MX168671B - Procedimento mejorado para la preparacion de compuestos glicidilo - Google Patents
Procedimento mejorado para la preparacion de compuestos glicidiloInfo
- Publication number
- MX168671B MX168671B MX004638A MX463886A MX168671B MX 168671 B MX168671 B MX 168671B MX 004638 A MX004638 A MX 004638A MX 463886 A MX463886 A MX 463886A MX 168671 B MX168671 B MX 168671B
- Authority
- MX
- Mexico
- Prior art keywords
- aprotonic
- temperature
- solvent
- reaction
- preparation
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- -1 3,5-diphenyl-4-hydroxyphenyl Chemical group 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 238000010521 absorption reaction Methods 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000003068 static effect Effects 0.000 abstract 2
- 230000007704 transition Effects 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000007514 bases Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/27—Condensation of epihalohydrins or halohydrins with compounds containing active hydrogen atoms
- C07D301/28—Condensation of epihalohydrins or halohydrins with compounds containing active hydrogen atoms by reaction with hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
- C08G59/063—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with epihalohydrins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Epoxy Compounds (AREA)
- Epoxy Resins (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Paints Or Removers (AREA)
Abstract
La presente invención se refiere a procedimiento para la preparacíon de compuestos glicidilo mediante la racción de un compuesto que contiene por lo menos un grupo fenólico, por lo menos con la cantidad equivalente, calculada sobre el grupo fenólico, de una halogenohidrina en un solvente aprotónico substancialmente anhidro, en presencia de un compuesto básico sólido, substancialmente anhidro; caracterizado por el hecho de que: a) la reacción se lleva a cabo a una temperatura situada entre 40 y 80ºC, en presencia de carbonato alcalino, empleándose un solvente dipolar aprotónico con una constante de dielectricidad estática relativa de más de 25 (a 25ºC) y un momento dipolar eléctrico permanente de más de 2,5 D, que se caracteriza adicionalmente por una energía de transición de la banda de absorción solvatocrómica del N-(3,5-difenil-4-hidroxifenil)-2,4,6-trifenilpiridinoperclorato disuelto, entre 168 y 197,4 kj/mol (a una temperatura de 25ºC), o b) la reacción se lleva a cabo a una temperatura situada entre 60 y 80ºC en presencia de hidróxido alcalino y de un catalizador de transferencia seleccionado entre el grupo consistente en un compuesto de amonio y/o de fosfonio y el agua de la reacción que se forma se descarga continuamente y se emplea un solvente inerte, aprotónico, apolar, con una constante de dielectricidad estática relativa de menos de 8,0 (a 25ºC) y un momento dipolar eléctrico permanente de menos de 2,0 D, que se caracteriza adicionalmente por una energía de transición de la banda de absorción solvatocrómica del N-(3,5-difenil-4-hidroxifenil)-2,4,6-trifenilpiridinioperclorato disuelto entre 140 y 165 kj/mol ( a 25ºc).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH531685 | 1985-12-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX168671B true MX168671B (es) | 1993-06-03 |
Family
ID=4291550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX004638A MX168671B (es) | 1985-12-13 | 1986-12-11 | Procedimento mejorado para la preparacion de compuestos glicidilo |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4722983A (es) |
| EP (1) | EP0226543B1 (es) |
| JP (1) | JPH0791281B2 (es) |
| KR (1) | KR940003293B1 (es) |
| BR (1) | BR8606154A (es) |
| CA (1) | CA1246596A (es) |
| DE (1) | DE3689111D1 (es) |
| ES (1) | ES2059307T3 (es) |
| MX (1) | MX168671B (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5098964A (en) * | 1991-01-31 | 1992-03-24 | Shell Oil Company | Process for preparing low-chlorine epoxy resins |
| US5098965A (en) * | 1991-01-31 | 1992-03-24 | Shell Oil Company | Process for preparing low-chlorine epoxy resins |
| US5633313A (en) * | 1995-04-24 | 1997-05-27 | Board Of Trustees Operating Michigan State University | Method and apparatus for in situ, non-invasive polymer cure determination |
| DE19749294C1 (de) | 1997-11-07 | 1999-04-01 | Daimler Benz Ag | Karosseriestruktur mit wenigstens einer Querverbindung |
| US8076495B2 (en) * | 2003-06-30 | 2011-12-13 | Huntsman Advanced Materials Americas Llc | Process for the preparation of aromatic N-gylcidyl amines |
| EP2948464A4 (en) * | 2013-01-22 | 2016-12-07 | Frx Polymers Inc | PHOSPHORUS-BASED EPOXY BINDINGS AND COMPOSITIONS THEREOF |
| CN104592167B (zh) * | 2014-12-31 | 2017-02-01 | 湖北绿色家园精细化工股份有限公司 | 一种制备苯基缩水甘油醚的方法 |
| CN114656617A (zh) * | 2022-04-21 | 2022-06-24 | 张家港衡业特种树脂有限公司 | 一种环氧树脂活性稀释剂的制备方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL105632C (es) * | 1956-12-19 | |||
| US3033821A (en) * | 1958-10-24 | 1962-05-08 | Devoe & Raynolds Co | Production of diglycidyl ethers |
| US3206482A (en) * | 1959-12-28 | 1965-09-14 | Shell Oil Co | Epoxy ethers |
| DE2533505C3 (de) * | 1974-08-02 | 1981-10-08 | Hoechst Ag, 6000 Frankfurt | Verfahren zum Herstellen von niedrigviskosen, niedermolekularen Glycidyläthern ein- oder mehrwertiger Phenole |
| IT1051400B (it) * | 1975-12-19 | 1981-04-21 | S I R S P A | Procedimento perfezionato per la preparazione di resine epossidiche liquide |
| FR2445843A1 (fr) * | 1979-01-05 | 1980-08-01 | Rhone Poulenc Ind | Procede de preparation de polyethers glycidyliques de polyphenols |
| FR2450266A1 (fr) * | 1979-03-02 | 1980-09-26 | Rhone Poulenc Ind | Procede de preparation de polyesthers glycidiques de polyphenols |
| FR2490654A1 (fr) * | 1980-08-27 | 1982-03-26 | Rhone Poulenc Ind | Procede de preparation de polyethers glycidiques de polyphenols |
| GB2120659B (en) * | 1982-04-28 | 1985-12-04 | Sumitomo Chemical Co | Process for producing glycidyl ethers of monohydric polyhydric phenols |
| JPS58189223A (ja) * | 1982-04-28 | 1983-11-04 | Sumitomo Chem Co Ltd | エポキシ樹脂の製造方法 |
| EP0096006A3 (de) * | 1982-05-28 | 1984-12-19 | Ciba-Geigy Ag | 3-(Ureidocyclohexylamino)-propan-1,2-diolderivate, Verfahren zu ihrer Herstellung, pharmazeutische Präparate enthaltend diese Verbindungen, sowie ihre therapeutische Verwendung |
| US4634713A (en) * | 1982-05-28 | 1987-01-06 | Ciba-Geigy Corporation | Antihypertensive 3-(ureidocyclohexyleneamino)propane-1,2-diol derivatives |
| JPS6031517A (ja) * | 1983-07-29 | 1985-02-18 | Sumitomo Chem Co Ltd | エポキシ樹脂の製造法 |
| US4518762A (en) * | 1983-09-08 | 1985-05-21 | Ciba Geigy Corporation | Process for making epoxy novolac resins with high epoxy values |
| US4582892A (en) * | 1985-05-28 | 1986-04-15 | The Dow Chemical Company | Process for the preparation of epoxy resins |
-
1986
- 1986-12-08 US US06/939,213 patent/US4722983A/en not_active Expired - Lifetime
- 1986-12-08 EP EP86810575A patent/EP0226543B1/de not_active Expired - Lifetime
- 1986-12-08 ES ES86810575T patent/ES2059307T3/es not_active Expired - Lifetime
- 1986-12-08 DE DE86810575T patent/DE3689111D1/de not_active Expired - Fee Related
- 1986-12-11 BR BR8606154A patent/BR8606154A/pt unknown
- 1986-12-11 CA CA000525013A patent/CA1246596A/en not_active Expired
- 1986-12-11 MX MX004638A patent/MX168671B/es unknown
- 1986-12-12 KR KR1019860010651A patent/KR940003293B1/ko not_active IP Right Cessation
- 1986-12-13 JP JP61297450A patent/JPH0791281B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA1246596A (en) | 1988-12-13 |
| KR940003293B1 (ko) | 1994-04-20 |
| BR8606154A (pt) | 1987-09-22 |
| EP0226543A3 (en) | 1988-06-15 |
| EP0226543A2 (de) | 1987-06-24 |
| DE3689111D1 (de) | 1993-11-04 |
| EP0226543B1 (de) | 1993-09-29 |
| JPS62148477A (ja) | 1987-07-02 |
| KR870006029A (ko) | 1987-07-08 |
| JPH0791281B2 (ja) | 1995-10-04 |
| ES2059307T3 (es) | 1994-11-16 |
| US4722983A (en) | 1988-02-02 |
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