NO152014B - DOUBLE DISHWASH - Google Patents
DOUBLE DISHWASH Download PDFInfo
- Publication number
- NO152014B NO152014B NO784258A NO784258A NO152014B NO 152014 B NO152014 B NO 152014B NO 784258 A NO784258 A NO 784258A NO 784258 A NO784258 A NO 784258A NO 152014 B NO152014 B NO 152014B
- Authority
- NO
- Norway
- Prior art keywords
- weight
- juice
- citrus
- active
- alkyl
- Prior art date
Links
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 26
- 235000020971 citrus fruits Nutrition 0.000 claims description 25
- 239000004094 surface-active agent Substances 0.000 claims description 24
- 241000207199 Citrus Species 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 10
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- -1 alkali metal salts Chemical class 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 230000003381 solubilizing effect Effects 0.000 claims description 2
- 239000000047 product Substances 0.000 description 19
- 235000005979 Citrus limon Nutrition 0.000 description 14
- 244000131522 Citrus pyriformis Species 0.000 description 14
- 238000004140 cleaning Methods 0.000 description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 10
- 238000004851 dishwashing Methods 0.000 description 8
- 239000013068 control sample Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000013601 eggs Nutrition 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 239000012085 test solution Substances 0.000 description 3
- 244000089742 Citrus aurantifolia Species 0.000 description 2
- 244000183685 Citrus aurantium Species 0.000 description 2
- 235000007716 Citrus aurantium Nutrition 0.000 description 2
- 244000276331 Citrus maxima Species 0.000 description 2
- 241001672694 Citrus reticulata Species 0.000 description 2
- 235000005976 Citrus sinensis Nutrition 0.000 description 2
- 240000002319 Citrus sinensis Species 0.000 description 2
- 241001522083 Citrus trifoliata Species 0.000 description 2
- 240000000560 Citrus x paradisi Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 235000000404 Poncirus trifoliata Nutrition 0.000 description 2
- 244000018633 Prunus armeniaca Species 0.000 description 2
- 235000009827 Prunus armeniaca Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- REICWNSBQADONN-UHFFFAOYSA-N 2-hydroxy-n,n-dimethyldodecan-1-amine oxide Chemical compound CCCCCCCCCCC(O)C[N+](C)(C)[O-] REICWNSBQADONN-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 240000000981 Citrus hystrix Species 0.000 description 1
- 235000002320 Citrus hystrix Nutrition 0.000 description 1
- 241000190410 Citrus longispina Species 0.000 description 1
- 235000001759 Citrus maxima Nutrition 0.000 description 1
- 235000001938 Citrus medica Nutrition 0.000 description 1
- 240000004307 Citrus medica Species 0.000 description 1
- 235000009088 Citrus pyriformis Nutrition 0.000 description 1
- 235000000882 Citrus x paradisi Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000015201 grapefruit juice Nutrition 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DZJFABDVWIPEIM-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)dodecan-1-amine oxide Chemical compound CCCCCCCCCCCC[N+]([O-])(CCO)CCO DZJFABDVWIPEIM-UHFFFAOYSA-N 0.000 description 1
- FQLPOSCSKORVRF-UHFFFAOYSA-N n,n-diethyltetradecan-1-amine oxide Chemical compound CCCCCCCCCCCCCC[N+]([O-])(CC)CC FQLPOSCSKORVRF-UHFFFAOYSA-N 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000015205 orange juice Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BGHJOVPDUCMEAT-UHFFFAOYSA-M potassium;phenylmethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)CC1=CC=CC=C1 BGHJOVPDUCMEAT-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Oppfinnelsen vedrører et flytende oppvaskmiddel med forbedret renseytelse. Mer spesielt vedrører oppfinnelsen et vandig oppvaskmiddel som er spesielt egnet for manuell ren-gjøring av tallerkner, glass, kjøkkenredskaper, bestikk og lignende. Det flytende oppvaskmiddel i henhold til oppfinnelsen inneholder saft av en citrusfrukt, f.eks. sitronsaft. The invention relates to a liquid dishwashing liquid with improved cleaning performance. More particularly, the invention relates to an aqueous washing-up liquid which is particularly suitable for manual cleaning of plates, glasses, kitchen utensils, cutlery and the like. The liquid washing-up liquid according to the invention contains juice of a citrus fruit, e.g. lemon juice.
Flytende vaskemiddelblandinger som inneholder sitronsaft er kjent på området. US-patent nr. 3.650.968 beskriver rengjør-ingsmidler for fjerning av fiskelukt, som omfatter 30-80 vekt% vann, 0,1-35 vekt% vaskemiddel og 0,1-15 vekt% citrus-saft (sitronsaft). Disse flytende vaskemiddelblandinger har imid-lertid meget dårlige oppvaskegenskaper og kan derfor ikke anvendes tilfredsstillende for rengjøring av tallerkner, glass, kjøkkenredskaper, bestikk og lignende. Liquid detergent compositions containing lemon juice are known in the art. US Patent No. 3,650,968 describes cleaning agents for removing fish odors, which comprise 30-80% by weight water, 0.1-35% by weight detergent and 0.1-15% by weight citrus juice (lemon juice). These liquid detergent mixtures, however, have very poor washing-up properties and therefore cannot be used satisfactorily for cleaning plates, glasses, kitchen utensils, cutlery and the like.
Det er et formål med oppfinnelsen å tilveiebringe et effektivt flytende oppvaskmiddel som dessuten er spesielt effektivt mot vanskelig smuss, f.eks. fra tallerkner, kjeler og panner og andre kjøkkenredskaper. It is an aim of the invention to provide an effective liquid washing-up agent which is also particularly effective against difficult dirt, e.g. from plates, pots and pans and other kitchen utensils.
Med "vanskelig smuss" menes her den vanskelige ende av By "difficult dirt" is meant here the difficult end of
oppvaskspektret, f.eks. innbrente proteiner og stivelse-smuss. the dishwashing spectrum, e.g. burnt-in proteins and starch dirt.
Disse og andre formål ved oppfinnelsen, som vil fremgå These and other purposes of the invention, which will appear
av det følgende, kan oppnås ved å kombinere et organisk syntetisk overflateaktivt system av to overflateaktive midler som definert nedenunder, med en citrus-saft i en mengde av 5-50 of the following, can be obtained by combining an organic synthetic surfactant system of two surfactants as defined below, with a citrus juice in an amount of 5-50
vekt%, basert på hele blandingen. Hvilken som helst saft av en citrus-frukt som tilhører den generelle klasse av citrusfrukter % by weight, based on the whole mixture. Any juice of a citrus fruit belonging to the general class of citrus fruits
kan anvendes, f.eks.: søte appelsiner (citrus sinensis); sure eller bitre appelsiner (citrus auranticum); mandariner (citrus reticulata); grapefrukt (citrus paradisi); pumelos (citrus grandis); sitroner (citrus limon); lime (citrus aurantifolia); sitroner (citrus medica); papeda (citrus hystrix) og trifolie-appelsiner (citrus trifoliata), selv om sitronsaft vil fore-trekkes i forbindelse med oppfinnelsen på grunn av at den er etablert med hensyn til akseptabilitet hos forbrukeren. can be used, eg: sweet oranges (citrus sinensis); sour or bitter oranges (citrus auranticum); tangerines (citrus reticulata); grapefruit (citrus paradisi); pumelos (citrus grandis); lemons (citrus limon); lime (citrus aurantifolia); lemons (citrus medica); papeda (citrus hystrix) and trifoliate oranges (citrus trifoliata), although lemon juice will be preferred in connection with the invention because it has been established with regard to consumer acceptability.
Med mindre annet er angitt, refererer de prosentandeler av fruktsaft som er angitt i denne beskrivelse, til fruktsaft av enkelt styrke. Betegnelsen "enkelt styrke" anvendes her for å angi den gjennomsnittlige styrke på fruktsaft som er klemt ut av frukten. Hvis konsentrerte safter anvendes, vil disse bli angitt ved å betegne styrkefaktoren f.eks. som "4x konsentrat". Unless otherwise stated, the percentages of fruit juice given in this description refer to single strength fruit juice. The term "single strength" is used here to indicate the average strength of juice squeezed from the fruit. If concentrated juices are used, these will be indicated by designating the strength factor, e.g. as "4x concentrate".
Produktene i henhold til oppfinnelsen er derfor spesielt laget for generell anvendelse for konvensjonell oppvask. De kan anvendes i den konsentrerte vandige form eller i den konven-sjonelle, sterkt fortynnede oppvaskoperasjon, og som gir en god renseeffekt kombinert med et forbruker-akseptabelt skumnivå og skumstabilitet. The products according to the invention are therefore especially made for general use for conventional dishwashing. They can be used in the concentrated aqueous form or in the conventional, highly diluted dishwashing operation, and which provide a good cleaning effect combined with a consumer-acceptable foam level and foam stability.
Følgelig omfatter det vandige oppvaskmiddel i henhold til oppfinnelsen, som har en pH-verdi på 5,5-10, et organisk overflateaktivt system og en citrussaft, og dette oppvaskmiddel er karakterisert ved at det består i det vesentlige av Consequently, the aqueous washing-up liquid according to the invention, which has a pH value of 5.5-10, comprises an organic surfactant system and a citrus juice, and this washing-up liquid is characterized in that it consists essentially of
a) 5-50 vekt% av citrussaft av enkelt styrke, eller en ekvi-valent mengde av en saft av multippel styrke, b) 15-43 vekt% av et organisk syntetisk overflateaktivt system som består av 1) 60-90 vekt% regnet på det overflateaktive system, av et første overflateaktivt middel utvalgt fra gruppen som består av vannløselige Cg_^g-alkylbenzensulfonater og c0 _n-alkylpolyetoksysulfater med 1-25 etoksygrupper; a) 5-50% by weight of citrus juice of single strength, or an equivalent amount of a juice of multiple strength, b) 15-43% by weight of an organic synthetic surfactant system consisting of 1) 60-90% by weight calculated on the surface-active system, of a first surface-active agent selected from the group consisting of water-soluble C 6 -g alkylbenzenesulfonates and C 0 -n alkyl polyethoxy sulfates having 1-25 ethoxy groups;
og and
2) 10-40 vekt% regnet på det overflateaktivte system, av et annet overflateaktivt middel utvalgt fra gruppen som består av Co Q — z _ u-alkylpolyetoksysulfater med 1-25 etoksygrupper, aminoksyder med en C^0_2g~alkylgruppe og to C-L_4-alkyl- eller -hydroksyalkylgrupper, og Cg_24~ alkanol- eller -alkylfenoletoksylater med 5-30 etoksygrupper, under den forutsetning at begge de overflateaktive midler (1) og (2) ikke kan være Cg_20-alkylpolyetoksysulfater med 1-25 etoksygrupper, idet de overflateaktive midler, hvis de er ioneaktive, er tilstede i form av sine alkalimetallsalter, ammoniumsalter, lavere alkanolaminsalter eller lavere alkylaminsalter, c) vanlig benyttede oppløseliggjørende forbindelser og 0-80 vekt% vann. 2) 10-40% by weight, calculated on the surface-active system, of another surface-active agent selected from the group consisting of Co Q — z _ u-alkyl polyethoxy sulfates with 1-25 ethoxy groups, amine oxides with a C^0_2g~alkyl group and two C- L_4-alkyl- or -hydroxyalkyl groups, and Cg_24~ alkanol- or -alkylphenol ethoxylates with 5-30 ethoxy groups, under the condition that both the surface-active agents (1) and (2) cannot be Cg_20-alkylpolyethoxysulfates with 1-25 ethoxy groups, the surface-active agents, if they are ion-active, is present in the form of its alkali metal salts, ammonium salts, lower alkanolamine salts or lower alkylamine salts, c) commonly used solubilizing compounds and 0-80% by weight of water.
Eksempler på ikke-ioniske vannløselige kondensasjonsproduk-ter oppnådd ved kondensering av 5-30 mol av et alkylenoksyd med 1 mol av en organisk hydrofob forbindelse er: a) kondensatene av etylenoksyd med alifatiske rettkjedede eller forgrenede, primære eller sekundære alkoholer med mer enn 8 karbonatomer, f.eks. slike som stammer fra talg- eller kokos-nøttfettsyrer, som inneholder 5-20 etylenoksydgrupper, og forgrenede C^-C^-alkoholer som er kondensert med 5-20 etylenoksydgrupper ; b) kondensatene av etylenoksyd med alkylfenoler, i hvilke fenolene kan være mono- eller polyalkylerte og det totale antall karbonatomer i sidekjeden eller -kjedene er 5-18. Spesifikke eksempler er kondensatene av 1 mol nonylfenol med 8-15 mol etylenoksyd; c) kondensatene av etylenoksyd med fettsyreestere, fortrinnsvis monofettsyreestere av sukkeralkoholene, sorbitol og manitolj d) polyetenoksyestere oppnådd ved omsetning av etylenoksyd med karboksylsyre, idet sistnevnte er naturlige fettsyrer eller syntetiske fettsyrer laget av oksydert paraffinvoks som har 8-20 karbonatomer, eller alkylbenzo- eller naftensyrer som har 5-18 karbonatomer i alkylkjeden; e) kondensasjonsproduktene av fett-acylalkanolamider av typen C7_17-alkyl-CO-NHC2H4OH, C7_17-alkyl-CO-N(C2H4OH)2 med etylenoksyd; f) kondensas jonsproduktene av Cg_^g-alkyl-, Cg_-^g-alkenyl- og Cg_^g-alkylarylaminer med etylenoksyd. Et spesifikt eksempel er Examples of non-ionic water-soluble condensation products obtained by condensation of 5-30 mol of an alkylene oxide with 1 mol of an organic hydrophobic compound are: a) the condensates of ethylene oxide with aliphatic straight-chain or branched, primary or secondary alcohols with more than 8 carbon atoms , e.g. those derived from tallow or coconut fatty acids, containing 5-20 ethylene oxide groups, and branched C^-C^ alcohols condensed with 5-20 ethylene oxide groups; b) the condensates of ethylene oxide with alkylphenols, in which the phenols may be mono- or polyalkylated and the total number of carbon atoms in the side chain or chains is 5-18. Specific examples are the condensates of 1 mol of nonylphenol with 8-15 mol of ethylene oxide; c) the condensates of ethylene oxide with fatty acid esters, preferably monofatty acid esters of the sugar alcohols, sorbitol and mannitol oil d) polyethene oxyesters obtained by reaction of ethylene oxide with carboxylic acid, the latter being natural fatty acids or synthetic fatty acids made from oxidized paraffin wax having 8-20 carbon atoms, or alkylbenzo- or naphthenic acids having 5-18 carbon atoms in the alkyl chain; e) the condensation products of fatty acylalkanolamides of the type C7_17-alkyl-CO-NHC2H4OH, C7_17-alkyl-CO-N(C2H4OH)2 with ethylene oxide; f) the condensation ion products of C₆₆₆ alkyl, C₆₆₆-alkenyl and C₆₆₆ alkylarylamines with ethylene oxide. A specific example is
kondensasjonsproduktet av 1 mol av et dodecylamin med 9-12 mol etylenoksyd. the condensation product of 1 mole of a dodecylamine with 9-12 moles of ethylene oxide.
Spesifikke eksempler på aminoksyder er dimetyldodecylamin-oksyd, dietyltetradecylaminoksyd, bis-(2-hydroksyetyl)-dodecylamin-oksyd og dimetyl-2-hydroksydodecylaminoksyd. Specific examples of amine oxides are dimethyldodecylamine oxide, diethyltetradecylamine oxide, bis-(2-hydroxyethyl)dodecylamine oxide and dimethyl-2-hydroxydodecylamine oxide.
Det er oppdaget at det ovenfor definerte overflateaktive system kan benyttes effektivt i kombinasjon med citrus-saft, It has been discovered that the surfactant system defined above can be used effectively in combination with citrus juice,
særlig sitronsaft, i de ovenfor angitte mengdeforhold, for til-veiebringelse av den ønskelige kombinerte effekt med hensyn til god vaskeevne, god skumopptreden og forbedret ytelse når det gjelder vanskelig smuss, særlig innbrente eller inntørkede proteiner eller stivelsesmuss, over et vidt pH-område fra praktisk sur pH til alkalisk pH, nemlig 5,5-10. Et foretrukket pH-område for produktet i henhold til oppfinnelsen er in particular lemon juice, in the above stated quantity ratios, for providing the desirable combined effect with regard to good washing ability, good foam performance and improved performance when it comes to difficult dirt, in particular burnt-in or dried-in proteins or starch sludge, over a wide pH range from practically acidic pH to alkaline pH, namely 5.5-10. A preferred pH range for the product according to the invention is
fra 6 til 8,5, mer spesielt fra 7 til 8,5. from 6 to 8.5, more particularly from 7 to 8.5.
Hvilken som helst kombinasjon av de ovenfor beskrevne første og andre overflateaktive midler kan anvendes for dannelse av det organiske syntetiske overflateaktive system i produktet i henhold til oppfinnelsen. Any combination of the first and second surfactants described above can be used to form the organic synthetic surfactant system in the product according to the invention.
Typiske eksempler på overflateaktive systemer er alkyl-benzensulfonat/alkylpolyetoksysulfat-blandinger; alkylbenzensulfo-nat/alkylpolyetoksysulfat/ikke-ioniske blandinger; alkylsulfat/- alkylbenzensulfonat/alkylpolyetoksysulfat-blandinger og alkyl-sulfat/alkylpolyetoksysulfat/aminoksyd-blandinger. Typical examples of surfactant systems are alkyl benzene sulphonate/alkyl polyethoxy sulphate mixtures; alkyl benzene sulfonate/alkyl polyethoxy sulfate/nonionic mixtures; alkyl sulfate/alkyl benzene sulfonate/alkyl polyethoxy sulfate mixtures and alkyl sulfate/alkyl polyethoxy sulfate/amine oxide mixtures.
Som forklart ovenfor, kan hvilken som helst type av citrus-saft i en mengde av 5-50 vekt% anvendes i forbindelse med oppfinnelsen, idet sitron-, lime-, appelsin- og grapefruktsafter er representative for den generelle klasse. Den minste mengde på 5 vekt% av citrus-saft brukes fordi effekten for lavere mengder er ikke signifikant eller praktisk talt null. Selv om enhver an-del over 5% av citrus-saft kan brukes, i henhold til hva som er praktisk mulig, er det funnet at store mengder ikke er nødvendig for å oppnå de ønskede fordeler. Dessuten, da det er et tydelig fall i økningen av ytelseforbedringene med økende saftinnhold over 10%, og det er et hurtig fall særlig i det høyere prosent-område, vil anvendelse av for store mengder av saft ikke rett-ferdiggjøre de ekstra høye omkostninger som involveres. As explained above, any type of citrus juice in an amount of 5-50% by weight can be used in connection with the invention, lemon, lime, orange and grapefruit juices being representative of the general class. The minimum amount of 5% by weight of citrus juice is used because the effect for lower amounts is not significant or practically zero. Although any proportion above 5% of citrus juice may be used, as far as is practical, it has been found that large amounts are not necessary to obtain the desired benefits. Also, since there is a clear drop in the increase in performance improvements with increasing juice content above 10%, and there is a rapid drop especially in the higher percentage range, the application of excessive amounts of juice will not justify the extra high costs that get involved.
50%, fortrinnsvis 2 5%, regnes som en bekvem praktisk 50%, preferably 2 5%, is considered a convenient practical
øvre grense for enkeltstyrke-citrus-saft i produktet i henhold til oppfinnelsen, da citrus-saft ved konsentrasjoner over disse prosenter ikke gir noen ytterligere fordeler som ville kompensere de store omkostninger med ekstra citrus-saft. upper limit for single-strength citrus juice in the product according to the invention, as citrus juice at concentrations above these percentages does not provide any additional benefits that would compensate for the large costs of extra citrus juice.
Et citrus-saft-nivå som det er særlig fordelaktig å an-vende i den flytende vaskemiddelblanding i henhold til oppfinnelsen, er fra 5 til 10 vekt%. A citrus juice level which is particularly advantageous to use in the liquid detergent mixture according to the invention is from 5 to 10% by weight.
Citrus-safter er tilgjengelige på markedet. De presen-teres generelt enten som enkeltstyrkesafter eller som konsentrater med forskjellige styrkegrader, d.v.s. fra 2x konsentrater og opp til 10x konsentrater. Sitronsaft inneholder en rekke forskjellige klasser av kjemiske forbindelser inklusive syrer, sukkere, amino-syrer, oljer og sporelementer. Analysedata angående citrus-saf te r finnes i følgende litteratur: Citrus juices are available in the market. They are generally presented either as single-strength juices or as concentrates with different degrees of strength, i.e. from 2x concentrates and up to 10x concentrates. Lemon juice contains a number of different classes of chemical compounds including acids, sugars, amino acids, oils and trace elements. Analysis data regarding citrus juices can be found in the following literature:
a) "Chemical Constituents of Citrus Fruits", Supp. 2 (1970) a) "Chemical Constituents of Citrus Fruits", Supp. 2 (1970)
av Kefford and Chandler; by Kefford and Chandler;
2) "Biochemistry of Fruits and their Products", bind 1 (1970) 2) "Biochemistry of Fruits and their Products", Volume 1 (1970)
Ed. A. C. Hulme. Oath. A. C. Hulme.
Innen hver klasse er det flere forskjellige bestanddeler som hver for seg kan bestemmes analytisk. Hovedsyren i citrus-saft er sitronsyre, som er til stede i en mengde av ca. 5-6 vekt%. Within each class there are several different constituents which can be determined analytically. The main acid in citrus juice is citric acid, which is present in an amount of approx. 5-6% by weight.
Det er ikke kjent nøyaktig hvilken av bestanddelene som It is not known exactly which of the constituents
er til stede i citrus-saften som er ansvarlig for forbedring av rengjøringseffekten, men det antas at det frembringes en synergist-isk effekt ved kombinasjonen av en eller flere bestanddeler som er til stede i citrus-saft og det aktive system som anvendes i produktet i henhold til oppfinnelsen. is present in the citrus juice which is responsible for improving the cleaning effect, but it is believed that a synergistic effect is produced by the combination of one or more components present in the citrus juice and the active system used in the product in according to the invention.
I tillegg til de ovenfor beskrevne essensielle ingredienser kan det flytende vaskemiddel i henhold til oppfinnelsen eventuelt inneholde andre ikke-essensielle materialer. Slike eventuelle ingredienser inkluderer ytterligere overflateaktive midler, forskjellig fra dem som er spesifisert som første og andre overflateaktive midler i det organiske syntetiske overflateaktive system; byggersalter som kan tilsettes for å påskynde rengjørings-og smussfjerningseffektiviteten til de overflateaktive midler i produktet, f.eks. fosfater, polyfosfater, fosfonater, karbonater, polyacetater og polykarboksylater; skum-frembringende midler, f. eks. kokosnøttfettsyre-dietanolamid; hydrotroper og solubiliser-ende midler, f.eks. de lavere alkanoler som inneholder 2-4 karbonatomer, spesielt etanol, urinstoff, natrium- eller kaliumtoluen-sulfonat og natrium- eller kaliumxylensulfonat, som generelt tilsettes for å fremkalle fasestabilitet spesielt når det gjelder blandinger med høye konsentrasjoner av over flateaktive midler; konserveringsmidler; parfyme og farvemidler. Videre kan, etter ønske, sure eller alkaliske substanser for pH-justering og også skuremidler innblandes i vaskemidlet i henhold til oppfinnelsen - In addition to the essential ingredients described above, the liquid detergent according to the invention may optionally contain other non-essential materials. Such optional ingredients include additional surfactants other than those specified as first and second surfactants in the organic synthetic surfactant system; building salts which can be added to speed up the cleaning and soil removal effectiveness of the surfactants in the product, e.g. phosphates, polyphosphates, phosphonates, carbonates, polyacetates and polycarboxylates; foam-producing agents, e.g. coconut fatty acid diethanolamide; hydrotropes and solubilizing agents, e.g. the lower alkanols containing 2-4 carbon atoms, especially ethanol, urea, sodium or potassium toluene sulphonate and sodium or potassium xylene sulphonate, which are generally added to induce phase stability especially in the case of mixtures with high concentrations of surfactants; preservatives; perfumes and dyes. Furthermore, if desired, acidic or alkaline substances for pH adjustment and also scouring agents can be mixed into the detergent according to the invention -
Foretrukne blandinger er slike som inneholder 15-4 3 vekt% av det ovenfor beskrevne organiske syntetiske overflateaktive system, 5-25 vekt% sitronsaft og ca. 15-75 vekt% vann. Spesielt foretrukket er slike som har et aktivt vaskemiddelinnhold på mer enn 3 5 vekt%. Preferred mixtures are those which contain 15-43% by weight of the organic synthetic surfactant system described above, 5-25% by weight lemon juice and approx. 15-75% by weight water. Particularly preferred are those which have an active detergent content of more than 35% by weight.
Oppfinnelsen skal i det følgende illustreres ved hjelp av eksempler: In the following, the invention shall be illustrated by means of examples:
Eksempler I- III Examples I-III
Følgende blandinger ble laget: The following mixtures were made:
For å bestemme hvor lett det er å rengjøre innbrent smuss fra underlag etter bløting, ble følgende halv-flis-sammenlignings-testmetode anvendt: Tilsmussede underlag i form av kvadratiske emaljefliser (10 x 10 cm) neddyppes i løsninger av testproduktene ( 1 liter) ved 0,15% konsentrasjoner. Løsningen er ved 45°C ved begynnelsen av testen og gjenoppvarmes når temperaturen faller til 40°C (anvendelse av en liten neddyppings-spiral). Flisene undersøkes for å finne de første tegn på at smusset på en av dem er myknet, og så fjernes alle fra testløsningen og rengjøres (neddyppings-tiden varierer mellom 5 og 50 min.). Rengjøringen utføres i 30 sekunder under anvendelse av en Brillo Swish svamp dyppet i den aktuelle testløsning. To determine how easy it is to clean baked-on dirt from substrates after soaking, the following half-tile comparison test method was used: Soiled substrates in the form of square enamel tiles (10 x 10 cm) are immersed in solutions of the test products (1 liter) at 0.15% concentrations. The solution is at 45°C at the start of the test and is reheated when the temperature drops to 40°C (using a small immersion coil). The tiles are examined to find the first signs that the dirt on one of them has softened, and then all are removed from the test solution and cleaned (immersion time varies between 5 and 50 min.). The cleaning is carried out for 30 seconds using a Brillo Swish sponge dipped in the relevant test solution.
Smuss og tilsmussingsmetode Dirt and soiling method
Testene ble utført med fruktpaifyll (kirsebær og aprikos) og en blanding av mel og fruktpaifyll (1:4). Paifyllet moses fint ved at det presses gjennom en 240 ^um sikt, og det lages en fin pasta av mel/paifyll-blandingen. The tests were carried out with fruit pie filling (cherry and apricot) and a mixture of flour and fruit pie filling (1:4). The pie filling is finely mashed by pressing it through a 240 µm sieve, and a fine paste is made from the flour/pie filling mixture.
Smusset påføres underlaget ved "screen printing", idet det ble brukt to passeringer. Smusset innbrennes så midt i en stor ovn (Gallenkamp Oven Model OV330) i 4 minutter. Temperaturen må være 250°C før de tilsmussede underlag settes inn i ovnen, og det er ønskelig at innsettingen i ovnen gjøres hurtig slik at man unn-går at temperaturen faller til under 220°C. The dirt is applied to the substrate by "screen printing", as two passes were used. The dirt is then burned in the middle of a large oven (Gallenkamp Oven Model OV330) for 4 minutes. The temperature must be 250°C before the soiled substrates are placed in the oven, and it is desirable that the insertion in the oven is done quickly so as to avoid the temperature falling below 220°C.
Resultater Results
Disse er fullstendig gjengitt i tabell 1 nedenunder. These are fully reproduced in table 1 below.
Vurdering ble foretatt av en teknisk skolert jury, idet graden av smussfjerning ble gradert etter følgende skala: Assessment was carried out by a technically trained jury, as the degree of dirt removal was graded according to the following scale:
0 = fullstendig rent 0 = completely clean
1 = fremdeles noe tilsmusset 1 = still somewhat soiled
2 = moderat tilsmusset 2 = moderately soiled
3 = betydelig tilsmusset 3 = significantly soiled
4 = ingen synlig rengjøring. 4 = no visible cleaning.
Karakterene ble tatt som gjennomsnitt av 8 resultater for hvert produkt og kontrollprøve. Produkt A ble brukt som kontroll-prøve. The marks were taken as the average of 8 results for each product and control sample. Product A was used as a control sample.
Av ovenstående resultater går det tydelig frem at blandingene I, II og III i henhold til oppfinnelsen, med sitronsaft, From the above results, it is clear that the mixtures I, II and III according to the invention, with lemon juice,
er overlegne i forhold til blandingene A og B som ligger utenfor oppfinnelsen. are superior to mixtures A and B which lie outside the invention.
Eksempel IV Example IV
Innflytelsen av pH-verdien ble undersøkt ved at man vurderte ytelsen av den følgende flytende blanding i en bløtetest. The influence of the pH value was investigated by assessing the performance of the following liquid mixture in a soaking test.
Sammensetning Composition
Det ble utført sammenligninger ved anvendelse av de standard emaljefliser (10 x lo cm) som ble tilsmusset med aprikospai-fyll/mel og stekt som i eksemplene I-lli. Halv-flis-sammenligninger i vann av 11,3° tysk hårdhet ble utført ved 45°C. Comparisons were made using the standard enamel tiles (10 x 10 cm) which were smeared with apricot pie filling/flour and baked as in Examples I-lli. Half-tile comparisons in 11.3° German hardness water were performed at 45°C.
Testprodukter ble testet på vilkårlig måte, og alle tester ble duplisert. Test products were tested randomly, and all tests were duplicated.
pH-justeringer ble utført ved 45°C under anvendelse av fortynnet svovelsyre (0,1 M) og fortynnet natriumhydroksyd (0,1 M), og måling av pH-verdien ved slutten av hver test ble også foretatt. pH adjustments were made at 45°C using dilute sulfuric acid (0.1 M) and dilute sodium hydroxide (0.1 M), and measurement of the pH at the end of each test was also made.
Et produkt av den ovennevnte nominelle sammensetning uten sitronsaft ble brukt som kontrollprøve. A product of the above nominal composition without lemon juice was used as a control sample.
Det ble foretatt vurdering av en teknisk skolert jury for An assessment was made by a technically trained jury for
å fastslå graden av smuss som var igjen på hver halv-flis, idet man brukte følgende skala: to determine the degree of dirt left on each half-tile, using the following scale:
0 = fullstendig rent 0 = completely clean
1 = fremdeles noe tilsmusset 1 = still somewhat soiled
2 = moderat tilsmusset 2 = moderately soiled
3 = betydelig tilsmusset 3 = significantly soiled
4 = ingen synlig rengjøring 4 = no visible cleaning
Disse karakterer var tatt som gjennomsnitt ( 6 resultater for hvert testprodukt og hver kontrollprøve ved hver pH-verdi), These grades were taken as an average (6 results for each test product and each control sample at each pH value),
og en smussdifferanse mellom kontrollprøven og testproduktet ble beregnet. and a dirt difference between the control sample and the test product was calculated.
Ovenstående tabell viser at produktet i henhold til oppfinnelsen viser en tydelig overlegenhet ved pH 5,5, 7,0/ 8,5 og 10,0, idet resultater ved pH 8,5 er særlig gode. The above table shows that the product according to the invention shows a clear superiority at pH 5.5, 7.0/8.5 and 10.0, the results at pH 8.5 being particularly good.
Eksempel V Example V
Den fremgangsmåte som ble anvendt, var som følger: The procedure used was as follows:
1. Det ble fremstilt et eggsmuss ved omhyggelig blanding av tørket eggpulver og vann i forholdet 1:1. 2. En 5 cm strimmel med smuss ble fordelt ved "screen-printing" på sentrum av en 30 x 25 cm glassflis. 3. Flisene ble innbrent i 30 minutter ved 200°C. Fem vurderinger kunne så utføres tvers over hver flis. Minst to kontroll- 1. An egg mixture was prepared by carefully mixing dried egg powder and water in a ratio of 1:1. 2. A 5 cm strip of dirt was distributed by "screen-printing" on the center of a 30 x 25 cm glass tile. 3. The tiles were baked in for 30 minutes at 200°C. Five assessments could then be carried out across each tile. At least two control
vurderinger ble utført på hver flis. assessments were performed on each tile.
4. Det ble laget fem 5 cm groper tvers over flisen under anvendelse av "<p>lasticine"-strimler. 6 ml løsning (0,15%) ble an-bragt i en grop. Under anvendelse av et hode som var dekket med j-klede og en 1,5 kg vekt ble antall gnidninger for ren-gjøring av den 5 cm strimmel med smuss registrert. 5. Resultater for testløsningen ble beregnet som prosent av ytelsen for den nærmeste kontrollprøve i flisen. 4. Five 5 cm pits were made across the tile using "<p>lasticine" strips. 6 ml of solution (0.15%) was placed in a well. Using a head covered with j-cloth and a 1.5 kg weight, the number of rubs to clean the 5 cm strip of dirt was recorded. 5. Results for the test solution were calculated as a percentage of the performance for the nearest control sample in the tile.
Resultatene fra testene under anvendelse av vann av 5°H er oppført i nedenstående tabell. The results of the tests using water of 5°H are listed in the table below.
Ovenstående resultater viser tydelig hvor meget bedre produktene til v, i henhold til oppfinnelsen er, inneholdende henholdsvis 5 til 50% sitronsaft, er i forhold til kontrollprøven når det gjelder rengjøring av innbrent egg. The above results clearly show how much better the products of v, according to the invention, containing respectively 5 to 50% lemon juice, are compared to the control sample when it comes to cleaning burnt eggs.
Eksempel VI Example VI
Følgende blandinger ble sammenlignet i en standard-tallerken-vasketest med hensyn på oppvaskytelse så vel som i en test for bestemmelse av hvor lett det var å rengjøre innbrent smuss fra underlag etter bløting, under anvendelse av den test-metode som er beskrevet i eksemplene I—III. The following compositions were compared in a standard dishwashing test for dishwashing performance as well as in a test to determine the ease of cleaning baked-on soil from substrates after soaking, using the test method described in Examples I —III.
Standard-tallerken-vasketestene ble utført under anvendelse av følgende testbetingelser: Produktkonsentrasjoner: 0,15% og 0,45% Løsningens temperatur: 45°c The standard plate washing tests were carried out using the following test conditions: Product concentrations: 0.15% and 0.45% Solution temperature: 45°c
Standard-saus-smuss, 5 g/tallerken: fett, stivelse, olje-og stearinsyrer. Standard sauce dirt, 5 g/plate: fat, starch, oleic and stearic acids.
Resultatene er gjengitt i nedenstående tabell. The results are reproduced in the table below.
Resultater fra testen for bestemmelse av hvor lett det var å rengjøre innbrent smuss fra underlag. Karakterene ble tilveie-bragt fra 5 resultater for hvert produkt anvendt ved 0,75% konsentrasjoner. Results from the test to determine how easy it was to clean burnt-on dirt from the substrate. The grades were provided from 5 results for each product used at 0.75% concentrations.
Ovenstående resultater viser tydelig de overlegne egen-skaper ved blanding VI i henhold til oppfinnelsen i forhold til blanding D i henhold til teknikkens stand, både når det gjelder oppvask og ytelse i forbindelse med innbrent smuss. The above results clearly show the superior properties of mixture VI according to the invention compared to mixture D according to the state of the art, both when it comes to washing dishes and performance in connection with baked-on dirt.
Eksempler VII- IX Examples VII-IX
Følgende flytende oppvaskmiddelblandinger er innen opp-finnelsens ramme: The following liquid dishwashing detergent mixtures are within the scope of the invention:
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5347277 | 1977-12-22 |
Publications (3)
Publication Number | Publication Date |
---|---|
NO784258L NO784258L (en) | 1979-06-25 |
NO152014B true NO152014B (en) | 1985-04-09 |
NO152014C NO152014C (en) | 1985-07-17 |
Family
ID=10467944
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO784258A NO152014C (en) | 1977-12-22 | 1978-12-18 | DOUBLE DISHWASH |
Country Status (18)
Country | Link |
---|---|
JP (1) | JPS5850680B2 (en) |
AT (1) | ATA910978A (en) |
AU (1) | AU520258B2 (en) |
BE (1) | BE873051A (en) |
BR (1) | BR7808426A (en) |
CA (1) | CA1109756A (en) |
CH (1) | CH641836A5 (en) |
DE (1) | DE2855778B2 (en) |
DK (1) | DK574778A (en) |
FI (1) | FI63056C (en) |
FR (1) | FR2412610A1 (en) |
GR (1) | GR66577B (en) |
IT (1) | IT1109668B (en) |
NL (1) | NL7812439A (en) |
NO (1) | NO152014C (en) |
PT (1) | PT68972A (en) |
SE (1) | SE442019B (en) |
ZA (1) | ZA787143B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6081781U (en) * | 1983-11-14 | 1985-06-06 | 第一精工株式会社 | fishing weights |
JP2668388B2 (en) * | 1988-05-16 | 1997-10-27 | ライオン株式会社 | Liquid polishing composition |
DE19927936B4 (en) * | 1999-06-18 | 2009-04-09 | Predinal Gmbh | Use of juices of naturally grown citrus fruits as a microbicidal component in disinfectants |
EP1111031A1 (en) * | 1999-12-22 | 2001-06-27 | The Procter & Gamble Company | cleaning composition |
US6551984B1 (en) * | 2002-04-09 | 2003-04-22 | Colgate-Palmolive Company | High foaming, grease cutting light duty liquid composition containing at least one natural extract |
DE102005056289A1 (en) * | 2005-11-24 | 2007-05-31 | Predinal Gmbh | Disinfecting agent for combating harmful arthropod comprises citrus juice of the family Rutaceae as active agent, surfactant, alcohols, hydrotropic agents and further auxiliary materials |
-
1978
- 1978-12-18 FI FI783879A patent/FI63056C/en not_active IP Right Cessation
- 1978-12-18 CA CA318,100A patent/CA1109756A/en not_active Expired
- 1978-12-18 NO NO784258A patent/NO152014C/en unknown
- 1978-12-19 GR GR57926A patent/GR66577B/el unknown
- 1978-12-20 AT AT0910978A patent/ATA910978A/en unknown
- 1978-12-20 ZA ZA787143A patent/ZA787143B/en unknown
- 1978-12-21 NL NL7812439A patent/NL7812439A/en not_active Application Discontinuation
- 1978-12-21 AU AU42795/78A patent/AU520258B2/en not_active Expired
- 1978-12-21 FR FR7835882A patent/FR2412610A1/en active Granted
- 1978-12-21 SE SE7813213A patent/SE442019B/en unknown
- 1978-12-21 BR BR7808426A patent/BR7808426A/en unknown
- 1978-12-21 JP JP53156958A patent/JPS5850680B2/en not_active Expired
- 1978-12-21 CH CH1303278A patent/CH641836A5/en not_active IP Right Cessation
- 1978-12-21 IT IT69927/78A patent/IT1109668B/en active
- 1978-12-21 DK DK574778A patent/DK574778A/en not_active Application Discontinuation
- 1978-12-22 BE BE192548A patent/BE873051A/en not_active IP Right Cessation
- 1978-12-22 DE DE2855778A patent/DE2855778B2/en not_active Ceased
- 1978-12-22 PT PT68972A patent/PT68972A/en unknown
Also Published As
Publication number | Publication date |
---|---|
PT68972A (en) | 1979-01-01 |
AU4279578A (en) | 1979-06-28 |
FI63056C (en) | 1983-04-11 |
IT1109668B (en) | 1985-12-23 |
FI63056B (en) | 1982-12-31 |
FR2412610B1 (en) | 1982-12-17 |
ATA910978A (en) | 1981-07-15 |
JPS5499108A (en) | 1979-08-04 |
CH641836A5 (en) | 1984-03-15 |
SE442019B (en) | 1985-11-25 |
IT7869927A0 (en) | 1978-12-21 |
CA1109756A (en) | 1981-09-29 |
NO152014C (en) | 1985-07-17 |
NL7812439A (en) | 1979-06-26 |
DK574778A (en) | 1979-06-23 |
AU520258B2 (en) | 1982-01-21 |
JPS5850680B2 (en) | 1983-11-11 |
DE2855778A1 (en) | 1979-06-28 |
BE873051A (en) | 1979-06-22 |
FR2412610A1 (en) | 1979-07-20 |
GR66577B (en) | 1981-03-27 |
BR7808426A (en) | 1979-08-21 |
FI783879A (en) | 1979-06-23 |
NO784258L (en) | 1979-06-25 |
SE7813213L (en) | 1979-06-23 |
DE2855778B2 (en) | 1980-03-27 |
ZA787143B (en) | 1980-07-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4614612A (en) | Liquid detergent composition | |
US3956199A (en) | Dishwashing compositions | |
DE68925560T2 (en) | Enzyme-containing detergent composition | |
US10723980B2 (en) | Cleaning compositions including fermented fruit solutions and methods for making and using the same | |
CH639688A5 (en) | CLEANING AND DETERGENT. | |
CA2235755A1 (en) | Cleaning/sanitizing methods, compositions, and/or articles for produce | |
NO154348B (en) | FOAMING, Aqueous detergent. | |
JPS61293541A (en) | Biological decomposable surfactant and detergent compositioncontaining the same | |
NO152014B (en) | DOUBLE DISHWASH | |
US5096621A (en) | Detergent composition containing di-long chain alkyl amine oxides | |
DE69728303T2 (en) | cleaning supplies | |
US5342450A (en) | Use of noncorrosive chemical composition for the removal of soils originating from an animal or vegetable source from a stainless steel surface | |
NO329115B1 (en) | Aqueous detergent from a natural product | |
CN113773919A (en) | Full-ecological detergent composition | |
EP0035184A2 (en) | Detergent for use in a machine | |
JPH0438797B2 (en) | ||
DE69830723T2 (en) | CLEANING COMPOSITION, METHOD AND / OR ARTICLE FOR HARD SURFACES | |
NO141123B (en) | DISHWASHER MIXTURE WITH REPLACEMENT POWER FOR MANUAL USE | |
EP0407626A1 (en) | Phosphate-free liquid washing and cleaning composition | |
Leenerts et al. | Soil removal by dishwashing detergents | |
EP0095136B1 (en) | Rinsing agents for use in mechanical dishwashing | |
US6225268B1 (en) | Liquid detergent composition | |
NO141370B (en) | DETERGENT MIXTURE FOR MANUAL DISHWASHING | |
DE4032125C2 (en) | Dishwashing liquid | |
EP0243927A2 (en) | Liquid detergent composition |