MX353038B - Process for producing fluorine-containing olefin. - Google Patents
Process for producing fluorine-containing olefin.Info
- Publication number
- MX353038B MX353038B MX2014008825A MX2014008825A MX353038B MX 353038 B MX353038 B MX 353038B MX 2014008825 A MX2014008825 A MX 2014008825A MX 2014008825 A MX2014008825 A MX 2014008825A MX 353038 B MX353038 B MX 353038B
- Authority
- MX
- Mexico
- Prior art keywords
- group
- containing olefin
- producing fluorine
- chlorine
- chromium oxide
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title 1
- 229910052731 fluorine Inorganic materials 0.000 title 1
- 239000011737 fluorine Substances 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910021478 group 5 element Inorganic materials 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 abstract 1
- 239000012025 fluorinating agent Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
- B01J37/26—Fluorinating
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B01J35/30—
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Abstract
This invention provides a process for producing a fluoroolefin comprising reacting, in a vapor phase, a fluorinating agent and a chlorine-containing alkene or a chlorine-containing alkane in the presence of at least one catalyst selected from the group consisting of chromium oxide containing a Group 5 element and fluorinated chromium oxide containing a Group 5 element. According to the process of the present invention, the target fluoroolefin can be obtained with high starting material conversion and good selectivity.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261590500P | 2012-01-25 | 2012-01-25 | |
US201261653006P | 2012-05-30 | 2012-05-30 | |
US201261703951P | 2012-09-21 | 2012-09-21 | |
PCT/JP2013/052120 WO2013111911A1 (en) | 2012-01-25 | 2013-01-24 | Process for producing fluorine-containing olefin |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014008825A MX2014008825A (en) | 2014-10-24 |
MX353038B true MX353038B (en) | 2017-12-18 |
Family
ID=47714491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014008825A MX353038B (en) | 2012-01-25 | 2013-01-24 | Process for producing fluorine-containing olefin. |
Country Status (8)
Country | Link |
---|---|
US (1) | US9452958B2 (en) |
EP (1) | EP2807137B1 (en) |
JP (1) | JP5888436B2 (en) |
KR (1) | KR101643487B1 (en) |
CN (1) | CN104105681B (en) |
ES (1) | ES2625204T3 (en) |
MX (1) | MX353038B (en) |
WO (1) | WO2013111911A1 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106458795B (en) * | 2014-05-16 | 2019-12-27 | 大金工业株式会社 | Method for producing composition containing 1, 2-dichloro-3, 3, 3-trifluoropropene (HCFO-1223xd) and/or 1,1, 2-trichloro-3, 3, 3-trifluoropropene (CFO-1213xa) |
MX2017014398A (en) | 2015-05-21 | 2018-03-23 | Chemours Co Fc Llc | HYDROFLUORINATION OF 1233xf TO 244bb BY SbF5. |
JP6328589B2 (en) * | 2015-05-29 | 2018-05-23 | ダイキン工業株式会社 | Method for producing fluorine-containing olefin |
JP6623561B2 (en) * | 2015-05-29 | 2019-12-25 | ダイキン工業株式会社 | Method for producing fluorine-containing olefin |
GB2559056B (en) * | 2015-07-17 | 2019-09-11 | Mexichem Fluor Sa De Cv | Process for preparing 245cb and 1234yf from 243db |
EP3412645B1 (en) * | 2016-02-03 | 2021-03-24 | Daikin Industries, Ltd. | Method for producing tetrafluoropropene |
JP2017193511A (en) | 2016-04-21 | 2017-10-26 | ダイキン工業株式会社 | Method for producing hydrochlorofluorocarbon and/or hydrofluorocarbon |
CN106349005B (en) * | 2016-08-25 | 2018-08-28 | 浙江衢州巨新氟化工有限公司 | A kind of method of coproduction trifluoropropyl alkenes product and tetrafluoropropene class product |
EP3578536B1 (en) | 2017-01-31 | 2023-12-06 | Daikin Industries, Ltd. | Method for producing fluorohalogenated hydrocarbon |
US10236517B2 (en) * | 2017-08-16 | 2019-03-19 | GM Global Technology Operations LLC | Method for manufacturing and cleaning a stainless steel fuel cell bipolar plate |
GB2580623A (en) * | 2019-01-17 | 2020-07-29 | Mexichem Fluor Sa De Cv | Method |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2713634B1 (en) * | 1993-12-09 | 1996-01-19 | Atochem Elf Sa | Catalytic fluorination of halogenated hydrocarbons in the gas phase. |
CZ7197A3 (en) | 1994-07-11 | 1998-02-18 | Alliedsignal Inc. | Process for preparing 1,1,1,3,3-pentafluoropropane |
US5710352A (en) * | 1996-09-19 | 1998-01-20 | Alliedsignal Inc. | Vapor phase process for making 1,1,1,3,3-pentafluoropropane and 1-chloro-3,3,3-trifluoropropene |
US5895825A (en) * | 1997-12-01 | 1999-04-20 | Elf Atochem North America, Inc. | Preparation of 1,1,1,3,3-pentafluoropropane |
JP4271415B2 (en) | 2002-07-15 | 2009-06-03 | セントラル硝子株式会社 | Method for producing 1,3,3,3-tetrafluoropropene |
US8062552B2 (en) * | 2005-05-19 | 2011-11-22 | Brookhaven Science Associates, Llc | Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates |
JP4314391B2 (en) * | 2005-07-07 | 2009-08-12 | 独立行政法人産業技術総合研究所 | Fluorination catalyst, method for producing the same, and method for producing fluorine compounds using the catalysts |
CN1911512B (en) * | 2005-07-07 | 2011-12-07 | 独立行政法人产业技术综合研究所 | Fluorination catalysts, method for their preparation, and method for producing fluorinated compounds using the catalysts |
US8766020B2 (en) * | 2008-07-31 | 2014-07-01 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
GB0806422D0 (en) * | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
US7829747B2 (en) * | 2008-04-24 | 2010-11-09 | Honeywell International Inc. | Process for dehydrofluorination of 3-chloro-1,1,1,3-tetrafluoropropane to 1-chloro-3,3,3-trifluoropropene |
CN102405203B (en) * | 2009-04-23 | 2015-04-08 | 大金工业株式会社 | Process for preparation of 2,3,3,3-tetrafluoropropene |
ES2616232T3 (en) | 2009-12-23 | 2017-06-12 | Arkema France | Catalytic fluorination in gas phase from 1233XF to 1234YF |
US8426656B2 (en) * | 2010-04-05 | 2013-04-23 | Honeywell International Inc. | Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene |
CA2796343A1 (en) * | 2010-04-14 | 2011-10-20 | Arkema Inc. | Process for the manufacture of tetrafluoroolefins |
EP2665693B1 (en) | 2011-01-21 | 2017-07-19 | Arkema France | Catalytic gas phase fluorination |
-
2013
- 2013-01-24 EP EP13704241.2A patent/EP2807137B1/en active Active
- 2013-01-24 ES ES13704241.2T patent/ES2625204T3/en active Active
- 2013-01-24 CN CN201380006497.1A patent/CN104105681B/en active Active
- 2013-01-24 MX MX2014008825A patent/MX353038B/en active IP Right Grant
- 2013-01-24 JP JP2014551904A patent/JP5888436B2/en active Active
- 2013-01-24 WO PCT/JP2013/052120 patent/WO2013111911A1/en active Application Filing
- 2013-01-24 US US14/358,101 patent/US9452958B2/en active Active
- 2013-01-24 KR KR1020147023697A patent/KR101643487B1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
CN104105681A (en) | 2014-10-15 |
MX2014008825A (en) | 2014-10-24 |
KR20140114897A (en) | 2014-09-29 |
WO2013111911A1 (en) | 2013-08-01 |
CN104105681B (en) | 2016-11-09 |
US20140303412A1 (en) | 2014-10-09 |
KR101643487B1 (en) | 2016-07-27 |
EP2807137A1 (en) | 2014-12-03 |
EP2807137B1 (en) | 2017-04-26 |
JP5888436B2 (en) | 2016-03-22 |
US9452958B2 (en) | 2016-09-27 |
ES2625204T3 (en) | 2017-07-18 |
JP2015509096A (en) | 2015-03-26 |
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