MX3415E - Mejoras en la hidroformilacion de una olefina - Google Patents
Mejoras en la hidroformilacion de una olefinaInfo
- Publication number
- MX3415E MX3415E MX000184U MX18476U MX3415E MX 3415 E MX3415 E MX 3415E MX 000184 U MX000184 U MX 000184U MX 18476 U MX18476 U MX 18476U MX 3415 E MX3415 E MX 3415E
- Authority
- MX
- Mexico
- Prior art keywords
- hydroformylation
- around
- hydrogen
- carbon
- olefin
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
La presente invención se refiere a mejoras en la hidroformilación de una olefina que tiene hasta alrededor de 25 átomos de carbono y siendo reaccionado con hidrogeno y monoxido de carbono en una zona de reacción de fade líquida para producir un derivado aldehido de la olefina, llevandose a cabo la hidroformilación a una temperatura que va desde alrededor de 50ºC., hasta alrededor de 200ºC., bajo una presión parcial combinada de hidrógeno y monóxido de carbono de alrededor de 68 atmósferas, y con una relación de presión parcial de hidrogenorespecto a aquella de monóxido de carbono desde alrededor de 10:1 hasta 1:10 en que la mejora comprende catalizar la hidroformilación con un hidruro de carbonilo de rodio en una combinación compleja con un derivado ferroceno de las siguientes estructuras: (ver figura). En que Q es P, As o Sb y R es fenilo o un alquilo inferior.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US56973875A | 1975-04-21 | 1975-04-21 | |
US65040576A | 1976-01-19 | 1976-01-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
MX3415E true MX3415E (es) | 1980-11-11 |
Family
ID=27075133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX000184U MX3415E (es) | 1975-04-21 | 1976-04-21 | Mejoras en la hidroformilacion de una olefina |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS51127052A (es) |
CA (1) | CA1082722A (es) |
DE (1) | DE2617306A1 (es) |
FR (1) | FR2308635A1 (es) |
GB (4) | GB1537918A (es) |
IT (1) | IT1059224B (es) |
MX (1) | MX3415E (es) |
NL (1) | NL7604204A (es) |
SE (1) | SE7604604L (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4536589A (en) * | 1981-11-09 | 1985-08-20 | The Dow Chemical Company | Polymers of ferrocene |
CA1327365C (en) * | 1988-06-29 | 1994-03-01 | Stephen R. Stobart | Process for catalytic hydroformylation |
JP5960577B2 (ja) * | 2012-10-23 | 2016-08-02 | Jnc株式会社 | ヒドリド金属錯体を用いて水素分子から電子を取り出す方法、および基質を還元する方法 |
EP4074683A1 (de) * | 2021-04-16 | 2022-10-19 | Evonik Operations GmbH | Verfahren zur hydroxymethylierung und hydroformylierung von alkenen mittels cu-katalysators |
-
1976
- 1976-04-05 CA CA249,599A patent/CA1082722A/en not_active Expired
- 1976-04-16 JP JP51042593A patent/JPS51127052A/ja active Pending
- 1976-04-16 FR FR7611370A patent/FR2308635A1/fr active Granted
- 1976-04-20 IT IT22472/76A patent/IT1059224B/it active
- 1976-04-20 GB GB51351/77A patent/GB1537918A/en not_active Expired
- 1976-04-20 GB GB51353/77A patent/GB1537920A/en not_active Expired
- 1976-04-20 GB GB15923/76A patent/GB1537917A/en not_active Expired
- 1976-04-20 GB GB51352/77A patent/GB1537919A/en not_active Expired
- 1976-04-21 SE SE7604604A patent/SE7604604L/xx unknown
- 1976-04-21 MX MX000184U patent/MX3415E/es unknown
- 1976-04-21 DE DE19762617306 patent/DE2617306A1/de active Pending
- 1976-04-21 NL NL7604204A patent/NL7604204A/xx not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
GB1537917A (en) | 1979-01-10 |
FR2308635A1 (fr) | 1976-11-19 |
DE2617306A1 (de) | 1976-11-04 |
JPS51127052A (en) | 1976-11-05 |
NL7604204A (nl) | 1976-10-25 |
GB1537920A (en) | 1979-01-10 |
IT1059224B (it) | 1982-05-31 |
GB1537918A (en) | 1979-01-10 |
GB1537919A (en) | 1979-01-10 |
CA1082722A (en) | 1980-07-29 |
FR2308635B1 (es) | 1978-05-19 |
SE7604604L (sv) | 1976-10-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE28183T1 (de) | Hydroformylierungsverfahren. | |
NL288059A (es) | ||
MX162547A (es) | Procedimiento continuo de hidroformulacion para la produccion de un aldehido | |
ATE26696T1 (de) | Hydroformylierungsverfahren. | |
SE8007140L (sv) | Forfarande for framstellning av aldehyder | |
ATE16475T1 (de) | Hydroformylierungsverfahren. | |
ID20555A (id) | Proses-proses untuk menghasilkan alkohol tak jenuh | |
SE7704141L (sv) | Hydroformyleringsforfarande | |
KR830004193A (ko) | 에틸렌과 고급올레핀과의 하이드로포르밀화방법 | |
ES466145A1 (es) | Procedimiento para la conversion de un compuesto organico olefinicamente insaturado | |
ES8104982A1 (es) | Procedimiento perfeccionado para la fabricacion de aldehidos | |
MX3415E (es) | Mejoras en la hidroformilacion de una olefina | |
Inoue et al. | Synthesis of formates from alcohols, carbon dioxide, and hydrogen catalysed by a combination of group VIII transition-metal complexes and tertiary amines | |
ES308301A1 (es) | Procedimiento para la obtencion de hidrogeno. | |
SE7709110L (sv) | Hydroformyleringsforfarande | |
GB1495595A (en) | Manufacture of 1,6-hexanediol | |
ES462430A1 (es) | Procedimiento para hacer reaccionar formaldehido, monoxido de carbono e hidrogeno. | |
ES406577A1 (es) | Procedimiento para la elaboracion de mezclas de hidroformi-lacion. | |
ES466267A1 (es) | Mejora en un procedimiento para hidroformilar una alfa-ole- fina. | |
GB1079209A (en) | Improvements in the oxo process | |
ES374695A1 (es) | Un procedimiento para la preparacion de esteres de acidos aminocarboxilicos saturados. | |
ES364187A1 (es) | Procedimiento para la disociacion catalitica de isobutiral-dehidos. | |
JPS55153732A (en) | Alcohol manufacture | |
ES390410A1 (es) | Procedimiento para la sintesis directa de alcoholes por me-dio de reaccion oxo. | |
Matsui et al. | Hydroformylation of Olefins Using Rhodium Complex Catalysts (Part 1) Effects of Reaction Variables on Reactivity and Selectivity |