MA44800A1 - Récupérateur pour la valorisation de minerais de phosphate carbones - Google Patents
Récupérateur pour la valorisation de minerais de phosphate carbonesInfo
- Publication number
- MA44800A1 MA44800A1 MA44800A MA44800A MA44800A1 MA 44800 A1 MA44800 A1 MA 44800A1 MA 44800 A MA44800 A MA 44800A MA 44800 A MA44800 A MA 44800A MA 44800 A1 MA44800 A1 MA 44800A1
- Authority
- MA
- Morocco
- Prior art keywords
- sodium
- improved
- phosphate
- recuperator
- fatty acid
- Prior art date
Links
- 238000011084 recovery Methods 0.000 title abstract 2
- IHTFTOGFXXXQBO-UHFFFAOYSA-B [C+4].[C+4].[C+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [C+4].[C+4].[C+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O IHTFTOGFXXXQBO-UHFFFAOYSA-B 0.000 title 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 3
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 3
- 239000000194 fatty acid Substances 0.000 abstract 3
- 229930195729 fatty acid Natural products 0.000 abstract 3
- 150000004665 fatty acids Chemical class 0.000 abstract 3
- 238000005188 flotation Methods 0.000 abstract 3
- 239000010452 phosphate Substances 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 abstract 3
- 239000000126 substance Substances 0.000 abstract 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- -1 alkaline earth metal carbonate Chemical class 0.000 abstract 1
- LPTWEDZIPSKWDG-UHFFFAOYSA-N benzenesulfonic acid;dodecane Chemical compound OS(=O)(=O)C1=CC=CC=C1.CCCCCCCCCCCC LPTWEDZIPSKWDG-UHFFFAOYSA-N 0.000 abstract 1
- 229910001748 carbonate mineral Inorganic materials 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000002516 radical scavenger Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 229940080272 sodium coco-sulfate Drugs 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 abstract 1
- 239000001488 sodium phosphate Substances 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 abstract 1
- 235000019801 trisodium phosphate Nutrition 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/0006—Settling tanks provided with means for cleaning and maintenance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/021—Froth-flotation processes for treatment of phosphate ores
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/01—Treating phosphate ores or other raw phosphate materials to obtain phosphorus or phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/38—Condensed phosphates
- C01B25/40—Polyphosphates
- C01B25/41—Polyphosphates of alkali metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/38—Condensed phosphates
- C01B25/42—Pyrophosphates
- C01B25/425—Pyrophosphates of alkali metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/06—Phosphate ores
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Fats And Perfumes (AREA)
Abstract
L'invention concerne un procédé de flottation utilisant un récupérateur amélioré pour éliminer les impuretés à base de carbonates de métaux alcalino-terreux hors de minerais de phosphate. La charge de flottation peut être traitée à l'aide du récupérateur de carbonate amélioré à un ph acide, et soumise à une flottation inverse. Le trop-plein de la cellule peut être recueilli en tant que déchet dans lequel les minéraux carbonatés dominent, et le sous-écoulement de la cellule peut correspondre au concentré de phosphate. Le récupérateur peut être constitué d'une combinaison de produits chimiques, comprenant : (1) un quelconque type d'acide gras, qu'il s'agisse d'un acide gras classique, d'un acide gras saponifié ou d'un acide gras modifié ; (2) des produits chimiques comportant des groupes sulfonate ou sulfate, tels que l'acide dodécylbenzène sulfonique (ddbsa) ou son sel, le dodécylsulfate de sodium (sds), le laurylsulfate de sodium (sls), le cocosulfate de sodium (scs), etc. ;et (3) des produits chimiques contenant du phosphore, tels que le tripolyphosphate de sodium (stpp), l'hexamétaphosphate de sodium (sfmp), le phosphate trisodique (tsp), le tétrasodiumpyrophosphate (tspp), etc. Avec ce récupérateur amélioré, la sélectivité de séparation et la récupération de phosphate peuvent être considérablement améliorées.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662374523P | 2016-08-12 | 2016-08-12 | |
US15/672,891 US10434520B2 (en) | 2016-08-12 | 2017-08-09 | Collector for beneficiating carbonaceous phosphate ores |
PCT/US2017/046297 WO2018031774A1 (fr) | 2016-08-12 | 2017-08-10 | Récupérateur pour la valorisation de minerais de phosphate carbonés |
Publications (2)
Publication Number | Publication Date |
---|---|
MA44800A1 true MA44800A1 (fr) | 2020-04-30 |
MA44800B1 MA44800B1 (fr) | 2020-11-30 |
Family
ID=61160775
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MA44800A MA44800B1 (fr) | 2016-08-12 | 2017-08-10 | Récupérateur pour la valorisation de minerais de phosphate carbones |
Country Status (5)
Country | Link |
---|---|
US (1) | US10434520B2 (fr) |
BR (1) | BR112019002354A2 (fr) |
MA (1) | MA44800B1 (fr) |
SA (1) | SA519401019B1 (fr) |
WO (1) | WO2018031774A1 (fr) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MA44916B1 (fr) | 2016-08-26 | 2020-11-30 | Ecolab Usa Inc | Modificateurs sulfonés pour flottation par mousse |
WO2018222524A1 (fr) * | 2017-05-30 | 2018-12-06 | Ecolab Usa Inc. | Compositions et procédés améliorés pour la flottation par mousse inverse de minerais de phosphate |
CN110152889A (zh) * | 2019-06-04 | 2019-08-23 | 瓮福(集团)有限责任公司 | 一种硅钙质磷矿反浮选脱硅除杂组合捕收剂及其制备方法和应用 |
CN110142145A (zh) * | 2019-06-04 | 2019-08-20 | 瓮福(集团)有限责任公司 | 一种浮选脱除硅钙质胶磷矿中倍半氧化物及镁杂质的工艺 |
CN110090738B (zh) * | 2019-06-13 | 2021-04-16 | 河北瓮福正昌工贸有限公司 | 一种除方解石的磷块石反浮选捕收剂及其制备方法与应用 |
CN110369152B (zh) * | 2019-07-15 | 2021-12-03 | 宜都兴发化工有限公司 | 一种微细粒磷矿浮选工艺 |
CN110639708A (zh) * | 2019-10-09 | 2020-01-03 | 南京工业大学 | 一种基于多通道陶瓷膜分布器的细粒磷灰石浮选方法及浮选*** |
CN111036412B (zh) * | 2019-11-27 | 2021-03-16 | 东北大学 | 一种抑制剂hpma在磷矿石正浮选脱镁中的应用 |
CN111215247B (zh) * | 2020-01-07 | 2021-04-23 | 中南大学 | 一种用于高钙萤石正浮选的抑制剂及浮选方法 |
CN111617885B (zh) * | 2020-05-18 | 2022-09-16 | 宜都兴发化工有限公司 | 一种低镁高倍半胶磷矿同步反浮选工艺 |
EP4342587A1 (fr) * | 2022-09-22 | 2024-03-27 | ArrMaz Products Inc. | Composition collectrice pour enrichir des minerais de phosphate carbonés |
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EP2376230B1 (fr) | 2008-12-11 | 2014-07-30 | Basf Se | Enrichissement de minerais de valeur à partir de résidu minier (tailings) |
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ES2938544T3 (es) | 2011-07-29 | 2023-04-12 | Kemira Oyj | Polímeros inhibidores de incrustaciones y métodos para prevenir la formación de incrustaciones |
EP2872453B1 (fr) | 2012-07-10 | 2020-10-28 | Kemira Oyj | Compositions antitartre à base de polymères étiquetés et procédés d'inhibition de la formation de tartre |
CN103056036B (zh) * | 2013-01-25 | 2014-04-23 | 中国地质科学院矿产综合利用研究所 | 一种胶磷矿常温正浮选捕收剂的制备方法 |
WO2014176419A1 (fr) | 2013-04-24 | 2014-10-30 | Kemira Oyj | Polymères d'inhibition de la formation de dépôt et procédés pour le contrôle de la formation de dépôt |
PT2883573T (pt) | 2013-12-13 | 2018-01-04 | Omya Int Ag | Composição de limpeza abrasiva |
CN105873653B (zh) | 2014-01-08 | 2018-08-10 | 巴斯夫欧洲公司 | 通过淘析减少包含磁性附聚物的体积流的方法 |
-
2017
- 2017-08-09 US US15/672,891 patent/US10434520B2/en active Active
- 2017-08-10 MA MA44800A patent/MA44800B1/fr unknown
- 2017-08-10 BR BR112019002354A patent/BR112019002354A2/pt not_active Application Discontinuation
- 2017-08-10 WO PCT/US2017/046297 patent/WO2018031774A1/fr active Application Filing
-
2019
- 2019-02-04 SA SA519401019A patent/SA519401019B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
SA519401019B1 (ar) | 2022-09-08 |
MA44800B1 (fr) | 2020-11-30 |
US20180043373A1 (en) | 2018-02-15 |
WO2018031774A1 (fr) | 2018-02-15 |
BR112019002354A2 (pt) | 2019-06-18 |
US10434520B2 (en) | 2019-10-08 |
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