KR970065563A - 알루미늄 화합물 함유 고체 촉매 성분, 올레핀 중합용 촉매 및 올레핀 중합체의 제조방법 - Google Patents
알루미늄 화합물 함유 고체 촉매 성분, 올레핀 중합용 촉매 및 올레핀 중합체의 제조방법 Download PDFInfo
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- KR970065563A KR970065563A KR1019970008898A KR19970008898A KR970065563A KR 970065563 A KR970065563 A KR 970065563A KR 1019970008898 A KR1019970008898 A KR 1019970008898A KR 19970008898 A KR19970008898 A KR 19970008898A KR 970065563 A KR970065563 A KR 970065563A
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- containing solid
- catalyst component
- solid catalyst
- transition metal
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- 239000011949 solid catalyst Substances 0.000 title claims abstract 20
- 150000001336 alkenes Chemical class 0.000 title claims abstract 16
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract 13
- -1 Aluminum compound Chemical class 0.000 title claims abstract 12
- 239000003054 catalyst Substances 0.000 title claims abstract 12
- 229920000098 polyolefin Polymers 0.000 title claims abstract 5
- 238000006116 polymerization reaction Methods 0.000 title claims 10
- 238000002360 preparation method Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 12
- 150000003623 transition metal compounds Chemical class 0.000 claims abstract 9
- 229910052723 transition metal Inorganic materials 0.000 claims abstract 8
- 150000003624 transition metals Chemical class 0.000 claims abstract 8
- 238000004519 manufacturing process Methods 0.000 claims abstract 4
- 230000000379 polymerizing effect Effects 0.000 claims abstract 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 239000004711 α-olefin Substances 0.000 claims 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 2
- 229940126062 Compound A Drugs 0.000 abstract 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
담체를 오가노알루미늄옥시 화합물과 접촉시킨 다음 친전자성 그룹을 보유하는 화합물과 접촉시켜 수득한 알루미늄 화합물 함유 고체 촉매 성분, 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분, 알루미늄 화합물 함유 고체 촉매 성분과 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매 및 올레핀 중합용 촉매를 사용하여 올레핀을 중합시키거나 공중합시킴을 포함하는 올레핀 중합체의 제조방법.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (19)
- 담체를 오가노알루미늄옥시 화합물과 접촉시킨 다음 친전자성 그룹을 보유하는화합물과 접촉시켜 수득한 알루미늄 화합물 함유 고체 촉매 성분.
- 제1항에 있어서, 친전자성 그룹을 보유하는 화합물이 또한 극성 작용성 그룹을 보유하는 알루미늄 화합물함유 고체 촉배 성분.
- 제1항에 있어서, 친전자자성 그룹을 보유하는 화합물이 할로겐화 페놀인 알루미늄 화합물 함유 고체 촉매 성분.
- 제1항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.
- 제2항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.
- 제3항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.
- 제4항에 있어서, 전이 금속 화합물이 메탈로센 전이 금속 화합물인 전이 금속 함유 고체 촉매 성분.
- 제1항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
- 제2항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
- 제3항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
- 제4항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
- 제5항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
- 제6항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
- 제7항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.
- 제8항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.
- 제9항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.
- 제14항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.
- 제15항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.
- 제16항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP96-062610 | 1996-03-19 | ||
JP06261096A JP3959132B2 (ja) | 1996-03-19 | 1996-03-19 | アルミニウム化合物含有固体触媒成分、オレフィン重合用触媒及びオレフィン重合体の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970065563A true KR970065563A (ko) | 1997-10-13 |
KR100473441B1 KR100473441B1 (ko) | 2005-07-18 |
Family
ID=13205265
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019970008898A KR100473441B1 (ko) | 1996-03-19 | 1997-03-17 | 알루미늄화합물함유고체촉매성분,올레핀중합용촉매및올레핀중합체의제조방법 |
Country Status (6)
Country | Link |
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US (2) | US6100213A (ko) |
JP (1) | JP3959132B2 (ko) |
KR (1) | KR100473441B1 (ko) |
CN (1) | CN1097063C (ko) |
DE (1) | DE19711304B4 (ko) |
SG (1) | SG83662A1 (ko) |
Families Citing this family (22)
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JP4440355B2 (ja) | 1998-03-25 | 2010-03-24 | 住友化学株式会社 | 改質された粒子、それよりなる担体、それよりなるオレフィン重合用触媒成分、それを用いてなるオレフィン重合用触媒、およびオレフィン重合体の製造方法 |
US6664208B1 (en) | 1999-09-07 | 2003-12-16 | Sumitomo Chemical Company, Limited | Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocarbon polymer |
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DE69219206T2 (de) * | 1991-05-31 | 1997-08-28 | Mitsui Petrochemical Ind | Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation |
DE4139262A1 (de) * | 1991-11-29 | 1993-06-03 | Basf Ag | Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen |
US5939346A (en) * | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
US5391793A (en) * | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
DE69403928T2 (de) * | 1993-04-09 | 1997-12-18 | Tosoh Corp | Katalysator und Verfahren zur Olefin-Polymerisation |
JP3196419B2 (ja) * | 1993-05-20 | 2001-08-06 | 出光興産株式会社 | アルミニウムオキシ化合物及びそれを含有する重合用触媒 |
ES2122394T3 (es) * | 1994-06-03 | 1998-12-16 | Pcd Polymere Ag | Soporte para catalizador, catalizadores soportados de metaloceno y su empleo para la obtencion de poliolefinas. |
-
1996
- 1996-03-19 JP JP06261096A patent/JP3959132B2/ja not_active Expired - Fee Related
-
1997
- 1997-03-17 SG SG9700812A patent/SG83662A1/en unknown
- 1997-03-17 KR KR1019970008898A patent/KR100473441B1/ko not_active IP Right Cessation
- 1997-03-18 DE DE19711304A patent/DE19711304B4/de not_active Expired - Fee Related
- 1997-03-19 CN CN97110051A patent/CN1097063C/zh not_active Expired - Fee Related
- 1997-03-19 US US08/820,046 patent/US6100213A/en not_active Expired - Fee Related
-
2000
- 2000-02-29 US US09/516,028 patent/US6333388B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR100473441B1 (ko) | 2005-07-18 |
US6333388B1 (en) | 2001-12-25 |
CN1097063C (zh) | 2002-12-25 |
SG83662A1 (en) | 2001-10-16 |
JPH09249707A (ja) | 1997-09-22 |
DE19711304B4 (de) | 2009-01-08 |
US6100213A (en) | 2000-08-08 |
DE19711304A1 (de) | 1997-10-30 |
CN1168387A (zh) | 1997-12-24 |
JP3959132B2 (ja) | 2007-08-15 |
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