NO346349B1 - Method to create a turbulent and directional movement of expanded glass particles after entering a plastic state - Google Patents

Method to create a turbulent and directional movement of expanded glass particles after entering a plastic state Download PDF

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Publication number
NO346349B1
NO346349B1 NO20200660A NO20200660A NO346349B1 NO 346349 B1 NO346349 B1 NO 346349B1 NO 20200660 A NO20200660 A NO 20200660A NO 20200660 A NO20200660 A NO 20200660A NO 346349 B1 NO346349 B1 NO 346349B1
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Norway
Prior art keywords
plate body
glass particles
glass
powder
particles
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NO20200660A
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Norwegian (no)
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NO20200660A1 (en
Inventor
Finn Erik Solvang
Norman Blank
Original Assignee
Valunor Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Valunor Ag filed Critical Valunor Ag
Priority to CN202180034051.4A priority Critical patent/CN115515897A/en
Priority to EP23190126.5A priority patent/EP4273109A3/en
Priority to AU2021272735A priority patent/AU2021272735A1/en
Priority to MX2022014183A priority patent/MX2022014183A/en
Priority to CN202180034048.2A priority patent/CN115515896A/en
Priority to EP21725833.4A priority patent/EP4149884B1/en
Priority to HUE21725833A priority patent/HUE063569T2/en
Priority to EP21725832.6A priority patent/EP4149883A1/en
Priority to MX2022014187A priority patent/MX2022014187A/en
Priority to PCT/IB2021/053938 priority patent/WO2021229400A1/en
Priority to HRP20230953TT priority patent/HRP20230953T1/en
Priority to AU2021271289A priority patent/AU2021271289B2/en
Priority to PL21725833.4T priority patent/PL4149884T3/en
Priority to ES21725833T priority patent/ES2953398T3/en
Priority to PCT/IB2021/053936 priority patent/WO2021229399A1/en
Publication of NO20200660A1 publication Critical patent/NO20200660A1/en
Publication of NO346349B1 publication Critical patent/NO346349B1/en
Priority to US17/896,412 priority patent/US11976000B2/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/10Forming beads
    • C03B19/108Forming porous, sintered or foamed beads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B1/00Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
    • B07B1/28Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/10Forming beads
    • C03B19/109Glass-melting furnaces specially adapted for making beads
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/02Pretreated ingredients
    • C03C1/026Pelletisation or prereacting of powdered raw materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C11/00Multi-cellular glass ; Porous or hollow glass or glass particles

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Road Repair (AREA)

Description

Field of invention:
The present invention relates to the method of creating a high frequent, turbulent and directional movement of one or more expanded glass particles made from recycled glass and a blowing agent when entering a plastic state at high temperature to avoid sticking or merger of particles during the expansion phase. In the expansion phase the particles will move more than 85% of time in air.
Background:
There is an increasing demand for expanded glass pellets made from recycled glass to be used as insulants, lightweight aggregates in concrete, or fillers in epoxy, or other applications where low weight, low water absorption, flowability and high insulation capacity is needed.
Traditionally expanded glass pellets have been made from recycled glass powder, water glass, one or more additional blowing agents, and some time metakaolin, all mixed in order to form a slurry, then granulated into pellets and dried, to be foamed at temperature between 780<o>C and 950<o>C, preferably at temperatures below 850<o>C in a rotary kiln as mentioned in WO 2016/124428 A1.
Other prior art suggests the use of recycled glass powder and SiC as the blowing agent as part of a two-stage sintering process where foaming takes place at temperatures above 850<o>C, as mentioned in WO 2019/002561 A1.
To be able to produce an approximately spherical and expanded glass product at temperatures above 850<o>C with SiC as the blowing agent, the problem of sticking or merger of the particles when they enter a plastic state needs to be overcome, and especially when the production volume is large.
Prior art shows good results of using virgin kaolin powder as a release agent to overcome problem at process temperatures below 850<o>C.
On the other side, at temperatures above 850<o>C the release agent transforms into metakaolin and it loses some of its release agent properties. In addition, the metakaolin tends to melt into the surface of the expanded pellets in its plastic state due to the softening of the product, hence reducing the release properties of the agent. This problem increases as closer to the elastic state of the expanded glass pellets the foaming process needs to take place, and it increases with time at 3 operating temperature, and the amount of blowing agent used due to excess heat created from the exotherm reaction taking place inside the pellets that again reduces the viscosity of the expanded particle.
This invention overcomes the problem of prior art of sticking or merger of the expanded glass pellets at temperatures above 850<o>C and at all temperatures below the transition temperature where the expanded glass pellets enters an elastic state, making it possible to produce continuously large volume of expanded glass pellets and gaining economies of scale.
Summary of the invention:
The present invention provides a method of creating a high frequent, turbulent, and directional movement of glass particles that are applied to the surface of a horizontally angled plate body exposed to vertically angled g-forces at high temperature, the plate body being attached on top of a vibration table with a vibration engine attached under, where the frequency of the vibration engine is in the range from 25Hz to 75Hz.
Further embodiments of the method according to the present invention are described in the dependent patent claims.
The present invention has as one of its objectives to overcome the disadvantages of the prior art, by introducing a method to be able to make large volumes of approximately spherical expanded glass products at high temperature without any risk of sticking or merger of the expanded glass pellets before it has reached its solid state after cooling.
The present invention comprises a method to create a high frequent, turbulent and directional movement of one or more expanded glass particles at temperatures above 850<o>C and to avoid sticking or merger of the particles when entering a plastic state, but below the elastic state of the particle.
According to one aspect, the particles are added onto a horizontally angled vibrating plate body placed inside a furnace.
According to another aspect, the uniformly created and vertically angled g-force on top of the plate body, created by a vibration engine located under the plate body and outside the furnace, should be strong enough to create a turbulent movement in the particles, keep the particles in air more than 85% of the time, limit the time two particles are in direct contact with each other to not create any sticking or merger opportunities between them.
According to another aspect, the particles should move in one direction through the furnace to enable control of process time for each particle.
According to another aspect, different combinations of release agents are introduced to create a mineral on the surface of the particles and on the surface of the plate body, further reduce the risk of sticking or merger of particles or sticking to the plate body, when production volume is large.
According to another aspect, different combinations of water glass solutions are introduced to coat the particles to enhance strength or alter the surface of the particles or increase waterproofing of the particles or to bind dust.
According to another aspect, the expanded glass pellets can be used as filler in concrete, as filler in epoxy, as filler in artificial turf systems, or as filler in water filtration cartridges.
Brief description of the drawings:
The invention will now be described with reference to the attached figures, wherein:
Fig.1 shows particles (1) on top of a plate body (3) on top of a vibration engine (9) attached under a vibration table.
Fig.2 shows the surface of the plate body (3) and the g-force distribution (4)
Fig.3 shows the plate body (3) and the vibration engine (9) and the particle (1) movement from the side.
Fig.4 shows the result from example 1 of where particles move in an independent, turbulent, and directional movement over the plate body at a temperature of 850<o>C.
Fig.5 shows the result from example 2 of where particles move in an independent, turbulent, and directional movement over the plate body at a temperature of 25<o>C.
Fig.6 shows approximately spherical expanded glass pellets made according to example 1.
Detailed description:
The invention will now be described with reference to the drawings, which show sintered glass particles on top of a plate body under positive or negative acceleration and at high temperature.
The reference numeral 1 indicates a particle made from recycled glass and a blowing agent.
2 indicates the surface of a plate body
3 indicated the plate body
4 indicates a position on top of the plate body
5 indicated the directional movement of a particle
6 indicates the turbulent movement on one particle
7 indicated a projectile mode of one particle
8 indicates the free fall mode of one particle
9 indicates the vibration engine
10 indicates horizontally angle on the plate body
11 indicates the vertically stroke angle on the vibration engine
A detailed description of the method.
Fig.1 and fig.3 shows a plate body (3) being attached on top of a vibration table with a vibration engine (9) attached under. The vertically angle of the stroke from the vibration engine (11) can be adjusted to force the particles (1) to move in one direction (5). The length of the legs on the plate body (3) can be designed to give the desired horizontally angle (10) on the plate body (3).
Fig.2 shows that the vibration engine (9) must be designed so that it can deliver a force large enough to create a g-force from 3G to 8 G (4) on the surface (2) of the plate body (3) to keep the particles (1) in air more than 85% of the time and to operate at frequencies in the range of 25Hz to 75Hz. The difference in g-force on any point (4) on the surface (2) of the plate body (3) should be no more than 1.5G, preferably less than 1G to be able to create a directional movement (5) over the plate body (3).
The plate body (3) must be designed in a material that can withstand stress from vibration in the range of 25hz to 75hz, preferably 28hz to 50hz, and withstand cyclical oxidation, at a minimum temperature of 850<o>C and maximum 950<o>C.
The g-force created on top (2) of the plate body (3) must be large enough to create a turbulent (6) and directional (5) movement of a glass particle (1) of the desired size and density and to keep the particles(1) in air more than 85% of time.
The frequency of the vibrating engine (9) must be set high enough to limit the contact time between the particles (1) to no more than 40 milliseconds, preferably below 28 milliseconds. As smaller the particles (1) as higher the frequency is needed.
The plate body (3) is placed inside a furnace, while the vibration table and vibration engine (9) are placed outside the furnace to protect from the heat.
The vibration engine (9) should deliver a directional linear vibration energy, obtained by using two vibration motors there the rotational directions are opposite of each other.
Various aspects / details of the invention
According to one aspect of the invention, the vertically g-forces are formed by positive or negative acceleration of the plate body (3) indicated by (2πf)<2>A/G+1, where f=frequency, A=amplitude and G=gravitational constant.
According to another aspect of the invention, the positive and negative acceleration of the plate body (3) is greater than G.
According to another aspect of the invention, the positive and negative acceleration of the particle (1) is between 0 and the acceleration of the plate body (3).
According to another aspect of the invention, the direction of stroke of the vibration engine (9) has a vertical angle (11) from 0.1<o>to 25<o>.
According to another aspect of the invention, the particle (1) is either in a projectile mode (7) or in a free fall mode (8).
According to another aspect of the invention, the degree of turbulence (6) in the particle (1) is affected by the difference in g-force between the plate body (3) and the particle (1), the greater the difference in g-force, the greater the turbulent movement of particle (1).
According to another aspect of the invention, the particles (1) are in air more than 85% of the time. According to another aspect of the invention, the frequency of the vibration engine (9) is in the range from 25Hz to 75Hz, preferably from 28Hz to 50 Hz.
According to another aspect of the invention, the operating temperature in the furnace should be from 564<o>C to 950<o>C, preferably from 850<o>c to 920<o>C.
According to another aspect of the invention, the particles (1) contain a minimum of 65wt% SiO2, 10wt% Na2O and 5wt% CaO.
According to another aspect of the invention, the particles (1) have a particle size from 0.01mm to 60.0mm, preferably 0.2mm to 8.0mm.
According to another aspect of the invention, the particles (1) are approximately spherical.
According to another aspect of the invention, the particles (1) have a density from 0.5kg/l to 1.8kg/l. According to another aspect of the invention, the particles (1) have a directional speed above the plate body (3) from 0.005m/sec. to 0.5m/sec.
According to another aspect of the invention, the plate body (3) has a horizontal angle from 0.1 degrees to 25 degrees.
According to another aspect of the invention, the particles (1) are made from 80-99wt% recycled glass powder, 0.01-10wt% micro silica, and 1-10wt% SiC powder, sintered at temperature from 650<o>C to 850<o>C for a minimum of 10 min. and a maximum of 180 min., then crushed into desired particle size.
According to another aspect of the invention, the foaming agent consist of SiC particles with a fraction size of 0.1<10-6>m to 40<10-6>m, preferably 0.1<10-6>m to 2.0<10-6>m.
According to another aspect of the invention, the particles (1) are powder coated with 0.5-10wt% of virgin kaolin powder and 0.5-5wt% of talc power before the particle is heated up, to act as a release agent.
According to another aspect of the invention, the particles (1) can alternatively be made from a slurry of 80-90wt% recycled glass powder, 7-12wt% of water glass, 0-3wt% metakaolin powder, pelletized in a granulator pan, then dried.
According to another aspect of the invention, the particles (1) are coated with 0.1wt%-5wt% of a Sodium-silicate solution before coated with kaolin and talc.
According to another aspect of the invention, the expanded particles (1) can be treated with different water glass solutions at temperatures from 0.1<o>C to 200<o>C. for dust binding or strength enhancing or water proofing or for making the surface smoother.
According to another aspect of the invention, the excess kaolin powder and talc powder that fall off the particles (1) during movement, will sinter into a mineral on top of the surface of the plate body (3), where in contact with the moving particles (1).
According to another aspect of the invention, some of the kaolin and talc powder that stays on the surface of the particles (1) during expansion phase, will sinter into a mineral on the surface of the particle (1).
According to another aspect of the invention, the expanded particles (1) after cooling, can be used as filler in artificial turf systems or filler in shotcrete, or filler in mortar and plaster, or filler in precast concrete, or filler in epoxy or filler inside water filtration cartridges.
According to another aspect of the invention, the plate body (3) is made from a metal with high creep strength, very good resistance to isothermal and, particularly, cyclic oxidation, with good structural stability at temperatures up to 950<o>C, such as Sandvik 253MA, Nikrothal80 or similar alloys.
According to another aspect of the invention, the plate body (3) can be thermally coated on the surface to increase the resistance to cyclic oxidation.
Exemplary embodiments:
Example 1:
According to an example of operating modus where the following conditions where used:
1. Particles made from a sintered mixture of recycled glass powder and SiC as the blowing agent.
2. Particle Size: 1-2mm
3. Particle density: 1,2kg/l
4. Particles powder coated with 4% kaolin powder.
5. Temperature: 850<o>C
6. G-force: Not able to measure inside furnace at maximum temperature. Measured to 4.8-5.2G at ambient temperature.
7. Frequency: 43Hz
8. Vertical angle of vibration stroke: 5<0>
9. Horizontal angle of plate body: 3<o>
From example 1 we observed the following movement in the particle (Fig.4):
10. One directional speed over the plate body: 0.07m/s
11. Vertical jump of the particles above the surface of the plate body: 1-6mm
12. Observed a turbulent and independent movement of the particles
No sticking or merger of expanded glass particles was observed (fig.6).
Example 2:
According to an example of operating modus where the following conditions where used:
1. Particles made from a sintered mixture of recycled glass powder and SiC as the blowing agent.
2. Particle Size: 1-2mm
3. Particle density: 1,2kg/l
4. Particles were dry coated with 4% kaolin powder.
5. Temperature: 25<o>C
6. G-force: 4,8G - 5,2G measured on the surface of the plate body
7. Frequency: 43Hz
8. Vertical angle of vibration stroke: 5<0>
9. Horizontal angle of plate body: 3<o>
From example 2 we observed the following movement in the particle (Fig.5): 10. One directional speed over the plate body: 0.07m/s
11. Vertical jump of the particles above the surface of the plate body: 1-6mm 12. Observed turbulent and independent movement of the particles.

Claims (25)

Claims:Claims: 1. A method of creating a high frequent, turbulent, and directional movement of glass particles that are applied to the surface (2) of a horizontally angled plate body (3) exposed to vertically angled g‐forces at high temperature, the plate body (3) being attached on top of a vibration table with a vibration engine (9) attached under, where the frequency of the vibration engine (9) is in the range from 25Hz to 75Hz.1. A method of creating a high frequent, turbulent, and directional movement of glass particles that are applied to the surface (2) of a horizontally angled plate body (3) exposed to vertically angled g‐forces at high temperature, the plate body (3) being attached on top of a vibration table with a vibration engine (9) attached below, where the frequency of the vibration engine (9) is in the range from 25Hz to 75Hz. 2. A method according to claim 1, where the g‐forces are formed by positive or negative acceleration of the plate body (3) indicated by (2πf)<2>A/G+1, where f=frequency, A=amplitude and G=gravitational constant.2. A method according to claim 1, where the g‐forces are formed by positive or negative acceleration of the plate body (3) indicated by (2πf)<2>A/G+1, where f=frequency, A=amplitude and G=gravitational constant. 3. A method according to claim 1, where positive and negative acceleration of the plate body (3) is greater than G and the positive and negative acceleration of the glass particles is between 0 and the acceleration of the plate body (3).3. A method according to claim 1, where positive and negative acceleration of the plate body (3) is greater than G and the positive and negative acceleration of the glass particles is between 0 and the acceleration of the plate body (3). 4. A method according to claim 2, where a constant g‐force of a minimum of 3 and a maximum of 8 works on the plate body (3) and where there is a maximum g‐force difference of 1.5 at any point on the upper surface (2) of the plate body (3) to obtain a directional movement. 4. A method according to claim 2, where a constant g-force of a minimum of 3 and a maximum of 8 works on the plate body (3) and where there is a maximum g-force difference of 1.5 at any point on the upper surface (2) of the plate body (3) to obtain a directional movement. 5. A method according to claim 1, where the glass particles are either in a projectile mode (7) or in a free fall mode (8).5. A method according to claim 1, where the glass particles are either in a projectile mode (7) or in a free fall mode (8). 6. A method according to claim 1, where the glass particles need to be in air more than 85% of the time.6. A method according to claim 1, where the glass particles need to be in air more than 85% of the time. 7. A method according to claim 2, where the g‐force is made from directional linear vibration energy.7. A method according to claim 2, where the g-force is made from directional linear vibration energy. 8. A method according to claim 7, where the directional linear vibration energy is obtained by using two vibration motors where the rotational directions are opposite of each other.8. A method according to claim 7, where the directional linear vibration energy is obtained by using two vibration motors where the rotational directions are opposite of each other. 9. A method according to claim 1, where the operating temperature is from 564<o>C ‐ 950<o>C, and which affects both the plate body (3) and the glass particles at the same time.9. A method according to claim 1, where the operating temperature is from 564<o>C - 950<o>C, and which affects both the plate body (3) and the glass particles at the same time. 10. A method according to claim 1, where the glass particles has a directional movement above the plate body (3) of from 0.005m/s to 0.5m/s.10. A method according to claim 1, where the glass particles have a directional movement above the plate body (3) of from 0.005m/s to 0.5m/s. 11. A method according to claim 1, where the plate body (3) has a horizontal angle (10) from 0.1<o >to 25<o>.11. A method according to claim 1, where the plate body (3) has a horizontal angle (10) from 0.1<o>to 25<o>. 12. A method according to claim 1, where the direction of stroke of the vibration engine (9) has a vertical angle (11) from 0,1<o >to 25<o>.12. A method according to claim 1, where the direction of stroke of the vibration engine (9) has a vertical angle (11) from 0.1<o>to 25<o>. 13. A method according to claim 1, where the glass particles are made from 80 ‐ 99wt% recycled glass powder, 0.01 ‐ 10wt% micro silica, and 1 ‐ 10wt% SiC powder, sintered at a temperature of from 650<o>C to 850<o>C for a minimum of 10 minutes and a maximum of 180 minutes. 13. A method according to claim 1, where the glass particles are made from 80 ‐ 99wt% recycled glass powder, 0.01 ‐ 10wt% micro silica, and 1 ‐ 10wt% SiC powder, sintered at a temperature of from 650<o>C to 850<o>C for a minimum of 10 minutes and a maximum of 180 minutes. 14. A method according to claim 13, comprising a foaming agent, where the foaming agent consists of 1 ‐ 10wt% of SiC powder with a particle range from 0.01*10<‐6>m to 40*10<‐6>m before sintering.14. A method according to claim 13, comprising a foaming agent, where the foaming agent consists of 1 ‐ 10wt% of SiC powder with a particle range from 0.01*10<‐6>m to 40*10<‐6>m before sintering. 15. A method according to claim 1, where the glass particles is made from a slurry of 80 ‐ 90wt% recycled glass powder, 7 ‐ 12wt% of water glass, 0 ‐ 3wt% metakaolin powder, pelletized in a granulator pan, then dried.15. A method according to claim 1, where the glass particles are made from a slurry of 80 ‐ 90wt% recycled glass powder, 7 ‐ 12wt% of water glass, 0 ‐ 3wt% metakaolin powder, pelletized in a granulator pan, then dried . 16. A method according to claim 1, where the glass particles have a particle size from 0.01mm to 60mm.16. A method according to claim 1, where the glass particles have a particle size from 0.01mm to 60mm. 17. A method according to claims 13 or 15, where the glass particles are coated with 0.5wt% -10wt% of kaolin powder and 0.5wt% ‐ 5wt% of talc powder before the glass particles are heated up according to claim 9, to act as a release agent.17. A method according to claims 13 or 15, where the glass particles are coated with 0.5wt% -10wt% of kaolin powder and 0.5wt% - 5wt% of talc powder before the glass particles are heated up according to claim 9, to act as a release agent. 18. A method according to claims 13 or 15, where the glass particles are coated with 0.1wt% -5wt% of a Sodium‐silicate solution before coated according to claim 17.18. A method according to claims 13 or 15, where the glass particles are coated with 0.1wt% -5wt% of a Sodium‐silicate solution before coated according to claim 17. 19. A method according to claims 3, 5 and 17, where excess coating powder releases from the glass particles and fall onto the surface (2) of the plate body (3) and exposed to impact from the moving glass particles, and exposure to a temperature from 564<o>C ‐ 950<o>C, creates a sintered mineral on the surface (2) of the plate body (3).19. A method according to claims 3, 5 and 17, where excess coating powder releases from the glass particles and fall onto the surface (2) of the plate body (3) and exposed to impact from the moving glass particles, and exposure to a temperature from 564<o>C - 950<o>C, creates a sintered mineral on the surface (2) of the plate body (3). 20. A method according to claim 19, where the mineral created acts as a release surface to avoid sticking of the glass particles at temperatures from 564<o>C ‐ 950<o>C.20. A method according to claim 19, where the mineral created acts as a release surface to avoid sticking of the glass particles at temperatures from 564<o>C ‐ 950<o>C. 21. A method according to claim 1, where the expanded glass particles after cooling are used as filler material in artificial turf systems, or as filler in shotcrete, or as filler for precast concrete, or as filler in plasters and mortar, or as filler in epoxy, or as filler for use in water filtration cartridges.21. A method according to claim 1, where the expanded glass particles after cooling are used as filler material in artificial turf systems, or as filler in shotcrete, or as filler for precast concrete, or as filler in plasters and mortar, or as filler in epoxy, or as filler for use in water filtration cartridges. 22. A method according to claim 21, where the expanded glass particles before use can be treated with different water glass solutions for dust binding or strength enhancing or water proofing or for making the surface smoother.22. A method according to claim 21, where the expanded glass particles before use can be treated with different water glass solutions for dust binding or strength enhancing or water proofing or for making the surface smoother. 23. A method according to claim 22, where the expanded glass particles are sprayed with water glass at temperatures between 0.1<o>C and 200<o>C.23. A method according to claim 22, where the expanded glass particles are sprayed with water glass at temperatures between 0.1<o>C and 200<o>C. 24. A method according to claim 1, where the plate body (3) consists of a metal with high creep strength, very good resistance to isothermal and, particularly, cyclic oxidation, good structural stability at temperatures up to 950<o>C, such as Sandvik 253MA, Nikrothal80 or alloys with similar or better characteristics.24. A method according to claim 1, where the plate body (3) consists of a metal with high creep strength, very good resistance to isothermal and, particularly, cyclic oxidation, good structural stability at temperatures up to 950<o>C, such as Sandvik 253MA, Nikrothal80 or alloys with similar or better characteristics. 25. A method according to claim 24, where the plate body (3) is thermally coated on the upper surface (2) to increase the resistance to cyclic oxidation. 25. A method according to claim 24, where the plate body (3) is thermally coated on the upper surface (2) to increase the resistance to cyclic oxidation. PATENTKRAVPATENT CLAIMS 1. En fremgangsmåte for å skape en høy frekvent, turbulent og retningsbestemt bevegelse av glasspartikler som påføres overflaten (2) på et horisontalt vinklet platelegeme (3) utsatt for vertikalt vinklede g-krefter ved høy temperatur, platelegemet (3) festes på toppen av et vibrasjonsbord med en vibrasjonsmotor (9) festet under, hvor frekvensen til vibrasjonsmotoren (9) er i området fra 25Hz til 75Hz.1. A method of creating a high frequency, turbulent and directional movement of glass particles applied to the surface (2) of a horizontally angled plate body (3) subjected to vertically angled g-forces at high temperature, the plate body (3) being fixed on top of a vibration table with a vibration motor (9) fixed underneath, where the frequency of the vibration motor (9) is in the range from 25Hz to 75Hz. 2. Fremgangsmåte ifølge krav 1, hvor g-kreftene dannes ved positiv eller negativ akselerasjon av platelegemet (3) antydet med (2πf)<2>A/G+1, hvor f = frekvens, A = amplitude og G = gravitasjonskonstant.2. Method according to claim 1, where the g-forces are formed by positive or negative acceleration of the plate body (3) indicated by (2πf)<2>A/G+1, where f = frequency, A = amplitude and G = gravitational constant. 3. Fremgangsmåte ifølge krav 1, hvor positiv og negativ akselerasjon av platelegemet (3) er større enn G og den positive og negative akselerasjonen til glasspartiklene er mellom 0 og akselerasjonen til platelegemet (3).3. Method according to claim 1, where positive and negative acceleration of the plate body (3) is greater than G and the positive and negative acceleration of the glass particles is between 0 and the acceleration of the plate body (3). 4. Fremgangsmåte ifølge krav 2, hvor en konstant g-kraft på minimum 3 og maksimum 8 virker på platelegemet (3) og hvor det er en maksimal g-kraftforskjell på 1,5 på hvilket som helst punkt på den øvre overflaten (2) på platelegemet (3) for å oppnå en retningsbestemt bevegelse.4. Method according to claim 2, where a constant g-force of minimum 3 and maximum 8 acts on the plate body (3) and where there is a maximum g-force difference of 1.5 at any point on the upper surface (2) on the plate body (3) to achieve a directional movement. 5. Fremgangsmåte ifølge krav 1, hvor glasspartiklene enten er i en prosjektilmodus (7) eller i en fritt fall modus (8).5. Method according to claim 1, where the glass particles are either in a projectile mode (7) or in a free fall mode (8). 6. Fremgangsmåte ifølge krav 1, hvor glasspartiklene må være i luft mer enn 85% av tiden.6. Method according to claim 1, where the glass particles must be in air more than 85% of the time. 7. Fremgangsmåte ifølge krav 2, hvor g-kraften er laget av retningsbestemt lineær vibrasjonsenergi.7. Method according to claim 2, where the g-force is made of directional linear vibration energy. 8. Fremgangsmåte ifølge krav 7, hvor den retningsbestemte lineære vibrasjonsenergien oppnås ved å bruke to vibrasjonsmotorer hvor rotasjonsretningene er motsatt av hverandre.8. Method according to claim 7, where the directional linear vibration energy is obtained by using two vibration motors where the directions of rotation are opposite to each other. 9. Fremgangsmåte ifølge krav 1, hvor driftstemperaturen er fra 564<o>C - 950<o>C, og som påvirker både platelegemet (3) og glasspartiklene samtidig. 9. Method according to claim 1, where the operating temperature is from 564<o>C - 950<o>C, and which affects both the plate body (3) and the glass particles at the same time. 10. Fremgangsmåte ifølge krav 1, hvor glasspartiklene har en retningsbestemt bevegelse over platelegemet (3) på fra 0,005 m/s til 0,5 m/s.10. Method according to claim 1, where the glass particles have a directional movement over the plate body (3) of from 0.005 m/s to 0.5 m/s. 11. Fremgangsmåte ifølge krav 1, hvor platelegemet (3) har en horisontal vinkel (10) fra 0,1<o >til 25<o>.11. Method according to claim 1, where the plate body (3) has a horizontal angle (10) from 0.1<o> to 25<o>. 12. Fremgangsmåte ifølge krav 1, hvor vibrasjonsmotorens (9) slagretning har en vertikal vinkel (11) fra 0,1<o >til 25<o>.12. Method according to claim 1, where the vibration motor's (9) stroke direction has a vertical angle (11) from 0.1<o> to 25<o>. 13. Fremgangsmåte ifølge krav 1, hvor glasspartiklene er laget av 80 - 99 vekt% resirkulert glasspulver, 0,01 - 10 vekt% mikrosilika og 1 - 10 vekt% SiC pulver, sintret ved en temperatur fra 650<o>C til 850<o>C i minimum 10 minutter og maksimalt 180 minutter.13. Method according to claim 1, where the glass particles are made of 80 - 99% by weight recycled glass powder, 0.01 - 10% by weight microsilica and 1 - 10% by weight SiC powder, sintered at a temperature from 650<o>C to 850< o>C for a minimum of 10 minutes and a maximum of 180 minutes. 14. Fremgangsmåte ifølge krav 13, omfattende et skummiddel, hvor skummiddelet består av 1 - 10 vekt% SiC-pulver med et partikkelområde fra 0,01*10<-6>m til 40*10<-6>m før sintring.14. Method according to claim 13, comprising a foaming agent, where the foaming agent consists of 1 - 10% by weight of SiC powder with a particle range from 0.01*10<-6>m to 40*10<-6>m before sintering. 15. Fremgangsmåte ifølge krav 1, hvor glasspartiklene er laget av en oppslemming av 80 - 90 vekt% resirkulert glasspulver, 7 - 12 vekt% vannglass, 0 - 3 vekt% metakaolin pulver, pelletisert i en granulatorbeholder og deretter tørket.15. Method according to claim 1, where the glass particles are made from a slurry of 80 - 90% by weight recycled glass powder, 7 - 12% by weight water glass, 0 - 3% by weight metakaolin powder, pelletized in a granulator container and then dried. 16. Fremgangsmåte ifølge krav 1, hvor glasspartiklene har en partikkelstørrelse fra 0,01 mm til 60 mm.16. Method according to claim 1, where the glass particles have a particle size from 0.01 mm to 60 mm. 17. Fremgangsmåte ifølge krav 13 eller 15, hvor glasspartiklene er belagt med 0,5 vekt% - 10 vekt% kaolinpulver og 0,5 vekt% - 5 vekt% talkum før glasspartiklene varmes opp ifølge krav 9, for å fungere som et løsemiddel.17. Method according to claim 13 or 15, where the glass particles are coated with 0.5 wt% - 10 wt% kaolin powder and 0.5 wt% - 5 wt% talc before the glass particles are heated according to claim 9, to act as a solvent. 18. Fremgangsmåte ifølge krav 13 eller 15, hvor glasspartiklene er belagt med 0,1 vekt% -5 vekt% av en natriumsilikatoppløsning før de belegges i henhold til krav 17.18. Method according to claim 13 or 15, where the glass particles are coated with 0.1% by weight - 5% by weight of a sodium silicate solution before they are coated according to claim 17. 19. Fremgangsmåte ifølge krav 3, 5 og 17, hvor overflødig beleggpulver frigjøres fra glasspartiklene og faller på overflaten (2) på platelegemet (3) og utsettes for støt fra glasspartiklene i bevegelse, og eksponering for en temperatur fra 564<o>C - 950<o>C, skaper et sintret mineral på overflaten (2) av platelegemet (3). 19. Method according to claims 3, 5 and 17, where excess coating powder is released from the glass particles and falls on the surface (2) of the plate body (3) and is subjected to impact from the glass particles in motion, and exposure to a temperature from 564<o>C - 950<o>C, creates a sintered mineral on the surface (2) of the plate body (3). 20. Fremgangsmåte ifølge krav 19, hvor det dannede mineral fungerer som en frigjøringsoverflate for å unngå at glasspartiklene kleber ved temperaturer fra 564<o>C -950<o>C.20. Method according to claim 19, where the formed mineral acts as a release surface to prevent the glass particles from sticking at temperatures from 564<o>C -950<o>C. 21. Fremgangsmåte ifølge krav 1, hvor de ekspanderte glasspartiklene etter avkjøling brukes som fyllmateriale i kunsttorv systemer, eller som fyllstoff i sprøytebetong, eller som fyllstoff for ferdigbetong, eller som fyllstoff i gips og mørtel, eller som fyllstoff i epoxy, eller som fyllstoff for bruk i vannfiltreringskassetter.21. Method according to claim 1, where the expanded glass particles after cooling are used as filler in artificial turf systems, or as filler in shotcrete, or as filler for ready-mixed concrete, or as filler in plaster and mortar, or as filler in epoxy, or as filler for use in water filtration cartridges. 22. Fremgangsmåte ifølge krav 21, hvor de ekspanderte glasspartiklene før bruk kan behandles med forskjellige vannglassløsninger for støvbinding eller styrkeforbedring eller vanntetting eller for å gjøre overflaten jevnere.22. Method according to claim 21, where the expanded glass particles before use can be treated with different water glass solutions for dust binding or strength improvement or waterproofing or to make the surface smoother. 23. Fremgangsmåte ifølge krav 22, hvor de ekspanderte glasspartiklene sprøytes med vannglass ved temperaturer mellom 0,1<o>C og 200<o>C.23. Method according to claim 22, where the expanded glass particles are sprayed with water glass at temperatures between 0.1<o>C and 200<o>C. 24. Fremgangsmåte ifølge krav 1, hvor platelegemet (3) består av et metall med høy krypstyrke, meget god motstand mot isotermisk og spesielt syklisk oksidasjon, god strukturell stabilitet ved temperaturer opp til 950<o>C, slik som Sandvik 253MA, Nikrothal80 eller legeringer med lignende eller bedre egenskaper.24. Method according to claim 1, where the plate body (3) consists of a metal with high creep strength, very good resistance to isothermal and especially cyclic oxidation, good structural stability at temperatures up to 950<o>C, such as Sandvik 253MA, Nikrothal80 or alloys with similar or better properties. 25. Fremgangsmåte ifølge krav 24, hvor platelegemet (3) er termisk belagt på den øvre overflaten (2) for å øke motstand mot syklisk oksidering. 25. Method according to claim 24, where the plate body (3) is thermally coated on the upper surface (2) to increase resistance to cyclic oxidation.
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EP21725832.6A EP4149883A1 (en) 2020-05-10 2021-05-10 Method and furnace for producing expanded silica particles
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EP23190126.5A EP4273109A3 (en) 2020-05-10 2021-05-10 Expandable silica particle
HRP20230953TT HRP20230953T1 (en) 2020-05-10 2021-05-10 Expandable silica particle
CN202180034048.2A CN115515896A (en) 2020-05-10 2021-05-10 Expandable silica particles
EP21725833.4A EP4149884B1 (en) 2020-05-10 2021-05-10 Expandable silica particle
HUE21725833A HUE063569T2 (en) 2020-05-10 2021-05-10 Expandable silica particle
CN202180034051.4A CN115515897A (en) 2020-05-10 2021-05-10 Method and furnace for producing expanded silica particles
MX2022014187A MX2022014187A (en) 2020-05-10 2021-05-10 Expandable silica particle.
AU2021272735A AU2021272735A1 (en) 2020-05-10 2021-05-10 Method and furnace for producing expanded silica particles
MX2022014183A MX2022014183A (en) 2020-05-10 2021-05-10 Method and furnace for producing expanded silica particles.
AU2021271289A AU2021271289B2 (en) 2020-05-10 2021-05-10 Expandable silica particle
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ES21725833T ES2953398T3 (en) 2020-05-10 2021-05-10 Expandable silica particle
PCT/IB2021/053936 WO2021229399A1 (en) 2020-05-10 2021-05-10 Method and furnace for producing expanded silica particles
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US7381261B1 (en) * 2006-12-21 2008-06-03 United States Gypsum Company Expanded perlite annealing process
WO2019002561A1 (en) * 2017-06-30 2019-01-03 Glassolite As Preparation of sintered granulate for the manufacturing of a foamed glass pellets

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Publication number Priority date Publication date Assignee Title
US3148045A (en) * 1958-11-21 1964-09-08 Union Carbide Corp Methods and apparatus for producing sized spherical particles
AT348363B (en) * 1975-03-20 1979-02-12 Salm & Co O DEVICE FOR GRIPPING BOTTLES
US4846676A (en) * 1987-03-31 1989-07-11 General Kinematics Corporation Oscillating discharge chute
US7381261B1 (en) * 2006-12-21 2008-06-03 United States Gypsum Company Expanded perlite annealing process
WO2019002561A1 (en) * 2017-06-30 2019-01-03 Glassolite As Preparation of sintered granulate for the manufacturing of a foamed glass pellets

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