MX337472B - Catalysts for making ethanol from acetic acid. - Google Patents
Catalysts for making ethanol from acetic acid.Info
- Publication number
- MX337472B MX337472B MX2012004839A MX2012004839A MX337472B MX 337472 B MX337472 B MX 337472B MX 2012004839 A MX2012004839 A MX 2012004839A MX 2012004839 A MX2012004839 A MX 2012004839A MX 337472 B MX337472 B MX 337472B
- Authority
- MX
- Mexico
- Prior art keywords
- catalysts
- acetic acid
- metal
- rhenium
- ruthenium
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
Catalysts and processes for forming catalysts for use in hydrogenating acetic acid to form ethanol. In one embodiment, the catalyst comprises a first metal, a silicaceous support, and at least one metasilicate support modifier. Preferably, the first metal is selected from the group consisting of copper, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, titanium, zinc, chromium, rhenium, molybdenum, and tungsten. In addition the catalyst may comprise a second metal preferably selected from the group consisting of copper, molybdenum, tin, chromium, iron, cobalt, vanadium, tungsten, palladium, platinum, lanthanum, cerium, manganese, ruthenium, rhenium, gold, and nickel.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/588,727 US8309772B2 (en) | 2008-07-31 | 2009-10-26 | Tunable catalyst gas phase hydrogenation of carboxylic acids |
PCT/US2010/022950 WO2011056247A2 (en) | 2009-10-26 | 2010-02-02 | Catalysts for making ethanol from acetic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2012004839A MX2012004839A (en) | 2012-05-29 |
MX337472B true MX337472B (en) | 2016-03-04 |
Family
ID=46506680
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012004839A MX337472B (en) | 2009-10-26 | 2010-02-02 | Catalysts for making ethanol from acetic acid. |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP2493606A2 (en) |
CN (1) | CN102333588B (en) |
AU (1) | AU2010315899A1 (en) |
BR (1) | BR112012009792A2 (en) |
CA (1) | CA2778767A1 (en) |
MX (1) | MX337472B (en) |
WO (1) | WO2011056247A2 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130197278A1 (en) * | 2012-01-27 | 2013-08-01 | Celanese International Corporation | Process For Manufacturing Ethanol Using A Metallic Catalyst Supported on Titania |
CN102600842A (en) * | 2012-03-02 | 2012-07-25 | 山西盛驰科技有限公司 | Catalyst for preparing ethanol through hydrogenation of acetic acid as well as preparation method and application thereof |
US8536383B1 (en) * | 2012-03-14 | 2013-09-17 | Celanese International Corporation | Rhodium/tin catalysts and processes for producing ethanol |
CN104043484B (en) * | 2013-03-13 | 2016-10-12 | 中国石油天然气股份有限公司 | A kind of acetic acid catalytic hydrogenation prepares the catalyst of ethanol and preparation thereof and application |
CN103331167A (en) * | 2013-07-19 | 2013-10-02 | 新地能源工程技术有限公司 | Catalyst for directly preparing ethanol from acetic acid, preparation method and application |
CN105258185A (en) * | 2015-11-14 | 2016-01-20 | 无锡清杨机械制造有限公司 | Range hood with air purifying function |
CN105646143B (en) * | 2016-02-23 | 2018-09-04 | 上海华谊(集团)公司 | The method of acetic acid co-productiono f ethanol ethyl acetate |
CN106345512B (en) * | 2016-08-03 | 2019-03-05 | 江苏大学 | A kind of bianry alloy catalyst and its preparation method and application |
CN108358752A (en) * | 2018-04-18 | 2018-08-03 | 肖锦 | A kind of method of acetic acid hydrogenation ethyl alcohol |
WO2020058822A1 (en) * | 2018-09-17 | 2020-03-26 | Sabic Global Technologies B.V. | Catalysts for producing alcohols and ethers from synthesis gas |
US11559795B2 (en) * | 2018-09-19 | 2023-01-24 | Sabic Global Technologies, B.V. | Bimetallic catalysts supported on zeolites for selective conversion of n-butane to ethane |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2882244A (en) | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US3130007A (en) | 1961-05-12 | 1964-04-21 | Union Carbide Corp | Crystalline zeolite y |
GB8509530D0 (en) | 1985-04-13 | 1985-05-15 | Bp Chem Int Ltd | Hydrogenation of carboxylic acids |
GB8707595D0 (en) | 1987-03-31 | 1987-05-07 | British Petroleum Co Plc | Chemical process |
US5149680A (en) | 1987-03-31 | 1992-09-22 | The British Petroleum Company P.L.C. | Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters |
US5137861A (en) * | 1991-01-22 | 1992-08-11 | Mobil Oil Corp. | Catalyst comprising a hydrogenation metal and a delaminated layered silicate |
US5821111A (en) | 1994-03-31 | 1998-10-13 | Bioengineering Resources, Inc. | Bioconversion of waste biomass to useful products |
USRE35377E (en) | 1993-05-27 | 1996-11-12 | Steinberg; Meyer | Process and apparatus for the production of methanol from condensed carbonaceous material |
US5977010A (en) * | 1995-06-15 | 1999-11-02 | Engelhard Corporation | Shaped hydrogenation catalyst and processes for their preparation and use |
US5945570A (en) * | 1998-10-29 | 1999-08-31 | Arhancet; Juan Pedro | Catalyst and process for preparing 1,3-propanediol |
US6232352B1 (en) | 1999-11-01 | 2001-05-15 | Acetex Limited | Methanol plant retrofit for acetic acid manufacture |
US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
US6685754B2 (en) | 2001-03-06 | 2004-02-03 | Alchemix Corporation | Method for the production of hydrogen-containing gaseous mixtures |
EP1277826A1 (en) * | 2001-07-18 | 2003-01-22 | ATOFINA Research | Hydrogenation and dehydrogenation processes and catalysts therefor |
US7608744B1 (en) * | 2008-07-31 | 2009-10-27 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
-
2010
- 2010-02-02 CN CN201080003926.6A patent/CN102333588B/en not_active Expired - Fee Related
- 2010-02-02 WO PCT/US2010/022950 patent/WO2011056247A2/en active Application Filing
- 2010-02-02 CA CA2778767A patent/CA2778767A1/en not_active Abandoned
- 2010-02-02 EP EP10702393A patent/EP2493606A2/en not_active Withdrawn
- 2010-02-02 AU AU2010315899A patent/AU2010315899A1/en not_active Abandoned
- 2010-02-02 MX MX2012004839A patent/MX337472B/en active IP Right Grant
- 2010-02-02 BR BR112012009792A patent/BR112012009792A2/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU2010315899A1 (en) | 2012-05-17 |
AU2010315899A2 (en) | 2012-06-21 |
CN102333588A (en) | 2012-01-25 |
CA2778767A1 (en) | 2011-05-12 |
WO2011056247A2 (en) | 2011-05-12 |
BR112012009792A2 (en) | 2016-10-18 |
CN102333588B (en) | 2014-04-09 |
EP2493606A2 (en) | 2012-09-05 |
WO2011056247A3 (en) | 2011-10-27 |
MX2012004839A (en) | 2012-05-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration |