MX2013012389A - Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas. - Google Patents
Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas.Info
- Publication number
- MX2013012389A MX2013012389A MX2013012389A MX2013012389A MX2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A
- Authority
- MX
- Mexico
- Prior art keywords
- metal
- plasma
- oxidative
- dehydrations
- noble metal
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052751 metal Inorganic materials 0.000 title abstract 4
- 230000018044 dehydration Effects 0.000 title abstract 2
- 238000006297 dehydration reaction Methods 0.000 title abstract 2
- 229910000510 noble metal Inorganic materials 0.000 title abstract 2
- 230000001590 oxidative effect Effects 0.000 title abstract 2
- 208000005156 Dehydration Diseases 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 239000012876 carrier material Substances 0.000 abstract 3
- 239000007769 metal material Substances 0.000 abstract 3
- 239000002131 composite material Substances 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 238000005422 blasting Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/466—Osmium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/468—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
- B01J37/0223—Coating of particles by rotation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Plasma & Fusion (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un método para producir un catalizador que comprende de 0.05 a 0.25 % en peso de metales nobles, preferiblemente para la deshidrogenación oxidativa de alcoholes olefínicamente instaurados, que comprende los siguientes pasos: a) generación de un plasma de corriente directa, b) introducción de metal y material de soporte en el plasma, c) vaporización de metal y material de soporte y material portador en el plasma o "rociado" del cuerpo sólido de metal y material portador en el plasma y haciendo reaccionar las partículas, d) enfriamiento en donde se obtienen las partículas muy pequeñas de un material mixto, y e) aplicación del material mixto al portador de catalizador actual. La invención además se refiere a un catalizador producido correspondientemente y al uso del mismo.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11164044 | 2011-04-28 | ||
PCT/EP2012/054386 WO2012146436A1 (de) | 2011-04-28 | 2012-03-13 | Edelmetallkatalysatoren mit geringer metallbeladung für oxidative dehydrierungen |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2013012389A true MX2013012389A (es) | 2013-11-04 |
Family
ID=45812801
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2013012389A MX2013012389A (es) | 2011-04-28 | 2012-03-13 | Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2701840A1 (es) |
JP (1) | JP6023790B2 (es) |
CN (1) | CN103501895B (es) |
MX (1) | MX2013012389A (es) |
WO (1) | WO2012146436A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109806865A (zh) * | 2017-11-20 | 2019-05-28 | 中国科学院大连化学物理研究所 | 一种金催化剂的制备及其在异戊烯醇氧化反应中的应用 |
CN108080002A (zh) * | 2017-12-01 | 2018-05-29 | 中海油天津化工研究设计院有限公司 | 多元活性组分高度分散的低碳烷烃脱氢催化剂及制备方法 |
CN113015574A (zh) | 2018-11-13 | 2021-06-22 | 巴斯夫欧洲公司 | 包含银催化剂体的催化剂床和烯属不饱和醇的氧化脱氢方法 |
WO2023099727A1 (en) | 2021-12-03 | 2023-06-08 | Basf Se | Process for preparing isoprenal and/or prenal |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
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DE2020865C3 (de) | 1970-04-29 | 1975-05-07 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von alpha, beta-ungesättigten Carbonylverbindungen |
DE2715209C3 (de) | 1977-04-05 | 1981-11-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von 3-Alkyl-buten-l-alen |
NL8201396A (nl) * | 1982-04-01 | 1983-11-01 | Dow Chemical Nederland | Zilver katalysator en een werkwijze voor de bereiding daarvan. |
DE3612213A1 (de) | 1986-04-11 | 1987-10-15 | Basf Ag | Rohrbuendelreaktor, dessen verwendung bei exothermen organischen reaktionen und verfahren zur herstellung von ketonen und aldehyden mit hilfe des rohrbuendelreaktors |
DE3633885A1 (de) * | 1986-10-04 | 1988-04-07 | Basf Ag | Verfahren zur kontinuierlichen herstellung von aliphatischen aldehyden und ketonen |
EP0357293B1 (en) | 1988-08-30 | 1996-02-28 | Union Carbide Corporation | Catalysts for the production of ethylene oxide and their preparation processes |
DE4311608A1 (de) | 1993-04-08 | 1994-12-15 | Huels Chemische Werke Ag | Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid |
CN1182717A (zh) * | 1996-10-31 | 1998-05-27 | 住友化学工业株式会社 | 氯气的生产方法 |
US5989648A (en) | 1997-05-06 | 1999-11-23 | The Penn State Research Foundation | Plasma generation of supported metal catalysts |
DE19722567A1 (de) | 1997-05-28 | 1998-12-03 | Basf Ag | Verfahren zur kontinuierlichen technischen Herstellung ungesättigter aliphatischer Aldehyde in einem Rohrbündelreaktor |
JP4000392B2 (ja) * | 1997-11-05 | 2007-10-31 | 独立行政法人産業技術総合研究所 | 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法 |
JPH11323192A (ja) * | 1998-05-15 | 1999-11-26 | Mitsubishi Materials Corp | 帯電防止効果のある光触媒膜とその形成用の光触媒塗料 |
EP1034843A1 (de) * | 1999-03-10 | 2000-09-13 | Sulzer Metco AG | Verfahren zur Herstellung einer beschichteten Struktur, die sich zum Durchführen von heterogenen Katalysen eignet |
JP2001261337A (ja) * | 2000-03-23 | 2001-09-26 | C I Kasei Co Ltd | 銀微粒子を複合した二酸化チタン微粒子の製造方法 |
US6689192B1 (en) | 2001-12-13 | 2004-02-10 | The Regents Of The University Of California | Method for producing metallic nanoparticles |
JP5628472B2 (ja) * | 2004-04-19 | 2014-11-19 | エスディーシーマテリアルズ, インコーポレイテッド | 気相合成による高スループットの材料発見方法 |
EP1810001A4 (en) | 2004-10-08 | 2008-08-27 | Sdc Materials Llc | DEVICE AND METHOD FOR SAMPLING AND COLLECTING POWDERS FLOWING IN A GASSTROM |
JP4565191B2 (ja) * | 2006-01-30 | 2010-10-20 | 国立大学法人山梨大学 | 微粒子触媒の製造方法、微粒子触媒、及び改質装置 |
JP2007302612A (ja) * | 2006-05-12 | 2007-11-22 | Nippon Shokubai Co Ltd | ケトンの製造方法 |
JP4970120B2 (ja) * | 2007-04-13 | 2012-07-04 | 公立大学法人首都大学東京 | 金微粒子を担体に分散・固定する方法 |
US8142619B2 (en) * | 2007-05-11 | 2012-03-27 | Sdc Materials Inc. | Shape of cone and air input annulus |
DE102008014910A1 (de) | 2008-03-19 | 2009-09-24 | Basf Se | Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung |
WO2010087445A1 (ja) * | 2009-02-02 | 2010-08-05 | パイオニア株式会社 | TiO2ナノ粒子 |
JP5278189B2 (ja) * | 2009-06-19 | 2013-09-04 | 株式会社明電舎 | 光触媒再生方法及び腐食性ガス浄化装置 |
US8604252B2 (en) * | 2009-07-02 | 2013-12-10 | Basf Se | Supported noble metal comprising catalyst for oxidative dehydrogenation or epoxidation |
DE102009034773A1 (de) * | 2009-07-25 | 2011-01-27 | Bayer Materialscience Ag | Verfahren zur Herstellung von Chlor durch Gasphasenoxidation an nanostrukturierten Rutheniumträgerkatalysatoren |
US8669202B2 (en) * | 2011-02-23 | 2014-03-11 | SDCmaterials, Inc. | Wet chemical and plasma methods of forming stable PtPd catalysts |
-
2012
- 2012-03-13 CN CN201280020648.4A patent/CN103501895B/zh not_active Expired - Fee Related
- 2012-03-13 EP EP12708045.5A patent/EP2701840A1/de not_active Withdrawn
- 2012-03-13 WO PCT/EP2012/054386 patent/WO2012146436A1/de active Application Filing
- 2012-03-13 JP JP2014506805A patent/JP6023790B2/ja not_active Expired - Fee Related
- 2012-03-13 MX MX2013012389A patent/MX2013012389A/es unknown
Also Published As
Publication number | Publication date |
---|---|
WO2012146436A1 (de) | 2012-11-01 |
EP2701840A1 (de) | 2014-03-05 |
JP6023790B2 (ja) | 2016-11-09 |
CN103501895B (zh) | 2016-05-25 |
JP2014516770A (ja) | 2014-07-17 |
CN103501895A (zh) | 2014-01-08 |
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