MX9306653A - Proceso para recuperar azufre e hidrogeno a partir de sulfuro de hidrogeno. - Google Patents
Proceso para recuperar azufre e hidrogeno a partir de sulfuro de hidrogeno.Info
- Publication number
- MX9306653A MX9306653A MX9306653A MX9306653A MX9306653A MX 9306653 A MX9306653 A MX 9306653A MX 9306653 A MX9306653 A MX 9306653A MX 9306653 A MX9306653 A MX 9306653A MX 9306653 A MX9306653 A MX 9306653A
- Authority
- MX
- Mexico
- Prior art keywords
- hydrogen
- sulfur
- anthrahydroquinone
- anthraquinone
- hydrogen sulfide
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C46/00—Preparation of quinones
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Un proceso para convertir ácido sulfhídrico que esta contenido en una corriente gaseosa de alimentación en azufre elemental e hidrogeno. El proceso comprende el contacto de la corriente gaseosa de alimentación con un solvente polar orgánico que tiene una antraquinona, y opcionalmente un agente acomplejante, disuelto en la misma, reaccionando el ácido sulfhídrico gaseosos y la antraquinona para producir azufre y una antrahidroquinona en el solvente, y deshidrogenando catalíticamente la antrahidroquinona a antraquinona e hidrógeno. De conformidad con la presente invención, una cantidad relativamente pequeña de agua se añade al solvente polar orgánico incrementando por lo mismo el azufre elemental que se precipita y se recupera así. La adición de agua antes o durante la producción de azufre incrementa también la selectividad del producto del hidrogeno en la subsecuente deshidrogenación de la antrahidroquinona.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/983,936 US5334363A (en) | 1992-12-01 | 1992-12-01 | Process for recovering sulfur and hydrogen from hydrogen sulfide |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9306653A true MX9306653A (es) | 1994-06-30 |
Family
ID=25530194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9306653A MX9306653A (es) | 1992-12-01 | 1993-10-26 | Proceso para recuperar azufre e hidrogeno a partir de sulfuro de hidrogeno. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5334363A (es) |
EP (1) | EP0672019B1 (es) |
AU (1) | AU5133393A (es) |
CA (1) | CA2153669C (es) |
DE (1) | DE69315857T2 (es) |
MX (1) | MX9306653A (es) |
RU (1) | RU2110469C1 (es) |
SG (1) | SG41936A1 (es) |
WO (1) | WO1994012431A1 (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0731782B1 (en) * | 1994-09-29 | 1999-08-25 | Marathon Oil Company | Process for catalytically dehydrogenating anthrahydroquinone |
WO1996027425A1 (en) * | 1995-03-06 | 1996-09-12 | Marathon Oil Company | Hydrogen sulfide conversion process |
US5736117A (en) * | 1995-09-29 | 1998-04-07 | Marathon Oil Company | Sulfur debonding agent enhancing sulfur recovery from a hydrogen sulfide conversion process |
AU7117696A (en) * | 1995-11-14 | 1997-06-05 | Marathon Oil Company | Gas treating process |
AU1022797A (en) * | 1996-02-14 | 1997-09-02 | Marathon Oil Company | Process for removing sulfur as a liquid during gas treating |
US5733516A (en) * | 1996-09-09 | 1998-03-31 | Gas Research Institute | Process for removal of hydrogen sulfide from a gas stream |
US7718152B2 (en) * | 2007-04-24 | 2010-05-18 | Swapsol Corp. | Process and system for destroying carbonaceous materials and composition and system thereof |
MX2010003050A (es) * | 2007-09-20 | 2010-05-27 | Swapsol Corp | Procedimiento para destruir materiales carbonosos y composicion y sistema de los mismos. |
WO2009132031A2 (en) * | 2008-04-21 | 2009-10-29 | Swapsol Corp. | Hydrogen sulfide conversion to hydrogen |
RU2445255C2 (ru) * | 2010-03-12 | 2012-03-20 | Закрытое акционерное общество Производственная компания "Лаборатория импульсной техники" (ЗАО ПК "ЛИТ") | Способ утилизации сероводорода, содержащегося в газах |
WO2016201585A1 (en) | 2015-06-19 | 2016-12-22 | Bio-H2-Gen Inc. | Method for producing hydrogen gas from aqueous hydrogen sulphide |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL130370C (es) * | 1958-11-17 | |||
US3923966A (en) * | 1973-11-21 | 1975-12-02 | Du Pont | Direct manufacture of hydrogen peroxide from hydrogen sulfide |
JPS5422790B2 (es) * | 1974-05-13 | 1979-08-09 | ||
JPS5192828A (en) * | 1975-02-13 | 1976-08-14 | 11 aminoantorakinonno kangenseiseiho | |
US4355012A (en) * | 1975-09-12 | 1982-10-19 | American Color & Chemical Corporation | Mixed anthraquinonedisulfonic acids |
US4100256A (en) * | 1977-03-18 | 1978-07-11 | The Dow Chemical Company | Hydrolysis of carbon oxysulfide |
US4176125A (en) * | 1977-11-17 | 1979-11-27 | Kawasaki Kasei Chemicals Ltd. | Process for producing 1,4-dihydroanthraquinone |
US4592905A (en) * | 1985-01-14 | 1986-06-03 | Marathon Oil Company | Conversion of hydrogen sulfide to sulfur and hydrogen |
US4581128A (en) * | 1985-01-14 | 1986-04-08 | Marathon Oil Company | Hydrocarbon desulfurization process |
US4847429A (en) * | 1987-08-03 | 1989-07-11 | Eastman Kodak Company | Synthesis of phenylhydroquinones |
US5180572A (en) * | 1991-11-19 | 1993-01-19 | Marathon Oil Company | Conversion of hydrogen sulfide to sulfur and hydrogen |
-
1992
- 1992-12-01 US US07/983,936 patent/US5334363A/en not_active Expired - Lifetime
-
1993
- 1993-09-20 CA CA002153669A patent/CA2153669C/en not_active Expired - Fee Related
- 1993-09-20 EP EP93922273A patent/EP0672019B1/en not_active Expired - Lifetime
- 1993-09-20 WO PCT/US1993/008916 patent/WO1994012431A1/en active IP Right Grant
- 1993-09-20 SG SG1995001318A patent/SG41936A1/en unknown
- 1993-09-20 AU AU51333/93A patent/AU5133393A/en not_active Abandoned
- 1993-09-20 RU RU95117119A patent/RU2110469C1/ru active
- 1993-09-20 DE DE69315857T patent/DE69315857T2/de not_active Expired - Fee Related
- 1993-10-26 MX MX9306653A patent/MX9306653A/es not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0672019B1 (en) | 1997-12-17 |
EP0672019A1 (en) | 1995-09-20 |
AU5133393A (en) | 1994-06-22 |
DE69315857T2 (de) | 1998-07-16 |
SG41936A1 (en) | 1997-08-15 |
DE69315857D1 (de) | 1998-01-29 |
RU2110469C1 (ru) | 1998-05-10 |
US5334363A (en) | 1994-08-02 |
CA2153669A1 (en) | 1994-06-09 |
CA2153669C (en) | 1999-02-02 |
WO1994012431A1 (en) | 1994-06-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration | ||
MM | Annulment or lapse due to non-payment of fees |