surface of the plate body: 1-6mm 12. Observed turbulent and independent movement of the particles.
Claims (25)
Priority Applications (16)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21725832.6A EP4149883A1 (en) | 2020-05-10 | 2021-05-10 | Method and furnace for producing expanded silica particles |
PCT/IB2021/053938 WO2021229400A1 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
EP23190126.5A EP4273109A3 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
HRP20230953TT HRP20230953T1 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
CN202180034048.2A CN115515896A (en) | 2020-05-10 | 2021-05-10 | Expandable silica particles |
EP21725833.4A EP4149884B1 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
HUE21725833A HUE063569T2 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
CN202180034051.4A CN115515897A (en) | 2020-05-10 | 2021-05-10 | Method and furnace for producing expanded silica particles |
MX2022014187A MX2022014187A (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle. |
AU2021272735A AU2021272735A1 (en) | 2020-05-10 | 2021-05-10 | Method and furnace for producing expanded silica particles |
MX2022014183A MX2022014183A (en) | 2020-05-10 | 2021-05-10 | Method and furnace for producing expanded silica particles. |
AU2021271289A AU2021271289B2 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
PL21725833.4T PL4149884T3 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
ES21725833T ES2953398T3 (en) | 2020-05-10 | 2021-05-10 | Expandable silica particle |
PCT/IB2021/053936 WO2021229399A1 (en) | 2020-05-10 | 2021-05-10 | Method and furnace for producing expanded silica particles |
US17/896,412 US11976000B2 (en) | 2020-05-10 | 2022-08-26 | Expandable silica particles and methods for making and using the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20200545 | 2020-05-10 |
Publications (2)
Publication Number | Publication Date |
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NO20200660A1 NO20200660A1 (en) | 2021-11-11 |
NO346349B1 true NO346349B1 (en) | 2022-06-20 |
Family
ID=79170610
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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NO20200660A NO346349B1 (en) | 2020-05-10 | 2020-06-04 | Method to create a turbulent and directional movement of expanded glass particles after entering a plastic state |
Country Status (1)
Country | Link |
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NO (1) | NO346349B1 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3148045A (en) * | 1958-11-21 | 1964-09-08 | Union Carbide Corp | Methods and apparatus for producing sized spherical particles |
AT348363B (en) * | 1975-03-20 | 1979-02-12 | Salm & Co O | DEVICE FOR GRIPPING BOTTLES |
US4846676A (en) * | 1987-03-31 | 1989-07-11 | General Kinematics Corporation | Oscillating discharge chute |
US7381261B1 (en) * | 2006-12-21 | 2008-06-03 | United States Gypsum Company | Expanded perlite annealing process |
WO2019002561A1 (en) * | 2017-06-30 | 2019-01-03 | Glassolite As | Preparation of sintered granulate for the manufacturing of a foamed glass pellets |
-
2020
- 2020-06-04 NO NO20200660A patent/NO346349B1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3148045A (en) * | 1958-11-21 | 1964-09-08 | Union Carbide Corp | Methods and apparatus for producing sized spherical particles |
AT348363B (en) * | 1975-03-20 | 1979-02-12 | Salm & Co O | DEVICE FOR GRIPPING BOTTLES |
US4846676A (en) * | 1987-03-31 | 1989-07-11 | General Kinematics Corporation | Oscillating discharge chute |
US7381261B1 (en) * | 2006-12-21 | 2008-06-03 | United States Gypsum Company | Expanded perlite annealing process |
WO2019002561A1 (en) * | 2017-06-30 | 2019-01-03 | Glassolite As | Preparation of sintered granulate for the manufacturing of a foamed glass pellets |
Also Published As
Publication number | Publication date |
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NO20200660A1 (en) | 2021-11-11 |
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