MXPA06004871A - Stabilized body care products, household products, textiles and fabrics - Google Patents

Abstract

Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain hindered nitroxyl, hydroxylamine and hydroxylamine salt compounds and selected organic UV filters. The stabilized products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.

Description

STABILIZED PRODUCTS FOR THE CARE OF THE BODY, FOR THE HOME, TEXTILES AND FABRICS DESCRIPTION Field of the invention The present invention relates to the use of selected compounds of nitroxyl, hydroxylamine and hindered hydroxylamine salt and organic UV filters selected for the protection of body care products, personal care products, household products, of products for the care of fabrics, of institutional and industrial products, of textiles and fabrics against the damaging effects of light, heat and oxygen. Since consumers today can choose from a wide variety of products for home and personal care products, producers need to clearly communicate how their brands are unique.

Sophisticated products that contain fragrances and new assets in many colorful formulations, shown in transparent and translucent packaging are now very common. It is mandatory for commercial success that the pleasing appearance, the effectiveness of the product and the fresh smell of a consumer product last throughout its entire life cycle even when it is significantly exposed to UV light. This exposure can lead to decomposition processes and strong color degradation destroying the appearance of the product, the active ingredients and the fragrance. Various clear product stabilization techniques packaged by means of UV light absorption are known and commonly used. For example broadband UV light stabilizers of the benzotriazole class improve product stability and shelf life due to their very good UV-A and UV-B absorption properties, compared with other absorbers such as benzophenones which They mainly absorb UV-B light. However, by only absorbing UV light, not all potential degradation pathways are blocked. Surprisingly it was found that effective protection can be achieved with specific compounds selected from nitroxyl compounds, hydroxylamine and hindered hydroxylamine salt and specific organic UV absorbers.

BACKGROUND WO 01/07550 describes the treatment of fabric with hindered amine stabilizers. The U.S. patent 6,254,724 describes the stabilization of pulp and paper with hindered amine-based compounds.

Detailed description The present invention pertains to a stabilized composition comprising: (a) a body care product, household product, textile or fabric and (b) an effective stabilizing amount of at least one compound selected to consist of the group (i) hindered nitroxyl compounds of the formula (I) (ii) hydroxylamine compounds of the formula (II) HO-N and A ^ -Q, a_ (iii) compounds of the hindered hydroxylamine salt of the formula (III) in which Gi and G are independently alkyl of 1 to 4 carbon atoms or are pentamethylene together, Zi and Z2 are each methyl, or Zi and Z2 together form a linking portion which can be further substituted by a carboxy group or urethane, ester, ether, hydroxy, oxo, cyanohydrin, amide or amino, X is an inorganic or organic anion, such as phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, format, acetate, benzoate, citrate, oxalate, tartrate, acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, tiglato, ascorbate, polymethacrylate, a nitrilotriacetic acid carboxylate, hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid or acid diethylenetriaminpentaacetic acid, a diethylenetriaminepentamethylenephosphonate, an alkylsulfonate or an arylsulfonate, and where the total charge of the cations h equals the total charge of the nions j: and (c) an organic UV filter selected from (cl) dibenzoylmethane derivatives; (c2) cinnamic acid esters; (c3) camphor derivatives; and (c4) trianilino-s-triazine derivatives. For example, X is chloride, bisulfite, bisulfate, sulfate, phosphate, nitrate, ascorbate, acetate, citrate or carboxylate of ethylenediaminetetraacetic acid or diethylenetriaminpentaacetic acid; for example X is bisulfate or citrate. The nitroxyl, hydroxylamine and hindered hydroxylamine salt compounds of component (b) are, for example, of the formulas A to EE and A * to EE * ; (Q) (V *); (w) (EE *) in which E is oxyl or hydroxyl, R is hydrogen or methyl, in formula A and A *, n is 1 or 2, when n is 1, Ri is hydrogen, alkyl of 1 to 18 carbon atoms, alkenyl of 2-18 carbon atoms, propargyl, glycidyl, alkyl of 2 to 50 carbon atoms interrupted by one to twenty oxygen atoms, alkyl substituted by one to ten hydroxyl groups or interrupted by oxygen atoms and substituted by the hydroxyl groups, or Ri is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by -COOZ wherein Z is hydrogen, alkyl of 1 to 4 carbon atoms or phenyl, or where Z is the substituted alkyl by - (COO ~) nMn + where n is 1-3 and M is a metal ion of the 1st, 2nd or 3rd group of the periodic table or is Zn, Cu, Ni or Co, or M is a group Nn + (R2) where R2 is alkyl of 1 to 8 carbon atoms or benzyl, when n is 2, Ri is alkylene of 1 to 12 carbon atoms, alkenylene of 4 to 12 carbon atoms, xylylene or alkylene of 1 to 50 atoms of carbon interrupted by one to twenty oxygen atoms, substituted by one to ten hydroxyl groups or interrupted by oxygen atoms and replaced by hydroxyl groups, in formula B and B *, m is from 1 to 4, when m is 1, R2 is alkyl of 1 to 18 carbon atoms, alkyl of 3 to 18 carbon atoms interrupted by -COO-, or R2 is -CH2 (OCH2CH2) nOCH3 wherein n is 1 to 12, or R2 is cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon atoms, or the aryl substituted by one to four alkyl groups of 1 to 4 carbon atoms, or R2 is -NHR3 where R3 is alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon atoms, or the aryl substituted by one to four alkyl of 1 to 4 carbon atoms arbono, or R2 is -N (R3) 2 where R3 is as defined above, when m is 2, R2 is alkylene of 1 to 12 carbon atoms, alkenylene of 4 to 12 carbon atoms, xylylene, alkylene of 2 to 12 carbon atoms interrupted by -COO-, or R2 is -CH2 (OCH2CH2) nOCH2- where n is 1 to 12, or R2 is cycloalkylene of 5 to 12 carbon atoms, aralkylene of 7 to 15 carbon atoms or arylene from 6 to 12 carbon atoms, or R2 is -NHRNH- where R is alkylene of 2 to 18 carbon atoms, cycloalkylene of 5 to 12 carbon atoms, aralkylene of 8 to 15 carbon atoms or arylene of 6 to 12 atoms carbon, or R2 is -N (R3) RN (R3) - where R3 and R are as defined above, or R2 is -CO- or -NH-CO-NH-, when m is 3, R is alkantriyl 3 to 8 carbon atoms or benzentriil, or when m is 4, R 2 is the alkyntetranyl of 5 to 8 carbon atoms or bencentetrail, in the formula C and C *, Rio is hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 atoms of carbon, aralkyl of 7 to 15 carbon atoms, alkanoyl of 2 to 18 carbon atoms, alkenoyl of 3 to 5 carbon atoms or benzoyl, x is 1 or 2, when x is 1, Rii is hydrogen, alkyl of 1 to 18 carbon atoms, alkenyl of 2 to 18 carbon atoms, propargyl, glycidyl, alkyl of 2 to 50 carbon atoms interrupted by one to twenty oxygen atoms, the alkyl substituted by one to ten hydroxyl groups or interrupted by the atoms of oxygen and substituted by the hydroxyl groups, or Rn is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by -COOZ wherein Z is hydrogen, alkyl of 1 to 4 carbon atoms or phenyl, or where Z is the alkyl substituted by - (COO ~) nMn + where n is 1-3 and M is a metal ion of the 1st, 2nd or 3rd group of the periodic table or is Zn, Cu, Ni or Co or M is a group Nn + (R2 ) where R is hydrogen, alkyl of 1 to 8 carbon atoms or benzyl, or when x is 2, Rii is alkylene of 1 to 12 carbons no, alkenylene of 4 to 12 carbon atoms, xylylene or alkylene of 1 to 50 carbon atoms interrupted by one to twenty oxygen atoms, substituted by one to ten hydroxyl groups or interrupted by oxygen atoms and replaced by hydroxyl groups, in the formula D and D *, Rio is as defined above, and is 1 to 4, and R_ is defined as R2 above in the formula E and E *, k is 1 or 2, when it is 1, R-20 and R21 are independently alkyl of 1 to 12 carbon atoms, alkenyl of 2 to 12 carbon atoms or aralkyl of 7 to 15 carbon atoms, or R20 is also hydrogen, or R2o and R2? together they are alkylene of 2 to 8 carbon atoms or the alkylene substituted by hydroxyl, or are acyloxy-alkylene of 4 to 22 carbon atoms, or when k is 2, R20 and R-21 are together (-CH2) 2C (CH2 -) 2, in formula F and F *, R30 is hydrogen, alkyl of 1 to 18 carbon atoms, benzyl, glycidyl or alkoxyalkyl of 2 to 6 carbon atoms, g is 1 or 2, when g is 1, R_? is defined as Ri above when n is 1, when g is 2, R3i is defined as Ri above when n is 2, in the formula G and G *, Qi is -NR41- or -O-, Ei is alkylene of 1 to 3 carbon atoms or Ei is -CH2-CH (R4) -O- where R42 is hydrogen, methyl or phenyl or Ei is - (CH2) 3-NH- or Ei is a direct bond, R40 is hydrogen or alkyl of 1 to 18 carbon atoms, R_? is hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms, or R4? is -CH2-CH (R42) -) -OH where R42 is as defined above, in the formula H and H *, p is 1 or 2, T4 is as defined for Rn when x is 1 or 2, M e And they are independently methylene or carbonyl, for example M is methylene and Y is carbonyl, in the formula lei *, this formula denotes a repeating structural unit of a polymer where i is ethylene or 1, 2-propylene or is the unit repeating structure derived from an alpha-olefin copolymer with an acrylate or an alkyl methacrylate, and where q is 2 to 100, Qi is -N (R4?) - or -0- where R4? is as defined above, in the formula J and J *, r is 1 or 2, T7 is as defined for Ri when n is 1 or 2 in the formula A, for example T7 is octamethylene when r is 2, in the formula L and L *, u is 1 or 2, T13 is as defined for R_ when n is 1 or 2 in formula A, provided that T_3 'is not hydrogen when u is 1, in formula M and M *, Ei and E, being different, each are -CO- or -N (E5) ~ where E5 is hydrogen, alkyl of 1 to 12 carbon atoms or alkoxycarbonylalkyl of 4 to 22 carbon atoms, for example Ei is - CO- and E2 is -N (E5) -, E3 is hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl, naphthyl or phenyl substituted by chloro or by alkyl of 1 to 4 carbon atoms, or phenylalkyl from 7 to 12 carbon atoms, or the phenylalkyl substituted by alkyl of 1 to 4 carbon atoms, E4 is hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl or phenylalkyl of 7 to 12 carbon atoms, or E3 and E4 jun Examples are polymethylene of 4 to 17 carbon atoms or polymethylene substituted by one to four alkyls of 1 to 4 carbon atoms, for example methyl, in the formula N, Ri is as defined for Ri in formula A when n is 1, G3 is a direct bond, alkylene of 1 to 12 carbon atoms, phenylene or -NH-Gi-NH- where Gi is alkylene of 1 to 12 carbon atoms, in formula 0 and 0 *, Rio is as defined for Rio in formula C, in the formula P and P *, E6 is a tetravalent aliphatic or aromatic radical, for example neopentantenyl or bencentetrail, in the formula T and T *, R5? is hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, or aryl of 6 to 10 carbon atoms, R52 is hydrogen or alkyl of 1 to 18 carbon atoms, or R51 and R52 together are alkylene of 4 to 8 carbon atoms, f is 1 or 2, when f is 1, R50 is as defined for Rn in formula C when x is 1, or R50 is - (CH2) zCOORs4 where Z is 1 to 4 and R54 is hydrogen or alkyl of 1 to 18 carbon atoms, or R5 is a metal ion of the Io, 2nd or 3rd group of the periodic table or of a group - N (Rss) where R55 is hydrogen, alkyl of 1 to 12 carbon atoms or benzyl, when f is 2, R50 is as defined for Rn in formula C when x is 2, in formula U and U *, R53, 54, R55 and R56 are independently alkyl of 1 to 4 carbon atoms or are in pentamethylene set. in the formula V and V *, R57 / R58, R59 and R-60 are independently alkyl of 1 to 4 carbon atoms or are pentamethylene together. in the formula W and W *, R-61, Rd2 R-63 and Rβ are independently alkyl of 1 to 4 carbon atoms or are pentamethylene together, R65 is alkyl of 1 to 5 carbon atoms, M is hydrogen or oxygen , where in formulas X to CC and X * to CC * n is 2 to 3, Gi is hydrogen, methyl, ethyl, butyl or benzyl, m is 1 to 4, x is 1 to 4, when x is 1, Ri and R are independently alkyl of 1 to 18 carbon atoms, alkyl interrupted by one to five oxygen atoms, alkyl substituted by 1 to 5 hydroxyl groups or alkyl interrupted by oxygen atoms and substituted by hydroxyl groups; cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms or the aryl substituted by one to three alkyl of 1 to 8 carbon atoms or R_ is also hydrogen, or Ri and R2 are together tetramethylene, pentamethylene, hexamethylene or 3-oxapentamethylene, when x is 2, Ri is hydrogen, alkyl of 1 to 8 carbon atoms, the alkyl interrupted by one or two oxygen atoms, the alkyl substituted by a hydroxyl group , or the alkyl interrupted by one or two oxygen atoms and substituted by a hydroxyl group, R2 is alkylene of 2 to 18 carbon atoms, the alkylene interrupted by one to five oxygen atoms, the alkylene substituted by 1 to 5 hydroxyl groups or the alkylene interrupted by the oxygen atoms and substituted by the hydroxyl groups; o-, m- or p-phenylene or the phenylene substituted by one or two alkyls of 1 to 4 carbon atoms, or R2 is - (CH2) kO [(CH2) kO] h (CH2) - where k is 2 a 4 and h is 1 to 40, or R? And R2 together with the two N atoms to which they are attached are in-1,4-diyl pipers, when x is 3, Ri is hydrogen R 2 is alkylene of 4 to 8 carbon atoms interrupted by a nitrogen atom, when x is 4, Ri is hydrogen, R is alkylene of 6 to 12 carbon atoms interrupted by two nitrogen atoms, R3 is hydrogen, alkyl of 1 to 8 carbon atoms, alkyl interrupted by one or two oxygen atoms, alkyl substituted by a hydroxyl group, or interrupted by one or two oxygen atoms and substituted by a hydroxyl group, P is 2 or 3, and Q is an alkali metal, ammonium or N + (G?) 4, in the formula DD and DD * m is 2 or 3, when m is 2, G is - (CH2CHR-0) rCH2CHR-, where r is 0 to 3, and R is hydrogen or methyl, and when m is 3, G is glyceryl, in formula EE and EE * G2 is -CN, -CONH2 or -COOG3 where G3 is hydrogen, alkyl of 1 to 18 carbon atoms or phenyl, X is an inorganic or organic anion , such as phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartarate, acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate , gluconate, malate, mandelate, tiglato, ascorbate, polyethacrylate, a nitrilotriacetic acid carboxylate, hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid or diethylenetriaminepentaacetic acid, a diethylenetriaminepentamethylenephosphonate, an alkylsulfonate or an arylsulfonate, and where the total charge of the cations is equal to the total charge of the anions. For example, the compounds of component (b) are those of formulas A, A *, B, B *, C, C *, D, D *, Q, Q *, R, R *, S, S *, X, X *, Y, Y *, Z and Z *, R is hydrogen, in the formula A and A * n is 1 or 2, when n is 1, Ri is hydrogen, alkyl of 1 to 6 carbon atoms, alkenyl of 2-6 carbon atoms, propargyl, glycidyl, alkyl of 2 to 20 carbon atoms interrupted by one to ten oxygen atoms, the alkyl substituted by one to five hydroxyl groups or interrupted by the oxygen atoms and substituted by the hydroxyl groups, or Ri is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by -COOZ where Z is hydrogen or alkyl of 1 to 4 carbon atoms, when n is 2, Ri is alkylene of 1 to 8 atoms carbon, alkenylene of 4 to 8 carbon atoms, alkylene of 1 to 20 carbon atoms interrupted by one to ten oxygen atoms, substituted by one to five hydroxyl groups or interrupted by oxygen atoms and sub substituted by the hydroxyl groups, in formula B and B * m is 1 or 2 when m is 1, R2 is alkyl of 1 to 4 carbon atoms or R2 is CH2 (OCH2CH2) nOCH3 where n is 1 to 12, or R2 is phenyl, or the phenyl substituted by one to three methyl groups, R 2 is -NHR 3 where R 3 is alkyl of 1 to 4 carbon atoms or phenyl or the phenyl substituted by one or two methyl groups, when m is 2, R 2 is alkylene from 1 to 8 carbon atoms, alkenylene of 4 to 8 carbon atoms, or R2 is -CH2 (OCH_CH2) nOCH2- where n is from 1 to 12, R2 is NHRNH where R4 is from 2 to 6 carbon atoms, aralkylene of 8 to 15 carbon atoms or arylene of 6 to 12 carbon atoms, R2 is -CO- or - NHCONH, in formula C and C *, Rio is hydrogen or, alkanoyl of 1 to 3 carbon atoms, x is 1 or 2, when x is 1, Rn is hydrogen, alkyl of 1 to 6 carbon atoms or glycidyl, Rii is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by COOZ where Z is hydrogen or alkyl of 1 to 4 á carbon atoms, when x is 2, Rn is alkylene of 1 to 6 carbon atoms, in formula D and D *, Rio is hydrogen, and is 1 or 2, R? 2 is defined as R2 above, in the formula Y, Y *, Z and Z *, x is 1 or 2, when x is 1, Ri and R are independently alkyl of 1 to 4 carbon atoms, or Ri and R2 are together tetramethylene, or pentamethylene, R2 is hydrogen or alkyl of 1 to 4 carbon atoms, the alkyl group substituted by a hydroxyl group, when x is 2, Ri is hydrogen, alkyl of 1 to 4 carbon atoms, alkyl substituted by a hydroxyl group, R2 is alkylene of 2 to 6 carbon atoms, R3 is as defined above. For example, the compounds of component (b) are those of formulas A, A *, B, B *, C, C *, D, D *, Q, Q *, R and R *, R is hydrogen, in formula A and A *, h is 1, Ri is hydrogen, alkyl of 1 to 4 carbon atoms, glycidyl, alkyl of 2 to 4 carbon atoms interrupted by one or two oxygen atoms, alkyl substituted by one or two hydroxyl groups or interrupted by oxygen atoms and replaced by hydroxyl groupsor Ri is alkyl of 1 to 4 carbon atoms substituted by -COOZ where Z is hydrogen or alkyl of 1 to 4 carbon atoms, in formula B and B *, m is 1 or 2, R2 is alkyl of 1 to 4 carbon atoms or R2 is CH2 (OCH2CH2) nOCH3 where n is 1 to 4, when m is 2, R2 is alkylene of 1 to 8 carbon atoms, in formula C and C *, Rio is hydrogen or alkanoyl of 1 or 2 carbon atoms, x is 1 or 2, when x is 1, Rn is hydrogen, alkyl of 1 to 4 carbon atoms or glycidyl, Rii is alkyl of 1 to 4 carbon atoms substituted by COOZ where Z is hydrogen or alkyl of 1 to 4 carbon atoms, when x is 2, Rn is alkylene of 1 to 6 carbon atoms, in formula D and D *, Rio is hydrogen, and is 1 or 2, R? 2 is defined as R2 above. For example, the nitroxyl, hydroxylamine and hindered hydroxylamine salt compounds of component (b) are selected from bis (l-oxyl-2, 2-6-6-tetramethylpiperidin-4-yl sebacate); bis (1-bis (l-hydroxy-2, 2-6-6-tetramethylpiperidin-4-yl) -2,6-6-tetramethylpiperidin-4-yl sebacate); l-hydroxy-2, 2-6-6-tetramethyl-4-acetoxypiperidinium citrate; l-oxyl-2, 2,6,6-tetramethyl-4-acetamidopiperidine; 1-hydroxy-2, 2, 6, 6-tetramethyl-4-acetamidopiperidine; 1-hydroxy-2, 2-6-6-tetramethyl-4-acetamidopiperidinium bisulfate; l-oxyl-2, 2,6,6-tetramethyl-4-oxo-piperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxo-piperidine; l-hydroxy-2, 2, 6,6-tetramethyl-4-oxo-piperidinium acetate; l-oxyl-2,2,6,6-tetramethyl-4-methoxy-piperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-methoxy-piperidine; l-hydroxyl-2, 2,6,6,6-tetramethyl-4-methoxy-piperidinium acetate; l-oxyl-2, 2,6,6,6-tetramethyl-4-acetoxypiperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetoxypiperidine; l-oxyl-2,2,6,6-tetramethyl-4-propoxy-piperidine; l-hydroxy-2, 2-6-6-tetramethyl-4-propoxy-piperidinium acetate; l-hydroxy-2, 2,6,6-tetramethyl-4-propoxy-piperidine; l-oxyl-2, 2,6,6,6-tetramethyl-4- (2-hydroxy-4-oxapentoxy) piperidine; l-hydroxy-2, 2, 6,6-tetramethyl-4- (2-hydroxy-4-oxapentoxy) piperidinium acetate; 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium chloride; 1-hydroxy-2,2-6-6-tetramethyl-4-hydroxypiperidinium acetate; 1-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium bisulfate; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxy? -peridinium citrate; bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium citrate); tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium citrate); tetra (1-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium) ethylenediaminetetraacetate; tetra (l-hydroxy-2, 2,6,6-tetramethyl-4-acetamidopiperidinium) ethylenediaminetetraacetate; tetra (l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxopiperidinium) ethylenediaminetetraacetate; penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6-tetramethyl-4-hydroxypiperidinium); penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium); penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxopiperidinium); tri (l-hydroxy-2, 2,6,6-tetramethyl-4-hydroxypiperidinium nitrilotriacetate); tri (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium nitrilotriacetate); tri (1-hydroxy-2, 2, 6,6-tetramethyl-4-oxopiperidinium nitrilotriacetate); penta diethylenetriaminepentamethylenephosphonate (1-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium); Penta diethylenetriaminepentamethylene phosphonate (1-hydroxy-2,2,6,6-tetramethyl-4-acetamidopiperidinium); and penta diethylenetriaminepentamethylenephosphonate (1-hydroxy-2,2,6,6-tetramethyl-4-oxopiperidinium). For example, the hindered nitroxyl, hydroxylamine and hydroxylamine salt compounds of component (b) are selected from 1-oxyl-2, 2, 6,6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium chloride; 1-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium acetate; 1-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium bisulfate; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium citrate; bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium citrate); tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium citrate); tetra (1-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium) ethylenediaminetetraacetate; tetra (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium) ethylenediaminetetraacetate; tetra (l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxopiperidinium) ethylenediaminetetraacetate; pent diethylenetriaminpentaacetate (l-hydroxy-2, 2,6, 6-tetramethyl-4-hydroxypiperidinium); penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium); and penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6-tetramethyl-4-oxopiperidinium). For example, the compounds of component (b) are selected from l-hydroxy-2-, 2-6-6-tetramethyl-4-hydroxypiperidinium citrate; bis (l-hydroxy-2, 2,6,6-tetramethyl-4-hydroxypiperidinium citrate); tris (l-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium citrate); L-hydroxy-2,2-6-6-tetramethyl-4-hydroxypiperidinium dTPA; DTPA of bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); DTPA of tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); DTPA tetrakis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); DTPA of pentakisd-hydroxy-2, 2,6,6-tetramethyl-4-hydroxypiperidinium); L-hydroxy-2,2-6-6-tetramethyl-4-hydroxypiperidinium EDTA; EDTA of bis (l-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium); EDTA of tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); EDTA of tetrakis (l-hydroxy-2, 2,6,6-tetramethyl-4-hydroxypiperidinium); 1-hydroxy-2,2,6,6-tetramethyl-4-oxo-piperidinium citrate; bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxo-piperidinium citrate); tris (l-hydroxy-2,2,6,6-tetramethyl-4-oxo-piperidinium citrate); DTPA of 1-hydroxy-2, 2, 6,6-tetramethyl-4-oxo-piperidinium; DTPA of bis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-oxo-piperidinium); DTPA of tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxo-piperidinium); DTPA tetrakis (l-hydroxy-2, 2, 6, 6-tetramethyl-4-oxo-piperidinium); DTPA of pentakis (l-hydroxy-2, 2, 6, 6-tetramethyl-4-oxo-piperidinium); EDTA of l-hydroxy-2, 2, 6, 6-tetramethyl-4-oxo-piperidinium; EDTA of bis (1-hydroxy-2,2,6,6-tetramethyl-4-oxo-piperidinium); EDTA of tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxo-piperidinium); EDTA of tetrakis (l-hydroxy-2, 2,6,6-tetramethyl-4-oxo-piperidinium); l-hydroxy-2, 2-6-6-tetramethyl-4-acetamidopiperidinium citrate; bis (l-hydroxy-2,2,6,6-tetramethyl-4-acetamidopiperidinium citrate); tris (l-hydroxy-2, 2,6,6-6-tetramethyl-4-acetamidopiperidinium citrate); L-Hydroxy-2,2-6-6-tetramethyl-4-acetamidopiperidinium DTPA; DTPA of bis (l-hydroxy-2, 2,6,6-tetramethyl-4-acetamidopiperidinium); Tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium) DTPA; DTPA tetrakis (1-hydroxy-2,2,6,6-tetramethyl-4-acetamidopiperidinium); Pentakis DTPA (l-hydroxy-2, 2,6,6-tetramethyl-4-acetamidopiperidinium); EDTA of l-hydroxy-2, 2-6-6-tetramethyl-4-acetamidopiperidinium; EDTA of bis (1-hydroxy-2,2,6,6-tetramethyl-4-acetamidopiperidinium); EDTA of tris (l-hydroxy-2, 2,6,6-6-tetramethyl-4-acetamidopiperidinium); Tetrakis EDTA (l-hydroxy-2, 2,6,6-tetramethyl-4-hydroxypiperidinium); l-hydroxy-2, 2-6-6-tetramethyl-4-acetoxypiperidinium citrate; bis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-acetoxypiperidinium citrate); tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-acetoxipiperidinium citrate); DTPA of l-hydroxy-2, 2-6-6-tetramethyl-4-acetoxipiperidinium; DTPA of bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetoxipiperidinium); Tris (l-hydroxy-2,6,6,6-tetramethyl-4-acetoxypiperidinium) DTPA; DTPA tetrakis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-acetoxipiperidinium); DTPA of pentakis (l-hydroxy-2, 2,6,6-tetramethyl-4-acetoxipiperidinium); EDTA of l-hydroxy-2, 2-6-6-tetramethyl-4-acetoxypiperidinium; EDTA of bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetoxipiperidinium); EDTA of tris (1-hydroxy-2,2,6,6-tetramethyl-4-acetoxipiperidinium) and tetrakis EDTA (l-hydroxy-2, 2,6,6-tetramethyl-4-acetoxipiperidinium). The counterions mentioned above are ethylenediaminetetraacetic acid (EDTA), diethylenetriaminpentaacetic acid (DTPA), hydroxyethylenediaminetriacetic acid (HEDTA), nitrilotriacetic acid (NTA) or diethylenetriaminepentamethylenephosphonic acid (DTPMPA). The organic absorbent UV component (cl) is preferably selected from butyl methoxydibenzoylmethane, ethylhexyl methoxydibenzoylmethane and isopropyl dibenzoylmethane. Component (cl) is preferably selected from 4-tert-butyl-4'-methoxydibenzoylmethane and 4-ethylhexyl-4'-methoxydibenzoylmethane. More preferred is l- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propan-l, 3-dione. Component (c2) is preferably selected from octylmethoxycinnamate (2-ethylhexyl ester of 4-methoxycinnamic acid), diethanolamine methoxycinnamate (diethanolamine salt of 4-methoxycinnamic acid), isoamyl p-methoxycinnamate (2-isoamyl ester of 4-methoxycinnamic acid). ethoxycinnamic), 2,5-diisopropylmethyl cinnamate and an amido derivative of cinnamic acid, and preferably octyl methoxycinnamate. Component (c3) is preferably selected from 4-methyl-benzylidene camphor (3- (4'-methyl) benzylidene-boron-2-one), 3-benzylidene camphor (3-benzylidene-boronano-2-one), polyacrylamidomethylbenzylidene camphor. { N- [2 (and 4) -2-oxiborn-3-ylidene-methyl) benzyl acrylamide polymer]} , trimonium-benzylidene camphor sulfate [3- (4'-trimethylammonium) -benzylidene-boron-2-one methylsulfate], 3,3'- (1,4-phenylenedimethine) bis (7, terephthalidene) dialkanforsulfonic acid 7-dimethyl-2-oxo-bicyclo [2.2.1] heptane-1-methanesulfonic acid.) Or its salts, and benzylidene camphor-sulfonic acid [3- (4 '-sulfo) benzylidenbornan-2-one] or its salts and preferably of 4-methyl-benzylidene camphor Component (c4) is preferably selected from diethylhexylbutamido triazone and ethylhexyl triazone Preferably ethylhexyl triazone is used The organic UV filters according to component (c) are can be used in admixture with other commercially available UV filters.The convenient UV absorbers that can be used are listed in the following table: Table 1: Additional UV absorbers derived from p-aminobenzoic acid, for example 2-ethylhexyl ester of 4-dimethylaminobenzoic acid derivatives of salicylic acid, for example 2-ethylhexyl ester of salicylic acid benzophenone derivatives, for example 2-hydroxy-4 -methoxybenzophenone and its derivative 5-sulfonic acid diphenylacrylates, for example 2-cyano-3, 3-diphenylacrylate, 2-ethylhexyl and 3- (benzofuranyl) 2-cyanoacrylate esters of 3-imidazol-4-yl acrylic derivatives of benzofuran , especially derivatives of 2- (p-aminophenyl) benzofuran, described in EP-A-582 189, US-A-5 338 539, US-A-5 518 713 and EP-A-613 893; polymeric UV absorbers, for example the benzylidene malonate derivatives described in EP-A-709 080 hydroxyphenyltriazine compounds, for example 2- (4'-methoxyphenyl) -4,6-bis (2'-hydroxy-4 '- n-octyloxyphenyl) -1,3,5- Table 1: Additional triazine UV absorbers; 2, 4-bis. { [4- (3- (2-propyloxy) -2-hydroxy-propyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine; 2, 4- bis. { [4- (Tris (trimethylsilyloxy-silylpropyloxy) -2-hydroxy] -phenyl] -6- (4-methoxyphenyl) -1,3,5-triazine; 2,4-bis { [4- (2"-methylpropenyloxy) -2-hydroxy] -phenyl.} .6- (4-methoxyphenyl) -1,3,5-triazine; 2,4-bis { [4- (1 ', 1', 1 ', 3', 5 ', 5', 5 '-heptamethyltrisilyl-2"-methyl-propyloxy) -2-hydroxy] -phenyl.}. -6- (4-methoxyphenyl) -1,3,5-triazine compounds of benzotriazole, for example 2, 2'-methylene-bis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol 2-phenylbenzimidazole-5-sulfonic acid and its methyl o-aminobenzoate salts Preferably mixtures of dibenzoylmethane derivatives (cl component) with diphenylacrylates are used; - dibenzoylmethane derivatives (cl component) with cinnamic acid esters (component c2). The present compositions may further comprise other traditional additives, for example antioxidants. Accordingly, the present invention also pertains to a stabilized composition comprising: (a) body care products, household products, institutional and industrial products, textile or fabric, (b) an effective stabilizing amount of at least a compound selected from the group consisting of: (i) hindered nitroxyl compounds of the formula (I), (ii) hindered hydroxylamine compounds of the formula (II) and (iii) hindered hydroxylamine salt compounds of the formula ( III), (c) an organic UV filter selected from (cl) dibenzoylmethane derivatives; (c2) cinnamic acid esters; (c3) camphor derivatives; and (c4) trianilino-s-triazine derivatives; and (d) at least one compound selected from the group consisting of antioxidants, tocopherol, tocopherol acetate, hindered amine light stabilizers, complexing agents, optical brighteners, surfactants and polyorganosiloxanes. Additional suitable antioxidants are selected for example from hindered phenolic and benzofuranone stabilizers.

Suitable antioxidants are selected, for example, from the group consisting of: M = H, ammonium, alkali The hindered amine light stabilizers (HALS) of component (d) are, for example, known commercial compounds. For example, they are selected from the group consisting of bis (2, 2,6,6-tetramethylpiperidin-4-yl) sebacate, bis (2, 2,6,6-tetramethylpiperidin-4-yl) succinate, bis (1,2) , 2, 6, 6-pentamethylpiperidin-4-yl) sebacate, bis (1,2, 2,6,6-pentamethylpiperidyl) ester of n-butyl-3,5-di-tert-butyl-4-hydroxybenzyl-mononic acid , the condensate of 1-hydroxyethyl-2, 2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, the condensate of N, N'-bis (2, 2, 6,6-tetramethyl-4-piperidyl) hexamethylenediamine and 4-tert-octylamin-2,6-dichloro-1,3,5-s-triazine, tris (2, 2, 6, 6-tetramethyl-4-piperidyl) nitrilotriacetate, tetrakis (2,2,6,6) -tetramethyl-4-piperidyl) -1,2,3, 4-butantetratoate, 1,1 '- (1,2-ethanediyl) -bis (3,3,5,5-tetramethylpiperazinone), 4-benzoyl-2, 2,6,6-tetramethylpiperidine, 4-stearyloxy-2,2,6,6-tetramethylpiperidine, bis (1,2, 2,6,6-pentamethylpiperidyl) -2-n-butyl-2- (2-hydroxy) 3, 5-di-tert-butylbenzyl) malonate, 3-n-octyl-7, 7,9, 9-tetramethyl-1,3,8-triazaspiro [4.5] decan- 2,4-dione, the condensate of N, N-bis (2, 2, 6,6-tetramethyl-4-piperidyl) hexamethylenediamine and 4-morpholin-2,6-dichloro-1,3,5-triazine, the Condensate of 2-chloro-4,6-di (4-n-butylamin-2,2,6,6-tetramethylpiperidyl) -1,3,5-triazine and 1, 2-bis (3-aminopropylamino) ethane, the condensate of 2-chloro-4,6-di (4-n-butylamino-1, 2,2,6,6-pentamethylpiperidyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) ethane, 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-l, 3,8-triazaspiro [4.5] decane-2,4-dione, 3-dodecyl- (2,2,6,6) -tetramethyl-4-piperidyl) pyrrolidin-2, 5-dione, 3-dodecyl-1- (1,2,2,6,6-pentamethyl-4-piperidyl) -pyrrolidine-2,5-dione, a mixture of 4-hexadecyloxy- and 4-stearyloxy-2, 2,6,6,6-tetramethylpiperidine, the condensate of N, N'-bis (2,2,6,6-tetramethyl-4-piperidyl) hexamethylenediamine and 4-cyclohexylamin-2 , 6-dichloro-l, 3, 5-triazine, the condensate of 1,2-bis (3-aminopropylamino) ethane and 2,4,6-trichloro-1,3,5-triazine 4-butylamino-2, 2 , 6,6-tetramethylpiperidine (CAS registry. No. [136504-96-6]); (2,2,6,6-tetramethyl-4-piperidyl) -n-dodecyl succinimide, (1,2,2,6,6-pentamethyl-4-piperidyl) -n-dodecyl succinimide, 2-undecyl-7,7,9,9-tetramethyl-l-oxa-3,8-diaza-4-oxo- spiro [4, 5] decane, the reaction product of 7,7,9,9-tetramethyl-2-cycloundecyl-l-oxa-3, 8-diaza-4-oxospiro [4, 5] decane and epichlorohydrin, tetra (2, 2, 6, 6-tetramethylpiperidin-4-yl) -butan-1, 2,3,4-tetracarboxylate, tetra (1,2,2,6,6-pentamethylpiperidin-4-yl) -butan-1 , 2,3,4-tetracarboxylate, 2,2,4,4-tetramethyl-7-oxa-3, 20-diaza-21-oxo-dispiro [5.1.11.2] -heneicosan, 8-acetyl-3-dodecyl- l, 3, 8-triaza-7, 7,9, 9-tetramethyl spiro [4, 5] -decan-2,4-dione where m is a value of 5-50, wherein R = H or CH3 The complexing formers of the component (d) or example for complexes containing nitrogen or polysaccharides derived natural polysaccharides, for example those containing phosphate, phosphonate or methylphosphonate groups, for example the derivatives of chitin, eg sulfochitin, carboxymethyl uitin, phosphochitin or chitosan derivatives, for example sulfochitosan, carboxymethylchitosan or phosphochitosan. Complex formers, for example, are selected from the group consisting of ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), ß-alanindiacetic acid (EDETA) or acid ethylenediamindisuccinic (EDDS) , amintrimethylenephosphoric acid (ATMP) that makes up the formula ^ ", serindiacetic acid (SDA) which forms the acid formula H00C-CH2, CH, -C00H 2 HOOC "asparagindiacetic that makes up the formula and methylglycine-acetic acid (MGDA) that makes up the Current stabilizing systems are particularly suitable for stabilizing body care products, in particular for use in skin care products, such as bath and shower products, preparations containing fragrances and odoriferous substances, care products of the hair, dentifrices, preparations of deodorizers and antiperspirants, decorative preparations, formulations of protection against light and preparations containing active ingredients. Suitable products for skin care are, in particular, body oils, body lotions, body gels, treatment creams, ointments for skin protection, shaving preparations, such as foam or gels for shaving, skin powders, such as baby powder, moisturizing gels, moisturizing sprays, aerosols to revitalize the body, cellulite gels and hair removal preparations. The preparations containing fragrances and odoriferous substances are in particular extracts, perfumes, toilet waters and shaving lotions (aftershave preparations). Suitable hair care products are, for example, shampoos for humans and animals, in particular dogs, hair conditioners, styling and hair styling products, permanent agents, aerosols and hair sprays, gels for hair hair, hair fixatives and agents that dye or whiten hair. Suitable dentifrices are particular toothpastes, toothpastes, mouthwashes, mouthwashes, plate preparations and denture cleaning agents. Suitable decorative preparations are in particular lipsticks, nail varnishes, eye shadows, mascaras, dry and wet makeup, rouge, powders, depilatory agents and tanning lotions. Suitable cosmetic formulations containing active ingredients are particular preparations of hormones, vitamin preparations, such as tocopherol, ascorbic acid, vitamin Q, D and K, carotenoids such as retinol, retinal, retinoic acid and lycopene, preparations of plant extracts, antibacterial preparations, preparations containing unstable amino acids containing dipeptides, oligopeptides and polypeptides for example methionine, cysteine, cystine, tryptophan, phenylalanine, tyrosine, preparations containing phenols, poylphenols or flavonoids.

A further aspect of the present invention is the stabilization of active ingredients selected from Vitamins, carotenoids, plant extracts, antibacterials, phenols, polyphenols or flavonoids which comprises applying to them at least one compound of component (b) and at least one compound of component (c). Current body care products can be in the form of creams, ointments, pastes, foams, gels, lotions, powders, makeups, sprays, pencils, sprays or wipes. The current stabilizer systems may be present in the oil phase or in the aqueous or aqueous / alcoholic phase. The additives of component (b) and (c) are present, for example, in body and home care products in a concentration of about 5 to about 10000 ppm, based on the total formulation, preferably from about 10 to about 5000 ppm, and preferably from about 100 to about 1000 ppm. For example, the additives of component (b) and (c) are present in body care products and household products in a concentration of about 5, 10, 15, 20, 25, 35, 40, 45 or 50 ppm, based on the total formulation.

For example, the additives of component (b) and (c) are present from about 5 to about 1000 ppm in the formulations (compositions) of this invention. The ratio of component (b) to component (c) is in the present composition from 1: 1000 to 1000: 1, preferably from 1: 100 to 100: 1, preferably from 1:10 to 10: 1. In addition, the cosmetic or pharmaceutical preparations may contain other auxiliaries as described below. As water-containing and oil-containing emulsions (eg W / O, O /, 0 / W / O emulsions and W / O / or microemulsions) the preparations contain, for example, 0.1 to 30% by weight, preferably 0.1 to 15% by weight and especially from 0.5 to 10% by weight, based on the total weight of the composition, of one or more UV absorbers, from 1 to 60% by weight, especially from 5 to 50% by weight and preferably from 10 to 35% by weight, based on the total weight of the composition, of at least one oil component, from 0 to 30% by weight, especially from 1 to 30% by weight and preferably from 4 to 20% by weight. % by weight, based on the total weight of the composition, of at least one emulsifier, from 10 to 90% by weight, especially from 30 to 90% by weight, based on the total weight of the composition, of water , and from 0 to 88.9% by weight, especially from 1 to 50% by weight, of additional cosmetically acceptable auxiliaries. The cosmetic or pharmaceutical compositions / preparations according to the invention may also contain one or more additional compounds as described below.

Fatty Alcohols Guerbet alcohols based on fatty alcohols having from 6 to 18, preferably from 8 to 10 carbon atoms including cetyl alcohol, stearyl alcohol, cetearyl alcohol, oleyl alcohol, octyldodecanol, C 2 -Cl 5 alcohol benzoate, alcohol of acetylated lanolin, etc.

Esters of fatty acids Esters of linear fatty acids of C6-C24 with linear alcohols of C3-C2, esters of carboxylic acids of C6-C? 3 branched with linear C6-C2 fatty alcohols, esters of linear fatty acids of C6-C2 with branched alcohols, especially 2-ethylhexanol, esters of hydroxycarboxylic acids with linear or branched C6-C2 fatty alcohols, especially dioctyl malate, fatty acid esters linear and / or branched with polyhydric alcohols (for example propylene glycol, dimerdiol or trimetriol) and / or Guerbet alcohols, for example capric acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeseaaric acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and its technical grade mixtures (obtained, for example, in the removal of pressure from natural fats and oils, in the reduction of Roelen oxosynthesis aldehydes or in the dimerization of unsaturated fatty acids) with alcohols, for example, isopropyl alcohol, capric alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linoyl alcohol, linolenilic alcohol, elaeostearyl alcohol, arachidyl alcohol, gadolelic alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical grade mixtures (obtained, for example, in high pressure hydrogenation of technical grade methyl esters based on fats and oils or aldehydes). Roelen oxosynthesis and as monomer fractions or in the dimerization of unsaturated fatty alcohols). Examples of such ester oils are isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, n-butyl stearate, n-hexylurate, n-decyl oleate, isooctyl stearate, isononyl isonate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-hexylurate, 2-hexyldecysateate, 2-octyldodecyl palmitate, oleyl oleate, oleilerucate, eruciloleate, erucilerucate, cetearyl octanoate, cetyl palmitate, cetyl stearate, cetyl oleate, behenate of cetyl, cetyl acetate, myristyl myristate, myristyl behenate, myristyl oleate, myristyl stearate, myristyl palmitate, myristyl lactate, propylene glycol dicaprylate / caprate, stearylheptanoate, diisostearyl malate, octyl hydroxystearate, etc.

Other auxiliaries Diethylhexyl 2, 6-naphthalate, di-n-butyl adipate, di (2-ethylhexyl) -adipate, di (2-ethylhexyl) -succinate acelaat and diisotridecyl, and also diol esters, such as ethylene glycol dioleate , ethylene glycol diistridecanoate, propylene glycol di (2-ethylhexanoate), propylene glycol diisostearate, propylene glycol dipelargonate, butanediol diisostearate and neopentyl glycol dicaprylate. Esters of fatty alcohols of Ce -C2 and / or Guerbet alcohols with aromatic, saturated and / or unsaturated carboxylic acids, especially benzoic acid, esters of dicarboxylic acids of CC? 2 with linear or branched alcohols having from 1 to 22 atoms carbon or polyols having from 2 to 10 carbon atoms and from 2 to 6 hydroxy groups, or iminodisuccinic acid and salts of iminodisuccinic acid [CAS 7408-20-0] or latex particles.

Natural or synthetic triglycerides including esters and glyceryl derivatives Di- or tri-glycerides, based on Cß-Cis fatty acids, modified by reaction with other alcohols (caprylic / capric triglyceride, wheat germ glycerides, etc.). Esters of polyglycerol fatty acids (polyglyceryl-n such as polyglyceryl-4 caprate, polyglyceryl-2 isostearate, etc.) or castor oil, hydrogenated vegetable oil, sweet almond oil, wheat germ oil, sesame oil , hydrogenated cottonseed oil, coconut oil, avocado oil, corn oil, hydrogenated castor oil, shea butter, cocoa butter, soybean oil, mink oil, sunflower oil, safflower oil, Australian walnut oil, olive oil, hydrogenated tallow, apricot kernel oil, hazelnut oil, borago oil, etc. Waxes including esters of alcohols and long chain acids as well as compounds that have properties similar to waxes, eg, carnauba wax, beeswax (white or yellow), lanolin wax, candelilla wax, ozokerite, Japan wax, paraffin wax, microcrystalline wax, cerosine, cetearyl ester wax, beeswax ntética, etc. Also, hydrophilic waxes such as cetearyl alcohol or partial glycerides.

Pearlescent waxes: Esters of alkylene glycol, especially ethylene glycol distearate; fatty acid alkanolamides, especially coconut fatty acid diethanolamide; partial glycerides, especially monoglyceride of stearic acid; esters of polyvalent, unsubstituted or hydroxy substituted carboxylic acids with fatty alcohols having from 6 to 22 carbon atoms, especially long chain esters of tartaric acid; fatty substances, for example fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, which in total have at least 24 carbon atoms, especially laurone and distearyl ether; fatty acids, such as stearic acid, hydroxystearic acid or behenic acid, ring-opening olefin epoxide products having from 12 to 22 carbon atoms with fatty alcohols having from 12 to 22 carbon atoms and / or polyols which they have from 2 to 15 carbon atoms and from 2 to 10 hydroxy groups, and their mixtures.

Hydrocarbon oils: Mineral oil (light or heavy), petrolatum (yellow or white), microcrystalline wax, paraffinic and isoparaffinic compounds, hydrogenated isoparaffin molecules such as polydecenes and polybutene, hydrogenated polyisobutene, squalene, isohexadecane, isododecane and other plant and animal kingdoms.

Silicones or siloxanes (organosubstituted polysiloxanes) Dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones, and also silicone compounds modified by amino-, fatty-, alcohol-, polyether-, epoxy-, fluorine-, glucoside and / or alkyl-, which at temperature environment can be in liquid or resinous form. Linear polysiloxanes, dimethicone (Dow Corning 200 fluid, Rhodia Mirasil DM), dimethiconol, silicone cyclic fluids, cyclopentasiloxane volatiles (Dow Corning 345 fluid), phenyltrimethicone (Dow Corning 556 fluid). Also suitable are dimethicones, which are mixtures of dimethicones having an average chain length of 200 to 300 dimethylsiloxane units with hydrogenated silicates. A detailed examination by Todd et al. of suitable volatile silicones can also be found in Cosm. Toil. 91. 27 (1976).

Fluorinated or perfluorinated oils Perfluorhexane, dimethylcyclohexane, ethylcyclopentane, polyperfluoromethylisopropyl ether.

Emulsifiers For the compositions, any emulsifier conventionally used can be used. The emulsifying systems may comprise, for example: carbocyclic acids and their salts: alkaline sodium, potassium and ammonium soap, calcium or magnesium metal soap, organic base soap such as lauric, palmitic, stearic and oleic acid etc. Esters of phosphoric acid or alkyl phosphates, acid phosphate, diethanolamine phosphate, potassium cetyl phosphate. Esters of polyethylene glycol or ethoxylated carboxylic acids, PEG-n acylates. Linear fatty alcohols having from 8 to 22 carbon atoms, branched from 2 to 30 mol of ethylene oxide and / or from 0 to 5 mol of propylene oxide with fatty acids having from 12 to 22 carbon atoms and with alkylphenols having from 8 to 15 carbon atoms in the alkyl group. Fatty alcohol polyglycol ether such as Laureth-n, Ceteareth-n, ESteareth-n, Oleth-n. Fatty acid polyglycol ether such as PEG-n stearate, PEG-n oleate, PEG-n cocoate. Polyol esters and monoglycerides. Mono- and di-esters of C_2-C22 fatty acids of addition products of 1 to 30 mol of ethylene oxide with polyols. Fatty acid and polyglycerol ester such as glycerol monostearate, diisostearoyl polyglyceryl-3-diisostearate, polyglyceryl-3-diisostearate, triglyceryl diisostearate, polyglyceryl-2-sesquiisostearate or polyglyceryl dimetrate. Mixtures of compounds of a plurality of those kinds of substances are also suitable. Polyglycol esters of fatty acid such as diethylene glycol monostearate, esters of fatty acids and polyethylene glycol, esters of fatty acids and sucrose such as sucrose esters, esters of glycerol and sucrose such as sucroglycerides. Sorbitol and sorbitan, sorbitan mono- and di-esters of saturated and unsaturated fatty acids having from 6 to 22 carbon atoms and addition products of ethylene oxide. Polysorbate-n series, sorbitan esters such as sesquiisostearate, sorbitan, sorbitan of PEG- (6) -isostearate, laurate of PEG- (10) -sorbit, sorbitan of PEG-17-dioleate. Derivatives of glucose, Cs-C22 monoalkyl and oligoglycosides and analogs ethoxylated with glucose being preferred as the sugar component. O / W emulsifiers such as methylgluceth-20 sesquistearate, sorbitan stearate / sucrose cocoate, methyl glucose sesquistearate, cetearyl alcohol / cetearyl glucoside. W / O emulsifiers such as methyl glucose dioleate / methylglucose isostearate. Sulphates and sulphated derivatives, dialkylsulfosuccinates, dioctyl succinate, laurylalkyl sulfonate, linear sulfonated paraffins, sulfonated tetrapropylene sulfonate, sodium laureth sulphates, laurel sulfates of ammonium and ethanolamine, sulfates of lauryl ether, sulphates of sodium Laureth, sulfosuccinates, acetylisothionates, alkanolamide sulfates, taurines, methyltarurines, imidazole sulfates. Amine derivatives, amine salts, ethoxylated amines, oxide amine with chains containing a heterocycle such as alkyl imidazolines, pyridine derivatives, isoquinoteines, cetylpyridinium chloride, pyridinium cetyl bromide, quaternary ammonium such as cetyltrimethylammonium bromide (CTBA) , stearylalconium. Amide derivatives, alkanolamides such as acylamide DEA, ethoxylated amides such as PEG-n acylamide, oxidamide. Polysiloxane / polyalkyl / polyether copolymers and derivatives, dimethicone, copolyols, silicone polyethylene oxide copolymer, silicone glycol copolymer. Propoxylated ethers or POE-n (Meroxapols), Polaxamers or poly (oxyethylene) m-block-poly (oxypropylene) n-block (oxyethylene). Zwitterionic surfactants carrying at least one quaternary ammonium group and at least one carboxylate and / or sulfonate group in the molecule. The zwitterionic surfactants that are especially convenient are betaines, such as glycinates of N-alkyl-NN, -dimethylammonium, cocoalkyldimethylammonium glycinate, glycinates of N-acylaminopropyl-N, N-dimethylammonium, glycinate of cocoacylaminopropyldimethylammonium and 2-alkyl-3-carboxymethyl-3-hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and also the cocoacylaminoethylhydroxyethylcarboxymethylglycinate, N-alkylbetaine, N-alkylaminobetaines. Alkylimidazolines, alkylpeptides, lipoamino acids, self-emulsifying bases and compounds as described in K.F.DePolo, A short textbook of cosmetology "Brief textbook of cosmetology", chapter 8, table 8-7, p250-251. Nonionic emulsifiers such as beeswax PEG-6 (and) stearate of PEG-6 (and) polyglyceryl-2-isostearate [Apifac], glyceryl stearate (and) stearate of PEG-100. [Arlacel 165], glyceryl stearate PEG-5 [Arlaton 983S], sorbitan oleate (and) polyglyceryl-3-ricinoleate. [Arlacel 1689], sorbitan stearate and sucrose cocoate [Arlatone 2121], glyceryl stearate and Laureth-23 [Cerasynth 945], cetearyl alcohol and Ceteth-20 [Cetomacrogol wax], cetearyl alcohol and colisorbate 60 and PEG-150 and stearate-20 [Polawax GP 200, Polawax NF], cetearyl alcohol and cetearyl polyglycoside [Emulgade PL 1618], cetearyl alcohol and Ceteareth-20 [Emulgade 1000NI, Cosmowax], cetearyl alcohol and PEG-40 castor oil [Emulgade F special], cetearyl alcohol and PEG-40 castor oil and sodium cetearyl sulfate [Emulgade F], stearyl alcohol and Steareth-7 and Steareth-10 [Emulgator E 2155], cetearyl alcohol and Steareth-7 and Steareth-10 [ USNF emulsifying wax], glyceryl stearate and stearate PEG-75 [Gelot 64], propylene glycol acetate [Ceteth-3] [Hetester PCS], propylene glycol acetate [Hetester PHA], cetearyl alcohol and Ceteth-12 and Oleth-12 [Lanchitol N 21], PEG-6 stearate and stearate PEG-32 [Tefose 1500], stearate of PEG-6 and Ceteth-20 and Steareth-20 [Tefose 2000], stearate of PEG-6 and Ceteth-20 and glyceryl stearate and Steareth-20 [Tefose 2561], glyceryl stearate and Ceteareth-20 [Teginacid H, C, X].

Anionic emulsifiers such as SE stearate from PEG-2, glyceryl SE stearate [Monelgine, Cutina KD], propylene glycol stearate [Tegin P], cetearyl alcohol and sodium cetaryl sulfate [Lanette N, Cutina LE, Crodacol GP], cetearyl alcohol and Sodium lauryl sulphate [Lanette W], Trilaneth-4 phosphate and glycol stearate and PEG-2 stearate [Sedefos 75], glyceryl stearate and sodium lauryl sulfate [Teginacid special]. Cationic acid bases such as cetearyl alcohol and cetri onium bromide. The emulsifiers can be used in an amount of, for example, 1 to 30% by weight, especially 4 to 20% by weight and preferably 5 to 10% by weight, based on the total weight of the composition. When formulated in O / W emulsions, the amount of such an emulsifier system could preferably represent 5% to 20% of the oil phase.

Auxiliaries and additives Cosmetic / pharmaceutical preparations, for example creams, gels, lotions, alcoholic and aqueous / alcoholic solutions, emulsions, wax / fat compositions, stick preparations, powders or ointments, may additionally contain, as further auxiliaries and additives. , mild surfactants, agents with excess oil, consistency regulators, thickeners, polymers, stabilizers, biogenic active ingredients, deodorant active ingredients, anti-dandruff agents, film formers, inflammation agents, additional factors protecting against UV light, antioxidants , hydrotropic agents, preservatives, insect repellents, self-tanning agents, solubilizers, perfumed oils, dyes, antimicrobial agents and the like.

Agents with excess oil Substances suitable for use as agents with excess oil are, for example, lanolin and lecithin and also derivatives of polyethoxylated or acrylated lanolin and lecithin, fatty acid esters of polyol, monoglycerides and fatty acid alkanolamides, the latter they act simultaneously as foam stabilizers.

Surfactants Examples of suitable mild surfactants, ie surfactants especially well tolerated by the skin, include fatty alcohol polyglycol ether sulfates, monoglyceride sulphates, mono- and di-alkyl sulfosuccinates, fatty acid isothionates, fatty acid sarcosinates, taurides of fatty acids, fatty acid glutamates, α-olefin sulfonates, ether carboxylic acids, alkyl oligoglycosides, fatty acid glucamides, alkylamidobetaines and / or protein fatty acid condensation products, the latter preferably based on wheat proteins.

Consistency regulators / thickeners and rheology modifiers Silicon dioxide, magnesium silicates, aluminum silicates, polysaccharides or their derivatives for example hyaluronic acid, xanthan gum, guar guar, agar-agar, alginates, carrageenan, gellan gum, pectins , or modified cellulose such as hydroxycellulose, hydroxypropylmethylcellulose. In addition polyacrylates or homopolymer of acrylic acids and crosslinked polyacrylamides, carbomer (carbopol types 980, 981, 1382, ETD 2001, ETD2020, Ultrez 10) or Saleare range such as Saleare SC80 (Steareth-10 allyl ether / acrylate copolymer), Saleare SC81 (acrylate copolymer), Saleare SC91 and Saleare AST (sodium acrylate copolymer / PPG-1 Trideceth-6), sepigel 305 (polyacrylamide / Laureth-7), Simulgel NS and Simulgel EG (hydroxyethyl acrylate / taurato copolymer) of acryloyl dimethyl sodium), Stabilen 30 (cross-linked polymer of acrylates / vinyl isodecanoate), Pemulen TR-1 (cross-linked polymer of acrylates / alkyl acrylate C10-30), Luvigel EM (copolymer of sodium acrylates), Aculyn 28 (acrylate copolymer / beheneth-25 methacrylate), etc.

Suitable cationic polymer Suitable cationic polymers are, for example, cationic cellulose derivatives, for example a quaternized hydromethylcellulose obtainable under the name Polymer JR 400 from Amerchol, cationic starches, copolymers of diallyl onium salts and acrylamides, quaternized vinylpyrrolidone / vinylimidazole polymers, for example Luviquat® (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides, for example hydrolyzed hydroxypropyl lauryldimonium collagen (LamequatRL / Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, for example amidomethicones, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartaretin / Sandoz), copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat 550 / Chemviron), polyaminopolyamides, as described, for example, in FR-A-2 252 840, and water-soluble polymers reticulated from them, deriv cationic aliquots of chitin, for example quaternized chitosan, optionally distributed as microcrystals; the condensation products of dihaloalkyls, for example dibromobutane, with bis-dialkylamines, for example bis-dimethylamino-1,3-propane, guar cationic gum, for example Jaguar C-17, Jaguar C-16 from Celanese, quaternized ammonium salt polymers, example Mirapol A-15, Mirapol AD-1, Mirapol AZ-1 Miranol. Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, copolymers of vinyl acetate / crotonic acid, copolymers of vinylpyrrolidone / vinyl acrylate, copolymers of vinyl acetate / butylmaleate / isobornyl acrylate, copolymers and their esters of methylvinyl ether / maleic anhydride, non-crosslinked polyacrylic acids and polyacrylic acids crosslinked with polyols, acrylamidopropyl trimethyl ammonium chloride / acrylate copolymers, octyl acrylamide / methylmethacrylate ether-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, polyvinylpyrrolidone, vinylpyrrolidone / acetate copolymers of vinyl, terpolymers of vinylpyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam and also optionally ethers and silicones derived from cellulose. In addition, the polymers can be used as described in EP 1093796 (pages 3-8, paragraphs 17-68).

Biogenic Active Ingredients As biogenic active ingredients they should be understood as meaning, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, deoxyribonucleic acid, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides. , essential oils, plant extracts and vitamin complexes.

Active ingredients deodorants As deodorant active ingredients, for example, antiperspirants, for example aluminum chlorhydrates, are taken into consideration (see J. Soc. Cosm. Chem. 24. 281 (1973)). Under commercial trademark Locron® Hoechst AG, Frankfurt (RFA), it is commercially available, for example, aluminum chlorohydrate corresponding to the formula Al2 (OH) 5Cl x 2.5 H20, the use of which is especially preferred (see J. Farm. 26. 531 (1975)). In addition to the hydrochlorides, it is also possible to use aluminum hydroxyacetates and aluminum / zirconium acid salts. Esterase inhibitors can be added as additional deodorizing active ingredients. Such inhibitors are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and especially triethyl citrate (Hydagen CAT, Henkel), which inhibit the enzymatic activity and therefore reduce the formation of odor. Other substances which are considered as esterase inhibitors are sulfates or sterol phosphates, for example lanosterol, cholesterol, campesterol, stigmaterol and sulfate or sitosterol phosphate, dicarboxylic acids and their esters, for example glutaric acid., glutaric acid monoethyl ester, glutaric acid diethyl ester, adipic acid, adipic acid monoethyl ester, adipic acid diethyl ester, malonic acid and malonic acid diethyl ester and hydroxycarboxylic acids and their esters, for example citric acid, malic acid, tartaric acid or diethyl ester of tartaric acid. Antibacterial active ingredients that influence the flora of the germ and kill or inhibit the growth of bacteria that break down sweat can also be present in the preparations (especially in bar preparations). Examples include chitosan, phenoxyethanol and chlorhexidine gluconate, 5-chloro-2- (2,4-dichlorophenoxy) -phenol (Triclosan, Irgasan, Ciba Specialty Chemicals Inc.) have also proven to be especially effective.

Anti-Dandruff Agents As antidandruff agents, for example, climbazole, octopirox and zinc pyrithione can be used. Common film formers include, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, polymers of quaternary cellulose derivatives containing a high portion of acrylic acid, collagen, hyaluronic acid and its salts and similar compounds .

Hydrotropic agents To improve the flow behavior it is also possible to employ hydrotropic agents, for example ethoxylated or non-ethoxylated mono-alcohols, diols or polyols with a low number of carbon atoms or their ethers (eg ethanol, isopropanol, 1, 2). dipropionol, propylene glycol, glycerin, ethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether and the like). The polyols that come into consideration for that purpose preferably have from 2 to 15 carbon atoms and at least two hydroxy groups. The polyols can also contain other functional groups, especially amino groups, and / or can be modified with nitrogen. Typical examples are the following: glycerol, alkylene glycols, for example ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and also polyethylene glycols having an average molecular weight of 100 to 1000 Daltons; technical mixtures of oligoglycerol having an intrinsic degree of condensation of 1.5 to 10, for example technical diglycerol mixtures having a diglycerol content of 40 to 50% by weight; methylol compounds, for example, especially trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; lower alkyl glucosides, especially those having from 1 to 8 carbon atoms in the alkyl radical, for example methyl glucoside and butyl; sugar alcohols having from 5 to 12 carbon atoms, for example sorbitol or mannitol; sugars having from 5 to 12 carbon atoms, for example glucose or sucrose; amino sugars, for example glucamine; dialcoholamines, such as diethanolamine or 2-amino-1,3-propanediol.

Condoms Convenient preservatives include, for example, Methyl-, Ethyl-, Propyl-, Butyl- paraben, Benzalkonium chloride, 2-Bromo-2-nitro-propan-l, 3-diol, dehydroacetic acid, Diazolidinylurea, 2-Dichlorobenzyl alcohol, DMDM hydantoin, solution of formaldehyde, methyldibromoglutanitrile, phenoxyethanol, Sodium hydroxymethylglycinate, Imidazolidinylurea, Triclosan and additional classes of substances listed in the following reference: KFDePolo - A short textbook of cosmetology, chapter 7, Table 7-2, 7-3, 7-4 and 7-5, p210-219 .

Agents that inhibit bacteria Typical examples of agents that inhibit bacteria are condoms that have a specific action against gram-positive bacteria, such as 2,4,4'-trichloro-2'-hydroxydiphenyl ether, chlorhexidine (1, 6-di) (4-chlorophenyl-biguanido) hexane) or TCC (3,4,4'-trichlorocarbanilide). A large number of aromatic substances and essential oils also have antimicrobial characteristics. Typical examples are the active ingredients eugenol, menthol and thymol in clove oil, peppermint oil and thyme oil. A natural deodorant agent of interest is farnesol of terpene alcohol (3, 7, 11-trimethyl-2, 6, 10-dodecatrien-1-ol), which is present in lime blossom oil. Glycerol monolaurate has also been shown to be a bacteriostatic element. The present amount of antibacterial agents or which inhibit bacteria is generally 0.1 to 2% by weight, based on the solids content of the preparations.

Oils for perfume Perfume oils may be mentioned as mixtures of natural and / or synthetic aromatic substances. Natural aromatic substances are, for example, flower extracts (lilies, lavender, roses, jasmine, orange blossom, ylang-ylang), stems and leaves (geranium, patchouli, pips), fruit (anise, coriander, carraway, juniper), peel fruit (bergamot, lemons, oranges), roots (mace, angelica, celery, cardamom, cost, lily, calmus), wood (pine, sandalwood, guaiac, cedar, rosewood) , herbs and grasses (tarragon, lemon grass, sage, thyme), needles and twigs (fir, pine, Scots pine, mountain pine), resins and balsams (galbanum, alemi, benzoin, myrrh, frankincense, opoponax). Animal raw materials also come into consideration, for example civet and castoreum. Typical synthetic aromatic substances are, for example, products of the ester, ether, aldehyde, ketone, alcohol or hydrocarbon type. The aromatic compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, glycinate. of ethylmethylphenyl, allylcyclohexyl propionate, styrallyl propionate and benzyl salicylate. The ethers include, for example, benzylethyl ether; aldehydes include, for example, linear alkanes having from 8 to 18 hydrocarbon atoms, citral, citronellal, citronellyl oxyacetaldehyde, cyclamen aldehyde, hydroxy citronellal, lilial and bourgeonal; the ketones include, for example, ionones, isomethylionone and the methyl-cedryl ketone; the alcohols include, for example, anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpinol; and hydrocarbons include mainly terpenes and balsams. It is preferable, however, to use mixtures of the different aromatic substances that together produce an attractive odor. Essential oils of relatively low volatility, which are used primarily as aroma components, are also suitable as perfume oils, e.g. sage oil, chamomile oil, clove oil, lemon balm oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, frankincense oil, galbanum oil, laburnum oil and bleach oil Preference is given to the use of the essence of bergamot, dihydromircenol, lilial, liral, citronellol, phenylethyl alcohol, hexyl cinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, boisembrene forte, ambroxan, indole, hedione, sandelice, lemon oil, oil of tangerine, orange oil, allylic glycolate, cyclovertal, bleach oil, muscatel sage oil, damascone, geranium oil of bourbon, cyclohexyl salicylate, heart of vertofix, ISO-E-Super, Fixolide NP, evernil, gamma of iraldein, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, irotyl and floramat alone or as a mixture between them.

Other auxiliaries In addition, it is possible that the cosmetic preparations contain, as auxiliaries, antifoams, such as for example silicones, structurants, such as maleic acid, solubilizers, such as ethylene glycol, propylene glycol, glycerol or diethylene glycol, opacifiers, such as latex, copolymers of styrene / PVP or styrene / acrylamide, propellants, such as propane / butane mixtures, N20, dimethyl ether, C02, N2 or air, components known as couplers and developers as oxidation dye precursors, reducing agents, such as thioglycolic acid and its derivatives, thiolactic acid, cysteamine, thiomalic acid or mercaptoethanesulfonic acid, or oxidizing agents, such as hydrogen peroxide, potassium bromate or sodium bromate. Suitable insect repellents are, for example, N, N-diethyl-m-toluamide, 1,2-pentanediol or insect repellent 3535; Suitable self-tanning agents are, for example, dihydroxyacetone and / or erythrulose or dihydroxyacetone and / or dihydroxyacetone precursors as described in WO 01/85124 and / or erythrulose. The present stabilizing systems are particularly suitable for stabilizing products for body care, in particular: preparations for skin care, e.g. preparations for washing and cleaning the skin in the form of soaps in a tablet or liquid configuration, detergents without soap or laundry pastes, bath preparations, e.g. liquid preparations (foam baths, milks, shower preparations) or solid bath preparations, e.g. bath cubes and bath salts; preparations for skin care, e.g. emulsions for the skin, multi-emulsions or oils for the skin; natural fats for the skin, body lotions, body gels; ointments for skin protection; cosmetic preparations for personal care, e.g. facial makeup in the form of day creams or powdered creams, powder for the face (loose or tight), rouge or cream makeup, preparations for eye care, e.g. preparations for shading the eyes, mascara, eyeliner, eye creams or eye makeup creams; preparations for the care of the lips, e.g. lipsticks, lip gloss, lip contour pencils, nail care preparations, such as nail varnish, nail varnish removers, nail hardeners or cuticle removers; - preparations for the care of the feet, e.g. footbaths, foot powder, creams or balms for the feet, deodorants and special antiperspirants or preparations for removing calluses; light-protective preparations, such as milks, lotions, creams or oils for the sun, sun or tropical sun block, pre-tanning preparations or after-sun preparations; preparations for tanning the skin, e.g. self-tanning creams; depigmenting preparations, e.g. skin-whitening preparations or preparations for skin lightening; insect repellents, e.g. oils, lotions, sprays or insect repellent bars; deodorants, such as deodorant sprays, pump action aerosols, deodorant gels, sticks or pellets; antiperspirants, e.g. antiperspirants in stick, cream or beads; preparations for cleaning and caring for soiled skin, e.g. synthetic detergents (solids or liquids), preparations for peeling or rubbing or masks for peeling; preparations for hair removal removal in the chemical form (hair removal), e.g. powders for hair removal, liquid preparations hair removers, cream or paste preparations for hair removal or removal, hair removal preparations in the form of gel or aerosol foams; - preparations for shaving, e.g. shaving soap, foaming shaving creams, non-foaming shaving creams, foam and pre-shave gel preparations, shaving dry, aftershave lotions; fragrance preparations, e.g. preparations containing fragrances and odoriferous substances (essences, eau de toilette, eau de parfum, parfum de toilette, perfume), perfume oils or perfume creams; cosmetic preparations for hair treatment, e.g. preparations for washing hair in the form of shampoos and conditioners, hair care preparations, e.g. pretreatment preparations, hair toners, styling creams, styling gels, ointments, hair rinses, treatment packages, intensive hair treatments, hair structuring preparations, e.g. hair wave preparations for permanent waves (hot wave, warm wave, cold wave), hair straightening preparations, liquid hair setting preparations, hair mousses, hair sprays, bleaching preparations, e.g. hydrogen peroxide solutions, rinsing shampoos, rinsing creams, bleaching powders, whitening pastes or oils, temporary, semi-permanent or permanent hair dyes, preparations containing self-oxidizing dyes, or natural hair dyes, such as henna or chamomile; dentifrices, in particular toothpastes, toothpastes, mouthwashes, mouthwashes, plate preparations and denture cleaning agents; - decorative preparations, in particular lipsticks, varnishes for nails, eye shadows, mascaras, wet and dry makeup, rouge, powders, depilatory agents and tanning lotions; cosmetic formulations containing active ingredients, in particular hormonal preparations, vitamin preparations, preparations of plant extracts and antibacterial preparations. Suitable cosmetic formulations containing active ingredients are particular hormonal preparations, vitamin preparations, preparations of plant extracts and antibacterial preparations.

Forms of presentation The final formulations listed can exist in a wide variety of presentation forms, for example: in the form of liquid preparations such as a W / O emulsion, O / W, O / W / O, W / O / W or PIT and all kinds of microemulsions, - in the form of a gel, in the form of an oil, a cream, milk or. lotion, in the form of a bar, in the form of an aerosol (aerosol with propellant gas or pump action aerosol) or an aerosol, in the form of a foam, or in the form of a gum. Of special importance as cosmetic preparations for the skin are protective preparations against light, such as solar milks, lotions, creams, wipes, oils, sun or tropical blockers, pre-tanning preparations or after-sun preparations., also preparations that tan the skin, for example self-tanning creams. Of particular interest are sun protection creams, lotions for sun protection, milk for sun protection and sun protection preparations in the form of an aerosol. Of special importance as cosmetic preparations for hair are the above preparations for hair treatment, especially preparations for hair washing in the form of shampoos, hair conditioners, hair care preparations, e.g. preparations for pretreatment, hair toners, styling creams, styling gels, ointments, hair rinses, treatment packages, intensive hair treatments, hair straightening preparations, liquid preparations for hair fixation, foams and lacquers for hair The hair. Of special interest are preparations for washing hair in the form of shampoos. A shampoo has, for example, the following composition: 0.01 to 5% by weight of component (b) according to the invention, 12.0% by weight of sodium Laureth-2-sulfate, 4.0 % by weight of cocamidopropyl betaine, 3.0% by weight of sodium chloride, and adjusted with 100% water (ad 100). For example, the following hair cosmetic formulations can be used in particular: a) spontaneously emulsifying common formulation, consisting of the component (b) according to the invention, optionally a UV absorber according to tables 1-3, C0-oxoalcohol PEG-6- and sorbitan sesquioleate, to which water and any desired quaternary ammonium compound is added, for example, 4% of minkamidopropyl dimethyl-2-hydroxyethylammonium chloride or Quaternium 80 is added; a2) spontaneously emulsifying common formulation consisting of component (b) according to the invention, optionally a UV absorber according to tables 1-3, tributyl citrate and PEG-20 sorbitan monooleate, to which water and any desired compound of quaternary ammonium, for example 4% of minkamidopropyl dimethyl-2-hydroxyethylammonium chloride or Quaternium 80; b) quat-doped solutions of component (b) according to the invention in butyltriglycol and tributyl citrate; and optionally a UV absorber according to tables 1-3; c) mixtures or solutions of component (b) according to the invention with n-alkylpyrrolidone; and optionally a UV absorber according to tables 1-3. Laundry detergents, laundry aids, laundry pre-treatment products, laundry enhancers, fabric treatments (eg, aerosol starches, fabric fresheners), fabric softeners or other products, of which the additives of the component (b) and (c) are intended for deposition on fabrics with use, the household products of this invention are considered, and the above-mentioned concentration levels also belong to these. The present additives of component (b) and (c) are effective in stabilizing laundry detergents and fabric softeners, as well as fabrics treated therewith.

The following is a list of examples of the body care products of this invention and their ingredients: Current body care products, household products, textiles and fabrics have high stability towards color changes and chemical degradation of the ingredients present in these products. For example, current compositions comprising a dye are found to have excellent color stability.

Accordingly, the present invention further pertains to a stabilized composition comprising (a) a body care product, a household, textile or fabric product, (b) an effective stabilizing amount of at least one compound selected from the group consisting of (i) hindered nitroxyl compounds of formula (I), (ii) hindered hydroxylamine compounds of formula (II) and (iii) hindered hydroxylamine salt compounds of formula (III), (c) a filter Organic UV selected from (ci) dibenzoylmethane derivatives; (c) cinnamic acid esters; (c3) camphor derivatives; (c4) trianilino-s-triazine derivatives; and (e) a dye. The dyes according to the present invention are for example: inorganic pigments, for example iron oxide (iron oxide red, iron oxide yellow, iron oxide black, etc.), groceries, chromium oxide green or black of smoke; - natural or synthetic organic pigments; dispersion dyes that can be solubilized in solvents such as hair dyes of type HC, for example HC Red No. 3, HC Blue No. 2 and the rest of hair dyes listed in International Cosmetic Ingredient Dictionary and Handbook, 7- edition (1997) or dispersion dyes listed Color Index International or Society of Dyers and Colourists; color varnishes (insoluble salts of soluble dyes, such as Ca, Ba or Al salts of anionic dyes); soluble anionic or cationic dyes, such as acid (anionic) dyes, basic (cationic) dyes, direct dyes, reactive dyes or solvent dyes; fluorescent dyes; - fluorescein and isothiocyanates. Generally, all substances that have an absorption in the visible light of electromagnetic radiation (wavelength of about 4000 to 700 nm) are suitable for the coloring of products for the home and for the care of the body. The absorption is often caused by the following chromophores: Azo- (mono-, di, tris- or poly-) stilbene-, carotenoid-, diarylmethane-, triarylmethane-, xanthen-, acridin-, quinoline, metin- (also polymethine) -), thiazole-, indamin-, indophenol-, azin-, oxazine, thiazine-, anthraquinone-, indigoid-, phthalocyanine- and synthetic, natural and inorganic chromophores. Current stabilizing systems are also used in cleaning and household treatment agents, for example in laundry and fabric softener products, liquid cleaning and scouring agents, glass detergents, neutral cleaners (multi-purpose cleaners), cleaners household acids (bath), bathroom cleaners, for example in washing, rinsing and dish washing agents, kitchen and oven cleaners, rinse agents, dishwashing detergents, footwear greases, polishing waxes, detergents and floor greases, metal, glass and ceramic cleaners, textile care products, rugs and carpet shampoos, mildew removers, color and stains (stain remover salt), furniture and multipurpose polishes and disinfectants of leather and vinyl (leather and vinyl sprays) and environmental deodorants. The present invention also relates to home care and fabric care products such as drain cleaners, disinfectant solutions, upholstery cleaners, automotive care products (eg, cleaning and / or polishing and protecting paint, tires, chrome, vinyl, leather, fabric, rubber, plastic and fabric), degreasers, polishes (glass, wood, leather, plastic, marble, granite, tile, etc.), and polishes and cleaners of metals. Antioxidants are suitable for protecting fragrances in over the products as well as in dryer sheets. The current invention also relates to home care products such as candles, gel candles, environmental deodorants and fragrance oils (for the home). The stabilizers of the present invention can be used in the treatment of fabrics that occurs after the use of the fabric, referred to as fabric care. Such treatments include laundry, which uses detergents, laundry aids and / or fabric conditioners, and the application of products not based on fabric care detergents, such as, for example, aerosol products. When used in this way, the current stabilizers are intended for deposition on the fabric and are used to protect the fabric, dyes and fragrances associated with these fabrics from environmental damage. Typical examples of cleaning and treatment agents for the home are: The present stabilizers are incorporated, for example, by dissolution in an oil phase or alcoholic or aqueous phase, where it is required at high temperature. The present invention also pertains to a method for stabilizing a body care product, a product for the home, textile or fabric, comprising incorporating therein or applying at least one compound of component (b) and at least one composed of component (c), preferably at least one compound of the formulas A to EE and A * to EE *.

Preferably a dibenzoylmethane derivative (= component ci), preferably 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1,3-dione is used as component (c). In the case of stabilized fabrics, for example dyed fabrics, the current stabilizers are applied to these via deposition of for example detergents, fabric conditioners or products not based on detergents for the care of fabrics. The current fabrics are natural or synthetic and can be woven or non-woven. The present invention also pertains to a method for stabilizing a body care product, a product for the home, textile or fabrics, each of which contains a dye, which comprises incorporating them or applying at least one compound of the same. formulas (I), (II) and (III) (= component (b)), and at least one compound of component (c), for example at least one compound of formulas A to EE and A * to EE * and at least one compound of component (c). Preferably a dibenzoylmethane derivative (= component ci) is used as component (c) and preferably 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1,3-dione.

The stabilizers of the formulas (I), (II) and (III) (= component (b)) together with the organic UV absorbers (component (c)) are very effective for the stabilization of dyes in the present compositions. The textiles of this invention are for example textile fiber materials, for example nitrogen-containing or hydroxy-containing fiber materials, for example textile fiber materials are selected from cellulose, silk, wool, synthetic polyamides, leather and polyurethanes. Cotton, linen and hemp, pulp and regenerated cellulose are included. Cellulose mixtures are also included, for example mixtures of cotton and polyamide or of cotton / polyester blends. The additives of the present invention are applied, for example, to textiles in a dyeing or printing process, or in a finishing process. For example, the additives can be applied as part of a dye formulation. The additives can be applied to textiles for example in an inkjet printing process. The additives are applied, for example, as part of an aqueous solution of the dye or printing paste. They can be applied in a method of exhaustion or dyeing by the method of pad dying, where the textiles are impregnated with aqueous dye solutions, which may contain salts, and the dyes and additives are fixed, after an alkaline treatment or presence of alkali, if appropriate with the action of heat or by storage at room temperature for several hours. After fixing, the dyeings or prints are rinsed thoroughly with cold and hot water, if appropriate with the addition of an agent having a dispersing action and promoting diffusion of the non-fixed portions. Dye or ink formulations for application to textiles may also comprise customary additives, for example, surfactants, defoamers, antimicrobials and the like, for example as disclosed in U.S. Pat. Nos. 6,281,339, 6,353,094 and 6,323,327, the descriptions of which are incorporated herein by reference. A further aspect of the present invention is the photostabilization of the UV filters according to component (c). Therefore, the present invention also relates to a method of photostabilization of a compound according to component (c), which comprises the application to this compound of at least one compound of component (b).

The following examples illustrate the invention. The percentages are in percent by weight unless otherwise indicated.

EXAMPLES The following stabilizers are used in the lower examples: A. Amine compound (= component (b)): B. Organic UV absorber (= component (c)) (Bl) Ethylhexylmethoxy cinnamate (B2) Butyl methoxydibenzoylmethane (B3) 4-Methylbenzylidene camphor (B4) Ethylhexyl triazone (B5) Butyl methoxydibenzoylmethane ethylhexylmethoxy cinnamate mixture (B6) Butyl and octocrylene methoxydibenzoylmethane mixture The components are thoroughly mixed in the sequence mentioned, at 50 ° C, a clear homogeneous solution is obtained. Excellent results are achieved.

Hydroxypropylcellulose is first pre-dissolved in half the alcohol (Vortex mixer) and loaded with aminomethylpropanol. The other components - with the exception of the acrylate resin - are dissolved in alcohol and this solution is added, with stirring, to the hydroxypropylcellulose. Subsequently, the acrylate resin is added and stirred until it is completely dissolved. Excellent results are achieved.

The components are mixed, with stirring, at room temperature until they dissolve completely. The pH is 6.5. Excellent results are achieved.

The components are mixed, with stirring, at room temperature until they dissolve completely. The pH is 6.5. Excellent results are achieved Preparation: The components are dissolved in the indicated sequence until a clear homogenous mixture is obtained.

Examples 31-36: Preparation of a floor wax Examples Preparation: The components are stirred in the indicated sequence until a homogeneous mixture is obtained.

Examples 37-42: Preparation of an eyeliner

Claims (40)

1. CLAIMS 1. A stabilized composition comprising (a) a body care product, household product, textile or fabric, (b) an effective stabilizing amount of at least one compound selected from the group consisting of (i) compounds of nitroxyl hindered from the formula (I) (ii) Hydroxylamine compounds hindered from the formula (II) HO (iii) compounds of the hydroxylamine salt hindered of the formula (III) in which Gi and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene, Zi and Z2 are each methyl, or Zi and Z2 together form a binding moiety that can be further substituted by an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or urethane group, X is an inorganic or organic anion, such as phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite , bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartrate, acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, tiglato, ascorbate, polymethacrylate, a nitrilotriacetic acid carboxylate, hydroxyethyl-ethylenediaminetriagnetic acid, ethylenediaminetetraacetic acid or diethylenetriaminpentaacetic acid, a diethylenetriamine pentamethylene phosphonate, an alkylsulphonate or an arylsulphonate, and where the total charge of the cations is ig ual to the total charge of the anions j; and (c) an organic UV filter selected from (ci) dibenzoylmethane derivatives; (c2) cinnamic acid esters; (c3) camphor derivatives; and (c) trianilin-s-triazine derivatives.
2. 2. A composition according to claim 1, characterized in that X is phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartrate. , acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, tiglato, ascorbate, polymethacrylate, a nitrilotriacetic acid carboxylate, hydroxyethylenediaminetriacetic acid, ethylenediaminetetraacetic acid or diethylenetriaminpentaacetic acid, a diethylenetriaminepentamethylene phosphonate, an alkylsulfonate or an arylsulfonate.
3. 3. A composition according to claim 1, characterized in that the compounds of component (b) are of the formulas A to EE and A * to EE * (EE *) wherein E is oxyl or hydroxyl, R is hydrogen or methyl, in the formula A and A *, n is 1 or 2, when n is 1, Ri is hydrogen, alkyl of 1 to 18 carbon atoms, alkenyl of 2-18 carbon atoms, propargyl, glycidyl, alkyl of 2 to 50 carbon atoms interrupted by one to twenty oxygen atoms, the alkyl substituted by one to ten hydroxyl groups or interrupted by the oxygen atoms and replaced by the hydroxyl groups, or Ri is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by -COOZ wherein Z is hydrogen, alkyl of 1 to 4 carbon atoms or phenyl, or where Z is alkyl substituted by - (COO) ") n Mn + where n is 1-3 and M is a metal ion of the 1st, 2nd or 3rd group of the periodic table or is Zn, Cu, Ni or Co, or M is a group Nn + (R2) where R is. alkyl of 1 to 8 carbon atoms or benzyl, when n is 2, Ri is alkylene of 1 to 12 carbon atoms, alkenylene of 4 to 12 carbon atoms, xylylene or alkylene of 1 to 50 carbon atoms interrupted by one a twenty oxygen atoms, substituted by one to ten hydroxyl groups or interrupted by oxygen atoms and substituted by hydroxyl groups, in formula B and B *, m is 1 to 4, when m is 1, R is alkyl of 1 to 18 carbon atoms, alkyl of 3 to 18 carbon atoms interrupted by -C00-, or R2 is -CH2 (OCH2CH2) nOCH3 where n is 1 to 12, or R2 is the cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon atoms, or the aryl substituted by one to four alkyl groups of 1 to 4 carbon atoms, or R2 is -NHR3 where R3 is alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon atoms, or aryl substituted by one to four alkyl of 1 to 4 atoms of carbon, or R is -N (R3) 2 where R3 is as defined above, when m is 2, R2 is alkylene of 1 to 12 carbon atoms, alkenylene of 4 to 12 carbon atoms, xylene, alkylene of 2 to 12 carbon atoms interrupted by -COO-, or R2 is -CH2 (OCH_CH_) nOCH2- where n is 1 to 12, or R2 is cycloalkylene of 5 to 12 carbon atoms, aralkylene of 7 to 15 carbon atoms or arylene from 6 to 12 carbon atoms, or R2 is -NHR4NH- where R4 is alkylene of 2 to 18 carbon atoms, cycloalkylene of 5 to 12 carbon atoms, aralkylene of 8 to 15 carbon atoms or arylene of 6 to 12 atoms of carbon, or R is -N (R3 (R4N (R3) - where R3 and R4 are as defined above, or R2 is -CO- or -NH-CO-NH-, when m is 3, R2 is alkantriyl of 3 to 8 carbon atoms or benzenetriyl, or when it is 4, R 2 is C 5 -C 8 alkyntetranyl or bencenthryl, in formula C and C *, Rio is hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms , aralkyl of 7 to 15 carbon atoms, alkanoyl of 2 to 18 carbon atoms, alkenoyl of 3 to 5 carbon atoms or benzoyl, x is 1 or 2, when x is 1, Rn is hydrogen, alkyl of 1 to 18 carbon atoms, alkenyl of 2 to 18 carbon atoms, propargyl, glycidyl, alkyl of 2 to 50 carbon atoms interrupted by one to twenty oxygen atoms, alkyl substituted by one to ten hydroxyl groups or interrupted by oxygen atoms and substituted by the hydroxyl groups, or Rn is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by -COOZ wherein Z is hydrogen, alkyl of 1 to 4 carbon atoms or phenyl, or where Z is the substituted alkyl by - (COO ~) nMn + where n is 1-3 and M is a metal ion of the 1st, 2nd or 3rd group of the periodic table or is Zn, Cu, Ni or Co, or M is a group Nn + (R2) 4 where R2 is hydrogen, alkyl of 1 to 8 carbon atoms or benzyl, or when x is 2, Rn is alkylene of 1 to 12 carbon atoms, alkenylene of 4 to 12 carbon atoms, xylylene or alkylene of 1 to 50 carbon atoms interrupted by one to twenty oxygen atoms, substituted by one to ten hydroxyl groups or interrupted by the atoms of oxygen and substituted by the hydroxyl groups, in the formula D and D *, Rio is as defined above, and is 1 to 4, and R? 2 is defined as R2 above in the formula E and E *, k is 1 or 2, when k is 1, R-20 and R-21 are independently alkyl of 1 to 12 carbon atoms, alkenyl of 2 to 12 carbon atoms or aralkyl of 7 to 15 carbon atoms, or R20 is also hydrogen, or R20 and R2? together they are alkylene of 2 to 8 carbon atoms or the alkylene substituted by hydroxyl, or are acyloxy-alkylene of 4 to 22 carbon atoms, or when k is 2, R20 and 21 are together (-CH2) 2C (CH2-) 2, in formula F and F *, R30 is hydrogen, alkyl of 1 to 18 carbon atoms, benzyl, glycidyl, or alkoxyalkyl of 2 to 6 carbon atoms, g is 1 or 2, when g is 1, R3i is define as R_ above when n is 1, when g is 2, R3_ is defined as Ri above when n is 2, in the formula G and G *, Qi is -NR41- or -O-, Ei is alkylene from 1 to 3 carbon atoms, or Ei is -CH2-CH (R42) -O- where R4 is hydrogen, methyl or phenyl, or Ei is - (CH2) 3-NH- or Ei is a direct bond, R0 is hydrogen or alkyl 1 to 18 carbon atoms, R? is hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms, or Ri is -CH_-CH (R_2) - OH where R42 is as defined above, in formula H and H *, p is 1 or 2, T4 is as defined for Rn when x is 1 or 2, M and Y are independently methylene or carbonyl, for example M is methylene and Y is carbonyl, in the formula lei *, this formula denotes a recurrent structural unit of a polymer where Ti is ethylene or, 2-propylene or is the repeating structural unit derived from an alpha-olefin copolymer with an acrylate or an alkyl methacrylate, and where q is 2 to 100, Qi is -N (R?) - 0 where R4i is as defined above, in the formula J and J *, r is 1 or 2, T7 is as defined for Ri when n is 1 or 2 in formula A, for example T7 is octamethylene when r is 2, in the formula L and L *, u is 1 or 2, T13 is as defined for Ri when n is 1 or 2 in formula A, provided that T? 3 is not hydrogen when u is 1, in the formula M and M *, Ei and E2, being different, each are -C0-0-N (E5) - where E5 is hydrogen, alkyl of 1 to 12 carbon atoms or alkoxycarbonylalkyl of 4 to 22 carbon atoms, for example Ei is -CO- and E2 is -N (E5) -, E3 is hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl, naphthyl or phenyl substituted by chloro or by alkyl of 1 to 4 carbon atoms, or phenylalkyl of 7 to 12 carbon atoms, or the phenylalkyl ilo substituted by alkyl of 1 to 4 carbon atoms, E is hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl or phenylalkyl of 7 to 12 carbon atoms, or E3 and E4 together are polymethylene of 4 to 17 atoms of carbon, or the polymethylene substituted by alkyl of one to four of 1 to 4 carbon atoms, for example methyl, in the formula N, Ri is as defined for Ri in the formula A when n is 1, G3 is a bond direct, alkylene of 1 to 12 carbon atoms, phenylene or -NH-G-Gi-NH- where Gi is alkylene of 1 to 12 carbon atoms, in the formula 0 and 0 *, Rio is as defined for Rio in the formula C, in the formula P and P *, E6 is a tetravalent aliphatic or aromatic radical, for example neopentantenyl or bencentetrail, in the formula T and T *, R51 is hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, or aryl of 6 to 10 carbon atoms, R52 is hydrogen or alkyl of 1 to 18 carbon atoms , or R51 and R52 together are alkylene of 4 to 8 carbon atoms, f is 1 or 2, when f is 1, R50 is as defined for Rn in formula C when x is 1, or R50 is - (CH2) zC00Rs where Z is 1 to 4 and R5 is hydrogen or alkyl of 1 to 18 carbon atoms, or R54 is a metal ion of the 1st, 2nd or 3rd group of the periodic table or a group -N (R5s) 4 where R55 is hydrogen, alkyl of 1 to 12 carbon atoms or benzyl, when f is 2, R50 is as defined for Rn in formula C when x is 2, in the formula U and U *, R53, R5, R55 and R56 are independently alkyl of 1 to 4 carbon atoms or are pentamethylene together. in the formula V and V *, R57, R58, R59 and Rso are independently alkyl of 1 to 4 carbon atoms or are pentamethylene together. in the formula W and W *, R-61, R62 Rd3 and R-6 are independently alkyl- of 1 to 4 carbon atoms or are pentamethylene together, R65 is alkyl of 1 to 5 carbon atoms, M is hydrogen or oxygen, where in formulas X to CC and X * to CC * n is 2 to 3, Gi is hydrogen, methyl, ethyl, butyl or benzyl, is 1 to 4, x is 1 to 4, when x is 1, Ri and R2 are independently alkyl of 1 to 18 carbon atoms, alkyl interrupted by one to five oxygen atoms, alkyl substituted by 1 to 5 hydroxyl groups or alkyl interrupted by oxygen atoms and substituted by hydroxyl groups; cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms or the aryl substituted by one to three alkyls of 1 to 8 carbon atoms, or Ri is also hydrogen, or Ri and R2 are together tetramethylene, pentamethylene, hexamethylene or 3-oxapentamethylene, when x is 2, Ri is hydrogen, alkyl of 1 to 8 carbon atoms, the alkyl interrupted by one or two oxygen atoms, the alkyl substituted by a hydroxyl group, or the alkyl interrupted by one or two oxygen atoms and substituted by a hydroxyl group, R 2 is alkylene of 2 to 18 carbon atoms, the alkylene interrupted by one to five oxygen atoms, the alkylene substituted by 1 to 5 hydroxyl groups or the alkylene interrupted by the oxygen atoms and substituted by the hydroxyl groups; o-, m- or p-phenylene or the phenylene substituted by one or two alkyls of 1 to 4 carbon atoms, or R2 is - (CH2) kO [(CH2) kO] h (CH2) k- where k is 2 a 4 and h is 1 to 40, or Ri and R2 together with the two N atoms to which they bind are piperazin-1,4-diyl, when x is 3, Ri is hydrogen R2 is alkylene of 4 to 8 atoms carbon interrupted by a nitrogen atom, when x is 4, Ri is hydrogen, R2 is alkylene of 6 to 12 carbon atoms interrupted by two nitrogen atoms, R3 is hydrogen, alkyl of 1 to 8 carbon atoms, the alkyl interrupted by one or two oxygen atoms, the alkyl substituted by a hydroxyl group, or interrupted by one or two oxygen atoms and substituted by a hydroxyl group, P is 2 or 3, and Q is an alkali metal, ammonium or N + salt (G?), In the formula DD and DD * m is 2 or 3, when m is 2, G is - (CH2CHR-0) rCH2CHR-, where r is 0 to 3, and R s is hydrogen or methyl, and when m is 3, G is glyceryl, in the formula EE and EE * G2 is -CN, -CONH2 or -COOG3 where G3 is hydrogen, alkyl of 1 to 18 carbon atoms or phenyl, X is an inorganic or organic anion, such as phosphate, phosphonate, carbonate, bicarbonate, nitrate , chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartrate, acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, tiglato, ascorbate, polymethacrylate , a nitrilotriacetic acid carboxylate, hydroxyethylenediaminetriacetic acid, ethylenediaminetetraacetic acid or diethylenetriaminpentaacetic acid, a diethylenetriaminepentamethylenephosphonate, an alkylsulfonate or an arylsulfonate, and where the total charge of the cations h is equal to the total charge of the anions j.
4. 4. A composition according to any of claims 3, characterized in that X is phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartrate, acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, tiglato, ascorbate, polymethacrylate, a nitrilotriacetic acid carboxylate, hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetraacetic acid or diethylenetriaminepentaacetic acid, a diethylenetriaminepentamethylenephosphonate, a alkylsulfonate or an arylsulfonate.
5. 5. A composition according to any of claims 1 to 3, characterized in that the compounds of component (b) are of the formulas A, A *, B, B *, C, C *, D, D *, Q, Q *, R, R *, S, S *, X, X *, Y, Y *, Z and Z *, where R is hydrogen, in the formula A and A * n is 1 or 2, when n is 1, Ri is hydrogen, alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, propargyl, glycidyl, alkyl of 2 to 20 carbon atoms interrupted by one to ten oxygen atoms, alkyl substituted by one to five hydroxyl groups or interrupted by the oxygen atoms and substituted by the hydroxyl groups, or Ri is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by -COOZ wherein Z is hydrogen or alkyl of 1 to 4 carbon atoms; carbon, when n is 2, Ri is alkylene of 1 to 8 carbon atoms, alkenylene of 4 to 8 carbon atoms, alkylene of 1 to 20 carbon atoms interrupted by one to ten oxygen atoms, substituted by one to five hydroxyl groups or interrupted by the oxygen atoms and substituted by the hydroxyl groups in the formula B and B * m is 1 or 2 when m is 1, R2 is alkyl of 1 to 4 carbon atoms or R is CH2 (OCH2CH2) nOCH3 where n is from 1 to 12, or 4 R 2 is phenyl, or phenyl substituted by one to three methyl groups, R is -NHR 3 where R 3 is alkyl of 1 to 4 carbon atoms or phenyl, or phenyl substituted by one or two groups methyl, when m is 2, R2 is alkylene of 1 to 8 carbon atoms, alkenylene of 4 to 8 carbon atoms, or R2 is -CH2 (OCH2CH2) nOCH2- where n is from 1 to 12, R2 is NHR4NH where R is 2 to 6 carbon atoms, aralkylene of 8 to 15 carbon atoms or arylene of 6 to 12 carbon atoms, R2 is -CO- or -NHCONH in formula C and C *, Rio is hydrogen or, alkanoyl of 1 to 3 carbon atoms, x is 1 or 2, when x is 1, Rn is hydrogen, alkyl of 1 to 6 carbon atoms or glycidyl, Rii is alkyl of 1 to 4 carbon atoms substituted by a carboxy group or by COOZ where Z is hydrogen or alkyl of 1 to 4 carbon atoms, when x is 2, Rn is alkylene of 1 to 6 carbon atoms, in formula D and D *, Rio is hydrogen, and is 1 or 2, R? is defined as R2 above, in the formula Y, Y *, Z and Z *, x is 1 or 2, when x is 1, Ri and 2 are independently alkyl of 1 to 4 carbon atoms, or Ri and R2 are together tetramethylene or pentamethylene, R2 is hydrogen or alkyl of 1 to 4 carbon atoms, the alkyl group substituted by a hydroxyl group, when x is 2, Ri is hydrogen, alkyl of 1 to 4 carbon atoms, the alkyl substituted by a group hydroxyl, R2 is alkylene of 2 to 6 carbon atoms, R3 is as defined above.
6. 6. A composition according to claim 5, characterized in that the compounds of component (b) are of the formulas A, A *, B, B *, C, C *, D, D *, Q, Q *, R and R *, wherein R is hydrogen, in the formula A and A *, h is 1, Ri is hydrogen, alkyl of 1 to 4 carbon atoms, glycidyl, alkyl of 2 to 4 carbon atoms interrupted by one or two oxygen atoms, the alkyl substituted by one or two hydroxyl groups or interrupted by the oxygen atoms and substituted by the hydroxyl groups, or Ri is alkyl of 1 to 4 carbon atoms substituted by -COOZ where Z is hydrogen or alkyl of 1 to 4 carbon atoms, in formula B and B *, m is 1 or 2, R2 is alkyl of 1 to 4 carbon atoms or R2 is CH2 (OCH_CH_) nOCH3 where n is 1 to 4, when m is 2, R2 is alkylene of 1 to 8 carbon atoms in formula C and C *, Rio is hydrogen or alkanoyl of 1 or 2 carbon atoms, x is 1 or 2, when x is 1, Rn is hydrogen, alkyl of 1 to 4 ato carbon or glycidyl, Rn is alkyl of 1 to 4 carbon atoms substituted by COOZ wherein Z is hydrogen or alkyl of 1 to 4 carbon atoms, when x is 2, Rn is alkylene of 1 to 6 carbon atoms in the formula D and D *, Rio is hydrogen, and is 1 or 2, R? 2 is defined as R2 above.
7. 7. A composition according to any one of claims 1 to 3, characterized in that the compounds of component (b) are selected from the group consisting of: bis (l-oxyl-2-, 2-6-6-tetramethyl-piperidine- sebacate) 4-ilo); bis (l-hydroxy-2, 2-6-6-tetramethylpiperidin-4-yl) sebacate; l-hydroxy-2, 2-6-6-tetramethyl-4-acetoxypiperidinium citrate; l-oxyl-2,2,6,6-tetramethyl-4-acetamidopiperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidine; l-hydroxy-2, 2-6-6-tetramethyl-4-acetamidopiperidinium bisulfate; l-oxyl-2, 2,6,6-tetramethyl-4-oxo-piperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxo-piperidine; l-hydroxy-2, 2, 6,6-tetramethyl-4-oxo-piperidinium acetate; l-oxyl-2,2,6,6-tetramethyl-4-methoxy-piperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-methoxy-piperidine; l-hydroxyl-2, 2,6,6,6-tetramethyl-4-methoxy-piperidinium acetate; l-oxyl-2, 2,6,6-tetramethyl-4-acetoxypiperidine; l-hydroxy-2, 2,6,6-tetramethyl-4-acetoxypiperidine; l-oxyl-2,2,6,6-tetramethyl-4-propoxy-piperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-propoxy-piperidinium acetate; l-hydroxy-2,2,6,6-tetramethyl-4-propoxy-piperidine; l-oxyl-2,2,6,6-tetramethyl-4- (2-hydroxy-4-oxapentoxy) piperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4- (2-hydroxy-4-oxapentoxy) piperidinium acetate; 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium chloride; 1-hydroxy-2-, 2-6-6-tetramethyl-4-hydroxypiperidinium acetate; 1- hydroxy-2-, 2-6-6-tetramethyl-4-hydroxypiperidinium bisulfate; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium citrate; bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium citrate); tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium citrate); tetra (1-hydroxy-2, 2,6,6-tetramethyl-4-hydroxypiperidinium) ethylenediaminetetraacetate; tetra (l-hydroxy-2, 2, 6, 6-tetramethyl-4-acetamidopiperidinium ethylenediaminetetraacetate); tetra (l-hydroxy-2, 2,6,6,6-tetramethyl-4-oxo-piperidinium) ethylenediaminetetraacetate; pentaethylenetriaminpentaacetate (1-hydroxy-2, 2,6,6-tetramethyl-4-hydroxy-piperidinium); penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium); penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6-tetramethyl-4-oxopiperidinium); tri (1-hydroxy-2, 2, 6,6-tetramethyl-4-hydroxypiperidinium nitrilotriacetate); tri (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamido-piperidinium nitrilotriacetate); tri (l-hydroxy-2, 2,6,6-tetramethyl-4-oxopiperidinium nitrilotriacetate); penta diethylenetriaminepentamethylenephosphonate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); penta diethylenetriaminepentamethylenephosphonate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium); and penta diethylenetriaminepentamethylenephosphonate (l-hydroxy-2,2,6,6-tetramethyl-4-oxopiperidinium).
8. 8. A composition according to any of claims 1 to 3, characterized in that the compounds of component (b) are selected from the group consisting of l-oxyl-2, 2,6,6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidine; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium chloride; l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium acetate; 1-hydroxy-2, 2-β-6-tetramethyl-4-hydroxypiperidinium bisulfate; 1-hydroxy-2,2-6-6-tetramethyl-4-hydroxypiperidinium citrate; bis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium citrate); tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium citrate); tetra (1-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium) ethylenediaminetetraacetate; tetra (l-hydroxy-2, 2,6,6-tetramethyl-4-acetamidopiperidinium) ethylenediaminetetraacetate; tetra (1-hydroxy-2, 2, 6, 6-tetramethyl-4-oxopiperidinium ethylenediaminetetraacetate); penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); penta diethylenetriaminpentaacetate (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamido-piperidinium); and penta diethylenetriaminpentaacetate (1-hydroxy-2,2,6,6-tetramethyl-4-oxopiperidinium).
9. 9. A composition according to any of claims 1 to 3, characterized in that the compounds of component (b) are selected from the group consisting of l-hydroxy-2-, 2-6-6-tetramethyl-4-hydroxypiperidinium citrate; bis (1-hydroxy-2, 2, 6,6-tetramethyl-4-hydroxypiperidinium citrate); tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium citrate); DTPA of l-hydroxy-2, 2-6-6-tetramethyl-4-hydroxypiperidinium; DTPA of bis (l-hydroxy-2,2,6,6-tetramethyl-4-hydroxy-piperidinium); DTPA of tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); DTPA tetrakis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-hydroxypiperidinium); DTPA of pentakis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium); L-hydroxy-2,2-6-6-tetramethyl-4-hydroxypiperidinium EDTA; DTA of bis (l-hydroxy2,2,6- bis (l-hydroxy2,6,6-tetramethyl-4-hydroxypiperidinium); tris (l-hydroxy-2,2,6,6- EDTA) tetramethyl-4-hydroxypiperidinium); tetrakis EDTA (1-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium); l-hydroxy-2, 2, 6,6-tetramethyl-4-oxo-citrate piperidinium; bis (l-hydroxy-2, 2,6,6-tetramethyl-4-oxo-piperidinium citrate); tris (l-hydroxy-2, 2, 6,6-tetramethyl-4-oxo-piperidinium citrate) ); DTPA of l-hydroxy-2, 2,6,6-tetramethyl-4-oxo-piperidinium; DTPA of bis (l-hydroxy-2, 2,6,6-tetramethyl-4-oxo-piperidinium); DTPA of tris (l-hydroxy-2, 2,6,6-tetramethyl-4-oxo-piperidinium); DTPA of tetrakis (1-hydroxy-2,2,6,6-tetramethyl-4-oxo-piperidinium); DTPA of pentakis (l-hydroxy-2, 2,6,6-tetramethyl-4-oxo-piperidinium); 1-hydroxy-2, 2, 6,6-tetramethyl-4-oxo-piperidinium EDTA; l-hydroxy-2, 2,6,6-tetramethyl-4-oxo-piperidinium); tris (1-hydroxy-2, 2, 6,6-tetramethyl-4-oxo-piperidinium) EDTA; tetrakis EDTA ( l-hydroxy-2, 2, 6, 6-tetramethyl-4-oxo-piperidinium); l-hydroxy-2, 2-6-6-tetramethyl-4-acetamidopiperidinium citrate; bis (l-hydroxy-2, 2, 6, 6-tetramethyl-4-acetamidopiperidinium citrate); tris (l-hydroxy-2,2,6,6-tetramethyl-4-acetamidopiperidinium citrate); DTPA of l-hydroxy-2, 2-6-6-tetramethyl-4-acetamidopiperidinium; DTPA of bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopipe-ridinium); Tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium) DTPA; DTPA tetrakis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetamidopiperidinium); DTPA of pentakis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-acetamidopiperidinium); EDTA of l-hydroxy-2, 2-6-6-tetramethyl-4-acetamidopiperidinium; EDTA from bis (l-hydroxy-2, 2,6,6-6-tetramethyl-4-acetamidopipe-ridinium); EDTA of tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-acetamidopiperidinium); EDTA of tetrakis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-hydroxypiperidinium); l-hydroxy-2,2-6-6-tetramethyl-4-acetoxypiperidinium citrate; bis (l-hydroxy-2,2,6,6-tetramethyl-4-acetoxypiperidinium citrate); tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-acetoxipiperidinium citrate); L-Hydroxy-2,2-6-6-tetramethyl-4-acetoxipiperidinium DTPA; DTPA of bis (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetoxypiperidinium); Tris (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetoxipiperidinium) DTPA; DTPA tetrakis (l-hydroxy-2, 2, 6, 6-tetramethyl-4-acetoxipiperidinium); DTPA of pentakis (1-hydroxy-2, 2, 6, 6-tetramethyl-4-acetoxipiperidinium); EDTA of l-hydroxy-2, 2-6-6-tetramethyl-4-acetoxypiperidinium; EDTA of bis (l-hydroxy-2, 2,6,6-tetramethyl-4-acetoxipiperidinium); EDTA of tris (l-hydroxy-2, 2, 6, 6-tetramethyl-4-acetoxipipe-ridinium) and tetrakis EDTA (l-hydroxy-2, 2,6,6,6-tetramethyl-4-acetoxipiperidinium).
10. 10. A composition according to any of claims 1 to 9, characterized in that (ci) is selected from butyl methoxydibenzoylmethane, ethylhexyl methoxydibenzoylmethane and isopropyl dibenzoylmethane 11. A composition according to claim 10, characterized in that (ci) is selected from 4-tert-butyl-4"-methoxydibenzoylmethane and 4-ethylhexyl-4'-methoxydibenzoylmethane 12. A composition according to claim 11, characterized in that (ci) is 1- (4-tert-butylphenyl). -3- (4-methoxyphenyl) propan-l, 3-dione. 13. A composition according to any one of claims 1 to 9, characterized in that (c2) is selected from octylmethoxycinnamate (2-ethylhexyl ester of 4-methoxycinnamic acid), from diethanolamine methoxycinnamate (diethanolamine salt of 4-methoxycinnamic acid), isoamyl methoxycinnamate (2-isoamyl ester of 4-ethoxycinnamic acid), 2,5-diisopropyl methyl cinnamate and an amido derivative of cinnamic acid. 14. A composition according to claim 13, characterized in that (c2) is the octylmethoxycinnamate. 15. A composition according to any of claims 1 to 9, characterized in that (c3) is selected from camphor of 4-methyl-benzylidene (3- (4'-methyl) benzylidene-bornan-2-one), of camphor of 3-benzylidene (3-benzylidene-boronano-2-one), of polyacrylamidomethylbenzylidene camphor. { N- [2 (and 4) -2-oxiborn-3-ylidene-methyl) benzyl] acrylamide polymer} , of trimonium-benzylidene camphor sulfate [3- (4'-trimethylammonium) -benzylidene-boronan-2-one methylsulfate], of terephthalidene dialkisphosphonic acid. { 3,3 '- (1,4-phenylenedimetin) -bis (7,7-dimethyl-2-oxo-bicyclo [2, 2, 1] heptan-1-methanesulfonic acid} or its salts, and camphor sulfonic acid of benzylidene [3- (4 '-sulfo) benzylidenbornan-2-one] or its salts 16. A composition according to claim 15, characterized in that (c3) is 4-methyl-benzylidene camphor. according to any of claims 1 to 9, characterized in that (c4) is selected from triazone of diethylhexylbutamido and of triazone of ethylhexyl 18. A composition according to claim 17, characterized in that (c4) is triazone of ethylhexyl. A composition according to any of claims 1 to 18, characterized by further comprising: (d) at least one compound selected from the group consisting of antioxidants, tocopherol, tocopherol acetate, hindered amine light stabilizers, complexes, optical brighteners, south Factants and polyorganosiloxanes. 20. A composition according to any of claims 1 to 19, characterized in that the compounds of the components (b) and (c) are present in household or body care products in a concentration of about 5 to approximately 10,000 PPM, based on the total formulation. 21. A composition according to any of claims 1 to 20, characterized in that the quotient of component (b) to component (c) is from 1: 1000 to 1000: 1. 22. A composition according to claim 21, characterized in that the ratio of component (b) to component (c) is from 1: 100 to 100: 1. 23. A composition according to any of claims 1 to 22, characterized in that the body care product is selected from skin care products, bath and shower products, liquid soaps, bar soaps , of preparations containing fragrances and odoriferous substances, of hair care products, of toothpastes, of deodorant and antiperspirant preparations, of decorative preparations, of formulations for protection against light and of preparations containing active ingredients. 24. A composition according to claim 23, characterized in that the skin care products are selected from body lotions, body gels, treatment creams, ointments for the protection of the skin, preparation for shaving and powder for the skin 25. A composition according to claim 23, characterized in that the preparations containing fragrances and olfactory substances are selected from essences, perfumes, toilet waters and shaving lotions. 26. A composition according to claim 23, characterized in that the hair care products are selected from shampoos., hair conditioners, 2 in 1 conditioners, rinse and leave conditioners, hair styling and styling agents, permanent agents, relaxers, hair sprays and lacquers, hair dyeing systems, hair dyeing systems permanent, semi-permanent and temporary, and agents that whiten the hair. A composition according to claim 23, characterized in that the decorative preparations are selected from lipsticks, nail varnishes, eye shadows, mascaras, wet and dry makeup, rouge, powders, depilatory agents, care products of the sun and for after the sun. 28. A composition according to claim 23, characterized in that the preparations containing active ingredients are selected from hormonal preparations, vitamin preparations, preparations of plant extracts and antibacterial preparations. 29. A composition according to any of claims 1 to 22, characterized in that the product for the home is selected from cleaning and treatment agents for the home. A composition according to claim 28, characterized in that the cleaning and household treatment agents are selected from laundry detergents and fabric softeners, fabric care products not based on detergents, liquid cleaning and scrubbing agents. , detergents for glass, neutral cleaners (multiple-use cleaners), acidic cleaners for the home (bathroom), bathroom cleaners, detergents, rinsing and dishwashing, kitchen and oven cleaners, rinsing agents, detergents dishwasher, shoe grease, grease wax, detergent and floor polishers, metal, glass and ceramic cleaners, textile care products, carpet cleaner and carpet shampoo, mildew remover, color and stains (salt remover) of stains), furniture and multipurpose greases and disinfectants leather and vinyl (aerosols for leather and vinyl) and environmental deodorants It is solid and liquid. 31. A method for stabilizing a body care product, a product for the home, a textile or a fabric, characterized in that it comprises incorporating therein or applying to them at least one compound of component (b) and at least one compound of component (c) according to claim 1. 32. n method according to claim 31, characterized in that at least one compound of the formulas A to EE and A * to EE * (= component (b)) according to claim 3 and at least one compound of component (c). 33. A method according to claim 32, characterized in that a dibenzoylmethane derivative (= component Ci) is used as the component (c). 34. A method according to claim 33, characterized in that l- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propan-l, 3-dione is used as the component (ci). 35. A method for stabilizing a body care product, a household product, a textile or a fabric, each of which contains a dye, characterized in that it comprises incorporating therein or applying to them at least one compound of the formulas (I), (II) and (III) (= component (b)) and at least one compound of component (c) according to claim 1. 36. A method for stabilizing a product for body care , a product for the home, a textile or a fabric, each of which contains a dye, characterized in that it comprises incorporating in them or applying at least one compound of the formulas A to EE and A * to EE * and so minus a compound of component (c) according to claim 3. 37. A method according to claim 36, characterized in that a dibenzoylmethane derivative (c component ci) is used as the component (c). 38. A method according to claim 37, characterized in that l- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propan-l, 3-dione is used as the component (ci). 39. A method for stabilizing an active ingredient selected from vitamins, carotenoids, plant extracts, antibacterials, phenols, polyphenols or flavonoids characterized in that the method comprises applying to them at least one compound of component (b) and at least one compound of the component (c). 40. A method for stabilizing a compound according to component (c), which comprises the application to this compound of at least one compound of component (b) according to claim 1.