MX9605852A - Composicion catalitica y proceso para seleccionar la hidrogenacion de diolefinas. - Google Patents

Composicion catalitica y proceso para seleccionar la hidrogenacion de diolefinas.

Info

Publication number
MX9605852A
MX9605852A MX9605852A MX9605852A MX9605852A MX 9605852 A MX9605852 A MX 9605852A MX 9605852 A MX9605852 A MX 9605852A MX 9605852 A MX9605852 A MX 9605852A MX 9605852 A MX9605852 A MX 9605852A
Authority
MX
Mexico
Prior art keywords
palladium
carbon atoms
accordance
catalyst composition
per molecule
Prior art date
Application number
MX9605852A
Other languages
English (en)
Other versions
MXPA96005852A (es
Inventor
Tin-Tack Peter Cheung
Marvin Merrill Johnson
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of MX9605852A publication Critical patent/MX9605852A/es
Publication of MXPA96005852A publication Critical patent/MXPA96005852A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Se describe una composicion catalítica, la cual consiste esencialmente de (a) por lo menos un material que contiene paladio, seleccionado del grupo que consiste de metal de paladio y oxidos de paladio, (b) por lo menos un yoduro de metal alcalino y (c) por lo menos un material de soporte inorgánico. En una modalidad preferida, el yoduro de metal alcalino es yoduro de potasio y el soporte inorgánico es alumina. También se describe un proceso mejorador para hidrogenar selectivamente las diolefinas que contienen 3-12 átomos de carbono por molécula, con gas de hidrogeno, a las correspondientes monoolefinas que contienen 3-12átomos de carbono por molécula, que se lleva a cabo con la composicion catalítica de esta invencion.
MXPA/A/1996/005852A 1996-02-01 1996-11-26 Composicion catalitica y proceso para seleccionarla hidrogenacion de diolefinas MXPA96005852A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US59532696A 1996-02-01 1996-02-01
US08/595,326 1996-02-01

Publications (2)

Publication Number Publication Date
MX9605852A true MX9605852A (es) 1998-05-31
MXPA96005852A MXPA96005852A (es) 1998-10-23

Family

ID=

Also Published As

Publication number Publication date
US5866735A (en) 1999-02-02
IN190085B (es) 2003-06-07
JPH09220472A (ja) 1997-08-26
AR004614A1 (es) 1998-12-16
KR970061351A (ko) 1997-09-12
AU692723B2 (en) 1998-06-11
TW400374B (en) 2000-08-01
DE69715062T2 (de) 2003-01-02
JP3934715B2 (ja) 2007-06-20
ES2183029T3 (es) 2003-03-16
EP0792685A1 (en) 1997-09-03
ID15801A (id) 1997-08-07
DE69715062D1 (de) 2002-10-10
CA2196349A1 (en) 1997-08-02
AU7049996A (en) 1997-08-07
CA2196349C (en) 2000-10-31
SG76488A1 (en) 2000-11-21
BR9605736A (pt) 1998-08-25
MY132592A (en) 2007-10-31
EP0792685B1 (en) 2002-09-04

Similar Documents

Publication Publication Date Title
MY132592A (en) Catalyst composition and process for selecting hydrogenation of diolefins
MY121137A (en) Selective hydrogenation process and catalyst therefor
MY129216A (en) Hydrogenation process and catalyst therefor.
DE3663626D1 (en) Co hydrogenation with molybdenum on wide-pore carbon catalysts
DE69942646D1 (de) Zumindest eisen, alkalimetall und edelmetall enthaltende dehydrierungskatalysatoren
MY115733A (en) Catalyst composition useful for hydrogenation of alkynes
PT1086745E (pt) Catalisadores de leito fixo
MY122933A (en) Process for selective hydrogenation of acetylene in an ethylene purification process
MXPA04001915A (es) Catalizador y proceso de isomerizacion de alta actividad.
MY121112A (en) Raney iron catalyst and a process for hydrogenating organic compounds using said catalyst.
MY137042A (en) Hydrogenation palladium-silver catalyst and methods
KR960029295A (ko) 알킨을 선택적으로 수소첨가시키는 방법
BR8605505A (pt) Catalisador,processo para a preparacao de um catalisador e processo para a preparacao de hidrocarbonetos por contactacao de um mistura de monoxido de carbono e hidrogenio
ES8600081A1 (es) Procedimiento para la separacion de alquinos de corrientes hidrocarbonadas que contienen 1,3-butadieno
WO2002002229A3 (en) Fischer-tropsch processes and catalysts using aluminum borate supports
CA2326538A1 (en) Dehydrogenation catalysts comprising at least iron, alkali metal and a noble metal
EP0233642A3 (en) Process for hydrogenation of organic compounds
GR3023727T3 (en) Epoxidation catalyst
DK0964745T3 (da) Fremgangsmåde til hydrogenering, hydroisomerisering og/eller hydroafsvovling af et med svovl kontamineret fødemateriale
MY114787A (en) Method of preparing a catalyst composition for isomerizing hydrocarbons
AU1749788A (en) Process for the selective reduction of 2-quinoxalines-4-oxides
ES8702480A1 (es) Un procedimiento para hidrorrefinar una corriente de alimentacion que contiene hidrocarburos
KR840007433A (ko) 열분해 가솔린 중 디엔류를 선택적으로 수호하는 방법
FR2720956B1 (fr) Catalyseur d'hydrogénation contenant du palladium, au moins un élément du groupe IB et au moins un métal alcalin et procédé d'hydrogénation catalytique utilisant ce catalyseur.
DE59910761D1 (de) Verfahren zur hydrierung von ungesättigten heterocyclischen verbindungen