MX359965B - Proceso y catalizador para mejorar gasolina. - Google Patents
Proceso y catalizador para mejorar gasolina.Info
- Publication number
- MX359965B MX359965B MX2014013647A MX2014013647A MX359965B MX 359965 B MX359965 B MX 359965B MX 2014013647 A MX2014013647 A MX 2014013647A MX 2014013647 A MX2014013647 A MX 2014013647A MX 359965 B MX359965 B MX 359965B
- Authority
- MX
- Mexico
- Prior art keywords
- tetramethylbenzene
- catalyst
- durene
- trimethylbenzene
- gasoline
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/043—Sulfides with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
- C07C2529/46—Iron group metals or copper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un proceso y catalizador para mejorar la gasolina que comprende dureno (1,2,4,5-tetrametilbenceno) y pseudocumeno, el proceso comprende la hidroisomerización de dureno (1,2,4,5-tetrametilbence no) y pseudocumeno (1,2,4-trimetilbenceno) contenidos en la gasolina en presencia de un catalizador que comprende un metal base sulfurado que es soportado sobre un portador ácido, convirtiendo de ese modo el dureno (1,2,4,5-tetrametilbenceno) a isodureno (1,2,4,5-tetrametilbenceno) y prehniteno (1,2,3,4-tetrametilbenceno) y convirtiendo el pseudocumeno (1,2,4-trimetilbenceno) a mesitileno (1,3,5-trimetilbenceno).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA201270284 | 2012-05-29 | ||
PCT/EP2013/055758 WO2013178375A1 (en) | 2012-05-29 | 2013-03-20 | Process and catalyst for upgrading gasoline |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014013647A MX2014013647A (es) | 2015-02-05 |
MX359965B true MX359965B (es) | 2018-10-18 |
Family
ID=47901124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014013647A MX359965B (es) | 2012-05-29 | 2013-03-20 | Proceso y catalizador para mejorar gasolina. |
Country Status (10)
Country | Link |
---|---|
US (1) | US10150714B2 (es) |
CN (1) | CN104334693B (es) |
AR (1) | AR091162A1 (es) |
AU (1) | AU2013269955B2 (es) |
BR (1) | BR112014029831A2 (es) |
CA (1) | CA2873955C (es) |
EA (1) | EA030888B1 (es) |
MX (1) | MX359965B (es) |
WO (1) | WO2013178375A1 (es) |
ZA (1) | ZA201408987B (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103864814B (zh) * | 2014-02-24 | 2016-06-22 | 中国海洋石油总公司 | 一种由甲醇制汽油合成油中制备均苯四甲酐的方法 |
CN104498112B (zh) * | 2014-12-25 | 2016-07-06 | 山西华顿实业有限公司 | M85甲醇汽油复合添加剂 |
WO2016174145A1 (en) * | 2015-04-28 | 2016-11-03 | Haldor Topsøe A/S | Heavy gasoline separation |
WO2021204621A1 (en) | 2020-04-06 | 2021-10-14 | Haldor Topsøe A/S | Selective production of light synthetic gasoline |
WO2022117644A1 (en) | 2020-12-01 | 2022-06-09 | Topsoe A/S | Selective and flexible production of synthetic gasoline |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3269937A (en) * | 1962-12-26 | 1966-08-30 | Shell Oil Co | Hydroisomerization process |
US3776968A (en) | 1968-08-05 | 1973-12-04 | Sun Oil Co | Catalytic conversion of polycyclic aromatic hydrocarbons in the pres-ence of hydrogen |
US3562342A (en) * | 1968-11-27 | 1971-02-09 | Texaco Inc | Isomerization of alkyl aromatics |
US3619408A (en) * | 1969-09-19 | 1971-11-09 | Phillips Petroleum Co | Hydroisomerization of motor fuel stocks |
US3912659A (en) * | 1972-05-15 | 1975-10-14 | Texaco Inc | Catalyst for conversion of alkylaromatics |
DE2225655A1 (de) | 1972-05-26 | 1973-12-06 | Kali Chemie Ag | Verfahren zur herstellung eines nickeltraegerkatalysators |
US4127471A (en) * | 1977-07-28 | 1978-11-28 | Texaco Inc. | Hydrocracking alkylaromatic-containing hydrocarbons at mild cracking conditions and then subjecting the alkylaromatic hydrocarbon to alkyl transfer |
US4384471A (en) * | 1980-12-10 | 1983-05-24 | Engelhard Minerals & Chemicals Corporation | Chromatographic analysis of hydrocarbon mixtures |
US4304951A (en) * | 1981-01-14 | 1981-12-08 | Mobil Oil Corporation | Hydrotreating of bottoms fractions resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate |
US4387261A (en) * | 1982-04-09 | 1983-06-07 | Mobil Oil Corporation | Treatment of effluent resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate |
US4508836A (en) * | 1982-07-27 | 1985-04-02 | Mobil Oil Corporation | Catalytic conversion process for aromatic feedstocks with hydrogen regeneration of coke-selectivated zeolite catalyst |
US5004854A (en) * | 1986-12-04 | 1991-04-02 | Mobil Oil Corp. | Pseudocumene and mesitylene production and coproduction thereof with xylene |
US5576256A (en) * | 1994-05-23 | 1996-11-19 | Intevep, S.A. | Hydroprocessing scheme for production of premium isomerized light gasoline |
RU2011106922A (ru) * | 2008-07-25 | 2012-08-27 | Конокофиллипс Компани (Us) | Улучшенный способ превращения исходного кислородсодержащего продукта в высокооктановый бензин |
RU2495082C2 (ru) * | 2008-09-10 | 2013-10-10 | Хальдор Топсеэ А/С | Способ и катализатор гидропереработки |
US8686206B2 (en) * | 2010-11-09 | 2014-04-01 | Primus Green Energy Inc. | Single loop multistage fuel production |
-
2013
- 2013-03-20 US US14/403,274 patent/US10150714B2/en active Active
- 2013-03-20 EA EA201492151A patent/EA030888B1/ru not_active IP Right Cessation
- 2013-03-20 MX MX2014013647A patent/MX359965B/es active IP Right Grant
- 2013-03-20 CA CA2873955A patent/CA2873955C/en active Active
- 2013-03-20 AU AU2013269955A patent/AU2013269955B2/en active Active
- 2013-03-20 BR BR112014029831A patent/BR112014029831A2/pt not_active Application Discontinuation
- 2013-03-20 CN CN201380028173.8A patent/CN104334693B/zh active Active
- 2013-03-20 WO PCT/EP2013/055758 patent/WO2013178375A1/en active Application Filing
- 2013-05-27 AR ARP130101832 patent/AR091162A1/es active IP Right Grant
-
2014
- 2014-12-08 ZA ZA2014/08987A patent/ZA201408987B/en unknown
Also Published As
Publication number | Publication date |
---|---|
BR112014029831A2 (pt) | 2017-06-27 |
CA2873955A1 (en) | 2013-12-05 |
CA2873955C (en) | 2020-12-29 |
CN104334693B (zh) | 2016-06-29 |
WO2013178375A1 (en) | 2013-12-05 |
ZA201408987B (en) | 2017-05-31 |
CN104334693A (zh) | 2015-02-04 |
AU2013269955B2 (en) | 2017-12-07 |
EA030888B1 (ru) | 2018-10-31 |
AR091162A1 (es) | 2015-01-14 |
EA201492151A1 (ru) | 2015-09-30 |
AU2013269955A1 (en) | 2014-12-18 |
US20150094510A1 (en) | 2015-04-02 |
MX2014013647A (es) | 2015-02-05 |
US10150714B2 (en) | 2018-12-11 |
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Legal Events
Date | Code | Title | Description |
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FG | Grant or registration |