NL7908588A - Werkwijze voor het katalytisch kraken van koolwater- stofolieen en voor deze werkwijze geschikte katalysator. - Google Patents

Werkwijze voor het katalytisch kraken van koolwater- stofolieen en voor deze werkwijze geschikte katalysator. Download PDF

Info

Publication number: NL7908588A
Authority: NL; Netherlands
Prior art keywords: catalyst; tin; cracking; hydrocarbon oils; boron
Prior art date: 1978-11-29

Application number

NL7908588A

Other languages

English (en)

Dutch (nl)

Original Assignee

Shell Int Research

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-11-29

Filing date

1979-11-27

Publication date

1980-06-02

1979-11-27 Application filed by Shell Int Research filed Critical Shell Int Research

1980-06-02 Publication of NL7908588A publication Critical patent/NL7908588A/nl

Links

239000003054 catalyst Substances 0.000 title claims description 37
238000000034 method Methods 0.000 title claims description 18
239000003921 oil Substances 0.000 title claims description 13
229930195733 hydrocarbon Natural products 0.000 title claims description 11
150000002430 hydrocarbons Chemical class 0.000 title claims description 11
239000004215 Carbon black (E152) Substances 0.000 title claims description 10
238000004523 catalytic cracking Methods 0.000 title claims description 8
238000005336 cracking Methods 0.000 claims description 16
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 14
229910001385 heavy metal Inorganic materials 0.000 claims description 12
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
229910021536 Zeolite Inorganic materials 0.000 claims description 9
239000010457 zeolite Substances 0.000 claims description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
229910052742 iron Inorganic materials 0.000 claims description 5
229910052720 vanadium Inorganic materials 0.000 claims description 5
229910052759 nickel Inorganic materials 0.000 claims description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 12
229910052796 boron Inorganic materials 0.000 description 12
230000000694 effects Effects 0.000 description 5
150000003606 tin compounds Chemical class 0.000 description 5
230000008929 regeneration Effects 0.000 description 4
238000011069 regeneration method Methods 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
-1 rare earth metal ions Chemical class 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
238000009835 boiling Methods 0.000 description 2
150000001639 boron compounds Chemical class 0.000 description 2
239000000571 coke Substances 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
230000037213 diet Effects 0.000 description 2
235000005911 diet Nutrition 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
LGQXXHMEBUOXRP-UHFFFAOYSA-N tributyl borate Chemical compound CCCCOB(OCCCC)OCCCC LGQXXHMEBUOXRP-UHFFFAOYSA-N 0.000 description 2
YXTDAZMTQFUZHK-ZVGUSBNCSA-L (2r,3r)-2,3-dihydroxybutanedioate;tin(2+) Chemical compound [Sn+2].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O YXTDAZMTQFUZHK-ZVGUSBNCSA-L 0.000 description 1
CQMNNMLVXSWLCH-UHFFFAOYSA-B 2-hydroxypropane-1,2,3-tricarboxylate;tin(4+) Chemical compound [Sn+4].[Sn+4].[Sn+4].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O CQMNNMLVXSWLCH-UHFFFAOYSA-B 0.000 description 1
XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
235000010338 boric acid Nutrition 0.000 description 1
229960002645 boric acid Drugs 0.000 description 1
229910052810 boron oxide Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 description 1
VDEKURXOWJYWCG-UHFFFAOYSA-N dodecyltin Chemical compound CCCCCCCCCCCC[Sn] VDEKURXOWJYWCG-UHFFFAOYSA-N 0.000 description 1
238000007580 dry-mixing Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
MLSKXPOBNQFGHW-UHFFFAOYSA-N methoxy(dioxido)borane Chemical compound COB([O-])[O-] MLSKXPOBNQFGHW-UHFFFAOYSA-N 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
UIEKYBOPAVTZKW-UHFFFAOYSA-L naphthalene-2-carboxylate;nickel(2+) Chemical compound [Ni+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 UIEKYBOPAVTZKW-UHFFFAOYSA-L 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000007096 poisonous effect Effects 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 1
RWWNQEOPUOCKGR-UHFFFAOYSA-N tetraethyltin Chemical compound CC[Sn](CC)(CC)CC RWWNQEOPUOCKGR-UHFFFAOYSA-N 0.000 description 1
JTGNPNLBCGBCMP-UHFFFAOYSA-N tetraoctylstannane Chemical compound CCCCCCCC[Sn](CCCCCCCC)(CCCCCCCC)CCCCCCCC JTGNPNLBCGBCMP-UHFFFAOYSA-N 0.000 description 1
CRHIAMBJMSSNNM-UHFFFAOYSA-N tetraphenylstannane Chemical compound C1=CC=CC=C1[Sn](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 CRHIAMBJMSSNNM-UHFFFAOYSA-N 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
BOOITXALNJLNMB-UHFFFAOYSA-N tricyclohexyl borate Chemical compound C1CCCCC1OB(OC1CCCCC1)OC1CCCCC1 BOOITXALNJLNMB-UHFFFAOYSA-N 0.000 description 1
NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite

Landscapes

Chemical & Material Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

NL7908588A 1978-11-29 1979-11-27 Werkwijze voor het katalytisch kraken van koolwater- stofolieen en voor deze werkwijze geschikte katalysator. NL7908588A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR7833732A FR2442881A2 (fr)	1978-11-29	1978-11-29	Procede de craquage catalytique d'hydrocarbures, et catalyseur pour la mise en oeuvre du procede
FR7833732		1978-11-29

Publications (1)

Publication Number	Publication Date
NL7908588A true NL7908588A (nl)	1980-06-02

Family

ID=9215508

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL7908588A NL7908588A (nl)	1978-11-29	1979-11-27	Werkwijze voor het katalytisch kraken van koolwater- stofolieen en voor deze werkwijze geschikte katalysator.

Country Status (7)

Country	Link
JP (1)	JPS5575486A (fr)
CA (1)	CA1149306A (fr)
DE (1)	DE2947710A1 (fr)
FR (1)	FR2442881A2 (fr)
GB (1)	GB2037177B (fr)
IT (1)	IT1127622B (fr)
NL (1)	NL7908588A (fr)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1297792B (de) *	1963-06-28	1969-06-19	Mobil Oil Corp	Verfahren zum katalytischen Kracken eines Kohlenwasserstoffoels
US3399132A (en) *	1966-07-28	1968-08-27	Chevron Res	Hydrocaracking of hydrocarbons with a catalyst composite comprising nickel and tin associated with a porous acidic inorganic oxide carrier
NZ183608A (en) *	1976-03-31	1978-12-18	Mobil Oil Corp	Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4101417A (en) *	1976-10-04	1978-07-18	Gulf Research & Development Company	Method of negating the effects of metals poisoning on zeolitic cracking catalysts

1978
- 1978-11-29 FR FR7833732A patent/FR2442881A2/fr active Granted
1979
- 1979-09-25 CA CA000336254A patent/CA1149306A/fr not_active Expired
- 1979-11-27 JP JP15254079A patent/JPS5575486A/ja active Granted
- 1979-11-27 IT IT27621/79A patent/IT1127622B/it active
- 1979-11-27 NL NL7908588A patent/NL7908588A/nl not_active Application Discontinuation
- 1979-11-27 DE DE19792947710 patent/DE2947710A1/de active Granted
- 1979-11-27 GB GB7940852A patent/GB2037177B/en not_active Expired

Also Published As

Publication number	Publication date
FR2442881A2 (fr)	1980-06-27
JPS5575486A (en)	1980-06-06
DE2947710A1 (de)	1980-06-12
IT1127622B (it)	1986-05-21
GB2037177B (en)	1982-12-22
JPH0114275B2 (fr)	1989-03-10
CA1149306A (fr)	1983-07-05
IT7927621A0 (it)	1979-11-27
GB2037177A (en)	1980-07-09
DE2947710C2 (fr)	1989-12-07
FR2442881B2 (fr)	1982-06-11

Legal Events

Date	Code	Title
1985-01-01	A85	Still pending on 85-01-01
1986-11-03	BA	A request for search or an international-type search has been filed
1986-11-03	BB	A search report has been drawn up
1987-04-01	BC	A request for examination has been filed
1990-11-01	BI	The patent application has been withdrawn

Publication	Publication Date	Title
US3977963A (en)	1976-08-31	Method of negating the effects of metals poisoning on cracking catalysts
KR100331611B1 (ko)	2002-04-09	유동 접촉 분해에 있어서 가솔린 황 감소
KR20020052181A (ko)	2002-07-02	유동 촉매 분해에서 가솔린 황의 감소
ZA200101694B (en)	2002-07-04	A composition for use in converting hydrocarbons, its preparation and use.
AU2001285091A1 (en)	2002-06-06	FCC process incorporating crystalline microporous oxide catalysts having increased lewis acidity
WO2002018516A1 (fr)	2002-03-07	Procede de craquage catalytique fluide a base de catalyseur a l'oxyde cristallin microporeux presentant une acidite de lewis accrue
US4256564A (en)	1981-03-17	Cracking process and catalyst for same containing indium to passivate contaminating metals
US4193891A (en)	1980-03-18	Passivation of metals on cracking catalyst with an antimony thiocarbamate
US3008897A (en)	1961-11-14	Hydrocarbon demetallization process
US4190552A (en)	1980-02-26	Passivation of metals on cracking catalysts with an antimony tris (hydrocarbyl sulfide)
RU2442649C2 (ru)	2012-02-20	Катализатор, уменьшающий уровень содержания серы в бензине, для способа каталитического крекинга в псевдоожиженном слое катализатора
JPS6328957B2 (fr)	1988-06-10
US4198317A (en)	1980-04-15	Passivation of metals which contaminate cracking catalysts with antimony tris (hydrocarbyl sulfonate)
CA1303541C (fr)	1992-06-16	Methode de suppression de l'effet d'empoisonnement par les metaux sur les catalyseurs utilises en craquage sur lit fluidise
US4334979A (en)	1982-06-15	Hydrocarbon cracking process using a catalyst containing germanium
CA1132122A (fr)	1982-09-21	Methode de fractionnement catalytique d'hydrocarbures, et catalyseur pour la mise en oeuvre de ladite methode
US5424262A (en)	1995-06-13	Fluidized cracking catalyst with in situ metal traps
US6110357A (en)	2000-08-29	Passivated catalysts for cracking process
US4263130A (en)	1981-04-21	Process for cracking hydrocarbons with a catalyst passivated with an antimony tris (hydrocarbyl sulfide)
US4257876A (en)	1981-03-24	Passivation of metals contaminating a cracking catalyst with trihydrocarbylantimony oxide and process for converting hydrocarbons
NL7908588A (nl)	1980-06-02	Werkwijze voor het katalytisch kraken van koolwater- stofolieen en voor deze werkwijze geschikte katalysator.
US4264434A (en)	1981-04-28	Passivation of metals which contaminate cracking catalysts with antimony tris (hydrocarbyl sulfonate)
US3723299A (en)	1973-03-27	Hydrogenation process
JPS62232485A (ja)	1987-10-12	流動接触分解触媒のナトリウム被毒の抑制法
US4632748A (en)	1986-12-30	Cracking process