MXPA98002555A - Cosmetic compositions detergents and uses - Google Patents

Abstract

The present invention relates to: new detergent compositions comprising, in a cosmetically acceptable medium. (A) a washing base comprising at least one anionic surfactant ether sulfate and at least one surface active agent of the alkylbetaine type and (B) a conditioning system comprising at least one cationic polymer dimethyl diatyl ammonium and at least one amine silicone. Application in the cleaning and treatment of keratin materials such as skin and hair

Description

COSMETIC COMPOSITIONS DETERGENTS AND UTILIZATION Field of the Invention The present invention relates to new cosmetic compositions with improved properties intended simultaneously for cleaning, for conditioning keratin materials and comprising, in a cosmetically acceptable support, a washing base consisting of surfactants with detergent power in which they are also present as conditioning agents, satonic polymers in association with aminated silicones. The invention also relates to the use of the said compositions in the aforementioned cosmetic application.

Background of the Invention For cleansing and / or washing the skin or the hair, the use of detergent compositions based essentially on conventional surfactants of the particularly anionic, nonionic and / or amphoteric type, but more particularly of the anionic type, is common. These compositions are applied to the skin or wet hair and the foam generated by massage or REF: 27114 friction with the hands allows, after rinsing with water, the elimination of the various dirt initially present on the skin or hair.

These basic compositions have, of course, a good washing power, but the inherent intrinsic cosmetic properties are still quite low, particularly in view of the fact that the relatively aggressive character of a cleaning treatment of this type can produce the long on the hair fiber damage more or less accused united in particular with the progressive elimination of the lipids or proteins contained within or on the surface of the latter.

Also, to improve the cosmetic properties of the detergent compositions indicated above, and more particularly those which are intended to be applied to sensitive hair (ie, hair that is damaged or weakened particularly under the chemical action of atmospheric agents and / or of hair treatments such as permanent, dyes or discolorations), it is now usual to introduce in these latter complementary cosmetics agents called conditioning agents intended primarily to repair or limit the ne sts e ects ndeseables nduced by the different treatments or aggressions experienced, more or less repeated, the hair fibers. These conditioning agents can, of course, also improve the cosmetic behavior of natural hair.

The conditioning agents most commonly used in shampoos today are cationic polymers, silicones and / or silicone derivatives, which in effect give washed, dry or wet hair an ease of unraveling, softness and clear smoothing. increased in relation to what can be obtained with the corresponding cleaning compositions that do not have them.

In sensitive hair, in order to obtain the cosmetics of the silicones along the length of the hair fiber, silicone and cationic polymer associations are preferably used.

However, despite recent progress in the field of shampoos based on cationic polymers and silicones, the latter do not really satisfy completely, so that there is still a strong need today to have new products that present, at the level of one or several cosmetic properties mentioned above, better yields.

The present invention satisfactorily addresses said need.

Thus, as a consequence of important investigations carried out on the subject, it has now been discovered by the applicant firm, in a totally unexpected and surprising way, that by using (A) a specific washing base and (B) a conditioning system comprising at least one polymer Particular cationic and at least one amino silicone, as defined below, it is possible to obtain detergent compositions having excellent cosmetic properties, in particular the disentangling, softness, flexibility and volume of the treated hair and all this while maintaining its good intrinsic washer power.

Description of the invention.

Thus, according to the present invention, new detergent compositions comprising, in a cosmetically acceptable medium, (A) a washing base comprising at least one anionic surfactant of the alkylether sulfate type and at least one amphoteric surfactant of the alkylbetanin type have now been proposed. of C8-C20 and (B) a conditioning system comprising at least one amino silicone and at least one cationic polymer selected from among the homopolymers which include units corresponding to the formulas (I) and / or (I) as the main constituent of the chain '). - ( formulas in which and t are equal to 0 or 1, the sum of k + t being equal to 1; R3 designates a hydrogen atom or a methyl radical; R x and R 2, independently of one another, designate an alkyl group having from 1 to 22 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has from 1 to 5 carbon atoms, a lower amidoalkyl group (1 to 5) carbon atoms) or Rx and R2 may designate, together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; And it is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate.

The subject of the invention is also the use in cosmetics of the compositions indicated above for the cleaning, conditioning of keratin materials such as hair and skin.

The compositions can, for example, be used for removing makeup from keratin materials such as the skin (for example from the face, neck or lips), the eyelashes, the eyebrows.

But other characteristics, aspects and advantages of the invention will also appear more clearly with the reading of the following description as well as of the concrete examples; but in no way restrictive, intended to illustrate it.

As indicated above, the essential constituents that fall within the composition of the hair products of the invention are (A) a washing base, (B) a conditioning system comprising (i) at least one aminated silicone and (ii) minus a particular cationic polymer.

A - BASE WASHER The compositions according to the invention necessarily comprise a washing base, generally aqueous, comprising one or more anionic surface-active agents of the alkyl ether sulfate type and one or more amphoteric surface-active agents C8-C20 alkylbetaine.

The minimum amount of washing base is just sufficient to give the final composition a satisfactory foaming and / or detergent power, and too much washing-up amount does not really provide any additional benefits.

Thus, according to the invention, the washing base can represent from 2% to 50% by weight, preferably from 10% to 35% by weight, and even more preferably from 12% to 25% by weight, of the total weight of the final composition. (i) Alkyl ether sulfate type anionic surfactant (s): The anionic surfactants of the alkyl ether sulfate type usable, alone or in mixtures, within the framework of the present invention, are the salts (in particular alkali salts, particularly sodium, ammonium salts, salts of amines, salts of aminoalcohols or salts of magnesium) alkyl ether sulphates, alkylamido ether sulphates, alkylarylether sulfates; the alkyl ether sulfosuccinates, the alkyl or acyl radical of all these various compounds preferably comprising from 8 to 24 carbon atoms, and the aryl radical which preferably designates a phenyl or benzyl group.

The average number of ethylene oxide or propylene oxide groups that can range particularly between 2 and 50 and more particularly between 2 and 10.

Among the anionic surfactants, it is preferred to use the salts of C 8 -C 14 alkylether sulfate and more particularly those of C 12 -C 14. These salts comprise in particular from 2 to 5 ethylene oxide groups.

The anionic surfactants are generally present in a proportion of 1 to 50% by weight, preferably 5 to 20% by weight, based on the total weight of the composition. (ii) Amphoteric Surfactant Agent (s): According to the invention, the amphoteric surfactants must be chosen from the alkyl (C8-C20) betaines of the formula: CH-, R - - CH- - C00"I CH-. wherein R designates an alkyl radical, linear or branched, of C8-C20, preferably of C10-C14, and more particularly of C12-C14.

In particular, it is preferred to use cocobetaine marketed by the company HENKEL under the name DEHYTON AB 30.

The surfactants are generally present at a ratio of 1 to 50% by weight, preferably 1 to 20% by weight, based on the total weight of the composition.

B - CONDITIONER SYSTEM (i) - Amino silicones According to an essential characteristic of the detergent compositions according to the invention, the latter also contain at least one aminated silicone.

In all of the foregoing or above, it is meant to designate by silicone or polysiloxane, in accordance with general acceptance, any polymer or oligomer organosilicate of linear or cyclic, branched or cross-linked structure, of variable molecular weight, obtained by polymerization and / or polycondensation of suitably functionalized silanes, essentially constituted by a repetition of main units in which the silicon atoms are linked together by oxygen atoms (siloxane bond = Si-O-Si =), the hydrocarbon radicals being optionally substituted directly linked by means of a carbon atom on the indicated silicon atoms. The most common hydrocarbon radicals are the alkyl radicals, in particular L-CK, and in particular methyl, the fluoroalkyl radicals, the aryl radicals and in particular phenyl, and the alkenyl radicals and in particular vinyl radicals; other types of radicals capable of being linked either directly or through a hydrocarbon radical to the siloxane chain are in particular hydrogen, halogens and in particular chlorine, bromine or fluorine, thiols, alkoxy radicals, polyoxyalkylene radicals (or polyethers) and in particular polyoxyethylene and / or polyoxypropylene, hydroxyl or hydroxyalkyl radicals, amide groups, acyloxy or acyloxyalkyl radicals, amphoteric or betaine groups, anionic groups such as carboxylates, thioglycolates, sulfosuccinates, thiosulfates, phosphates and sulfates, this list not being well understood in any way limiting (silicones called "organomodified").

According to the invention, silicone is designated by any silicone comprising at least one primary, secondary, tertiary amine or a quaternary ammonium group. The following can be cited: (a) the polysiloxanes referred to in the CTFA dictionary "amodimethicone" and corresponding to the formula: wherein x 'e and' are integers that depend on molecular weight, generally such that the indicated weight average molecular weight is between about 5 000 and 500 000; (b) the aminated silicones that respond to the formula: R'aG3-a-Si (° SiG2) n- (OSiGbR'2-b) m- ° -SiG3-a-R'a (IJI) wherein: G is a hydrogen atom, or a phenyl group, OH, or C1-C8 alkyl, for example methyl, a designates the number 0 or the integer from 1 to 3, in particular 0, b designates 0 or 1, and in particular 1, m and m are numbers such that the sum (n + m) can vary particularly from 1 to 2 000 and in particular from 50 to 150, being able to designate a number from 0 to 1999 and particularly from 49 to 149 and m may designate a number from 1 to 2 000, and particularly from 1 to 10; R 'is a monovalent radical of formula -Cq-H2qL in which q is a number from 2 to 8 and L is an optionally quaternized amino group selected from the groups: -NR "-CH: -CH, -N '(R"): -N (R "): -N3 (R"). A -NH © (R "): A -NH2 © (R": .- V -N (R ") - CH; -CH;, - N? R" H: wherein R "can designate hydrogen, phenyl, benzyl, or a saturated monovalent hydrocarbon radical, for example an alkyl radical having from 1 to 20 carbon atoms and A" represents a halogenide ion such as for example fluoride, chloride, bromide or iodide.

A product corresponding to this definition is the silicone called "trimethylsilyllamodimethicone", which corresponds to the formula: (CH, OS¡ (CH vz (IV m in which n and m have the meanings given above (see formula III).

Such polymers are described, for example, in the patent application EP-A-95238. (c) the aminated silicones that respond to the formula: wherein: R5 represents a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical of C-L-, ^, O-alkylene of C2-C18, for example methyl; Rs represents a divalent hydrocarbon radical, particularly an alkylene radical of C-c-18 or a divalent alkylene oxide group of C 1 -C 18, for example of C x C 8 linked to Si by a SiC bond; Q "is an anion such as a halide ion, particularly chloride or an organic acid salt (acetate ...); r represents an average statistical value of 2 to 20 and in particular 2 to 8; s represents a statistical average value from 20 to 200 and in particular from 20 to 50.

Such aminated silicones are more particularly described in US Pat. No. 4,185,087.

A silicone that enters in this class is the silicone marketed by the company Unión Carbide under the name "Ucar Silicone ALE 56". (d) the quaternary ammonium silicones of the formula: 2X r -.- R in which: R7, identical or different, represent a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical of C ^ C- ^, an alkenino radical of C2-C18 or a cycle comprising from 5 to 6 carbon atoms, for example methyl; Re represents a divalent hydrocarbon radical, particularly an alkylene radical of C-L-C- ^ or a divalent alkyleneoxy radical of C-L-C-, ^, for example of Cx-C8 linked to Si by a SiC bond; R8, identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical of CLC, an alkylene radical of C2-C18, a radical -R6-NHCOR7; X "is an anion such as a halide ion, particularly chloride or an organic acid salt (acetate ...); R represents an average statistical value of 2 to 200 and in particular of 5 to 100.

These silicones are described, for example, in the application EP-A-0530974.

The silicones that fall into this class are the silicones marketed by the company GOLDSCHMIDT under the names ABIL QUAT 3270, ABIL QUAT 3272, ABIL QUAT 3474. (e) the aminated silicones of formula (VII): Re (Vil) NH (C H. NH, wherein: -R1 f R2, R3, and R4, are identical or different, designate a C 1 -C 4 alkyl radical or a phenyl group, -R 5 designates an alkyl radical of C 0, or a hydroxyl group, - n is an integer that varies from 1 to 5, -m is an integer that varies from 1 to 5, and in which x is chosen such that the amine number is between 0.01 and 1 meq / g.

According to the invention, the aminated silicones can be in the form of oil, aqueous, alcoholic or hydroalcoholic solutions, in the form of dispersion or emulsion.

A particularly interesting embodiment is its use in the form of emulsions, in particular in the form of microemulsions or nanoemulsions.

For example, the product sold under the name "Cationic Emulsion DC 929" can be used by Dow Corning, which comprises, in addition to amodimethicone, a cationic surface agent derived from the tallow fatty acids Tallowtrimonium (CTFA), in association with a nonionic surface agent known under the name "Nonoxynol 10".

It is also possible, for example, to use the product marketed under the name "Cationic Emulsion DC 939" by Dow Corning, which also comprises amodimethicone, a cationic surface agent, trimethyl cetyl ammonium chloride in combination with a non-ionic surface agent. the trideceth-12.

Another commercial product which can be used according to the invention is the product marketed under the name "Dow Corning Q2 7224" by Dow Corning, which comprises, in combination, the thymethylsilylamodimethicone of formula (IV), an α-agent. nonionic surface of formula: C8H17-CeH4- (OCH2-CH2) n-0H wherein n = 40 also called octoxynol-40, another non-ionic surface agent of the formula: C12H25- (OCH2-CH2) nOH where n = 6 also isolaureth-6, and glycol. (i) Cationic polymer (s): In the sense of the present invention, the term "cathonic polymer" refers to any polymer that contains cationic groups and / or ionizable groups in cationic groups.

The compositions according to the invention also necessarily comprise a cationic polymer selected from the homopolymers which include units corresponding to the formula (I) or (I ') as the main constituent of the chain: -Cr - (25 formulas in which k and t are equal to 0 or 1, the sum of k + t being equal to 1, R3 denotes a hydrogen atom or a methyl radical, and Rx and R2, independently of each other, designate an alkyl group having from 1 to 22 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has from 1 to 5 carbon atoms, a lower amidoalkyl group (from 1 to 5 carbon atoms) or Rx and R 2 may designate together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholino, and Y is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulphite, sulfate, phosphate.

These polymers are described in particular in the French patent 2,080,759, in its certificate of addition 2,190,406 or in the patents US 3,996,146 and US 3,288,770.

Preferably, R-j_ and R2 denote independently of one another methyl or ethyl and R a hydrogen atom.

The cationic polymers used generally have a weight average molecular weight of between about 5000 and 5.10G, and preferably between about 104 and about 5.105.

Among the polymers defined above, mention may be made more particularly of the homopolymers of dimethyldialammonium chloride such as that marketed under the name "Merquart® 100" by the company Calgon.

Compositions according to the invention include amine silicones defined above with weight contents which may be between 0.05% and 10%, preferably between 0.1% and 5% and even more preferably between 0.2% and 3% , in relation to the total weight of the composition.

According to the invention, the cationic polymer (s) can represent from 0.001% to 10% by weight, preferably from 0.005% to 5% by weight, and even more preferably from 0.01% to 3% by weight, of the total weight of the final composition.

The vehicle, or carrier, of the detergent compositions according to the invention is preferably water or a hydroalcoholic solution of a lower C-8 alcohol such as ethanol, isopropanol or butanol or a mixture of water and alkylene glycol such as propylene glycol and ethers of glycol.

The detergent compositions according to the invention have a final pH generally comprised between 3 and . Preferably, it is comprised between 5.5 and 8. The adjustment of the pH to the desired value can be carried out conventionally by supplying a base (organic or mineral) in the composition, for example ammonia or a (poly) primary, secondary or tertiary amine such as monoethanolamine, diethanolamine, triethanolamine, isopropanolamine or 1,3-propanediamine, or also by supplying an acid, preferably a carboxylic acid such as, for example, citric acid.

The compositions according to the invention may contain, in addition to the previously defined association, viscosity regulating agents such as electrolytes or thickening agents. Mention may be made in particular of sodium chloride, sodium xylene sulfonate, scleroglucans, xanthan gums, fatty acid alkanolamides, alkyl ether carboxylic acid alkanolamides optionally oxyethylenated with up to 5 moles of ethylene oxide such as the product sold under the name "AMINOL A15" by the company CHEM Y, crosslinked polyacrylic acid and crosslinked C 10 -C 30 alkyl acrylic acid / acrylic acid copolymers. These viscosity regulating agents are used in the compositions according to the invention in proportions which can reach up to 10% by weight relative to the total weight of the composition.

The compositions according to the invention can also contain up to 5% pearlescent or opacifying agents well known in the state of the art such as, for example, sodium or magnesium palmitates, sodium or magnesium stearates and hydroxystearates, derivatives fatty chain acylates such as ethylene glycol or polyethylene glycol monostearates or distearates, fatty chain ethers such as distearylether or 1-hexadecyloxy octadecanol.

The compositions according to the invention can optionally also contain other agents which have the effect of improving the cosmetic properties of hair or skin. Mention may be made in this regard of cationic surfactants, anionic or non-ionic or cationic or amphoteric polymers, proteins, protein hydrolysates, ceramides, pseudoceramides, hydroxy acids, vitamins, panthenol, vegetable oils, animals, minerals or synthetics, hydro or liposoluble solar filters.

These compositions may also contain various adjuvants commonly used in cosmetics such as perfumes, preservatives, sequestering agents, foam stabilizers and acidulants or alkanilizers well known in cosmetics.

Of course, the person skilled in the art will take care in choosing this or these possible complementary compounds and / or their amounts in such a way that the advantageous properties intrinsically related to the association (washing base + specific cationic polymer + aminated silicone) according to the invention are not, or substantially, altered by the addition (s) considered.

These compositions may be in the form of more or less thick liquids, creams or gels and they are mainly suitable for washing, for the treatment of keratin materials such as skin or hair.

The compositions according to the invention are preferably used as shampoos for washing and conditioning the hair and are applied in this case to wet hair in effective amounts for washing, this application being followed by rinsing with water.

The compositions according to the invention can also be used as shower gels for washing and conditioning the hair and the skin, in which case they are applied to the skin and wet hair and rinsed after application.

The compositions according to the invention can also be used as make-up removers of keratin materials such as skin, eyelashes, eyebrows.

The subject of the invention is also a process for washing and conditioning keratin materials, such as hair, consisting of applying an effective amount of a composition as defined above to said wet materials, then rinsing with water afterwards. of a possible resting time.

Concrete, but by no means limiting, examples illustrating the invention will be given below.

E-JSMP Q 1 Two shampoo compositions were made, one according to the invention (composition A) and the other comparative one (composition B): (*) DEHYTRON® AB 30 from HENKEL (**): Homopolymer of dimethyl diatyl ammonium chloride marketed under the name MERQUAT® 100 (PM 400,000) by the company CALGON. (***): Amodimethicone commercialized in cationic emulsion with 35% of active material under the name FLUID DC 939 by the company Dow Corning.

Shampooing is carried out by applying approximately 12 g of composition A to previously wetted hair. Shampoo is made and then rinse thoroughly with water.

The procedure is the same as that indicated above with comparative composition B.

A group of experts evaluates the disentangling of wet hair, the disentangling of dried wet hair, the softness and the straightening of dry hair.

All the experts indicate a clear improvement of these properties for the hair treated with composition A according to the invention. gjSMPLQ 2 A shampoo with the following composition was prepared: (*) DEHYTON AB 30 of HENKEL (**) Homopolymer of dimethyl diatyl ammonium chloride marketed under the name MERQUAT® 100 (PM 400,000) by the company CALGON (***) Amodimethicone marketed in cationic emulsion with 35% active material under the name FLUID DC 939 by the company Dow Corning.

It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention.

Having described the invention as above, the content of the following is claimed as property.

Claims (13)

1. A detergent composition characterized in that it comprises, in a cosmetically acceptable medium, (A) a washing base comprising at least one anionic surfactant of the alkylether sulfate type and at least one amphoteric surfactant of the alkylbetaine type of c8 ~ c2o Y (ß) a system A conditioner comprising at least one amino silicone and at least one cationic polymer selected from the homopolymers which include units corresponding to the formulas (I) and / or (I ') as the main constituent of the chain: formulas in which k and t are equal to 0 or 1, the sum of k + t being equal to 1; R3 designates a hydrogen atom or a methyl radical; R 1 and R 2, independently of one another, designate an alkyl group having from 1 to 22 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has from 1 to 5 carbon atoms, a lower amidoalkyl group (1) to 5 carbon atoms) or R1 and R2 may designate, together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; And "it is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate.

2. The composition according to the preceding claim, characterized in that R and R, independently of one another, designate methyl or ethyl and R 3 designates a hydrogen atom.

3. The composition according to any one of the preceding claims, characterized in that said cationic polymer is chosen from the homopolymers of dimethyldiallylammonium chloride.

4. The composition according to any one of the preceding claims, characterized in that the anionic surfactants of the alkylether sulfate type are the salts of the alkyl ether sulphates, alkylamidoeter sulfates, alkylarylether sulfates; alkylether sulfosuccinates, the alkyl or acyl radical of all these various compounds preferably comprising from 8 to 24 carbon atoms, and the aryl radical which preferably designates a phenyl or benzyl group.

-. The composition according to any one of the preceding claims, characterized in that the anionic surfactant of the alkylether sulfate type is chosen from the salts of C10-C14 alkyl ether sulphates and more particularly those of C12-C14.

6. The composition according to any one of the preceding claims, characterized in that the amphoteric surfactant is of the alkylbetaine type 10 of C10-C14.

7. The composition according to any one of the preceding claims, characterized in that the aminated silicone is chosen from: (a) the polysiloxanes referred to in the CTFA dictionary "amodimethicone" and corresponding to the formula: O- • H pv. - Y 25 - * fc. - in which x 'e and' are integers that depend on the molecular weight, generally such that the indicated weight average molecular weight is between approximately 5 000 and 500 000; (b) the aminated silicones that respond to the formula: R'aG3-a-Si (° SiG2) n- (OSiGbR'2-b) - ° -SiG3-a-R'a (TII > wherein: 10 G is a hydrogen atom, or a phenyl group, OH, or C 1 -C 8 alkyl, for example methyl, a designates the number 0 or an integer from 1 to 3, in particular 0, b designates 0 or 1, and in particular 1, 15 m and n are numbers such that the sum (n + m) can vary particularly from 1 to 2 000 and in particular from 50 to 150, n can designate a number from 0 to 1 999 and particularly from 42 to 149 and being able to designate a number from 1 to 2 000, and particularly from 1 to 10; R 'is a monovalent radical of formula -CqH2qL in which q is a number from 2 to 8 and L is an optionally quaternized amino group selected from the groups: 25-NR-CH- - - -fR "); - (R"): -N '' (R "-NH- (R ', -: H .-' R" -N'R ") - r .- rí-N? R "H: wherein R "can designate hydrogen, phenyl, benzyl, or a monovalent saturated hydrocarbon radical, for example an alkyl radical having 1 to 20 carbon atoms and A" represents a halogenide ion such as for example fluoride, chloride, bromide or iodide. (c) the aminated silicones corresponding to the formula: wherein: R5 represents a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical of C ^ C ^, or alkylene of C2-C18, for example methyl, -Re represents a divalent hydrocarbon radical , particularly a C1-C18 alkylene radical or a C20-C18 divalent alkyleneoxy radical, for example from Cx-C8 linked to Si by a SiC bond; Q is an anion such as a halide ion, particularly chloride or an organic acid salt (acetate ...); r represents an average statistical value from 2 to 20 and in particular from 2 to 8; s represents an average statistical value of 20 to 200 and in particular of 20 to 50. (d) the quaternary aminium silicones of the formula: 2X " R_ R wherein: R7, identical or different, represents a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical of Cx-C- ^ g, an alkylene radical of C2-C18 or a ring that comprises 5 or 6 carbon atoms, for example methyl; R6 represents a divalent hydrocarbon radical, particularly an alkylene radical of Cx-C18 or a divalent alkyleneoxy radical of C-L-Cg linked to Si by a SiC bond; R8, identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical of CLC, an alkylene radical of C2-C18, a radical -Re-NHCOR7; X is an anion such as a halide anion, particularly chloride or an organic acid salt (acetate ...); R represents an average statistical value of 2 to 200 and in particular of 5 to 100; (e) the aminated silicones of formula (VI): (C_ i,. NH. wherein: - R x, R 2, R 3 and R 4, identical or different, designate a C 1 -C 4 alkyl radical or a phenyl group, - R 5 denotes a C 1 -C 4 alkyl radical, or a hydroxyl group, - n is a integer that varies from 1 to 5, - m is an integer that varies from 1 to 5, and in which x is chosen such that the amine number is between 0.01 and 1 meq / g.

8. A composition according to any one of the preceding claims, characterized in that said one or more anionic surfactants are present at a ratio of 1 to 50% by weight, preferably 5 to 20% by weight, based on total weight of the composition.

9. The composition according to any one of the preceding claims, characterized in that said or said amphoteric surfactants are present at a ratio of 1 to 50% by weight, preferably 1 to 20% by weight, based on the total weight of the agent. the composition.

10. The composition according to any one of the preceding claims, characterized in that said cationic polymer is present with a weight content comprised between 0.001% and 10% relative to the total weight of the composition, preferably between 0.005% and 5% by weight and in particular between 0.01% and 3%.

11. The composition according to any one of the preceding claims, characterized in that said aminated silicone is present with a weight content comprised between 0.05 and 10% with respect to the total weight of the composition, preferably between 0.1 and 5% by weight.

12. A use of a composition as defined in any one of the preceding claims for cleaning and / or conditioning and / or de-makeup of keratin materials.

13. A method of washing and conditioning keratin materials, such as hair, consisting of applying an effective amount of a composition as defined in any one of claims 1 to 11 to said wet materials, followed by a rinsing with water after an eventual resting time.