MY189165A - Polystyrene sulfonic acid resin catalyst, preparation method therefor and use thereof - Google Patents

Polystyrene sulfonic acid resin catalyst, preparation method therefor and use thereof

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Publication number
MY189165A
MY189165A MYPI2018701378A MYPI2018701378A MY189165A MY 189165 A MY189165 A MY 189165A MY PI2018701378 A MYPI2018701378 A MY PI2018701378A MY PI2018701378 A MYPI2018701378 A MY PI2018701378A MY 189165 A MY189165 A MY 189165A
Authority
MY
Malaysia
Prior art keywords
sulfonic acid
acid resin
isobutylene
catalyst
polystyrene sulfonic
Prior art date
Application number
MYPI2018701378A
Inventor
Shuai Yuan
Shaofeng Huang
Yan He
Yuan Li
Zhonghua Wang
Yanhong Lv
Weifeng Song
Longyue Dong
Zhenfeng Liu
Xueli Yu
Original Assignee
Wanhua Chemical Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wanhua Chemical Group Co Ltd filed Critical Wanhua Chemical Group Co Ltd
Publication of MY189165A publication Critical patent/MY189165A/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0228—Coating in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00539—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/06—Details of tube reactors containing solid particles
    • B01J2208/065—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of the platinum group metals, iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A polystyrene sulfonic acid resin catalyst and a preparation method therefor. The catalyst is separately used for performing dehydration of tertiary butyl alcohol (TBA) and isobutylene oligomerization to cogenerate isobutylene and diisobutylene (DIB). The catalyst comprises a polystyrene sulfonic acid resin, a metal, and a metal sulfate. The metal contains two parts: metal coated with the polystyrene sulfonic acid resin, and metal not coated with the polystyrene sulfonic acid resin. The metal sulfate is formed by converting the exposed surface of the metal not coated with the polystyrene sulfonic acid resin in the catalyst. When the catalyst is separately used in the dehydration of TBA and the isobutylene oligomerization, due to the high thermal conductivity of the catalyst, the two reactions are coupled, thus supplementing energy required by the dehydration of TBA and greatly reducing the hot-spot temperature of the bed layer of the isobutylene oligomerization. In the reaction, the conversion rate per pass of the dehydration of TBA may be 40% or more, and the selectivity of isobutylene is 99% or more. Moreover, there is no need to add inhibitor when the isobutylene oligomerization is catalyzed, because even if is isobutylene with a concentration greater than 80 wt% is used as a raw material, the selectivity of DIB is still 80% or more, and the conversion rate per pass is 90% or more. (Figure 1)
MYPI2018701378A 2016-06-03 2016-07-01 Polystyrene sulfonic acid resin catalyst, preparation method therefor and use thereof MY189165A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610393945.3A CN107457001B (en) 2016-06-03 2016-06-03 A kind of polystyrene sulfonic acid resin catalyst and its preparation method and application
PCT/CN2016/088186 WO2017206260A1 (en) 2016-06-03 2016-07-01 Polystyrene sulfonic acid resin catalyst, preparation method therefor and use thereof

Publications (1)

Publication Number Publication Date
MY189165A true MY189165A (en) 2022-01-30

Family

ID=60479515

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI2018701378A MY189165A (en) 2016-06-03 2016-07-01 Polystyrene sulfonic acid resin catalyst, preparation method therefor and use thereof

Country Status (6)

Country Link
JP (1) JP6526921B2 (en)
KR (1) KR102047352B1 (en)
CN (1) CN107457001B (en)
MY (1) MY189165A (en)
SG (1) SG11201803238YA (en)
WO (1) WO2017206260A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112745184B (en) * 2019-10-31 2022-08-12 中国石油化工股份有限公司 Method for producing isooctene by overlapping mixed C4 raw material with high olefin content
CN113880702B (en) * 2021-11-11 2024-02-02 万华化学集团股份有限公司 Preparation process of isomerised tridecanol
CN114349588B (en) * 2021-12-29 2023-09-19 万华化学集团股份有限公司 Preparation method of isooctane, isododecane and isohexadecane

Family Cites Families (15)

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US3760026A (en) * 1971-08-30 1973-09-18 Phillips Petroleum Co Synthesis of di-tert-butylethylene using olefin disproportionation
US4925989A (en) * 1987-06-01 1990-05-15 Texaco Inc. MTBE preparation from isobutylene/TBA and methanol in presence of an acid resin catalyst
CA2208273A1 (en) * 1994-12-30 1996-07-11 Kevin Joseph Edgar Process for preparing cellulose esters using a sulfonic acid resin catalyst
EP1388528B1 (en) * 2002-08-06 2015-04-08 Evonik Degussa GmbH Process for the oligomerisation of isobutene contained in hydrocarbon streams containing n-butene
CN101440013B (en) * 2007-11-22 2012-05-09 中国石油化工股份有限公司 Polymerization method for light olefins
US8067655B2 (en) * 2008-05-29 2011-11-29 Lyondell Chemical Technology, L.P. Diisobutylene process
CN102020526B (en) * 2009-09-09 2013-04-24 中国石油天然气股份有限公司 Preparing method of isobutene using tert-butyl alcohol
CN101757946B (en) * 2010-01-08 2012-07-18 凯瑞化工股份有限公司 Multi-functional group resin catalyst and preparation method thereof
CN102319586B (en) * 2011-06-10 2012-10-17 凯瑞化工股份有限公司 Resin catalyst used in alkylation reaction of isobutene and butylene and preparation method thereof
CN102329182A (en) * 2011-08-01 2012-01-25 天津市泰源工业气体有限公司 Method for preparing isobutene through direct hydration method
EP2776161A1 (en) * 2011-12-28 2014-09-17 Rohm and Haas Company Process for preparing a strong acid catalyst
JP2016085861A (en) * 2014-10-27 2016-05-19 昭和電工株式会社 Fuel battery electrode catalyst and method for manufacturing the same
CN104607252B (en) * 2014-12-17 2016-09-14 烟台大学 A kind of support type polystyrene sulfonic acid resin catalyst and preparation method thereof
CN105175203A (en) * 2015-09-08 2015-12-23 山东成泰化工有限公司 Method for preparing isobutene by MTBE (Methyl Tertiary Butyl Ether)
CN105130741B (en) * 2015-10-13 2017-01-04 宁波金海晨光化学股份有限公司 A kind of reactive distillation prepares the method for isoprene

Also Published As

Publication number Publication date
KR20180059527A (en) 2018-06-04
KR102047352B1 (en) 2019-11-21
WO2017206260A1 (en) 2017-12-07
CN107457001A (en) 2017-12-12
JP6526921B2 (en) 2019-06-05
SG11201803238YA (en) 2018-05-30
CN107457001B (en) 2019-09-20
JP2018532591A (en) 2018-11-08

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