MX338900B - Polyisobutylene prepared at high velocity and circulation rate. - Google Patents

Polyisobutylene prepared at high velocity and circulation rate.

Info

Publication number
MX338900B
MX338900B MX2014005059A MX2014005059A MX338900B MX 338900 B MX338900 B MX 338900B MX 2014005059 A MX2014005059 A MX 2014005059A MX 2014005059 A MX2014005059 A MX 2014005059A MX 338900 B MX338900 B MX 338900B
Authority
MX
Mexico
Prior art keywords
high velocity
circulation rate
psi
delta
tubes
Prior art date
Application number
MX2014005059A
Other languages
Spanish (es)
Other versions
MX2014005059A (en
Inventor
Sohel K Shaikh
Alfred Chiu
Patrick L Bradley
Gilbert D Valdez
Peggy J Macatangay
Original Assignee
Tpc Group Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tpc Group Llc filed Critical Tpc Group Llc
Publication of MX2014005059A publication Critical patent/MX2014005059A/en
Publication of MX338900B publication Critical patent/MX338900B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • B01J19/1837—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00065—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
    • B01J2219/0022—Control algorithm comparing a sensed parameter with a pre-set value calculating difference
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00222—Control algorithm taking actions
    • B01J2219/00227—Control algorithm taking actions modifying the operating conditions
    • B01J2219/00229—Control algorithm taking actions modifying the operating conditions of the reaction system
    • B01J2219/00231—Control algorithm taking actions modifying the operating conditions of the reaction system at the reactor inlet

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

A method of making a polyisobutylene polymer in a recirculating loop reactor with one or more reaction tubes in contact with a heat transfer medium includes controlling the delta P and polymerization reaction to provide a linear velocity of the reaction mixture of at least 11 ft/sec in the one or more tubes of the loop reactor and/or controlling the delta P and polymerization reaction of steps (b) and (c) to provide a recirculation ratio of the recirculation rate to the feed rate of at least 30: 1. Typically, the process utilizes a recirculating pump operating at a at a pressure differential of from 35 psi to 70 psi.
MX2014005059A 2011-10-26 2012-10-10 Polyisobutylene prepared at high velocity and circulation rate. MX338900B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161551526P 2011-10-26 2011-10-26
PCT/US2012/059464 WO2013062758A1 (en) 2011-10-26 2012-10-10 Polyisobutylene prepared at high velocity and circulation rate

Publications (2)

Publication Number Publication Date
MX2014005059A MX2014005059A (en) 2014-08-22
MX338900B true MX338900B (en) 2016-05-03

Family

ID=48168317

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014005059A MX338900B (en) 2011-10-26 2012-10-10 Polyisobutylene prepared at high velocity and circulation rate.

Country Status (12)

Country Link
US (2) US8946361B2 (en)
EP (1) EP2771369B1 (en)
JP (1) JP6126612B2 (en)
KR (1) KR101930736B1 (en)
CN (1) CN104024280B (en)
AR (1) AR088527A1 (en)
BR (1) BR112014009478B1 (en)
CA (1) CA2853063A1 (en)
MX (1) MX338900B (en)
MY (1) MY185146A (en)
SG (1) SG11201401508QA (en)
WO (1) WO2013062758A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6126612B2 (en) * 2011-10-26 2017-05-10 ティーピーシー・グループ・エルエルシー Polyisobutylene prepared with high speed and circulation rate
KR101523568B1 (en) * 2013-05-16 2015-05-28 대림산업 주식회사 Apparatus and method for selectively preparing reactive polyisobutylene and non-reactive polyisobutylene
KR102143729B1 (en) 2013-07-09 2020-08-11 다우 글로벌 테크놀로지스 엘엘씨 Ethylene/alpha-olefin interpolymers with improved pellet flowability
CN104193858B (en) * 2014-08-22 2016-06-15 山东鸿瑞新材料科技有限公司 Method and the automatic control system of polyisobutene is produced in successive polymerization
CN104945545A (en) * 2015-06-30 2015-09-30 清华大学 Preparation method of high-reactivity polyisobutene
WO2017151341A1 (en) 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
KR102287128B1 (en) 2016-04-08 2021-08-09 이네오스 유럽 아게 Polymerization apparatus and polymerization method
CN107522808B (en) * 2016-06-21 2020-09-15 中国石油化工股份有限公司 Preparation method of ethylene-octene copolymer
PL3481547T3 (en) * 2016-07-06 2023-09-11 Ineos Europe Ag Polymerisation process

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US5068490A (en) 1989-08-18 1991-11-26 Amoco Corporation BF3-tertiary etherate complexes for isobutylene polymerization
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US6562913B1 (en) * 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
DE19948947A1 (en) * 1999-10-11 2001-04-12 Basf Ag Process for the continuous production of polyisobutenes
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JP6126612B2 (en) * 2011-10-26 2017-05-10 ティーピーシー・グループ・エルエルシー Polyisobutylene prepared with high speed and circulation rate
US9309339B2 (en) * 2011-10-26 2016-04-12 Tpc Group Llc Mid-range vinylidene content, high viscosity polyisobutylene polymers
CN102872786A (en) * 2012-09-11 2013-01-16 宁波锦莱化工有限公司 Flat chlorination reaction device

Also Published As

Publication number Publication date
MY185146A (en) 2021-04-30
MX2014005059A (en) 2014-08-22
AR088527A1 (en) 2014-06-18
CA2853063A1 (en) 2013-05-02
CN104024280B (en) 2016-01-20
US8946361B2 (en) 2015-02-03
US9266980B2 (en) 2016-02-23
CN104024280A (en) 2014-09-03
US20150197584A1 (en) 2015-07-16
SG11201401508QA (en) 2014-05-29
JP6126612B2 (en) 2017-05-10
US20140235801A1 (en) 2014-08-21
BR112014009478B1 (en) 2021-09-21
WO2013062758A1 (en) 2013-05-02
KR101930736B1 (en) 2018-12-19
EP2771369B1 (en) 2017-02-15
EP2771369A1 (en) 2014-09-03
KR20140086983A (en) 2014-07-08
JP2014532774A (en) 2014-12-08
BR112014009478A2 (en) 2017-05-09
EP2771369A4 (en) 2015-06-03

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