MX155379A - Procedimiento continuo mejorado para la hidroformilacion de una olefina - Google Patents

Procedimiento continuo mejorado para la hidroformilacion de una olefina

Info

Publication number
MX155379A
MX155379A MX184472A MX18447280A MX155379A MX 155379 A MX155379 A MX 155379A MX 184472 A MX184472 A MX 184472A MX 18447280 A MX18447280 A MX 18447280A MX 155379 A MX155379 A MX 155379A
Authority
MX
Mexico
Prior art keywords
hydroformilation
olephine
improved procedure
continuous improved
continuous
Prior art date
Application number
MX184472A
Other languages
English (en)
Inventor
Ernst Billing
Donald Leroy Bunning
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of MX155379A publication Critical patent/MX155379A/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
MX184472A 1979-10-26 1980-10-24 Procedimiento continuo mejorado para la hidroformilacion de una olefina MX155379A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/088,827 US4283562A (en) 1979-10-26 1979-10-26 Hydroformylation process using stable rhodium catalyst

Publications (1)

Publication Number Publication Date
MX155379A true MX155379A (es) 1988-02-26

Family

ID=22213740

Family Applications (1)

Application Number Title Priority Date Filing Date
MX184472A MX155379A (es) 1979-10-26 1980-10-24 Procedimiento continuo mejorado para la hidroformilacion de una olefina

Country Status (14)

Country Link
US (1) US4283562A (es)
EP (1) EP0028378B1 (es)
JP (1) JPS5671032A (es)
KR (1) KR840000212B1 (es)
AU (1) AU538456B2 (es)
BR (1) BR8006845A (es)
CA (1) CA1137998A (es)
DE (1) DE3069950D1 (es)
IN (1) IN154537B (es)
MX (1) MX155379A (es)
PL (1) PL129099B1 (es)
SU (1) SU1678201A3 (es)
YU (1) YU42711B (es)
ZA (1) ZA806160B (es)

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US4450299A (en) * 1980-10-01 1984-05-22 Exxon Research And Engineering Co. Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes
US4593141A (en) * 1979-02-12 1986-06-03 Exxon Research And Engineering Co. Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
US4687866A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Ligand exchange process for producing alkyl diaryl phosphine rhodium carbonyl hydrides
US4522933A (en) * 1981-08-17 1985-06-11 Union Carbide Corporation Hydroformylation catalyst containing bisphosphine monooxide ligands
US4593011A (en) * 1981-08-17 1986-06-03 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4491675A (en) * 1981-08-17 1985-01-01 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
IT1140319B (it) * 1981-12-04 1986-09-24 Consiglio Nazionale Ricerche Catalizzatori contenenti fosfine steroidali chirale precessi catalitici asimmetrici che li impiegano
US4668809A (en) * 1982-05-03 1987-05-26 Exxon Research And Engineering Transition metal complex catalysts
US4595753A (en) * 1982-05-03 1986-06-17 Exxon Research And Engineering Co. Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride complex hydroformylation catalyst compositions
DE3372361D1 (en) * 1982-06-11 1987-08-13 Davy Mckee London Hydroformylation process
US4668823A (en) * 1983-12-30 1987-05-26 Union Carbide Corporation Process for the preparation of bulky alkyldiarylphosphines and unsymmetrical aryldialkyl phosphines
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) * 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4593127A (en) * 1985-01-11 1986-06-03 Union Carbide Corporation Hydroformylation process
US4625068A (en) * 1985-03-20 1986-11-25 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of internal olefins
US4642388A (en) * 1985-08-30 1987-02-10 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of alpha-substituted alpha-olefins
KR950012999B1 (ko) * 1986-07-01 1995-10-24 데이비 맥키(런던) 리미티드 하이드로포르밀화에 의한 알데히드의 제조방법
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
JPH031927U (es) * 1989-05-26 1991-01-10
US5001274A (en) * 1989-06-23 1991-03-19 Union Carbide Chemicals And Plastics Company Inc. Hydroformylation process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5731473A (en) * 1995-12-06 1998-03-24 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US6265619B1 (en) 1996-01-17 2001-07-24 Exxon Chemical Patents Inc. Oxygenates and processes for their manufacture
US5892119A (en) * 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
JP3864669B2 (ja) * 2000-05-08 2007-01-10 三菱化学株式会社 ヒドロホルミル化方法
WO2005007602A1 (en) 2003-07-03 2005-01-27 Union Carbide Chemicals & Plastics Technology Corporation Minimization of ligand degradation products, of reversion of same to useful phosphine ligands
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
DE10352261B4 (de) * 2003-11-08 2006-08-24 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von TCD-Dialdehyd
CA2575122C (en) * 2004-08-02 2013-06-25 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of a hydroformylation process
BRPI0609384B1 (pt) 2005-03-16 2015-09-15 Perstorp Specialty Chemicals Ab processo de hidroformilação com iso-seletividade
WO2009091669A1 (en) 2008-01-15 2009-07-23 Dow Global Technologies Inc. Sulfonated organophosphine compounds and use in hydroformylation processes
DE102009004655B4 (de) 2009-01-15 2013-02-14 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
DE102009016652A1 (de) 2009-04-07 2010-10-14 Oxea Gmbh Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
DE102009016651B4 (de) 2009-04-07 2011-11-17 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
IN2014CN02246A (es) 2011-09-30 2015-06-12 Dow Technology Investments Llc
EP2794537B1 (en) 2011-12-20 2016-01-06 Dow Technology Investments LLC A hydroformylation process
US8710276B2 (en) * 2012-05-24 2014-04-29 Lg Chem, Ltd. Catalyst compositions for hydroformylation reaction and hydroformylation process using the same
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
DE102012013969B4 (de) 2012-07-13 2017-09-14 Oxea Gmbh Verfahren zur Herstellung eines Gemisches stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
DE102012014396B4 (de) 2012-07-13 2018-01-11 Oxea Gmbh Verfahren zur Herstellung eines Vinylestergemisches aus einem Gemisch stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
DE102012014395B3 (de) 2012-07-13 2013-08-22 Oxea Gmbh Isononylamine ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE102012013968A1 (de) 2012-07-13 2014-04-03 Oxea Gmbh Carbonsäureester der Isononansäure ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
EP3414220B1 (en) 2016-02-11 2021-10-13 Dow Technology Investments LLC Processes for converting olefins to alcohols, ethers, or combinations thereof
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
CA3100779A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Methods of controlling hydroformylation processes
WO2019231613A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it
JP2021525165A (ja) 2018-05-30 2021-09-24 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスにおける触媒失活を遅らせるための方法、および/またはテトラホスフィン配位子の使用を遅らせるための方法
CN113698280B (zh) * 2020-05-21 2023-10-13 中国石油化工股份有限公司 一种烯烃加氢甲酰化方法
CN114515606B (zh) * 2020-11-20 2023-12-19 万华化学集团股份有限公司 一种氢甲酰化反应催化剂组合物及其应用
JP2024500349A (ja) 2020-12-22 2024-01-09 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化反応方法

Family Cites Families (10)

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US3448157A (en) * 1965-09-27 1969-06-03 Shell Oil Co Hydroformylation of olefins
US3487112A (en) * 1967-04-27 1969-12-30 Monsanto Co Vapor phase hydroformylation process
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3644446A (en) * 1969-07-01 1972-02-22 Union Oil Co Preparation of rhodium and iridium hydride carbonyl complexes
GB1338237A (en) * 1969-12-22 1973-11-21 Union Carbide Corp Hydroformylation process
US4101588A (en) * 1973-04-07 1978-07-18 Basf Aktiengesellschaft Production of bis-(dimethyl) acetals of hexane dialdehydes
IT1005691B (it) * 1973-04-07 1976-09-30 Basf Ag Processo per la preparazione di dialdeidi alifatiche o cicloalifa tiche e oppure dei loro acetali
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
ZA78146B (en) * 1977-01-25 1978-12-27 Union Carbide Corp Improved hydroformylation process
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins

Also Published As

Publication number Publication date
CA1137998A (en) 1982-12-21
DE3069950D1 (en) 1985-02-21
PL129099B1 (en) 1984-03-31
BR8006845A (pt) 1981-04-28
JPS5671032A (en) 1981-06-13
AU6367380A (en) 1981-04-30
US4283562A (en) 1981-08-11
JPH02332B2 (es) 1990-01-08
YU272280A (en) 1983-10-31
EP0028378B1 (en) 1985-01-09
ZA806160B (en) 1981-09-30
IN154537B (es) 1984-11-03
YU42711B (en) 1988-12-31
EP0028378A1 (en) 1981-05-13
KR830004326A (ko) 1983-07-09
PL227478A1 (es) 1981-07-10
SU1678201A3 (ru) 1991-09-15
AU538456B2 (en) 1984-08-16
KR840000212B1 (ko) 1984-02-29

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