MXPA99005565A - Compositions in dispersion ignifuga - Google Patents
Compositions in dispersion ignifugaInfo
- Publication number
- MXPA99005565A MXPA99005565A MXPA/A/1999/005565A MX9905565A MXPA99005565A MX PA99005565 A MXPA99005565 A MX PA99005565A MX 9905565 A MX9905565 A MX 9905565A MX PA99005565 A MXPA99005565 A MX PA99005565A
- Authority
- MX
- Mexico
- Prior art keywords
- silane
- acid
- esters
- aqueous dispersion
- silicon
- Prior art date
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 53
- 239000000203 mixture Substances 0.000 title description 18
- -1 phosphorus compound Chemical class 0.000 claims abstract description 37
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 18
- 239000011574 phosphorus Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000003377 silicon compounds Chemical class 0.000 claims abstract description 16
- 229920000620 organic polymer Polymers 0.000 claims abstract description 11
- 150000002148 esters Chemical class 0.000 claims description 35
- 229920001577 copolymer Polymers 0.000 claims description 24
- 239000000839 emulsion Substances 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 22
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 229920001567 Vinyl ester Polymers 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 229910052710 silicon Inorganic materials 0.000 claims description 13
- 239000010703 silicon Substances 0.000 claims description 13
- 150000003018 phosphorus compounds Chemical class 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 229920001519 homopolymer Polymers 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
- 150000001298 alcohols Chemical class 0.000 claims description 10
- 239000000470 constituent Substances 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 8
- VONWDASPFIQPDY-UHFFFAOYSA-N Dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000002657 fibrous material Substances 0.000 claims description 7
- 150000002238 fumaric acids Chemical class 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000004815 dispersion polymerization Substances 0.000 claims description 6
- 150000002689 maleic acids Chemical class 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N Ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 claims description 5
- 229920001276 Ammonium polyphosphate Polymers 0.000 claims description 5
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 5
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 4
- 235000011087 fumaric acid Nutrition 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical group CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive Effects 0.000 claims description 3
- 150000001412 amines Chemical group 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- 238000005470 impregnation Methods 0.000 claims description 3
- REZAIYDMQVPNCA-UHFFFAOYSA-N (3-hydroxyphenyl) dihydrogen phosphate Chemical compound OC1=CC=CC(OP(O)(O)=O)=C1 REZAIYDMQVPNCA-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- SKKPKVRWHCKIAK-UHFFFAOYSA-N 2-triethoxysilylethylphosphonic acid Chemical compound CCO[Si](OCC)(OCC)CCP(O)(O)=O SKKPKVRWHCKIAK-UHFFFAOYSA-N 0.000 claims description 2
- FBDVZTRAKUSSKE-UHFFFAOYSA-N 2-trimethoxysilylethylphosphonic acid Chemical compound CO[Si](OC)(OC)CCP(O)(O)=O FBDVZTRAKUSSKE-UHFFFAOYSA-N 0.000 claims description 2
- WHILMJRBTNKYAO-UHFFFAOYSA-N CC=C[Si](OCCOCC)(OCCOCC)OCCOCC Chemical compound CC=C[Si](OCCOCC)(OCCOCC)OCCOCC WHILMJRBTNKYAO-UHFFFAOYSA-N 0.000 claims description 2
- YACKEPLHDIMKIO-UHFFFAOYSA-N Methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N Triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- FIQMHBFVRAXMOP-UHFFFAOYSA-N Triphenylphosphine oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 claims description 2
- PMLWFQDHHJREGC-UHFFFAOYSA-N [SiH3]O[SiH3].C[SiH]([Si](C)(C)C)C Chemical compound [SiH3]O[SiH3].C[SiH]([Si](C)(C)C)C PMLWFQDHHJREGC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 239000004305 biphenyl Substances 0.000 claims description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000001244 carboxylic acid anhydrides Chemical group 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- MNFGEHQPOWJJBH-UHFFFAOYSA-N diethoxy-methyl-phenylsilane Chemical compound CCO[Si](C)(OCC)C1=CC=CC=C1 MNFGEHQPOWJJBH-UHFFFAOYSA-N 0.000 claims description 2
- KOWAYWQUMWNZJW-UHFFFAOYSA-N diethoxy-methyl-trimethylsilylsilane Chemical compound CCO[Si](C)([Si](C)(C)C)OCC KOWAYWQUMWNZJW-UHFFFAOYSA-N 0.000 claims description 2
- QZGNEODXJZDIBK-UHFFFAOYSA-N diethyl bis(trimethylsilyl) silicate Chemical compound CCO[Si](OCC)(O[Si](C)(C)C)O[Si](C)(C)C QZGNEODXJZDIBK-UHFFFAOYSA-N 0.000 claims description 2
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims description 2
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims description 2
- RJMRIDVWCWSWFR-UHFFFAOYSA-N methyl(tripropoxy)silane Chemical compound CCCO[Si](C)(OCCC)OCCC RJMRIDVWCWSWFR-UHFFFAOYSA-N 0.000 claims description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 150000002825 nitriles Chemical group 0.000 claims description 2
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 2
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 claims description 2
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical group OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- AKXUUJCMWZFYMV-UHFFFAOYSA-M tetrakis(hydroxymethyl)phosphanium;chloride Chemical compound [Cl-].OC[P+](CO)(CO)CO AKXUUJCMWZFYMV-UHFFFAOYSA-M 0.000 claims description 2
- 150000003568 thioethers Chemical group 0.000 claims description 2
- HXOGQBSDPSMHJK-UHFFFAOYSA-N triethoxy(6-methylheptyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCCC(C)C HXOGQBSDPSMHJK-UHFFFAOYSA-N 0.000 claims description 2
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 claims description 2
- GRCDEROHEMCMCO-UHFFFAOYSA-N trimethoxy(trimethylsilyl)silane Chemical compound CO[Si](OC)(OC)[Si](C)(C)C GRCDEROHEMCMCO-UHFFFAOYSA-N 0.000 claims description 2
- RVBVJEZJXBZDON-UHFFFAOYSA-N trimethoxy-[methoxy(dimethyl)silyl]silane Chemical compound CO[Si](C)(C)[Si](OC)(OC)OC RVBVJEZJXBZDON-UHFFFAOYSA-N 0.000 claims description 2
- NDPSWPCMEKRQBJ-UHFFFAOYSA-N tris(2-ethoxyethoxy)-methylsilane Chemical compound CCOCCO[Si](C)(OCCOCC)OCCOCC NDPSWPCMEKRQBJ-UHFFFAOYSA-N 0.000 claims description 2
- COIOYMYWGDAQPM-UHFFFAOYSA-N tris(2-methylphenyl)phosphane Chemical compound CC1=CC=CC=C1P(C=1C(=CC=CC=1)C)C1=CC=CC=C1C COIOYMYWGDAQPM-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N α-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- ZSJAXZNRNXJIKA-UHFFFAOYSA-N 3-diethoxyphosphorylpropyl(trimethoxy)silane Chemical compound CCOP(=O)(OCC)CCC[Si](OC)(OC)OC ZSJAXZNRNXJIKA-UHFFFAOYSA-N 0.000 claims 1
- KGGZEVXYIAMNCG-UHFFFAOYSA-O [NH4+].[NH4+].[NH4+].[O-]P([O-])=O Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])=O KGGZEVXYIAMNCG-UHFFFAOYSA-O 0.000 claims 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 1
- 210000000436 anus Anatomy 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- HZLIIKNXMLEWPA-UHFFFAOYSA-N diethoxy(dipropyl)silane Chemical compound CCC[Si](CCC)(OCC)OCC HZLIIKNXMLEWPA-UHFFFAOYSA-N 0.000 claims 1
- YHRRLJVICROTOJ-UHFFFAOYSA-L diphenoxyphosphoryl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OP([O-])(=O)[O-])OC1=CC=CC=C1 YHRRLJVICROTOJ-UHFFFAOYSA-L 0.000 claims 1
- 150000003003 phosphines Chemical class 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 description 38
- 239000003995 emulsifying agent Substances 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 11
- 239000003063 flame retardant Substances 0.000 description 11
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N fumaric acid Chemical compound OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 230000001681 protective Effects 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 3
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N (±)-Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- NEYTXADIGVEHQD-UHFFFAOYSA-N 2-hydroxy-2-(prop-2-enoylamino)acetic acid Chemical compound OC(=O)C(O)NC(=O)C=C NEYTXADIGVEHQD-UHFFFAOYSA-N 0.000 description 2
- 229940058905 Antimony compounds for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N Melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- DNTMQTKDNSEIFO-UHFFFAOYSA-N N-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N Vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001463 antimony compounds Chemical class 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N butyl 2-methylprop-2-enoate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- FNMTVMWFISHPEV-AATRIKPKSA-N dipropan-2-yl (E)-but-2-enedioate Chemical compound CC(C)OC(=O)\C=C\C(=O)OC(C)C FNMTVMWFISHPEV-AATRIKPKSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-tris(prop-2-enoxy)-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- GWRKYBXTKSGXNJ-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxyperoxy)propane Chemical compound CC(C)COOOCC(C)C GWRKYBXTKSGXNJ-UHFFFAOYSA-N 0.000 description 1
- PEUCDLBALASFEL-UHFFFAOYSA-N 3-trimethoxysilylpropylphosphonic acid Chemical compound CO[Si](OC)(OC)CCCP(O)(O)=O PEUCDLBALASFEL-UHFFFAOYSA-N 0.000 description 1
- AAOISIQFPPAFQO-UHFFFAOYSA-N 6,6-dimethylheptanoic acid Chemical compound CC(C)(C)CCCCC(O)=O AAOISIQFPPAFQO-UHFFFAOYSA-N 0.000 description 1
- 229940045714 Alkyl sulfonate alkylating agents Drugs 0.000 description 1
- WMGFVAGNIYUEEP-WUYNJSITSA-N Amylopectin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)O[C@H](OC[C@@H]2[C@H]([C@H](O)[C@@H](O)[C@@H](O[C@@H]3[C@H](O[C@H](O)[C@H](O)[C@H]3O)CO)O2)O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H]1O WMGFVAGNIYUEEP-WUYNJSITSA-N 0.000 description 1
- 229920000945 Amylopectin Polymers 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- YGEMXPPHJAAGEL-UHFFFAOYSA-N C(C)OP(OCC)=O.CCCCCCCCCC Chemical compound C(C)OP(OCC)=O.CCCCCCCCCC YGEMXPPHJAAGEL-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-L CHEBI:8154 Chemical class [O-]P([O-])=O ABLZXFCXXLZCGV-UHFFFAOYSA-L 0.000 description 1
- CZRCOWVNDIYQQC-UHFFFAOYSA-N COC(=O)C(O)NC(=O)C=CC Chemical compound COC(=O)C(O)NC(=O)C=CC CZRCOWVNDIYQQC-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N Dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229940039717 Lanolin Drugs 0.000 description 1
- 229920000126 Latex Polymers 0.000 description 1
- 229940067606 Lecithin Drugs 0.000 description 1
- 229920002521 Macromolecule Polymers 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinylpyrrolidone Chemical class C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- WJWHDNVSOFLCRY-UHFFFAOYSA-N P(OCC)(OCC)=O.C Chemical compound P(OCC)(OCC)=O.C WJWHDNVSOFLCRY-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N Pyrophosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 229910020263 SiP Inorganic materials 0.000 description 1
- 229940001941 Soy Proteins Drugs 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- WRWYTKCTJKBQST-UHFFFAOYSA-N [3-(hydroxymethylamino)-3-oxopropyl]phosphonic acid Chemical compound OCNC(=O)CCP(O)(O)=O WRWYTKCTJKBQST-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical compound OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000001413 amino acids Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- JZQAAQZDDMEFGZ-UHFFFAOYSA-N bis(ethenyl) hexanedioate Chemical compound C=COC(=O)CCCCC(=O)OC=C JZQAAQZDDMEFGZ-UHFFFAOYSA-N 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (Z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical class [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YLFBFPXKTIQSSY-UHFFFAOYSA-N dimethoxy(oxo)phosphanium Chemical compound CO[P+](=O)OC YLFBFPXKTIQSSY-UHFFFAOYSA-N 0.000 description 1
- 229960004419 dimethyl fumarate Drugs 0.000 description 1
- CGBYBGVMDAPUIH-ARJAWSKDSA-L dimethylmaleate(2-) Chemical compound [O-]C(=O)C(/C)=C(/C)C([O-])=O CGBYBGVMDAPUIH-ARJAWSKDSA-L 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- ZZTKVOKJMCZYBC-UHFFFAOYSA-L disodium;4-(2-dodecoxyethoxy)-4-oxo-2-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOCCOC(=O)CC(C([O-])=O)S([O-])(=O)=O ZZTKVOKJMCZYBC-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000004676 glycans Polymers 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000002209 hydrophobic Effects 0.000 description 1
- 230000000977 initiatory Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000005445 natural product Substances 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 210000000056 organs Anatomy 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002972 pentoses Chemical group 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- HETCEOQFVDFGSY-UHFFFAOYSA-N prop-1-en-2-yl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- GOPSAMYJSPYXPL-UHFFFAOYSA-N prop-2-enyl N-(hydroxymethyl)carbamate Chemical compound OCNC(=O)OCC=C GOPSAMYJSPYXPL-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
Abstract
The present invention relates to: Aqueous dispersion which can be prepared on the basis of at least one water-insoluble organic polymer, at least one silicon compound dispersed in water and at least one soluble or dispersible phosphorus compound in water
Description
COMPOSITION IN IGNIFUGANT DISPERSION
The invention concerns an aqueous dispersion, its preparation, its use and the products containing it. The use of halogen-containing additives or comonomers, optionally in combination with antimony compounds, is known for the flame retardant finishing of polymers. Flame retardant agents based on metal hydroxides such as AI (OH) 3 or Mg (OH) 2 generally have too little effect or impair the mechanical properties of the polymer because of the high amount used. Phosphorus-containing flame retardants, such as p. ex. Ammonium polyphosphate alone show, compared to halogenated compounds, also minor effects. In the case of aqueous dispersions of polymers, special requirements for flame retardants are raised: they must be water soluble or water dispersible; the dispersion containing the flame retardant agent must be stable, ie flocculation or coagulation must not be reached; in the dispersion film the flame retardant agent must be distributed in a stable and homogeneous manner. DE 3803030 C2 describes the use of phosphonates as flame retardants in synthetic materials such as a polyurethane, a polyvinyl chloride, a polyester and an epoxy resin.
European Patent EP 0733638 A1 discloses phosphorus-containing aromatic dicarboxylic acid esters as halogen-free flame retardants for polyester fiber materials. The German patent application publication document DE
OS 1950 8530 describes the simultaneous use of functionalized monomers and phosphorus compounds reactive with these functional groups in aqueous dispersion compositions in order to improve fireproofing. In the U.S. patent document US 5412014 A describes a process for the flame retardant finish of thermoplastic materials or thermosetting resins by a mixture of a silicone polymer powder (consisting of a polydiorganosiloxane and silicon dioxide) and a phosphorus-containing flame retardant. The invention was based on the mission to improve the state of the art and especially to make available aqueous dispersion compositions, which also without halogen and antimony compounds produce in the subsequent use p. ex. as a coating or impregnation agent, sufficient protection against flames. The invention was also based on the mission of making aqueous dispersion compositions available, which are suitable at the same time for the consolidation of fibrous materials and batts as well as for finishing and sizing of textile materials.
An object of the invention are aqueous dispersions which can be prepared on the basis of at least one water-insoluble organic polymer, at least one silicon compound dispersible in water and at least one phosphorus compound soluble or dispersible in water. Suitable water-insoluble organic polymers are preferably homopolymers and copolymers which are present in the form of an aqueous dispersion and which, if necessary at elevated temperature and / or in an alkaline medium, form a solid film after desiccation and, optionally, cross-linking . Preferred as water-insoluble polymers are vinyl ester homopolymers or copolymers containing one or more monomer units taken from the group consisting of vinyl esters of unbranched or branched alkyl carboxylic acids, preferably having 1 to 15 carbon atoms. , especially preferably from 1 to 10, and very particularly preferably from 1 to 3 C atoms; homopolymers or copolymers of (meth) acrylic acid esters containing one or more monomer units taken from the group consisting of esters with methacrylic acid and esters with acrylic acid of unbranched or branched alcohols with 1 to 12 carbon atoms C, especially preferably from 1 to 8, and very particularly preferably from 1 to 4 C atoms; homopolymers or copolymers of monoesters or diesters with fumaric and / or maleic acids of unbranched or branched alcohols with 1 to 12 C atoms, particularly preferably 1 to 8, and very particularly preferably 1 to 4; the homopolymers or copolymers of dienes such as butadiene or isoprene, as well as of olefins such as ethene or propene, the dienes being able to be copolymerized for example with styrene, esters with (meth) acrylic acid or the esters with fumaric or maleic acids; homopolymers or copolymers of vinylaromatic compounds such as styrene, methyl styrene or vinyl toluene. If appropriate, polyaddition and polycondensation film-forming polymers, which are insoluble in water, such as polyurethanes, polyesters, polyethers (except polyethylene oxide), polyamides, melamine and formaldehyde resins, phenol and formaldehyde resins, optionally are also suitable. also in the form of its oligomer precursor products. Preferred vinyl esters are vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethyl-hexanoate, vinyl laurate, 1-methyl-vinyl acetate, vinyl pivalate and vinyl esters of branched monocarboxylic acids in a with up to 15 C atoms, particularly preferably from 1 to 10, for example VeoVa9®-vinyl ester of neononanoic acid or VeoVa10®-vinyl ester of neodecanoic acid. Especially preferred are vinyl esters having a high ratio of O to CH, such as vinyl acetate.
Preferred esters with methacrylic acid or esters with acrylic acid are methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, t-butyl acrylate, methacrylate n-butyl, t-butyl methacrylate, 2-ethylhexyl acrylate. Especially preferred are the compounds methyl acrylate, methyl methacrylate, n-butyl acrylate and 2-ethylhexyl acrylate. Esters with methacrylic acid or esters with especially preferred acrylic acid are those having a high ratio of O to CH, such as methyl acrylate and methyl methacrylate. Preferred groups of esters with fumaric and maleic acids are the methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, t-butyl, hexyl, etii-hexyl and dodecyl groups. Esters with especially preferred fumaric and maleic acids are those having a high ratio of O to CH, such as dimethyl fumarate and dimethyl maleate. The copolymers of vinyl esters can optionally contain from 1.0 to 65% by weight, based on the total weight of the comonomer phase, preferably of α-olefins such as ethylene or propylene and / or vinyl aromatics such as styrene and / or or esters with acrylic acid or esters with methacrylic acid of alcohols with 1 to 15 C atoms such as methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate , t-butyl acrylate, n-butyl methacrylate, t-butyl methacrylate, 2-ethylhexyl acrylate and / or esters with ethylenically unsaturated dicarboxylic acids or their derivatives, such as diisopropyl fumarate, containing the esters of dimethyl, methyl and t-butyl, di-n-butyl, di-t-butyl and diethyl of maleic acid or fumaric acid, or maleic anhydride. Especially preferred are esters with acrylic acid or esters with methacrylic acid of alcohols having 1 to 8 carbon atoms, particularly preferably with 1 to 4 carbon atoms, such as methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, t-butyl acrylate, n-butyl methacrylate and t-butyl methacrylate. Preferably, the copolymers of vinyl esters contain less than 20% by weight, based on the total weight of the comonomer phase, of α-olefins and / or vinylaromatic compounds and / or esters with acrylic acid or esters with methacrylic acid of alcohols with more than 4 C atoms and / or esters with ethylenically unsaturated dicarboxylic acids of alcohols with more than 4 C atoms, so that a low O to CH ratio results in the copolymer. The copolymers of (meth) acrylic acid esters can optionally contain from 1.0 to 65% by weight, based on the total weight of the comonomer phase, preferably of α-olefins such as ethylene or propylene and / or vinyl aromatic compounds. such as styrene and / or esters of ethylenically unsaturated dicarboxylic acids or their derivatives such as diisopropyl fumarate, containing dimethyl, methyl and t-butyl, dibutyl and diethyl esters of maleic acid or fumaric acid, or acid anhydride maleic In a preferred embodiment, the copolymers of vinyl esters and the copolymers of (meth) acrylic acid esters additionally contain 0.05 to 10.0% by weight, based on the total weight of the comonomer mixture, preferably of monomers auxiliaries taken from the group of ethylenically unsaturated carboxylic acids, preferably acrylic acid or methacrylic acid; among the group of ethylenically unsaturated carboxylic acid amides, preferably acrylamide; among the group of ethylenically unsaturated sulphonic acids or their salts, preferably vinyl sulfonic acid; and / or among the group of comonomers several times ethnically unsaturated, for example divinyl adipate, diallyl maleate, allyl methacrylate or triallyl cyanurate. Suitable auxiliary monomers are also comonomers which have a crosslinking action, for example acrylamido glycolic acid (AGA), methylacrylamido glycolic acid methyl ester (MAGME), N-methylol acrylamide (NMAA), N-methylol methacrylamide, N- allyl methylol carbamate, alkyl ethers such as isobutoxy ether, or esters of N-methylol-acrylamide, of N-methylol-methacrylamide or of allyl N-methylol-carbamate. The corresponding to the copolymers of vinyl esters and to the copolymers of esters with (meth) acrylic acid serves for the copolymers of the esters with the maleic or fumaric acids. The preparation of the said water-insoluble, radically polymerizable polymers is preferably carried out in accordance with the emulsion polymerization process. The polymerization can be carried out discontinuously or continuously, with or without the use of seed latices, by previously arranging all the constituents or individual constituents of the reaction mixture, or by previously partially and subsequently dosing all the constituents or individual constituents of the reaction mixture, or according to the dosing process without previously having any constituent. All the dosages are preferably carried out as the respective component is consumed. The polymerization is preferably carried out in a temperature range from 0 to 100 ° C, particularly preferably from 20 to 100 ° C, most preferably from 30 to 90 ° C, and is initiated with the methods usually employed for emulsion polymerization. The initiation is carried out by means of the usual water-soluble radical-forming compounds, which are preferably used in amounts of 0.01 to 3.0% by weight, based on the total weight of the monomers. All the emulsifiers and / or protective colloids which are usually used in the case of emulsion polymerization can be used as dispersing agents. If necessary, up to 6% by weight of an emulsifier is used, based on the total weight of the monomers when carrying out the emulsion polymerization. Suitable emulsifiers are anionic or cationic as well as nonionic emulsifiers, provided that they are not soluble in the protective colloid. Preference is given to using protective colloids, especially preferably in amounts of up to 15% by weight, based on the total weight of the monomers. Examples thereof are preferably poly (vinyl alcohols) and their derivatives such as vinyl alcohol and vinyl acetate copolymers, poly (vinylpyrrolidones); polysaccharides in water-soluble form such as starches (amylose and amylopectin), cellulose, guar gum, tragacanthic acid, dextran, alginates and their carboxymethyl, methyl, hydroxyethyl and hydroxypropyl derivatives; proteins such as casein, soy proteins, gelatins; synthetic polymers such as poly [(meth) acrylic acid], poly [(meth) acrylamide], poly (vinyl sulfonic acids) and their water soluble copolymers; melamine and formaldehyde sulfonates, naphthalene and formaldehyde sulfonates, copolymers of styrene and maleic acid and of vinyl ethers and maleic acid. The organic polymers are present in an amount of preferably 30 to 70% by weight, particularly preferably 40 to 60% by weight, very particularly preferably 40 to 55% by weight, based on the total weight of the aqueous dispersion. Suitable water-dispersible silicon compounds are preferably silicic acid esters Si (OR ') 4, organo-organoxy-silane SiRn (OR') 4-n with n = 1 to 3, oligo-siloxanes of the general formula R3SiO (SiR2?) NSR3 with n = from 0 to 4, or its hydrolysis and condensation products, the R 'radicals representing alkyl radicals or alkoxyalkylene radicals with 1 to 4 carbon atoms, the same or different, preferably meaning methyl or ethyl , and R "being the same or different and meaning branched or unbranched alkyl radicals preferably having from 1 to 22 C atoms, particularly preferably from 1 to 10, most preferably from 1 to 4 C atoms, cycloalkyl radicals preferably having from 3 to 10 carbon atoms, particularly preferably from 5 to 6, very especially preferably 6 carbon atoms, alkylene radicals preferably having from 2 to 4 carbon atoms, aryl radicals, arylalkyl radicals and alkylaryl that have preferred preferably from 6 to 18 C atoms, particularly preferably from 6 to 12, very particularly preferably from 6 to 8 C atoms, said radicals R may also be substituted with ether, thioether, ester, amide groups, nitrile, hydroxyl, amine, carboxyl, sulfonic acid, carboxylic acid anhydride and carbonyl. Especially preferred silicon compounds are for example tetraethoxy-silane, methyl-tri (m) ethoxy-silane, methyl-tripropoxy-silane, methyl-tri (ethoxyethoxy) -silane, vinyn-tr (methoxyethoxy) s. lano, (meth) acryloxypropyl-triethoxy- or -trimethoxy-silane, ß-nitriloethyl-triethoxy-silane, mercapto-propyl-triethoxy- or -trimethoxy-silane, phenyl-triethoxy-silane, iso-octyl-triethoxy-silane, dipropyl -dietoxy-silane, methyl-phenyl-diethoxy-silane, diphenyl-dimethoxy-silane, methylvinyl-tri (ethoxyethoxy) silan as well as their disiloxanes and / or trisiloxanes. In addition, hexamethyl-diethoxy-trisiloxane, octamethyl-cyclotetrasiloxane, tetramethyl-diethoxy-disilane, trimethyl-trimethoxy-disilane, dimethyl-tetramethoxy-disilane and pentamethyl-disilane-disiloxane are to be mentioned. Said silicon compounds can be used preferably as such or in the form of their hydrolysis and condensation products. The said silicon compounds can be used alone or as a mixture. The preparation of organic silicon compounds can be carried out according to procedures such as those described in the works of Noli, Chemie und Technologie der Silicone, 2nd edition 1968, Weinheim, and Houben-Weyl, Methoden der organischen Chemie, tome E20, pages 1782 et seq., 2219 et seq., Georg Thieme Verlag, Stuttgart, 1987. The organosilicon compounds dispersible in water are preferably present in an amount of 0.5 to 60% by weight, particularly preferably 0, 5 to 20% by weight, very preferably from 0.5 to 10% by weight, based on the organic polymer portion. The silicon compounds are preferably added in the form of an emulsion of the organic polymer dispersion. Suitable emulsifiers are ammonium or cationic as well as nonionic emulsifiers. Suitable emulsifiers are common to one skilled in the art and are found, for example, in the work of Houben-Weyl, Methoden der organischen Chemie, volume XIV, 1, Makromolekulare Stoffe (macromolecular substances), Georg Thieme Verlag, Stuttgart, 1961, 192-208. Examples of emulsifiers are preferably anionic emulsifiers: 1. Alkyl sulfates, especially those having a chain length of 8 to 18 carbon atoms, alkyl- and alkylaryl ether sulfates with 8 to 18 carbon atoms in the hydrophobic radical and 1 to 40 units of ethylene oxide (EO) or propylene oxide (OP). 2. Sulfonates, especially alkyl sulfonates with 8 to 18 carbon atoms, alkylaryl sulfonates with 8 to 18 carbon atoms, taurides, esters and semi esters of sulfosuccinic acid with monovalent alcohols or alkylphenols having from 4 to 15 carbon atoms.; optionally, these alcohols or alkylphenols can also be ethoxylated with 1 to 40 units of EO. 3. Alkali metal and ammonium salts of carboxylic acids with 8 to 20 C atoms in the alkyl, a alkylaor alkyl radical. 4. Partial phosphoric acid esters and their alkali metal and ammonium salts, especially alkyl- and alkylaphosphates with 8 to 20 carbon atoms in the organic radical, alkyl ether or alkylaether phosphates with 8 to 20 carbon atoms. C atoms in the alkyl or alkylaradical and 1 to 40 units of EO. The nonionic emulsifiers are preferably: Poly (vinyl alcohol), which still has from 5 to 50%, preferably from 8 to 20% units of vinyl acetate, with a degree of polymerization of 500 to 3000. 6. Alkyl polyglycol ethers, preferably those having from 8 to 40 OE units and alkyl radicals from 8 to 20 C atoms. 7. Alkylapolyglycol ethers, preferably those having from 8 to 40 units of OE and 8 to 20. C atoms in the alkyl and aradicals. 8. Copolymers of ethylene oxide / propylene oxide (OE / OP) blocks, preferably those having from 8 to 40 units of EO or OP. 9. Products of addition of alkyl amines with alkyl radicals of 8 to 22 C atoms with ethylene oxide or propylene oxide. 10. Fatty acids with 6 to 24 carbon atoms. 11. Alkyl polyglycosides of the general formula R * -0-Zo, in which R * means a linear or branched, saturated or unsaturated alkyl radical, having on average 8 - 24 C atoms and Zo means an oligo-glycoside radical which has on average or = 1-10 hexose or pentose units or mixtures thereof. 12. Natural substances and their derivatives, such as lecithin, lanolin, saponins, celluloses; alkylic ethers of cellulose and carboxyalkylcelluloses, the alkyl groups of which each have up to 4 carbon atoms. 13. Linear organ (poll) siloxanes containing polar groups, especially those having alkoxy groups with up to 24 C atoms and / or up to 40 OE and / or OP groups. The cationic emulsifiers are preferably: 14. Salts of primary, secondary and tertiary fatty amines of
8 to 24 C atoms with acetic acid, sulfuric acid, hydrochloric acid and phosphoric acids. 15. Alkyl- and alkylbenzene-ammonium quaternary salts, especially those whose alkyl groups have from 6 to 24 C atoms, especially the halides, sulphates, phosphates and acetates. 16. Alkyl-pyridinium, alkyl-imidazolinium and alkyl oxazolium salts, especially those whose alkyl chain has up to 18 carbon atoms, especially the halides, sulphates, phosphates and acetates. The ampholytic emulsifiers are preferably: 17. Amino acids substituted with long chains such as N-alkyl-di (aminoethyl) glycine or salts of N-alkyl-2-amino-propionic acids. 18. Betaines, such as N- (3-acylamido-propii) -N: N-dimethylammonium salts with a C 8 -C 8 acyl radical and alkyl imidazolium betaines. The emulsifiers are generally used in amounts of preferably up to 10% by weight, based on the silicon compounds. Preferably, the amount amounts to < 1% by weight, based on organic polymers. Suitable water soluble or dispersible phosphorus compounds are preferably esters, amides or ester-amides of alkyl- or aryl-phosphonic acids, phosphoric acid or pyrophosphoric acid, tetrakis- (hydroxyalkyl) -phosphonium salts, salts of polyphosphoric acid , especially ammonium polyphosphate or triaryl- or trialkyl-phosphine oxides. Preferred phosphorus compounds are for example methane phosphonic acid diethyl ester, methane phosphonic acid dimethyl ester, d, (p) ethyl pentaerythritol diphosphonate, (m) ethyl-neopentyl phosphonate, triphenyl phosphate, tricresyl phosphate , resorcinol phosphate and bis-diphenyl, diphenyl phosphate and pentaerythritol, phenyl phosphate and neopentyl, nitrile-tris-methylenephosphonates of mono-, di- and tri-ammonium, dimethyl ester of [3 - [(hydroxy-methyl)] amino] -3-oxo-propyl] -phosphonic chloride, tetrakis (hydroxymethyl) -phosphonium chloride, ammonium polyphosphate, tritolyl-phosphine oxide and triphenyl-phosphine oxide. Especially preferred phosphorus compounds are the compounds diethyl ester of methane-phosphonic acid, dimethyl ester of methane-phosphonic acid, nitrile-tris-methylenephosphonates of mono-, di- and tri-ammonium, dimethyl ester of [3 - [(hydroxy -methyl) amino] -3-oxo-propyl] -phosphonic acid. The phosphorus compounds are used in amounts of preferably 0.1 to 90% by weight, particularly preferably 0.1 to 50% by weight, most preferably 5 to 30% by weight, based on the total weight of the organic polymers. Further preferred phosphorus compounds are those which additionally carry silicon in the molecule, such as, for example, diethyl ester of 2-triethoxysilyl-ethane-phosphonic acid, diethyl ester of 2-trimethoxysilyl-ethane-phosphonic acid, diethyl ester of 3-trimethoxysilyl -propane-phosphonic acid, diethyl ester of 2-tri [methoxyethoxy] silyl-ethano-phosphonic acid and 1,3-bis [diethylphosphonoethyl] -tetramethyl-di-loxane. The phosphorus compounds with silicon in the molecule are used in amounts of preferably 0.1 to 90% by weight, particularly preferably 0.1 to 50% by weight, very especially preferably 5 to 30% by weight , referred to the total weight of organic polymers.
The phosphorus compounds are preferably added as an aqueous solution or in the form of an emulsion - for whose composition the same as mentioned in the case of silicon compounds - is used for the dispersion of polymers. The mentioned phosphorus compounds can be used alone or as a mixture. Another object of the invention is a process for the preparation of an aqueous dispersion, the constituents being mixed together. In particular, an aqueous dispersion of a polymer, a silicon compound and a phosphorus compound are mixed together. In this case, the constituent of the polymer dispersion type is always used as an aqueous dispersion. The component component with silicon can be used as a 100% substance or as an aqueous emulsion. The constituent component with phosphorus can be used as a 100% substance, or in the case of a solid material as an aqueous solution or dispersion or in the case of a liquid as an aqueous solution or emulsion. All combinations of the above formulations are possible. A possibility of the process is preferred, according to which an aqueous dispersion of a polymer is mixed with an aqueous solution of the component with phosphorus and with an emulsion of the component with silicon.
A possibility of the process is also preferred, according to which an aqueous dispersion of the polymer is mixed with the component with 100% phosphorus and with an emulsion of the component with silicon. The constituents of the polymer dispersion types, silicon component and phosphorus component are mixed together by stirring or shaking, the dispersion of the polymer being preferably pre-arranged and the component with silicon and the phosphorus component then added. Preferably, the component is first mixed with silicon and the component with phosphor then the mixture is added to the polymer dispersion. The dispersions according to the invention are preferably used in coating compositions, impregnation agents or adhesives. In addition, these are used for the consolidation of fibrous materials or batts. The dispersion compositions can be used in typical applications sectors. For example, in coating agents or protective paints against fires, in adhesives or as binders for textile goods. The dispersion compositions according to the invention are especially suitable for the consolidation of fibrous materials, such as webs or wadding or also for the finishing and finishing of textile materials. Another object of the invention are fibrous materials, which contain the dispersions according to the invention. The substrates treated with the dispersion composition according to the invention are finished or prepared in a flame-retardant manner against untreated substrates. In the case of the finishing or sizing of textile materials, the dispersion according to the invention is used in a dilution of preferably 5 to 40% by weight in water. The dilution is adapted to the respective finishing or sizing process. Thus, when spraying it is from 10 to 25% by weight, when impregnated by a single face it is from 5 to 35% by weight and when applied in the form of foam it is from 20 to 30% by weight.
EXAMPLES
Preparation of the emulsion solution: 0.50 g of Aerosol A 102 (half ester-salt of sulfosuccinic acid) and 4.60 g of Genapol PF 40 (polymerization product based on propylene oxide and ethylene oxide) were dissolved in 232 g of H2O.
Preparation of the polymer films: A film on a flat base was spread out from the dispersion by means of a doctor blade, so that after drying a film thickness of approximately 250 μm was obtained. After drying in air for about 20 h, the polymer film was tempered in a drying oven for 5 min at 150 ° C. From the film, pieces with a size of 140 mm x 52 mm were cut and stored for at least 24 h in a desiccator over blue gel (Blaugel).
Determination of the oxygen index (LOI): The determination of the LOI was carried out in accordance with ISO 4589, with the difference that the samples, before the measurement, were stored for at least 24 h in a desiccator over blue gel (Blaugel).
EXAMPLE 1
4.22 g of methyl triethoxy silane and 2.94 g of dimethyl phosphonate (DMMP) were added with stirring in 15.8 g of the emulsion solution. The resulting emulsion was incorporated with stirring in 200 g of a crosslinkable dispersion of vinyl acetate and butyl acrylate (LT 420 from Wacker-Chemie GmbH) with a solids content of 48% and thoroughly mixed for 2 hours. h. The LOI of the polymer film obtained was 23.5.
EXAMPLE 2
8.44 g of methyl triethoxy silane and 5.88 g of DMMP were added with stirring in 31.6 g of the emulsion solution. The resulting emulsion was incorporated with stirring in 200 g of a crosslinkable dispersion of vinyl acetate and butyl acrylate (LT 420 from Wacker-Chemie GmbH) with a solids content of 48% and thoroughly mixed for 2 hours. h. The LOI of the obtained polymer film was 24.2.
EXAMPLE 3
7.8 g of Wacker's SiP ester (triethoxysilyl ethanophosphoric acid diethyl ester) were added with stirring in 15.8 g of the emulsion solution. The resulting emulsion was incorporated with stirring in 200 g of a crosslinkable dispersion of vinyl acetate and butyl acrylate (LT 420 from Wacker-Chemie GmbH) with a solids content of 48% and thoroughly mixed for 2 hours. h. The LOI of the polymer film obtained was 23.2.
EXAMPLE 4
4.22 g of methyl triethoxy silane and 6.59 g of n-decane phosphonic acid diethyl ester were added with stirring in 15.8 g of the emulsion solution. The resulting emulsion was incorporated with stirring in 200 g of a crosslinkable dispersion of vinyl acetate and butyl acrylate (LT 420 from Wacker-Chemie GmbH) with a solids content of 48% and thoroughly mixed for 2 hours. h. The LOI of the obtained polymer film was 22.6.
EXAMPLE 5
8.44 g of Wacker TES-40 (product of hydrolysis and condensation of tetraethoxysilane with a Si content of 40%) and 5.88 g of DMMP were incorporated with stirring into 31.6 g of the emulsion solution. The resulting emulsion was incorporated with stirring in 200 g of a crosslinkable dispersion of vinyl acetate and butyl acrylate (LT 420 from Wacker-Chemie GmbH) with a solids content of 48% and thoroughly mixed for 2 hours. h. The LOI of the obtained polymer film was 22.7.
EXAMPLE 6 (COMPARATIVE EXAMPLE)
The LOI of a crosslinkable dispersion of vinyl acetate and butyl acrylate (LT 420 from Wacker-Chemie GmbH) without the addition of additives containing silicon and phosphorus was 19.5.
EXAMPLE 7 (COMPARATIVE EXAMPLE)
.88 g of DMMP were incorporated with stirring into 31.6 g of the emulsion solution. The resulting emulsion was incorporated with stirring in 200 g of a crosslinkable dispersion of vinyl acetate and butyl acrylate (LT 420 from Wacker-Chemie GmbH) with a solids content of 48% and thoroughly mixed for 2 hours. h. The LOI of the polymer film obtained was 21.5.
Claims (14)
1. - Aqueous dispersion which can be prepared on the basis of at least one water-insoluble organic polymer, at least one silicon compound dispersible in water and at least one phosphorus compound soluble or dispersible in water.
2. Aqueous dispersion according to claim 1, characterized in that the water-dispersible silicon compound and the water soluble or dispersible phosphorus compound can also be replaced by a single compound, which is soluble or dispersible in water and contains both phosphorus and water. also silicon.
3. Aqueous dispersion according to claim 1 or 2, characterized in that the water-insoluble organic polymer consists of one or more polymers taken from the group consisting of homopolymers or copolymers of vinyl esters containing one or more monomer units taken from the group consisting of group of vinyl esters of unbranched or branched alkyl carboxylic acids; homopolymers or copolymers of (meth) acrylic acid esters containing one or more monomer units taken from the group consisting of esters with methacrylic acid and esters with acrylic acid of alcohols, homopolymers or copolymers of monoesters or diesters with fumaric acids and / or maleic of branched or unbranched alcohols; the homopolymers or copolymers of dienes as well as olefins, the dienes being able to be copolymerized with styrene, esters with (meth) acrylic acid or the esters with fumaric or maleic acids; homopolymers or copolymers of vinyl aromatic compounds such as styrene, methyl styrene and vinyl toluene.
4. Aqueous dispersion according to claim 1, characterized in that one or several silicon compounds are taken from the group formed by the silicic acid esters Si (OR ') 4, organo-organoxy-silanes SiRn (OR') 4-n with n = from 1 to 3, oligo-siloxanes of the general formula R3SiO (SiR2?) NSiR3 with n = 0 to 4 or their products of hydrolysis and condensation, the radicals representing alkyl or alkoxyalkyl radicals being the same or different and being the R equal or different and meaning branched or unbranched alkyl radicals, cycloalkyl radicals, alkylene radicals, aryl, arylalkyl or alkylaryl radicals, said radicals R may also be substituted with ether, thioether, ester, amide groups, nitrile, hydroxyl, amine, carboxyl, sulfonic acid, carboxylic acid anhydride and carbonyl, tetraethoxy-silane, methyl-tri (m) ethoxy-silane, methyl-tripropoxy-silane, methyl-tri (ethoxyethoxy) silane, vinyl-tri ( methoxyethoxy) sil anus, (meth) acryloxypropyl-triethoxy- or -trimethoxy-silane, ß-nitriloethyl-triethoxy-silane, mercaptopropyl-triethoxy- or -trimethoxy-silane, phenyl-triethoxy-silane, iso-octyl-triethoxy-silane, dipropyl-diethoxy -silane, methyl-phenyl-diethoxy-silane, diphenyl-dimethoxy-silane, methyl vinyl-tri (ethoxy-ethoxy) silane and their disiloxanes and / or trisiloxanes; hexamethyl-diethoxy-trisiloxane, octamethyl-cyclotetrasiloxane, tetramethyl-diethoxy-disilane, trimethyl-trimethoxy-disilane, dimethyl-tetramethoxy-disilane, pentamethyl-disilane-disiloxane and their hydrolysis and condensation products.
5. Aqueous dispersion according to claim 1, characterized in that one or more compounds are contained as phosphorus compounds from the group consisting of esters, amides or ester-amides of alkyl- or aryl-phosphonic acids, phosphoric acid or acid pyrophosphoric, salts of tetrakis (hydroxyalkyl) -phosphonium, salts of polyphosphoric acid, especially ammonium polyphosphate, or triaryl- or trialkyl-oxides of phosphines, diethyl ester of methane-phosphonic acid, dimethyl ester of methane-phosphonic acid, di (m) ) ethyl-pentaerythritol diphosphonate, (m) ethyl-neopentyl phosphonate, triphenyl phosphate, tricresyl phosphate, resorcinol phosphate and bis-diphenyl, diphenyl diphosphate and pentaerythritol, phenyl phosphate and neopentyl, nitrile-tris-methylene mono-di- and tri-ammonium phosphonates, [3- (hydroxymethyl) amino] -3-oxo-propyl-phosphonic acid dimethyl ester, tetrakis (hydroxymethyl) -phosphonium chloride, ammonium polyphosphate, tritolylphosphine I-oxide and triphenyl-phosphine oxide.
6. Aqueous dispersion according to claim 2, characterized in that the compound soluble or dispersible in water, containing both phosphorus and silicon, consists of one or more taken from the group consisting of diethyl ester of 2-triethoxysilyl-ethane-phosphonic acid , 2-trimethoxysilyl-ethane-phosphonic acid diesyl ester, 3-trimethoxysilyl-propane-phosphonic acid diethyl ester, 2-tri [methoxyethoxy] silyl-ethane-phosphonic acid diethyl ester and 1,3-bis [diethylphosphonoethyl] ] -tetramethyl-disiloxane.
7. Process for the preparation of an aqueous dispersion according to one or more of claims 1 to 6, characterized in that the constituents are mixed together.
8. Process for the preparation of an aqueous dispersion according to claim 7, characterized in that an aqueous polymer dispersion is mixed with the silicon and phosphorus compounds.
9. Process for the preparation of an aqueous dispersion according to claim 7, characterized in that an aqueous polymer dispersion is mixed with a solution, emulsion or dispersion of the silicon compounds and with a solution, emulsion or dispersion of the phosphorus compounds. .
10. Process for the preparation of an aqueous dispersion according to claim 9, characterized in that an aqueous dispersion of polymer is mixed with an aqueous solution of the component with phosphorus and with an emulsion of the component with silicon.
11. Process for the preparation of an aqueous dispersion according to claim 9, characterized in that an aqueous dispersion of polymer is mixed with the component with 100% phosphorus and with an emulsion of the component with silicon.
12. Use of dispersions according to one or more of claims 1 to 6 or prepared according to one of claims 7 to 11 in coating agents, impregnation agents or adhesives.
13. Use of dispersions according to one or more of claims 1 to 6 or prepared according to one of claims 7 to 11 for the consolidation of fibrous materials or batts.
14. Fibrous material, characterized in that it had been treated with dispersions according to one or several of claims 1 to 6 or prepared according to one of claims 7 to 11.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19832094.9 | 1998-07-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA99005565A true MXPA99005565A (en) | 2000-01-01 |
Family
ID=
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6111002A (en) | Flame-retardant dispersion composition | |
US6429239B1 (en) | Redispersible dispersion powder composition, process for its preparation and its use | |
JP3060316B2 (en) | Redispersible silicon-modified dispersed powder composition, method for producing the same and use thereof | |
KR101208866B1 (en) | Colloidal aqueous organopolysiloxane dispersions which contain binders and the use thereof | |
US5668216A (en) | Crosslinkabel dispersion powders as binders for fibers | |
ES2315808T3 (en) | CURABLE COMPOSITION AND USE OF THE SAME. | |
US5608011A (en) | Crosslinkable polymer powder compositions | |
US6114423A (en) | Redispersable cross-linkable dispersion powders | |
US20130052356A1 (en) | Paper Coating Compositions For Grease and Water Resistance | |
KR20000006154A (en) | Fiber bonding powder composition for consolidating fiber materials | |
US6090868A (en) | Process for treating mineral coating agent and binder compositions with plastics | |
MXPA99005565A (en) | Compositions in dispersion ignifuga | |
US9340908B2 (en) | Low formaldehyde and high wet strength vinyl acetate ethylene copolymer and vinyl acetate polymer dispersions | |
US6235843B1 (en) | Method for producing cross-linkable redispersible powders containing isocyanate groups | |
KR910003432B1 (en) | Stable latexes having phosphorous containing surface groups | |
CN105658868A (en) | Carpet product and process for the manufacturing of a carpet product | |
CN104284937A (en) | Curable epoxide containing formaldehyde-free compositions, articles including the same, and methods of using the same | |
GB2299094A (en) | Flame-resistant aqueous polymer formulations | |
JP2007327050A (en) | Curable composition | |
CN101798367A (en) | Vinyl acetate/butenedioic acid cycloalkyl ester copolymers and uses thereof |