NL7401405A - Ketone peroxide solns stabilized in inert solvents - by addn. of amine oxides - Google Patents

Ketone peroxide solns stabilized in inert solvents - by addn. of amine oxides

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Publication number
NL7401405A
NL7401405A NL7401405A NL7401405A NL7401405A NL 7401405 A NL7401405 A NL 7401405A NL 7401405 A NL7401405 A NL 7401405A NL 7401405 A NL7401405 A NL 7401405A NL 7401405 A NL7401405 A NL 7401405A
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NL
Netherlands
Prior art keywords
solns
addn
inert solvents
peroxide
stabilized
Prior art date
Application number
NL7401405A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to NL7401405A priority Critical patent/NL7401405A/en
Publication of NL7401405A publication Critical patent/NL7401405A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/32—Compounds containing nitrogen bound to oxygen

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Solns. of ketone peroxides in inert solvents are stabilised by the addn. of an amine oxide (R1)(R2)(R3) right arrow O (where R1 R2 and R3 are (OH-substd.), (cyclo)alkyl gps. and R1 and/or R2 may also = H), in an amt. sufficient to render the soln. stable to storage under adiabatic conditions at 55 degrees C. The peroxide solns. are known and useful e.g. as curing agents for unsatd. polyester resins; typical solns. are of methyl-ethylketone peroxide or cyclohexanone peroxide in dimethylphthalate, dibutylphthalate, ethyl acetate, etc. These solns. are stabilised e.g. by adding at least 0.1%, pref. 0.2-0.5% of an amine oxide, e.g. triethanolamine oxide or tributylamine oxide.
NL7401405A 1974-02-01 1974-02-01 Ketone peroxide solns stabilized in inert solvents - by addn. of amine oxides NL7401405A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7401405A NL7401405A (en) 1974-02-01 1974-02-01 Ketone peroxide solns stabilized in inert solvents - by addn. of amine oxides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7401405A NL7401405A (en) 1974-02-01 1974-02-01 Ketone peroxide solns stabilized in inert solvents - by addn. of amine oxides

Publications (1)

Publication Number Publication Date
NL7401405A true NL7401405A (en) 1974-04-25

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ID=19820667

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7401405A NL7401405A (en) 1974-02-01 1974-02-01 Ketone peroxide solns stabilized in inert solvents - by addn. of amine oxides

Country Status (1)

Country Link
NL (1) NL7401405A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2396750A1 (en) * 1977-07-04 1979-02-02 Akzo Nv COMPOSITION CONTAINING A CYCLOHEXANONE PEROXIDE AND A SOLVENT
EP1241233A1 (en) * 2001-03-16 2002-09-18 Illinois Tool Works Inc. Primer / primer surfacer
WO2002092561A1 (en) * 2001-05-17 2002-11-21 Atofina Organic peroxide heat stabiliser
EP1441003A1 (en) * 2003-01-22 2004-07-28 Atofina Chemicals, Inc. Unsaturated polyester resin compositions with improved processing and storage stability

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2396750A1 (en) * 1977-07-04 1979-02-02 Akzo Nv COMPOSITION CONTAINING A CYCLOHEXANONE PEROXIDE AND A SOLVENT
US4230889A (en) * 1977-07-04 1980-10-28 Akzona Incorporated Desensitized solution of dihydroperoxycyclohexane
EP1241233A1 (en) * 2001-03-16 2002-09-18 Illinois Tool Works Inc. Primer / primer surfacer
WO2002092561A1 (en) * 2001-05-17 2002-11-21 Atofina Organic peroxide heat stabiliser
FR2824840A1 (en) * 2001-05-17 2002-11-22 Atofina Heat stabilizers, useful for reacting rapidly with carbonated radicals resulting from decomposition of polymer initiators and for stabilization of organic peroxides, comprise nitroxyl radicals
US6992225B2 (en) 2001-05-17 2006-01-31 Arkema Organic peroxide heat stabilizer
EP1441003A1 (en) * 2003-01-22 2004-07-28 Atofina Chemicals, Inc. Unsaturated polyester resin compositions with improved processing and storage stability

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