MX165729B - Procedimiento para cepillar quimicamente y someter a tratamiento acido una varilla de cobre - Google Patents
Procedimiento para cepillar quimicamente y someter a tratamiento acido una varilla de cobreInfo
- Publication number
- MX165729B MX165729B MX010266A MX1026688A MX165729B MX 165729 B MX165729 B MX 165729B MX 010266 A MX010266 A MX 010266A MX 1026688 A MX1026688 A MX 1026688A MX 165729 B MX165729 B MX 165729B
- Authority
- MX
- Mexico
- Prior art keywords
- hot
- rod
- copper
- rolling
- chemically
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49988—Metal casting
- Y10T29/49989—Followed by cutting or removing material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49988—Metal casting
- Y10T29/49991—Combined with rolling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- ing And Chemical Polishing (AREA)
- Metal Rolling (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
Abstract
La presente invención se refiere a un procedimiento para la fabricación de varillas de cobre adecuadas para su estirado o laminado subsecuente para formar alambre de cobre, varilla que se caracteriza por que tiene una lisura de superficie mejorada y estar substancialmente libre de óxidos de superficie, que comprende los pasos de proveer una carga fundida de cobre de una pureza correspondiente a la pureza de cátodos de cobre refinados electrolíticamente, colar el baño fundido para formar barras de cobre coladas, laminar en caliente las barras de cobre coladas para formar una varilla de cobre laminada de caliente, regular la temperatura de la varilla de cobre laminada en caliente dentro de la escala de 121 a 649 grados C, regular el paso de la varilla de cobre laminada en caliente a través de una solución acuosa que contiene una concentración controlada de ácido sulfúrico dentro de la escala de 180 a 450 gramos/litro libre de ácido y una concentración controlada de peróxido de hidrógeno dentro de la escala de 5 a 50 gramos/litro de concentración para producir una varilla de cobre cepillada químicamente y sometida a tratamiento de baño de ácido laminada en caliente, regular la temperatura de la solución acuosa que contiene el ácido sulfúrico y el peróxido de hidrógeno estabilizado a una escala de entre 49 y 71 grados C, paso de la varilla de cobre laminada en caliente que se regula para proveer un tiempo de reacción de la escala de 2 segundos a 12 minutos que contiene una solución acuosa de ácido sulfúrico y peróxido de hidrógeno estabilizado, extraer una longitud de muestra de la varilla de cobre laminada en caliente cepillada químicamente y sometida a tratamiento ácido, someter la muestra a una prueba mecánica para obtener la indicación de la lisura de superficie de la varilla de cobre laminada en caliente cepillada químicamente y sometida a tratamiento ácido y ajustar una o más de los variables del proceso que comprenden la temperatura de la varilla de cobre laminada en caliente, la concentración de peróxido de hidrógeno en la solución acuosa, la concentración de ácido sulfúrico en la solución acuosa, el tiempo de paso de la varilla de cobre laminada en caliente a través de la solución y la temperatura de la solución acuosa con lo cual se mejora la lisura de superficie de la varilla de cobre laminada en caliente cepillada químicamente y sometida a tratamiento ácido y se remueven substancialmente los óxidos de superficie.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/009,775 US4754803A (en) | 1987-02-02 | 1987-02-02 | Manufacturing copper rod by casting, hot rolling and chemically shaving and pickling |
Publications (1)
Publication Number | Publication Date |
---|---|
MX165729B true MX165729B (es) | 1992-12-02 |
Family
ID=21739637
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX010266A MX165729B (es) | 1987-02-02 | 1988-02-01 | Procedimiento para cepillar quimicamente y someter a tratamiento acido una varilla de cobre |
Country Status (9)
Country | Link |
---|---|
US (1) | US4754803A (es) |
EP (1) | EP0277781B1 (es) |
JP (1) | JP2695423B2 (es) |
AT (1) | ATE76664T1 (es) |
CA (1) | CA1308002C (es) |
DE (1) | DE3871401D1 (es) |
ES (1) | ES2032957T3 (es) |
GR (1) | GR3004745T3 (es) |
MX (1) | MX165729B (es) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112720147A (zh) * | 2020-12-24 | 2021-04-30 | 无锡市红年金属制品科技有限公司 | 一种提高铜排表面处理效果的方法 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4899798A (en) * | 1988-11-28 | 1990-02-13 | Southwire Company | Method of and apparatus for recovering and reusing organic pickling vapors |
US5106454A (en) * | 1990-11-01 | 1992-04-21 | Shipley Company Inc. | Process for multilayer printed circuit board manufacture |
DE4136085C2 (de) * | 1991-10-30 | 1993-11-04 | Mannesmann Ag | Verfahren zum herstellen von sauerstoffreiem kupferdraht |
US5904157A (en) * | 1996-04-05 | 1999-05-18 | Phelps Dodge Industries, Inc. | Copper surface pickling system |
US6197210B1 (en) * | 1998-08-17 | 2001-03-06 | Gerber Plumbing Fixtures Corp. | Process for treating brass components to substantially eliminate leachabale lead |
EP1127946B1 (en) * | 2000-02-24 | 2005-10-12 | Mitsubishi Materials Corporation | Installation for producing continuously cast low-oxygen copper ingots |
DE10023480A1 (de) * | 2000-05-10 | 2001-11-15 | Sms Demag Ag | Verfahren zum Säubern oxidierter, warmgewalzter Kupferstäbe |
CA2443687C (en) | 2001-04-09 | 2009-08-11 | Vijay N. Madi | Hydrogen peroxide pickling of silicon-containing electrical steel grades |
AU2002252617B2 (en) | 2001-04-09 | 2007-05-31 | Ak Steel Properties, Inc. | Hydrogen peroxide pickling scheme for stainless steel grades |
WO2002081380A1 (en) * | 2001-04-09 | 2002-10-17 | Ak Properties, Inc. | Apparatus and method for removing hydrogen peroxide from spent pickle liquor |
US6803354B2 (en) | 2002-08-05 | 2004-10-12 | Henkel Kormanditgesellschaft Auf Aktien | Stabilization of hydrogen peroxide in acidic baths for cleaning metals |
US20090145856A1 (en) * | 2007-12-11 | 2009-06-11 | Raymond Letize A | Acid recycle process with iron removal |
RU2604162C2 (ru) * | 2014-02-19 | 2016-12-10 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Юго-Западный государственный университет" (ЮЗГУ) | Способ очистки поверхностей меди и ее сплавов от продуктов коррозии и окисления соединениями меди (ii) |
RU2639433C2 (ru) | 2016-04-12 | 2017-12-21 | Общество с ограниченной ответственностью "АНГАРА ДЕВЕЛОПМЕНТ", ООО "АНГАРА ДЕВЕЛОПМЕНТ" | Раствор для удаления отложений различной природы |
US11428482B2 (en) | 2016-04-12 | 2022-08-30 | Angara Global Ltd. | Industrial cleaning systems, including solutions for removing various types of deposits, and cognitive cleaning |
CN113235100A (zh) * | 2021-03-11 | 2021-08-10 | 中国科学院近代物理研究所 | 一种无氧铜钎焊前的表面处理方法 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2428804A (en) * | 1945-09-07 | 1947-10-14 | Esther M Terry | Copper cleaning composition |
US2678876A (en) * | 1950-12-26 | 1954-05-18 | Rca Corp | Conditioning of metal surfaces |
US2965521A (en) * | 1954-06-10 | 1960-12-20 | Crucible Steel Co America | Metal pickling solutions and methods |
US2856275A (en) * | 1956-11-20 | 1958-10-14 | Amchem Prod | Chemical treatment of refractory metal surfaces |
BE652530A (es) * | 1963-09-02 | |||
DE1255443B (de) * | 1964-08-22 | 1967-11-30 | Degussa | Verfahren zum chemischen AEtzen von gedruckten Schaltungen |
GB1119969A (en) * | 1965-04-27 | 1968-07-17 | Lancy Lab | Metal cleaning |
NL154561B (nl) * | 1965-04-27 | 1977-09-15 | Lancy Lab | Werkwijze voor het verwijderen van koper(i)oxyde en koper(ii)oxyde van een voorwerp met een oppervlak van koper of een koperlegering, werkwijze voor het bereiden van een hiervoor toe te passen beitsvloeistof en de door toepassing van deze beitswerkwijze verkregen voorwerpen. |
GB1157038A (en) * | 1967-09-19 | 1969-07-02 | Lancy Lab | Pickling Solutions for Removing Copper Oxides from Copper Containing Workpieces |
US3623532A (en) * | 1969-03-20 | 1971-11-30 | Southwire Co | Continuous pickling of cast rod |
BE757200A (fr) * | 1969-10-07 | 1971-03-16 | Westinghouse Electric Corp | Procede perfectionne pour produire du fil machine de cuivre |
SE388444B (sv) * | 1972-10-30 | 1976-10-04 | Southwire Co | Forfarande for kontinuerlig behandling av gjuten kopparstang med ett oxidskikt pa sin yta samt apparat for genomforande av forfarandet |
JPS526853B2 (es) * | 1972-12-22 | 1977-02-25 | ||
US3903244A (en) * | 1973-02-02 | 1975-09-02 | Fmc Corp | Stabilized hydrogen peroxide |
JPS5243195Y2 (es) * | 1973-09-22 | 1977-09-30 | ||
SE400575B (sv) * | 1974-12-13 | 1978-04-03 | Nordnero Ab | Bad for betning av koppar och dess legeringar |
SE400581B (sv) * | 1974-12-13 | 1978-04-03 | Nordnero Ab | Bad for kemisk polering av koppar och dess legeringar |
JPS5286933A (en) * | 1976-01-14 | 1977-07-20 | Tokai Electro Chemical Co | Method of treating surface of copper and copper alloy |
US4220706A (en) * | 1978-05-10 | 1980-09-02 | Rca Corporation | Etchant solution containing HF-HnO3 -H2 SO4 -H2 O2 |
US4175011A (en) * | 1978-07-17 | 1979-11-20 | Allied Chemical Corporation | Sulfate-free method of etching copper pattern on printed circuit boards |
DE2847267C2 (de) * | 1978-10-31 | 1993-12-23 | Decker Gmbh & Co Kg Geb | Stabilisator für eine wäßrige Lösung zum Beizen und/oder chemischen Glänzen von Gegenständen aus Kupfer oder Kupferlegierungen in einem mehrstufigen Verfahren und Verwendung des Stabilisators |
US4236957A (en) * | 1979-06-25 | 1980-12-02 | Dart Industries Inc. | Dissolution of metals utilizing an aqueous H2 SOY --H2 O.sub. -mercapto containing heterocyclic nitrogen etchant |
US4443268A (en) * | 1981-11-12 | 1984-04-17 | The Dow Chemical Company | Process for removing copper and copper oxide encrustations from ferrous surfaces |
JPS58197277A (ja) * | 1982-05-08 | 1983-11-16 | Mitsubishi Gas Chem Co Inc | 金属の化学的溶解処理液 |
US4401509A (en) * | 1982-09-07 | 1983-08-30 | Fmc Corporation | Composition and process for printed circuit etching using a sulfuric acid solution containing hydrogen peroxide |
FR2539140A1 (fr) * | 1983-01-07 | 1984-07-13 | Ugine Kuhlmann | Stabilisation de solutions aqueuses contenant du peroxyde d'hydrogene, de l'acide fluorhydrique et des ions metalliques |
JPS6061028U (ja) * | 1983-09-30 | 1985-04-27 | 松下電工株式会社 | エア−マツト |
US4510018A (en) * | 1984-02-21 | 1985-04-09 | The Lea Manufacturing Company | Solution and process for treating copper and copper alloys |
-
1987
- 1987-02-02 US US07/009,775 patent/US4754803A/en not_active Expired - Lifetime
-
1988
- 1988-01-22 CA CA000557154A patent/CA1308002C/en not_active Expired - Lifetime
- 1988-01-29 ES ES198888300778T patent/ES2032957T3/es not_active Expired - Lifetime
- 1988-01-29 DE DE8888300778T patent/DE3871401D1/de not_active Expired - Lifetime
- 1988-01-29 EP EP88300778A patent/EP0277781B1/en not_active Expired - Lifetime
- 1988-01-29 AT AT88300778T patent/ATE76664T1/de not_active IP Right Cessation
- 1988-02-01 MX MX010266A patent/MX165729B/es unknown
- 1988-02-01 JP JP63019718A patent/JP2695423B2/ja not_active Expired - Lifetime
-
1992
- 1992-05-28 GR GR920401000T patent/GR3004745T3/el unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112720147A (zh) * | 2020-12-24 | 2021-04-30 | 无锡市红年金属制品科技有限公司 | 一种提高铜排表面处理效果的方法 |
Also Published As
Publication number | Publication date |
---|---|
CA1308002C (en) | 1992-09-29 |
JPS63213685A (ja) | 1988-09-06 |
US4754803A (en) | 1988-07-05 |
JP2695423B2 (ja) | 1997-12-24 |
ATE76664T1 (de) | 1992-06-15 |
GR3004745T3 (es) | 1993-04-28 |
ES2032957T3 (es) | 1993-03-01 |
EP0277781B1 (en) | 1992-05-27 |
DE3871401D1 (de) | 1992-07-02 |
EP0277781A1 (en) | 1988-08-10 |
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