MX2012006967A - Proceso mejorado de carbonizacion. - Google Patents
Proceso mejorado de carbonizacion.Info
- Publication number
- MX2012006967A MX2012006967A MX2012006967A MX2012006967A MX2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A
- Authority
- MX
- Mexico
- Prior art keywords
- atoms
- source
- catalyst system
- x3and
- metal
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un método para incrementar el número de ciclos (TON) de un sistema de catalizadores para la monocarbonilación de compuestos etilénicamente insaturados con el uso de monóxido de carbono en presencia de un co-reactivo, aparte del agua o una fuente de la misma, que tiene un átomo de hidrógeno móvil. El sistema de catalizadores se obtiene al combinar: (a) un metal de grupo 8, 9 ó 10 o un compuesto adecuado del mismo; (b) un ligando de la fórmula general (I) (ver fórmula (I)) donde los grupos X3 y X4 representan por separado radicales univalentes de hasta 30 átomos o X3 y X4 forman juntos un radical bivalente de hasta 40 átomos y X5 tienen hasta 400 átomos; Q1 representa fósforo, arsénico o antimonio; y c) opcionalmente, una fuente de aniones.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0921876.9A GB0921876D0 (en) | 2009-12-15 | 2009-12-15 | Improved carbonylation process |
PCT/GB2010/052093 WO2011073653A1 (en) | 2009-12-15 | 2010-12-15 | Improved carbonylation process |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2012006967A true MX2012006967A (es) | 2012-07-17 |
Family
ID=41667109
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012006967A MX2012006967A (es) | 2009-12-15 | 2010-12-15 | Proceso mejorado de carbonizacion. |
Country Status (15)
Country | Link |
---|---|
US (1) | US20120309613A1 (es) |
EP (1) | EP2512670A1 (es) |
JP (2) | JP2013513653A (es) |
KR (1) | KR20120106974A (es) |
CN (1) | CN102740972B (es) |
AU (1) | AU2010332501B2 (es) |
BR (1) | BR112012014500A2 (es) |
CA (1) | CA2783586A1 (es) |
EA (1) | EA024236B1 (es) |
GB (1) | GB0921876D0 (es) |
MX (1) | MX2012006967A (es) |
SG (1) | SG181699A1 (es) |
TW (1) | TWI508780B (es) |
WO (1) | WO2011073653A1 (es) |
ZA (1) | ZA201204316B (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120309613A1 (en) * | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
AR088124A1 (es) * | 2011-04-01 | 2014-05-14 | Dsm Ip Assets Bv | Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio |
GB201122054D0 (en) * | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
WO2013107902A1 (en) | 2012-01-20 | 2013-07-25 | Dsm Ip Assets B.V. | Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture |
CN114409541A (zh) * | 2020-10-28 | 2022-04-29 | 上海浦景化工技术股份有限公司 | 一种乙烯羰基化制丙酸酯类的*** |
CN112480170B (zh) * | 2020-12-02 | 2023-03-14 | 中国海洋石油集团有限公司 | 一种双膦化合物、包含其的催化剂体系及其应用 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0055875B1 (en) | 1981-01-06 | 1986-08-20 | Shell Internationale Researchmaatschappij B.V. | Process for the carbonylation of olefins |
CA1231346A (en) | 1982-09-30 | 1988-01-12 | Eit Drent | Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst |
GB8531624D0 (en) | 1985-12-23 | 1986-02-05 | Shell Int Research | Carbonylation of ethylenically unsaturated compounds |
JPH0678269B2 (ja) * | 1986-01-09 | 1994-10-05 | 三菱化成株式会社 | オレフイン類のカルボニル化法 |
GB8605034D0 (en) | 1986-02-28 | 1986-04-09 | Shell Int Research | Carbonylation of compounds |
KR880007426A (ko) | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
GB8705699D0 (en) | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
US5158921A (en) | 1989-03-03 | 1992-10-27 | Shell Oil Company | Carbonylation catalyst and process |
CA2034971A1 (en) | 1990-02-05 | 1991-08-06 | Eit Drent | Carbonylation catalyst system |
FI91135C (fi) | 1990-03-19 | 1994-05-25 | Valmet Paper Machinery Inc | Menetelmä reikien poraamiseksi paperikoneen sylinterin vaippaan ja menetelmässä käytetty laitteisto |
CA2055628A1 (en) | 1990-12-03 | 1992-06-04 | Eit Drent | Carbonylation process and catalyst composition |
DE69204691T2 (de) | 1991-01-15 | 1996-04-11 | Shell Int Research | Verfahren zur Karbonylierung von Olefin. |
DE69210054T2 (de) | 1991-01-15 | 1996-12-12 | Shell Int Research | Carbonylierung von Olefinen |
DE69200122T2 (de) | 1991-02-15 | 1994-09-29 | Shell Int Research | Katalytisches System für die Carbonylierung. |
GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
US5618983A (en) * | 1995-08-25 | 1997-04-08 | E. I. Du Pont De Nemours And Company | Hydroformylation process |
GB9705699D0 (en) * | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
US6156934A (en) | 1997-03-26 | 2000-12-05 | Shell Oil Company | Diphosphines |
TW524801B (en) | 1999-03-22 | 2003-03-21 | Shell Int Research | Process for the carbonylation of conjugated dienes |
US6706912B2 (en) | 2000-03-14 | 2004-03-16 | Shell Oil Company | Process for the carbonylation of ethylenically unsaturated compounds |
DE10048874A1 (de) | 2000-09-29 | 2002-04-11 | Basf Ag | Katalysatorsystem und Verfahren zur Carbonylierung |
DE10228293A1 (de) | 2001-07-28 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Dialkylketonen |
WO2003070370A1 (en) | 2002-02-19 | 2003-08-28 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore |
US7485739B2 (en) | 2002-09-12 | 2009-02-03 | Lucite International Uk Ltd. | Catalyst system |
CA2526348A1 (en) | 2003-05-22 | 2004-12-02 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of a conjugated diene |
EP1651587A1 (en) * | 2003-07-03 | 2006-05-03 | Lucite International UK Limited | Process for the hydroformylation of ethylenically unsaturated compounds |
US7084291B2 (en) * | 2003-10-15 | 2006-08-01 | General Electric Company | Water resistant catalyst for the production of diaryl carbonates via the direct carbonylation of phenolic compounds |
WO2005082830A1 (en) | 2004-02-26 | 2005-09-09 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of ethylenically or acetylenically unsaturated compounds |
GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
JP2010511600A (ja) * | 2006-12-02 | 2010-04-15 | ルーサイト インターナショナル ユーケー リミテッド | 新規のカルボニル化配位子及びエチレン性不飽和化合物のカルボニル化におけるその使用 |
GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
GB0713624D0 (en) * | 2007-07-13 | 2007-08-22 | Lucite Int Uk Ltd | Improved solvent for catalyst system |
US20120309613A1 (en) * | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
-
2009
- 2009-12-15 US US13/516,176 patent/US20120309613A1/en not_active Abandoned
- 2009-12-15 GB GBGB0921876.9A patent/GB0921876D0/en not_active Ceased
-
2010
- 2010-12-15 EP EP10795448A patent/EP2512670A1/en not_active Withdrawn
- 2010-12-15 MX MX2012006967A patent/MX2012006967A/es not_active Application Discontinuation
- 2010-12-15 KR KR1020127018429A patent/KR20120106974A/ko not_active Application Discontinuation
- 2010-12-15 BR BR112012014500A patent/BR112012014500A2/pt not_active IP Right Cessation
- 2010-12-15 CN CN201080062848.7A patent/CN102740972B/zh not_active Expired - Fee Related
- 2010-12-15 WO PCT/GB2010/052093 patent/WO2011073653A1/en active Application Filing
- 2010-12-15 EA EA201290514A patent/EA024236B1/ru not_active IP Right Cessation
- 2010-12-15 AU AU2010332501A patent/AU2010332501B2/en not_active Ceased
- 2010-12-15 TW TW099144089A patent/TWI508780B/zh not_active IP Right Cessation
- 2010-12-15 SG SG2012043840A patent/SG181699A1/en unknown
- 2010-12-15 CA CA2783586A patent/CA2783586A1/en not_active Abandoned
- 2010-12-15 JP JP2012543906A patent/JP2013513653A/ja active Pending
-
2012
- 2012-06-12 ZA ZA2012/04316A patent/ZA201204316B/en unknown
-
2015
- 2015-06-03 JP JP2015113273A patent/JP2015214551A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EA024236B1 (ru) | 2016-08-31 |
ZA201204316B (en) | 2013-02-27 |
CN102740972A (zh) | 2012-10-17 |
AU2010332501A1 (en) | 2012-07-26 |
GB0921876D0 (en) | 2010-01-27 |
CA2783586A1 (en) | 2011-06-23 |
AU2010332501A2 (en) | 2012-08-02 |
KR20120106974A (ko) | 2012-09-27 |
AU2010332501B2 (en) | 2014-10-30 |
WO2011073653A1 (en) | 2011-06-23 |
BR112012014500A2 (pt) | 2016-08-16 |
EP2512670A1 (en) | 2012-10-24 |
EA201290514A1 (ru) | 2013-01-30 |
JP2015214551A (ja) | 2015-12-03 |
CN102740972B (zh) | 2015-02-11 |
JP2013513653A (ja) | 2013-04-22 |
TW201143889A (en) | 2011-12-16 |
SG181699A1 (en) | 2012-07-30 |
US20120309613A1 (en) | 2012-12-06 |
TWI508780B (zh) | 2015-11-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA | Abandonment or withdrawal |