NO20001143L - Brodannet fluorenyl/indenyl-metallocener og anvendelse derav - Google Patents
Brodannet fluorenyl/indenyl-metallocener og anvendelse deravInfo
- Publication number
- NO20001143L NO20001143L NO20001143A NO20001143A NO20001143L NO 20001143 L NO20001143 L NO 20001143L NO 20001143 A NO20001143 A NO 20001143A NO 20001143 A NO20001143 A NO 20001143A NO 20001143 L NO20001143 L NO 20001143L
- Authority
- NO
- Norway
- Prior art keywords
- indenyl
- bridged fluorenyl
- metallocenes
- indenyl metallocenes
- fluorenyl
- Prior art date
Links
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 title abstract 5
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 title abstract 5
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 title abstract 3
- 239000003446 ligand Substances 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Brodannede fluorenyl/indenyl-metallocener med substituenter ved 3-posisjonen av indenylet og anvendelsen derav i polymerisasjonen av olefiner er beskrevet. Det er også beskrevet en ny fremgangsmåte for fremstilling av brodannede fluorenyl/indenyl- ligander hvor indenylet har en substituent i 3-posisjonen og fremstillingen av metallocener med slike ligander.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/928,820 US5886202A (en) | 1997-01-08 | 1997-09-12 | Bridged fluorenyl/indenyl metallocenes and the use thereof |
PCT/US1998/013095 WO1999014219A1 (en) | 1997-09-12 | 1998-06-24 | Bridge fluorenyl/indenyl metallocenes and the use thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
NO20001143D0 NO20001143D0 (no) | 2000-03-06 |
NO20001143L true NO20001143L (no) | 2000-05-12 |
Family
ID=25456827
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO20001143A NO20001143L (no) | 1997-09-12 | 2000-03-06 | Brodannet fluorenyl/indenyl-metallocener og anvendelse derav |
Country Status (9)
Country | Link |
---|---|
US (1) | US5886202A (no) |
EP (1) | EP1023298A1 (no) |
KR (1) | KR20010023862A (no) |
CN (1) | CN1275985A (no) |
AU (1) | AU731445B2 (no) |
CA (1) | CA2302234A1 (no) |
HU (1) | HUP0004029A3 (no) |
NO (1) | NO20001143L (no) |
WO (1) | WO1999014219A1 (no) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2067525C (en) * | 1991-05-09 | 1998-09-15 | Helmut G. Alt | Organometallic fluorenyl compounds, preparation and use |
DE19637669A1 (de) | 1996-09-16 | 1998-03-19 | Hoechst Ag | Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung |
US6469188B1 (en) | 1999-01-20 | 2002-10-22 | California Institute Of Technology | Catalyst system for the polymerization of alkenes to polyolefins |
US6482905B1 (en) * | 1999-08-16 | 2002-11-19 | Phillips Petroleum Company | Unsymmetric unbridged bis-indenyl metallocenes and their use |
US6475947B1 (en) * | 1999-09-10 | 2002-11-05 | Phillips Petroleum Company | Oligomeric metallocenes and their use |
JP4554133B2 (ja) * | 1999-10-08 | 2010-09-29 | 三井化学株式会社 | メタロセン化合物、メタロセン化合物の製造方法、オレフィン重合触媒、ポリオレフィンの製造方法およびポリオレフィン |
US6534609B2 (en) | 2001-03-13 | 2003-03-18 | Chevron Phillips Chemical Company Lp | Method for making and using a metallocene catalyst system |
BR0211290A (pt) | 2001-07-19 | 2004-09-14 | Univation Tech Llc | Compostos de catalisador de metaloceno de baixa incorporação de comonÈmero |
US6936675B2 (en) * | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
CN1315919C (zh) * | 2001-07-19 | 2007-05-16 | 尤尼威蒂恩技术有限责任公司 | 具有改进物理性能的聚乙烯薄膜 |
RU2296135C2 (ru) * | 2001-07-19 | 2007-03-27 | Юнивейшн Технолоджиз, Ллс | Смешанные металлоценовые каталитические системы, содержащие компонент, обеспечивающий плохое включение сомономера, и компонент, обеспечивающий хорошее включение сомономера |
GB0118010D0 (en) | 2001-07-24 | 2001-09-19 | Borealis Tech Oy | Catalysts |
EP2511305B1 (en) | 2002-09-27 | 2019-05-29 | Mitsui Chemicals, Inc. | Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same |
US7026494B1 (en) | 2005-01-10 | 2006-04-11 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high melt index polymers without the use of hydrogen |
US7226886B2 (en) * | 2005-09-15 | 2007-06-05 | Chevron Phillips Chemical Company, L.P. | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
US7312283B2 (en) * | 2005-08-22 | 2007-12-25 | Chevron Phillips Chemical Company Lp | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
US7517939B2 (en) * | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
US7619047B2 (en) * | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
CN101781337B (zh) * | 2010-02-04 | 2013-11-13 | 华东理工大学 | 亚乙基桥联取代茚芴锆化合物及其制备方法和应用 |
CN102070731B (zh) * | 2011-01-28 | 2011-12-28 | 山东轻工业学院 | C2桥联茂金属异双核催化剂及其制备方法 |
CN102260284B (zh) * | 2011-05-26 | 2014-11-19 | 华东理工大学 | 亚乙基桥联茚芴锆化合物及其制备方法和高选择性催化丙烯二聚 |
US8431729B2 (en) | 2011-08-04 | 2013-04-30 | Chevron Phillips Chemical Company Lp | High activity catalyst compositions containing silicon-bridged metallocenes with bulky substituents |
US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
KR101685664B1 (ko) | 2014-09-05 | 2016-12-12 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법 |
CN105348330A (zh) * | 2014-11-05 | 2016-02-24 | 苏州亚培克生物科技有限公司 | 含3单取代或3,6二取代芴基的金属茂及其制备方法和应用 |
KR101768193B1 (ko) | 2014-12-15 | 2017-08-16 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법 |
EP3686209A1 (en) * | 2019-01-28 | 2020-07-29 | LANXESS Organometallics GmbH | Process for producing metallocenes |
KR102565858B1 (ko) * | 2019-07-30 | 2023-08-11 | 한화솔루션 주식회사 | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 |
US11325995B2 (en) | 2020-02-21 | 2022-05-10 | Chevron Phillips Chemical Company Lp | Metallocene catalysts for polyethylene |
CN112239474A (zh) * | 2020-09-22 | 2021-01-19 | 惠生(泰州)新材料科技有限公司 | 一种硅基桥联多取代茚-芴锆、铪络合物及其在烯烃高温聚合中的用途 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
US5393911A (en) * | 1991-05-09 | 1995-02-28 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
US5436305A (en) * | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
US5401817A (en) * | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
ES2082274T3 (es) * | 1991-05-27 | 1996-03-16 | Hoechst Ag | Procedimiento para la preparacion de poliolefinas sindiotacticas con amplia distribucion de masas moleculares. |
US5710224A (en) * | 1991-07-23 | 1998-01-20 | Phillips Petroleum Company | Method for producing polymer of ethylene |
US5594078A (en) * | 1991-07-23 | 1997-01-14 | Phillips Petroleum Company | Process for producing broad molecular weight polyolefin |
US5391789A (en) * | 1991-08-08 | 1995-02-21 | Hoechst Aktiengesellschaft | Bridged, chiral metallocenes, processes for their preparation and their use as catalysts |
US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
TW294669B (no) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
US5498581A (en) * | 1994-06-01 | 1996-03-12 | Phillips Petroleum Company | Method for making and using a supported metallocene catalyst system |
IT1275856B1 (it) * | 1995-03-03 | 1997-10-24 | Spherilene Srl | Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione |
SG64939A1 (en) * | 1995-07-17 | 2002-02-19 | Mitsui Chemicals Inc | Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer |
US5780659A (en) * | 1996-03-29 | 1998-07-14 | Phillips Petroleum Company | Substituted indenyl unbridged metallocenes |
CA2259905C (en) * | 1996-07-16 | 2006-01-31 | Exxon Chemical Patents, Inc. | Olefin polymerization process with alkyl-substituted metallocenes |
US5854363A (en) * | 1997-01-08 | 1998-12-29 | Phillips Petroleum Company | (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds |
US6329541B1 (en) * | 1997-01-08 | 2001-12-11 | Phillips Petroleum Company | Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds |
-
1997
- 1997-09-12 US US08/928,820 patent/US5886202A/en not_active Expired - Lifetime
-
1998
- 1998-06-24 KR KR1020007002543A patent/KR20010023862A/ko not_active Application Discontinuation
- 1998-06-24 CA CA002302234A patent/CA2302234A1/en not_active Abandoned
- 1998-06-24 AU AU81644/98A patent/AU731445B2/en not_active Ceased
- 1998-06-24 CN CN98810121A patent/CN1275985A/zh active Pending
- 1998-06-24 EP EP98931538A patent/EP1023298A1/en not_active Withdrawn
- 1998-06-24 WO PCT/US1998/013095 patent/WO1999014219A1/en not_active Application Discontinuation
- 1998-06-24 HU HU0004029A patent/HUP0004029A3/hu unknown
-
2000
- 2000-03-06 NO NO20001143A patent/NO20001143L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
KR20010023862A (ko) | 2001-03-26 |
NO20001143D0 (no) | 2000-03-06 |
AU8164498A (en) | 1999-04-05 |
WO1999014219A1 (en) | 1999-03-25 |
EP1023298A4 (en) | 2000-08-02 |
US5886202A (en) | 1999-03-23 |
CN1275985A (zh) | 2000-12-06 |
HUP0004029A2 (en) | 2001-03-28 |
HUP0004029A3 (en) | 2004-03-01 |
EP1023298A1 (en) | 2000-08-02 |
CA2302234A1 (en) | 1999-03-25 |
AU731445B2 (en) | 2001-03-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FC2A | Withdrawal, rejection or dismissal of laid open patent application |