MXPA05008346A - Control de tamano y morfologia de particulas en polimeros de vinilideno-aromatico moficados con hule. - Google Patents

Control de tamano y morfologia de particulas en polimeros de vinilideno-aromatico moficados con hule.

Info

Publication number
MXPA05008346A
MXPA05008346A MXPA05008346A MXPA05008346A MXPA05008346A MX PA05008346 A MXPA05008346 A MX PA05008346A MX PA05008346 A MXPA05008346 A MX PA05008346A MX PA05008346 A MXPA05008346 A MX PA05008346A MX PA05008346 A MXPA05008346 A MX PA05008346A
Authority
MX
Mexico
Prior art keywords
particle size
rubber modified
morphology control
aromatic polymers
monovinylidene aromatic
Prior art date
Application number
MXPA05008346A
Other languages
English (en)
Inventor
Bouquet Gilbert
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of MXPA05008346A publication Critical patent/MXPA05008346A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

La presente invencion es un proceso de polimerizacion en masa/solucion para producir un polimero modificado con hule que tiene control del tamano, la distribucion y la morfologia de las particulas de hule, a una velocidad incrementada, utilizando hules dienicos funcionalizados; donde la funcionalidad permite la polimerizacion con radical controlada.
MXPA05008346A 2003-02-05 2004-01-15 Control de tamano y morfologia de particulas en polimeros de vinilideno-aromatico moficados con hule. MXPA05008346A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US44572903P 2003-02-05 2003-02-05
PCT/US2004/000962 WO2004072136A1 (en) 2003-02-05 2004-01-15 Particle size and morphology control in rubber modified monovinylidene aromatic polymers

Publications (1)

Publication Number Publication Date
MXPA05008346A true MXPA05008346A (es) 2005-11-04

Family

ID=32869412

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA05008346A MXPA05008346A (es) 2003-02-05 2004-01-15 Control de tamano y morfologia de particulas en polimeros de vinilideno-aromatico moficados con hule.

Country Status (10)

Country Link
US (1) US20060058465A1 (es)
EP (1) EP1592722B1 (es)
JP (1) JP2006517002A (es)
KR (1) KR20050099528A (es)
CN (1) CN1795218A (es)
AT (1) ATE481431T1 (es)
CA (1) CA2515194A1 (es)
DE (1) DE602004029138D1 (es)
MX (1) MXPA05008346A (es)
WO (1) WO2004072136A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1785437B1 (en) * 2004-08-31 2009-07-29 Asahi Kasei Chemicals Corporation Impact-resistant vinylaromatic hydrocarbon resin
US8716409B2 (en) * 2006-12-29 2014-05-06 Firestone Polymers, Llc Carboxylate terminated polymers and their use in impact-modified plastics
CN104558429B (zh) * 2013-10-18 2017-11-07 中国石油化工股份有限公司 聚苯乙烯组合物生产方法及由此得到的聚苯乙烯组合物
TW202330677A (zh) 2021-12-10 2023-08-01 義大利商佛沙里斯股份有限公司 橡膠強化的乙烯芳香族(共)聚合物及其製備方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3123655A (en) * 1964-03-03 Process for extruding high impact thermoplastic
US2646418A (en) * 1951-05-25 1953-07-21 Dow Chemical Co Process for polymerizing monovinyl aromatic compounds with rubber
US2727884A (en) * 1953-04-13 1955-12-20 Dow Chemical Co Process of mass polymerization in vertical unmixed strata
US3346520A (en) * 1965-01-25 1967-10-10 Dow Chemical Co Process for making high impact styrene polymers in aqueous suspension
US3639522A (en) * 1969-06-04 1972-02-01 Dow Chemical Co Self-extinguishing high impact styrene polymers
US4221883A (en) * 1976-10-18 1980-09-09 The Dow Chemical Company Impact polymer process
US4146589A (en) * 1978-05-19 1979-03-27 Monsanto Company Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution
US4311819A (en) * 1979-07-18 1982-01-19 The Dow Chemical Company Preparation of alkenyl aromatic monomer butadiene rubber
US4409369A (en) * 1980-03-03 1983-10-11 The Dow Chemical Company Transparent impact resin and process for the preparation thereof
DE3486145T2 (de) * 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
US4572819A (en) * 1983-08-24 1986-02-25 The Dow Chemical Company Apparatus for anionic polymerization wherein the molecular weight of the polymer is closely controlled
US4585825A (en) * 1983-09-30 1986-04-29 The Dow Chemical Company Monovinylidene aromatic polymer resins having added amounts of high molecular weight polymer
US4666987A (en) * 1985-02-22 1987-05-19 The Dow Chemical Company In-mold polymerization of vinyl aromatic compound
JPS63278921A (ja) * 1987-05-12 1988-11-16 Nippon Erasutomaa Kk ゴムで変性されたスチレン系樹脂とその製造方法
GB8918157D0 (en) * 1989-08-09 1989-09-20 Dow Benelux A process for the preparation of rubber-reinforced monovinylidene aromatic polymers
FR2730241B1 (fr) * 1995-02-07 1997-02-28 Atofina Procede de fabrication d'une composition comprenant un polymere vinylaromatique et un caoutchouc par polymerisation en presence d'un radical libre stable
PL329115A1 (en) * 1996-03-29 1999-03-15 Dow Chemical Co In situ production of a block copolymer during polymerisation of an aromatic vinyl monomer
FR2768739B1 (fr) * 1997-09-19 2004-08-06 Atochem Elf Sa Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable
FR2769316B1 (fr) * 1997-10-03 1999-12-03 Atochem Elf Sa Copolymere greffe par polymerisation radicalaire en presence de radicaux stables, sa preparation et ses applications
FR2779437B1 (fr) * 1998-06-03 2004-10-15 Atochem Elf Sa Polymere vinylaromatique choc par polymerisation d'un monomere vinylaromatique en presence d'un radical libre stable et d'un amorceur de polymerisation
AU760128B2 (en) * 1998-09-03 2003-05-08 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
FR2791060A1 (fr) * 1999-03-18 2000-09-22 Atochem Elf Sa Procede de preparation d'un caoutchouc porteur de radical libre stable et utilisation dudit caoutchouc porteur pour la preparation d'un polymere vinylaromatique choc

Also Published As

Publication number Publication date
KR20050099528A (ko) 2005-10-13
EP1592722A1 (en) 2005-11-09
JP2006517002A (ja) 2006-07-13
DE602004029138D1 (de) 2010-10-28
ATE481431T1 (de) 2010-10-15
WO2004072136A8 (en) 2006-03-30
CA2515194A1 (en) 2004-08-26
EP1592722B1 (en) 2010-09-15
WO2004072136A1 (en) 2004-08-26
US20060058465A1 (en) 2006-03-16
CN1795218A (zh) 2006-06-28

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