NO141443B - PROCEDURE FOR THE MANUFACTURE OF A PRODUCT WHICH ENCOURAGES THE BIOLOGICAL DECOMPOSITION OF HYDROCARBONS - Google Patents
PROCEDURE FOR THE MANUFACTURE OF A PRODUCT WHICH ENCOURAGES THE BIOLOGICAL DECOMPOSITION OF HYDROCARBONS Download PDFInfo
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- NO141443B NO141443B NO744677A NO744677A NO141443B NO 141443 B NO141443 B NO 141443B NO 744677 A NO744677 A NO 744677A NO 744677 A NO744677 A NO 744677A NO 141443 B NO141443 B NO 141443B
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- cerium
- hydrocarbons
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- 229930195733 hydrocarbon Natural products 0.000 title claims description 11
- 150000002430 hydrocarbons Chemical group 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000000354 decomposition reaction Methods 0.000 title description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 229910052684 Cerium Inorganic materials 0.000 claims description 10
- 230000015556 catabolic process Effects 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229920005610 lignin Polymers 0.000 claims description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 6
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 5
- 235000014103 egg white Nutrition 0.000 claims description 5
- 210000000969 egg white Anatomy 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- 235000010446 mineral oil Nutrition 0.000 claims description 5
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims description 4
- 102000002322 Egg Proteins Human genes 0.000 claims description 4
- 108010000912 Egg Proteins Proteins 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- -1 rare earth salt Chemical class 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 230000009466 transformation Effects 0.000 claims description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims 2
- 239000013543 active substance Substances 0.000 claims 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000009264 composting Methods 0.000 description 3
- 230000004783 oxidative metabolism Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical compound COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 1
- 229910000636 Ce alloy Inorganic materials 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000023555 blood coagulation Effects 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 150000001785 cerium compounds Chemical class 0.000 description 1
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- UUMMHAPECIIHJR-UHFFFAOYSA-N chromium(4+) Chemical class [Cr+4] UUMMHAPECIIHJR-UHFFFAOYSA-N 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002496 oximetry Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
- C12N1/26—Processes using, or culture media containing, hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Genetics & Genomics (AREA)
- Organic Chemistry (AREA)
- Biotechnology (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Medicinal Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Virology (AREA)
- Tropical Medicine & Parasitology (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Fertilizers (AREA)
- Fats And Perfumes (AREA)
- General Preparation And Processing Of Foods (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Lubricants (AREA)
- Fodder In General (AREA)
Description
Foreliggende oppfinnelse angår en fremgangsmåte for fremstilling av et produkt som påskynder den biologiske nedbrytning av hydrokarboner, spesielt hydrokarboner i mineraloljeprodukter. The present invention relates to a method for producing a product which accelerates the biological breakdown of hydrocarbons, in particular hydrocarbons in mineral oil products.
Det er kjent at de sulfittavluter som oppstår ved for-arbeidning av ved etter sulfittfremgangsmåten som hovedandel inneholder lignosulfonsyre som vannoppløselig omdanningsprodukt av lignin og med SO^H-grupper. It is known that the sulphite liquors which occur during the processing of wood according to the sulphite method mainly contain lignosulfonic acid as a water-soluble conversion product of lignin and with SO^H groups.
Det foreligger et stort antall forslag hva angår anvendelse av denne ligninsulfonsyre, og noen av disse har også kunnet gjennomføres i praksis. Man oppnår f.eks. bindemidler for briketter, klebestoffer for lim og papir, gjødningsstoffer ved omdanning til humusstoffer, tilsetningsstoffer til kunststoff-pressmasser, emulgatorer for veibygningsmaterialer, hjelpemidler og foryaetningsmidler for tekstilforecUing, brannbeskyttelses-midler, garveekstrakter, flokkuleringsmidler for eggehvitefelling samt kondensasjonsprodukter for kautsjukindustrien. Videre er det kjent at ligninsulfonsyre benyttes til geldannelse ved oksydasjon av krom-IV-salter. There are a large number of proposals regarding the use of this ligninsulfonic acid, and some of these have also been implemented in practice. One achieves e.g. binders for briquettes, adhesives for glue and paper, fertilizers when converted into humic substances, additives for plastic pressing compounds, emulsifiers for road construction materials, auxiliaries and anti-corrosive agents for textile processing, fire protection agents, tanning extracts, flocculating agents for egg white precipitation as well as condensation products for the rubber industry. Furthermore, it is known that lignin sulphonic acid is used for gel formation by oxidation of chromium IV salts.
I kalsiumholdige sulfittavluter med et innhold på 50-60% tørrstoff foreligger det likeledes sukker og karbohydrater. For den slags stoffer er det kjent å overføre dem ved hjelp av mikroorganismer, f.eks. ved hjelp av gjærsopper, til anvendbare fett og eggehvitestoffer og også å benytte dem som ionebyttere (Rompp, Chemielexikon, avsnitt lignin; Fiedler, F. Mat. Dies. Univ. Greifswald 1957; Chemiker-Zeitung 1954, side 508). Calcium-containing sulphite liquors with a content of 50-60% dry matter also contain sugar and carbohydrates. For such substances, it is known to transfer them with the help of microorganisms, e.g. by means of yeasts, to usable fats and egg whites and also to use them as ion exchangers (Rompp, Chemielexikon, section lignin; Fiedler, F. Mat. Dies. Univ. Greifswald 1957; Chemiker-Zeitung 1954, page 508).
Angående cerium er det kjent at dette såvel som salter Regarding cerium, it is known that this as well as salts
av praseodym og neodym i en størrelsesorden for konsentrasjonen på 1:10.000 kan øke gjæringskraften for gjær, samt at koagula-sjonen av melk på grunnav lape kan akselereres ved tilsetning av disse salter og at blodets størkning in vitro hemmes eller for- of praseodymium and neodymium in an order of magnitude for the concentration of 1:10,000 can increase the fermentation power of yeast, as well as that the coagulation of milk due to lape can be accelerated by the addition of these salts and that blood clotting in vitro is inhibited or prevented
hindres (Hara s: Arch. f. exper. pathol. 100, 224; Drossbach: is prevented (Hara p: Arch. f. exper. pathol. 100, 224; Drossbach:
ZBL, Bakt. I, 21, 57). ZBL, Bakt. I, 21, 57).
Spesielle kolloidsystemer av salter av sjeldne jordarter Special colloidal systems of rare earth salts
er ut over dette kjent for at de som sporelementer er istand til å aktivere vekstutviklingen for planter, noe man kan se på kortere kimingstid, tidligere kimbladdannelse, bedre rotdannelse og tettere vekst. Ved eksperimentelle feltforsøk kan det påvises at man ved kulturer kan øke utbyttet ved anvendelse av slike sporelement-kolloider med 24,6%, hvorved plantene også blir mer resistente overfor sykdommer og andre skadedyr og -planter (H.A. Schweigart: Pflanzenernahrung durch Anreicherung der Saat mit Spurenelement-kontaktcolloiden, Vitalstoffe, Heft 20, 1960). I ytterligere publikasjoner påvises det at spesielle katalasefrie bakterier, slik som BAC. Delbruggi, kan gjennomføre sitt oksydative stoffskifte ved hjelp av ceriumperoksyd, det vil altså si at oksydative stoffskifteprosesser under spesielle forutsetninger kan på-virkes eller opprettes ved hjelp av ceriumforbindelser. Herved spiller sikkert ceriumets egenskaper med henblikk på valensskifte-muligheter og spenningsforskjellen på 1,57 volt, redoxpotensialet, en rolle. Det skal videre henvises til at ceriumlegeringer har funnet anvendelse under utnyttelse av oksygenaffinitetsegenskapene i f.eks. gassglødestrømper (Evens: Peroc. Soc. exper. Biol. a. Med. 73, 1955, 19, 198; Dipl.-Chem. E. Potratz, Zeitschrift fur diagnostiche und therapeutische Sondermethoden, bind IV, 1957) . in addition to this, it is known that, as trace elements, they are able to activate the growth development of plants, which can be seen in a shorter germination time, earlier cotyledon formation, better root formation and denser growth. In experimental field tests, it can be shown that the yield of crops can be increased by the use of such trace element colloids by 24.6%, whereby the plants also become more resistant to diseases and other pests and plants (H.A. Schweigart: Pflanzenernahrung durch Anreicherung der Saat mit The trace element contact colloid, Vitalstoffe, Heft 20, 1960). In further publications, it is demonstrated that special catalase-free bacteria, such as BAC. Delbruggi, can carry out its oxidative metabolism with the help of cerium peroxide, which means that oxidative metabolism processes under special conditions can be influenced or created with the help of cerium compounds. Hereby, cerium's properties with regard to valence change possibilities and the voltage difference of 1.57 volts, the redox potential, certainly play a role. Reference must also be made to the fact that cerium alloys have found use by exploiting the oxygen affinity properties in e.g. gas glow stockings (Evens: Peroc. Soc. exper. Biol. a. Med. 73, 1955, 19, 198; Dipl.-Chem. E. Potratz, Zeitschrift fur diagnostiche und therapeutische Sondermethoden, volume IV, 1957) .
Oljeholdige avfall, spesielt ikke mer benyttbar mineralolje, lagres f.eks. med henblikk på kompostering i vanntett anlagte oljediker, hvorved komposteringen skjer som normal biologisk nedbrytning meget langsomt. Oily waste, especially no longer usable mineral oil, is stored e.g. with a view to composting in watertight oil dykes, whereby the composting takes place as normal biological decomposition very slowly.
Til grunn for foreliggende oppfinnelse ligger kjennskap-ene angående påvirkning av den mikrobakterielle nedbrytning av hydrokarboner og overføring til eggehvite for små konsentrasjoner av salter av sjeldne jordarter til potensiering av det oksydative stoffskifte for mikroorganismer; og oppfinnelsen har til oppgave å frembringe en fremgangsmåte til fremstilling av en blanding som tilsettes brukte mineraloljeprodukter, hvorved den biologiske nedbrytning av disse produkter akselereres. The present invention is based on the knowledge regarding the influence of the microbacterial breakdown of hydrocarbons and the transfer to egg white of small concentrations of salts of rare earth species to potentiate the oxidative metabolism of microorganisms; and the invention has the task of producing a method for producing a mixture which is added to used mineral oil products, whereby the biological breakdown of these products is accelerated.
Denne oppgave løses ifølge oppfinnelsen ved at 50-150 g kalsiumligninsulfonat med et standardisert jerninnhold på 0,05-0,15% oppløses i vann og tilsettes en på forhånd bestemt mengde av et salt av sjeldne jordarter, fortrinnsvis 30-50 g cerium-IV-sulfat, og at denne oppløsning tilsettes et absorptivt virkende stoff omfattende enten en blanding av 25-100 g stearinsyre og 4-12 g trietanolamin eller 10-30%-ig aluminiumsulfatopp-løsning, hvilket produkt medvirker til en naturlig biologisk nedbrytning av nevnte hydrokarboner hvorved disse gjennomgår en kompleksbundet omdanning til fett og eggehvite. This task is solved according to the invention by dissolving 50-150 g of calcium lignin sulphonate with a standardized iron content of 0.05-0.15% in water and adding a pre-determined amount of a rare earth salt, preferably 30-50 g of cerium-IV -sulphate, and that an absorptive substance is added to this solution comprising either a mixture of 25-100 g of stearic acid and 4-12 g of triethanolamine or a 10-30% aluminum sulphate solution, which product contributes to a natural biological breakdown of said hydrocarbons whereby these undergo a complex transformation into fat and egg white.
Det er funnet at kalsiumholdige ligninsulfonater med følgende sammensetning kan tjene som foretrukket utgangsprodukt: It has been found that calcium-containing lignin sulfonates with the following composition can serve as the preferred starting product:
pH i den vandige oppløsning = 4,6. pH in the aqueous solution = 4.6.
Til grunn har man lagt at ifølge oksydimetriens lover It has been assumed that according to the laws of oximetry
kan bestemmelse av jern gjennomføres ved hjelp av cerium-IV-sulfat i 0,1N oppløsning. determination of iron can be carried out using cerium-IV-sulphate in 0.1N solution.
Herved går man ut fra følgende: 1 cm 3 forbrukt 0,1N cerium-IV-sulfat tilsvarer 5,585 mg jern. Bestemmelsen gjennom-føres ved tilsetning av ca. 5 cm 3 konsentrert svovelsyre ved en jernmengde på 0,1-0,2 g jern i 100 cm 3 væske som skal prøves. This is based on the following: 1 cm 3 consumed of 0.1N cerium-IV-sulphate corresponds to 5.585 mg of iron. The provision is carried out by adding approx. 5 cm 3 of concentrated sulfuric acid at an iron quantity of 0.1-0.2 g of iron in 100 cm 3 of liquid to be tested.
Bestemmelsesmuligheten gir en mulighet til å standardisere innholdet av jern i utgangsproduktet for ligninsulfonatene for å oppnå de samme utgangsbetingelser og for på den annen side ved innføring av bestemte mengder av ceriumsulfatet å oppnå optimale ceriuminnhold i sluttproduktet ved utregning av ceriuminnholdet i blandingen ifølge oppfinnelsen. Herved legges de oksydative egenskaper for cerium, henholdsvis dettes valensskifte til grunn. The determination option provides an opportunity to standardize the content of iron in the starting product for the ligninsulfonates in order to achieve the same starting conditions and, on the other hand, by introducing specific amounts of the cerium sulfate, to achieve optimal cerium content in the final product by calculating the cerium content in the mixture according to the invention. Hereby, the oxidative properties of cerium, respectively its valence change, are taken into account.
På grunn av det ovenfor anførte går man ifølge oppfinnelsen ut fra at de anvendte mengder av ligninsulfonat under hensyntagen til jerninnholdet på 0,1% med en mengde på 0,5 g etter forutgå-ende cerimetri, og under hensyntagen til omregningsfaktoren inneholder 1,4 mg cerium. Denne dosering ble ved den senere anvendelse av det oppnådde produkt erkjent som optimal. Due to the above, according to the invention, it is assumed that the amounts of lignin sulphonate used, taking into account the iron content of 0.1% with an amount of 0.5 g after previous cerimetry, and taking into account the conversion factor contain 1.4 mg cerium. This dosage was recognized as optimal during the later use of the product obtained.
Hvis det ifølge en videreutvikling av blandingen ifølge oppfinnelsen tilsettes en absorptivt virkende oppløsning av stearinsyre og trietanolamin, oppstår en masse med hvilken man f.eks. kan fore ut spilloljediker, før olje fylles i. Det fylte dike kan også dekkes med denne emulsjon. If, according to a further development of the mixture according to the invention, an absorptive-acting solution of stearic acid and triethanolamine is added, a mass is formed with which one e.g. can line out waste oil ditches, before oil is filled in. The filled ditch can also be covered with this emulsion.
Ved blanding av denne utf6ringsmasse med vann i et forhold på 1:1, flokkuleres det ut fra utf6ringsmassen et stoff som suger opp olje, men som dog er vannavstøtende. Dette utflokkulerte stoff avsetter seg i kantområdet, f.eks. langs oljedikets vegger. Den inntrengende olje spaltes deretter biologisk meget hurtig da denne nedbrytning potensieres på grunn av ceriumsaltet i den utflokkulerte masse. Oljen omsettes derved til stoffer som kan nyttiggjøres av planter. Nedbrytningen, dvs. av oljens hydrokarboner, oppnås også ved oksydasjon. Det oksygen som er nødvendig til dette hentes av bakteriene i blandingen ifølge oppfinnelsen fra vann, f.eks. grunnvannet, og også fra oljeemulsjonen fra det vann som blir fritt ved utflokkingen. By mixing this construction mass with water in a ratio of 1:1, a substance that absorbs oil but is water-repellent is flocculated from the construction mass. This flocculated material settles in the edge area, e.g. along the walls of the oil dike. The penetrating oil is then biologically broken down very quickly as this breakdown is potentiated due to the cerium salt in the flocculated mass. The oil is thereby converted into substances that can be utilized by plants. The breakdown, i.e. of the oil's hydrocarbons, is also achieved by oxidation. The oxygen required for this is obtained by the bacteria in the mixture according to the invention from water, e.g. the groundwater, and also from the oil emulsion from the water that becomes free during the flocculation.
Ved feltforsøk har man kunnet påvise at man ved anleggélse av dikesystemer for kompostering av oljeholdige avfall og ved å legge under bindemateriale hhv. filtermateriale under anvendelse av det ovenfor angitte stoff i ovenfor angitt mengde, kan oppnå In field tests, it has been possible to demonstrate that when constructing dike systems for composting oily waste and by placing binding material or filter material using the above-mentioned substance in the above-mentioned quantity, can be achieved
en påvisbar aerob nedbrytning med potensiert virkning av hydrokarboner ved oksydasjon, og at man samtidig kan oppnå en forbedret plantevekst på slike depoter på grunn av forbedret oksygen-utnyttelse og chelatdannelse. a demonstrable aerobic breakdown with potentiated effect of hydrocarbons by oxidation, and that at the same time improved plant growth can be achieved on such depots due to improved oxygen utilization and chelation.
Det kan påvises at den biologiske nedbrytning potensieres ved mineralolje av det ifølge oppfinnelsen frembrakte stoff, videre at oksydasjonshastigheten for hydrokarboner fordobles, hvorved den stimulerende virkning oppnås over ceriums redoxpotensial. It can be demonstrated that the biological degradation is potentiated by mineral oil of the substance produced according to the invention, further that the oxidation rate for hydrocarbons is doubled, whereby the stimulating effect is achieved above cerium's redox potential.
En slik prosess ble kontrollert over to år, hvorved man bemerket en temperatur på 30°C og hvor man videre oppnådde følgende data: Such a process was checked over two years, during which a temperature of 30°C was noted and where the following data was obtained:
Eksempler: Examples:
1) 100 g av et kalsiumligninsulfonat med et standardisert jerninnhold på 0,1 g oppløses i 1 liter vann. Til den til 75°C oppvarmede oppløsning settes 40,4 g cerium-IV-sulfat under stadig omrøring. Den således oppnådde oppløsning tjener som ut-gangsmateriale for de videre, eksempler. 2) Det i eksempel 1 utkrystalliserte stoff blir i en mengde på 0,5 g tilsatt til en absorptivt virkende blanding og emulsjon av ca. 50 g stearinsyre og 8 g trietanolamin i 1.000 cm 3 vann i en mengde på 2,0 g under stadig omrøring og oppvarming til 85°C. Det således oppnådde produkt brukes som filtermateriale for ut-f6ring og avdekking av anlagte depoter for grunnvannssikring ved innføring av oljeholdig avfall. 3) Til den under eksempel 1 oppnådde oppløsning tilsettes en mengde på 0,5 cm 3 av en likeledes absorptivt virkende 20%-ig aluminiumsulfatoppløsning ved en maksimaltemperatur på 35°C. Dette produkt tjener til demulgering av oljeholdige emulsjoner med anionisk, kationisk eller ikke-ionisk karakter. 1) 100 g of a calcium lignin sulphonate with a standardized iron content of 0.1 g is dissolved in 1 liter of water. 40.4 g of cerium-IV-sulphate are added to the solution heated to 75°C with constant stirring. The solution thus obtained serves as starting material for the further examples. 2) The substance crystallized in example 1 is added in an amount of 0.5 g to an absorptive-acting mixture and emulsion of approx. 50 g of stearic acid and 8 g of triethanolamine in 1,000 cm 3 of water in a quantity of 2.0 g with constant stirring and heating to 85°C. The product thus obtained is used as filter material for the removal and covering of constructed depots for groundwater protection when introducing oily waste. 3) To the solution obtained under example 1, a quantity of 0.5 cm 3 of an equally absorbent 20% aluminum sulphate solution is added at a maximum temperature of 35°C. This product serves to demulsify oily emulsions of anionic, cationic or non-ionic character.
De i beskrivelsen angitte mengder av de i blandingen fore-kommende bestanddeler samt de angitte temperaturer gjelder fore-trukne utførelsesformer og kan varieres innen visse grenser uten å gå utenfor oppfinnelsens ramme. De nevnte grenser er angitt i kravene. The quantities of the components present in the mixture as well as the temperatures specified in the description apply to preferred embodiments and can be varied within certain limits without going outside the scope of the invention. The aforementioned limits are specified in the requirements.
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2365170A DE2365170C3 (en) | 1973-12-29 | 1973-12-29 | Manufacture of a mixture to be added to the mineral oil products to be deposited |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO744677L NO744677L (en) | 1975-07-28 |
| NO141443B true NO141443B (en) | 1979-12-03 |
| NO141443C NO141443C (en) | 1980-03-12 |
Family
ID=5902242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO744677A NO141443C (en) | 1973-12-29 | 1974-12-23 | PROCEDURE FOR MANUFACTURING A PRODUCT THAT SPECIFIES THE BIOLOGICAL DEGRADATION OF HYDROCARBONES |
Country Status (6)
| Country | Link |
|---|---|
| CH (1) | CH617962A5 (en) |
| DE (1) | DE2365170C3 (en) |
| DK (1) | DK155041C (en) |
| FI (1) | FI53588C (en) |
| NO (1) | NO141443C (en) |
| SE (1) | SE395471B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE445991B (en) | 1978-09-07 | 1986-08-04 | Poul Albert Jodehl | APPLICATION OF A LIGNIN SULPHONATE-CONTAINING PRODUCT FOR PURIFICATION OF CONTAMINATED Aqueous Media |
| DE3637308C1 (en) * | 1986-11-03 | 1988-06-01 | Eberhard Potratz | Nutrient mixture for increasing the rate of biodegradation of mineral oil products and its use |
| US5401718A (en) * | 1992-11-24 | 1995-03-28 | Patel; Bharat B. | Tin/cerium compounds for lignosulfonate processing |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2079506A5 (en) * | 1970-02-03 | 1971-11-12 | Salomone Georges |
-
1973
- 1973-12-29 DE DE2365170A patent/DE2365170C3/en not_active Expired
-
1974
- 1974-12-20 CH CH1700574A patent/CH617962A5/en not_active IP Right Cessation
- 1974-12-23 SE SE7416261A patent/SE395471B/en not_active IP Right Cessation
- 1974-12-23 NO NO744677A patent/NO141443C/en unknown
- 1974-12-27 FI FI3763/74A patent/FI53588C/en active
- 1974-12-30 DK DK692774A patent/DK155041C/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FI376374A (en) | 1975-06-30 |
| SE395471B (en) | 1977-08-15 |
| DK692774A (en) | 1975-09-08 |
| DK155041B (en) | 1989-01-30 |
| DK155041C (en) | 1989-06-26 |
| NO141443C (en) | 1980-03-12 |
| FI53588C (en) | 1978-06-12 |
| CH617962A5 (en) | 1980-06-30 |
| DE2365170B2 (en) | 1979-06-21 |
| DE2365170C3 (en) | 1980-02-14 |
| NO744677L (en) | 1975-07-28 |
| SE7416261L (en) | 1975-07-30 |
| FI53588B (en) | 1978-02-28 |
| DE2365170A1 (en) | 1975-07-10 |
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