MD4062C1 - Compoziţie catalitică pentru reacţia Morita-Baylis-Hillman - Google Patents

Compoziţie catalitică pentru reacţia Morita-Baylis-Hillman

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Publication number
MD4062C1
MD4062C1 MDA20100004A MD20100004A MD4062C1 MD 4062 C1 MD4062 C1 MD 4062C1 MD A20100004 A MDA20100004 A MD A20100004A MD 20100004 A MD20100004 A MD 20100004A MD 4062 C1 MD4062 C1 MD 4062C1
Authority
MD
Moldova
Prior art keywords
baylis
morita
catalytic composition
hillman reaction
hillman
Prior art date
Application number
MDA20100004A
Other languages
English (en)
Russian (ru)
Other versions
MD4062B1 (ro
Inventor
Виорика ШАРГАРОВСКИ
Наталия СУКМАН
Татьяна ЮДИН
Даниела ДУКА
Еужения СТЫНГАЧ
Флюр МАКАЕВ
Original Assignee
Институт Химии Академии Наук Молдовы
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Институт Химии Академии Наук Молдовы filed Critical Институт Химии Академии Наук Молдовы
Priority to MDA20100004A priority Critical patent/MD4062C1/ro
Publication of MD4062B1 publication Critical patent/MD4062B1/ro
Publication of MD4062C1 publication Critical patent/MD4062C1/ro

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Invenţia se referă la compoziţiile catalitice, în particular la compoziţiile care conţin lichide ionice şi pot fi utilizate în reacţiile Morita-Baylis-Hillman.Compoziţia, conform invenţiei, conţine 4-dimetilaminopiridină şi hexafluorfosfat de 1,3-di(2-cianoetil)imidazoliu în calitate de lichid ionic, într-un raport al componentelor, respectiv, de 8:1.Rezultatul invenţiei constă în sporirea esenţială a randamentului reacţiei Morita-Baylis-Hillman.
MDA20100004A 2010-01-16 2010-01-16 Compoziţie catalitică pentru reacţia Morita-Baylis-Hillman MD4062C1 (ro)

Priority Applications (1)

Application Number Priority Date Filing Date Title
MDA20100004A MD4062C1 (ro) 2010-01-16 2010-01-16 Compoziţie catalitică pentru reacţia Morita-Baylis-Hillman

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MDA20100004A MD4062C1 (ro) 2010-01-16 2010-01-16 Compoziţie catalitică pentru reacţia Morita-Baylis-Hillman

Publications (2)

Publication Number Publication Date
MD4062B1 MD4062B1 (ro) 2010-08-31
MD4062C1 true MD4062C1 (ro) 2011-03-31

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ID=43569041

Family Applications (1)

Application Number Title Priority Date Filing Date
MDA20100004A MD4062C1 (ro) 2010-01-16 2010-01-16 Compoziţie catalitică pentru reacţia Morita-Baylis-Hillman

Country Status (1)

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MD (1) MD4062C1 (ro)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD4233C1 (ro) * 2012-03-02 2014-01-31 Институт Химии Академии Наук Молдовы Catalizator pentru sinteza derivaţilor 2-pirol-3-iloxindolului

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WO2007112238A2 (en) * 2006-03-24 2007-10-04 Chevron U.S.A. Inc. Alkylation process using an alkyl halide promoted ionic liquid catalyst
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CN101260079A (zh) * 2008-03-16 2008-09-10 浙江工业大学 一种7，8-二氢喹啉-2，5(1h，6h)-二酮类衍生物的制备方法
CN101260078A (zh) * 2008-03-16 2008-09-10 浙江工业大学 一种7，8-二氢喹啉-5(6h)-酮类衍生物的制备方法
WO2008152005A1 (de) * 2007-06-12 2008-12-18 Basf Se Katalysator für die härtung von epoxiden
CN101362100A (zh) * 2008-09-12 2009-02-11 复旦大学 手性胺-(硫)脲双功能催化剂及其合成方法和应用
KR20090063771A (ko) * 2007-12-14 2009-06-18 성균관대학교산학협력단 신규한 베타 치환된 모리타-베일리스-힐만 유도체
US20090216015A1 (en) * 2005-01-04 2009-08-27 The Queen's University Of Belfast Base Stable Ionic Liquids
WO2009110655A1 (en) * 2008-03-06 2009-09-11 Sungkyunkwan University Foundation For Corporate Collaboration Novel beta substituted morita-baylis-hillman derivatives

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1147595A (en) * 1965-04-01 1969-04-02 Bayer Ag Switching filaments and films of high molecular weight polyoxymethylenes
MD19C2 (ro) * 1980-06-02 1994-05-31 Эмерикэн Сайенэмид Компэни Procedeu de obţinere a 2-(2-imidazolin-2-il) piridinelor sau hinolinelor
RU2133641C1 (ru) * 1993-09-22 1999-07-27 Энститю Франсэ Дю Петроль Каталитическая композиция и способ димеризации олефинов
RU2189859C2 (ru) * 1996-12-12 2002-09-27 ЭНИКЕМ С.п.А. Каталитическая композиция и способ алкилирования и/или переалкилирования ароматических соединений
WO2000041809A1 (en) * 1999-01-15 2000-07-20 Bp Chemicals Limited Ionic liquid catalyst for alkylation
RU2189858C1 (ru) * 2001-03-20 2002-09-27 Закрытое акционерное общество "Новые каталитические технологии" Катализатор получения жидких углеводородов из низкомолекулярных кислородсодержащих органических соединений
KR20030062542A (ko) * 2002-01-17 2003-07-28 한국과학기술연구원 베타 메틸 베일리스-힐만 생성물 및 인듐을 이용한 그제조방법
US20090216015A1 (en) * 2005-01-04 2009-08-27 The Queen's University Of Belfast Base Stable Ionic Liquids
WO2007009299A1 (fr) * 2005-07-19 2007-01-25 Chengdu Institute Of Biology, Chinese Academy Of Sciences Prolylhydrazines n',n'-disubstituees optiquement pures, leur preparation et leur utilisation
US20070117822A1 (en) * 2005-09-12 2007-05-24 Puli Narender Novel antimalarial baylis-hillman adducts and a process for the preparation thereof
CN101215294A (zh) * 2006-03-03 2008-07-09 中国科学院长春应用化学研究所 一类手性联萘酚硅氧烷衍生物以及其制备方法
WO2007112238A2 (en) * 2006-03-24 2007-10-04 Chevron U.S.A. Inc. Alkylation process using an alkyl halide promoted ionic liquid catalyst
CN1948320A (zh) * 2006-11-10 2007-04-18 中国科学院上海有机化学研究所 手性膦硫脲化合物、合成方法及其应用
WO2008152005A1 (de) * 2007-06-12 2008-12-18 Basf Se Katalysator für die härtung von epoxiden
KR20090063771A (ko) * 2007-12-14 2009-06-18 성균관대학교산학협력단 신규한 베타 치환된 모리타-베일리스-힐만 유도체
WO2009110655A1 (en) * 2008-03-06 2009-09-11 Sungkyunkwan University Foundation For Corporate Collaboration Novel beta substituted morita-baylis-hillman derivatives
CN101260078A (zh) * 2008-03-16 2008-09-10 浙江工业大学 一种7，8-二氢喹啉-5(6h)-酮类衍生物的制备方法
CN101260079A (zh) * 2008-03-16 2008-09-10 浙江工业大学 一种7，8-二氢喹啉-2，5(1h，6h)-二酮类衍生物的制备方法
CN101362100A (zh) * 2008-09-12 2009-02-11 复旦大学 手性胺-(硫)脲双功能催化剂及其合成方法和应用

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
Garden S.J., Skakle M.S. Isatin derivatives are reactive electrophilic components for the Baylis-Hillman reaction. Tetrah. Lett., 2002, V.43, p. 1969…1972. *
Jiang T., Kuhen K.L., Wolf K., Yin H., Bieza K., Caldwell J., Bursulaya B., Wu T. Y-H., He Yun. Design, synthesis and biological evaluations of novel *
oxindoles as HIV-1 non-nucleoside reverse transcriptase inhibitors. Part I. Bioorg. Med. Chem. Lett., 2006, V. 16, p. 2105…2108. *
S.J., Skakle M.S. Isatin derivatives are reactive electrophilic components for the Baylis-Hillman reaction. Tetrah. Lett., 2002, V.43, p. 1969(1972. *
T., Kuhen K.L., Wolf K., Yin H., Bieza K., Caldwell J., Bursulaya B., Wu T. Y-H., He Yun. Design, synthesis and biological evaluations of novel oxindoles as HIV-1 non-nucleoside reverse transcriptase inhibitors. Part I. Bioorg. Med. Chem. Lett., 2006, V. 16, p. 2105(2108. *

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FG4A Patent for invention issued
KA4A Patent for invention lapsed due to non-payment of fees (with right of restoration)
MM4A Patent for invention definitely lapsed due to non-payment of fees