KR970001234B1 - Liquid detergent composition for body - Google Patents
Liquid detergent composition for body Download PDFInfo
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- KR970001234B1 KR970001234B1 KR1019940014235A KR19940014235A KR970001234B1 KR 970001234 B1 KR970001234 B1 KR 970001234B1 KR 1019940014235 A KR1019940014235 A KR 1019940014235A KR 19940014235 A KR19940014235 A KR 19940014235A KR 970001234 B1 KR970001234 B1 KR 970001234B1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
본 발명은 모발 및 인체세정에 적합한 투명 인체세정제에 관한 것으로 더욱 상세하게는 칼륨비누(Potassium Soap)를 주기체(Base)로 하여 모발 손상을 방지하는데 효과가 우수한 동백기름과 천연의 여러 식물성 오일중에서 점도가 높고 응고점이 낮으면서 높은 부착력으로 인해 피부보호제로 사용되어온 피마자유, 에탄올, 셀루루스 플리머인 HEC-QP-100MH을 첨가하여 저온안정성과 점도를 향상시킨 투명액체 인체세정제에 관한 것이다.The present invention relates to a transparent human cleanser suitable for washing hair and the human body, and more particularly, in a camellia oil and natural vegetable oils, which are excellent in preventing hair damage by using potassium soap (Potassium Soap) as a base. The present invention relates to a transparent liquid human cleanser having improved low temperature stability and viscosity by adding HEC-QP-100MH, which is a castor oil, ethanol, and cellulose plymer, which has been used as a skin protection agent due to its high viscosity and low freezing point.
일반적인 화장비누는 각종 동물성 유지 및 식물성 유지를 수산화나트륨을 사용하여 비누화반응을 시킨 다음 수분 12 내지 15% 정도의 칩(Chip)으로 만든 후 불쾌한 취기를 제거하기 위하여 향을 첨가하여 피부의 보습성, 윤활성을 위하여 각종 유연제나 보습제 기타 필요에 따라 여러가지 첨가제를 추가로 배합하여 고형으로 제조된 것을 말한다. 그러나 비누의 특성상 물과 접촉하면 지방산이 생성되며 이 유리된 지방산과 수중의 Ca, Mg 이온과 반응으로 생성된 금속염이 모발 세정시에 모발에 부착되어 모발을 거칠게 만들며 촉감을 나쁘게 한다. 또한 비이온, 양쪽성, 음이온 계통의 여러가지 합성 계면활성제를 이용한 샴푸류는 모발 세정시에는 비누기재(Soap Base)로 만든 제품보다 사용감이 우수하나 세안시에나 인체세정시에는 미끈거리는 감촉이 오랫동안 지속되므로 사용후 거부감을 느낄수도 있다. 기존의 액체비누는 주로 합성 계면활성제를 이용한 것이 주류를 이루고 있으며 비누기재(Soap Base)로 한 제품은 저온에서는 용기내에서 굳어 버리거나 비누의 결정화로 인하여 투명도를 유지할 수 없으며 점도조정제로 사용되는 염화나트륨으로 인하여 기포력이 현저히 떨어지며 이를 보완하기 위하여 음이온 계통의 합성 계면활성제를 사용함으로써 비누기재(Soap Base)로한 본래의 의미를 상실하게 된다.In general, cosmetic soaps are saponified with sodium hydroxide for various animal fats and vegetable fats, and then made into chips of about 12 to 15% of moisture, and then added fragrance to remove unpleasant odors. It refers to various softeners, moisturizers, etc. for the lubricity. However, due to the nature of soap, fatty acids are produced when it comes into contact with water, and the free fatty acids and metal salts formed by reaction with Ca and Mg ions in the water adhere to the hair when washing hair, making the hair rough and feeling bad. In addition, shampoos using non-ionic, amphoteric, and anionic synthetic surfactants have a better feeling of use than soap-based products when washing hair, but they have a long lasting texture when washing or washing the human body. You may feel rejected after use. Conventional liquid soaps are mainly composed of synthetic surfactants. Soap base products are hardened in a container at low temperatures or cannot be kept clear due to crystallization of soap. Sodium chloride is used as a viscosity modifier. Due to this, the foaming strength is significantly lowered and the original meaning of soap base is lost by using synthetic anionic surfactants to compensate for this.
이에 본 발명자들은 상기와 같은 액체비누의 단점을 해결하기 위해 연구한 결과 기존의 샴푸류나 인체세정재보다 적은 양의 합성 계면활성제를 사용하면서도 기포력, 세정력, 사용감이 우수하여 모발세정시나 세안시에 적합한 투명 액체비누를 제조할 수 있었다.Accordingly, the present inventors have studied to solve the disadvantages of the liquid soap as described above, while using a small amount of the synthetic surfactant than conventional shampoos or human cleansing agents, while having excellent foaming power, cleaning power, and feeling, Suitable clear liquid soaps could be prepared.
이하 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.
본 발명은 모발 및 인체세정에 적합한 액체세제를 제조하는데 있어서 전체 세제액의 5 내지 15중량%의 라우릭산(Lauric Acid) 및 미리스틱산(Myristic Acid)을 물에 용해시킨 다음 이에 맞는 당량의 KOH로 완전히 중화시킨다. 중화반응이 완결됨을 확인한 후 냉각하면서 액의 온도가 60℃ 되었을때 점도상승제 0.1 내지 0.5중량% 및 코카미도프로필 베타인(Cocamidopropyl Betain) 30%(CAB~30, 분자량 : 366) 1.0 내지 5.0중량%, 코코아야자 지방산 디에탄올 아마이드(Coconut fattyacid diethanol amide)(CDE, 분자량 : 301) 1.0 내지 5.0중량%, 피마자유 0.5 내지 3.0중량%, 동백기름 0.5 내지 3.0중량%를 첨가시킨 후 액이 완전히 균일할 때까지 교반을 계속하면서 냉각시킨다. 액의 온도가 45℃까지 냉각되었을때 에탄올 0.5중량% 및 향, 기타 필요에 따라 여러가지 첨가제를 배합한 후 실온에서 냉각시키고 여과하여 제조한다.In the present invention, in preparing a liquid detergent suitable for hair and human body washing, 5 to 15% by weight of lauric acid and myristic acid of the total detergent solution are dissolved in water, and then an equivalent amount of KOH. Neutralize completely. After confirming that the neutralization reaction was completed, when the temperature of the liquid was cooled to 60 ° C., 0.1 to 0.5% by weight of viscosity increasing agent and 30% of Cocamidopropyl Betain (CAB ~ 30, molecular weight: 366) 1.0 to 5.0% by weight %, Coconut fatty acid diethanol amide (CDE, molecular weight: 301) 1.0 to 5.0% by weight, castor oil 0.5 to 3.0% by weight, camellia oil 0.5 to 3.0% by weight after the solution is completely uniform Cool while continuing stirring until When the temperature of the liquid is cooled to 45 ℃, 0.5% by weight of ethanol and fragrance, and other additives as necessary to mix, then cooled at room temperature and prepared by filtration.
위의 공정을 도식화하면 다음과 같다.Schematic of the above process is as follows.
위의 제조공정에 의한 제품의 물성 및 사용감 측정결과는 다음 실시예를 통하여 설명한다.The measurement results of the physical properties and usability of the product by the above manufacturing process will be described through the following examples.
실시예 1Example 1
본 실험의 주원료인 라우릭산 및 미리스틱산은 순도 99% 이상의 제품을 사용하여야 하며 KOH는 45%로 희석된 용액을 사용하였으며 CAB-30, CDE는 동일한 활성을 가진 제품이라면 어느 것을 사용하여도 무방하다. 동백기름은 씨앗의 껍질을 제거하고 암출, 정제하여 얻은 기름으로 올레익산이 85 내지 90% 이상 함유한 것을 사용하였으며 피마자유는 피마자씨를 압출, 정제하여 얻은 기름으로서 리놀레익산을 80 내지 85% 이상 함유하고 비중이 0.95 내지 0.974, 응고점이 -10 내지 -18℃이며 불포화도가 81 내지 90인 물성을 가진 것을 사용하였다. 하이드록시에틸 셀루로스는 QP-100MH 등급(Grade)을 사용하였으며 비슷한 물성을 지닌 내트로졸(Netrozol) 250HHR을 사용하여도 무방하다.Lauric acid and myristic acid, the main raw materials of this experiment, should use products with purity of 99% or higher, KOH used solution diluted to 45%, and CAB-30 and CDE can use any product having the same activity. . Camellia oil is an oil obtained by removing, shelling and refining seeds, containing 85-90% or more of oleic acid. Castor oil is an oil obtained by extruding and refining castor seeds. 80-85% or more of linoleic acid. And a specific gravity of 0.95 to 0.974, a solidification point of -10 to -18 占 폚 and an unsaturation of 81 to 90 were used. Hydroxyethyl cellulose uses QP-100MH grade (Grade) and may be used with Netrozol 250HHR with similar properties.
앞에서 언급한 제조방법에 따라 다음 표 1의 실시예를 작성하여 각각의 물성과 사용감을 함께 나타내였으며 다음 실시예에 의해 본 발명이 제한되는 것은 아니다.According to the above-mentioned manufacturing method to prepare the examples of the following Table 1 to show each of the physical properties and usability, and the present invention is not limited by the following examples.
주) 기타 : 향, 염료, 방부제등-Note) Others: incense, dyes, preservatives, etc.-
상기 표에서 각 검사항목은 다음의 방법으로 실시하였다.Each test item in the table was carried out by the following method.
기포력 : 1% 수용액을 Ross-Miles 방법으로 실시하였다.Foaming force: A 1% aqueous solution was carried out by the Ross-Miles method.
기포안정도 : 기포력을 측정한 후 5분후의 기포의 높이를 측정하였다.Bubble stability: The bubble height was measured after 5 minutes.
안정도 : 5℃에서 1개월간 방치한 후 제품이 응고되는 정도를 관찰하여 유동성의 정도를 표시하였다.Stability: After standing at 5 ° C for 1 month, the degree of fluidity was indicated by observing the degree of solidification of the product.
● : 유동성 양호 ■ : 유동성 보통 ▲ : 완전히 굳음●: Good fluidity ■: Normal fluidity ▲: Completely hard
사용감 : 각각 일정량을 취하여 사용한 후 촉감, 헹굼성, 후감등을 종합적으로 비교 평가하였다.Usability: After taking a certain amount of each, and compared and evaluated the feeling, rinsing property, sense of afterglow.
● : 양호 ■ : 보통 ▲ : 불량●: Good ■: Normal ▲: Poor
상기 표에서 알 수 있듯이 동백기름과 피마자유가 각각 0.5% 이하이면 모발 세정시나 세안시에 뚜렷한 효과를 나타내지 않으며 반면에 3%를 초과하는 경우에는 기포력이 떨어지면서 사용감은 크게 증가하지 않았다.As can be seen from the above table, when camellia oil and castor oil were each 0.5% or less, the hair washing or washing face did not show a clear effect, whereas in the case of more than 3%, the feeling of foaming did not increase significantly.
실시예 4와 비교예 1,2는 각각 동백기름과 피마자유의 유.무에 대한 비교실험으로서 동백기름과 피마자유를 함께 사용할때 얻어지는 상승효과를 볼 수 있으며, 비교예 3에서는 염화물에 의한 안정도 및 기포력 저하를 볼 수 있다. 또한 비교예 4에서 알 수 있는 것과 같이 KOH를 당량 미만으로 사용하였을때도 안정도 저하를 나타낸다.Example 4 and Comparative Examples 1 and 2 show the synergistic effect obtained when using camellia oil and castor oil together as a comparative experiment on the presence or absence of camellia oil and castor oil, respectively. A decrease in bubble power can be seen. In addition, as can be seen from Comparative Example 4, even when KOH is used in an equivalent amount, the stability is lowered.
실시예 2Example 2
앞의 실시예 3 및 실시예 4에 의한 제품을 시판중인 샴푸와 화장비누에 대하여 비교품평을 한 결과를 다음표에 나타내었다. 품평은 총 60명의 품평자들이 15일간 상기 4가지 제품을 사용한 후 모발세정 및 세안에 대하여 촉감, 헹굼성, 사용후 감촉, 기포력등을 종합적으로 평가하여 가장 우수하다고 느끼는 제품을 선택하도록 하였다.The results of comparative evaluation of the commercially available shampoos and cosmetic soaps according to Example 3 and Example 4 are shown in the following table. A total of 60 reviewers used the above four products for 15 days to comprehensively evaluate the touch, rinsing properties, post-use feeling, and foaming power for hair cleaning and face washing to select the product that they feel the best.
품평결과 본 발명에 의한 인체세정제는 모발 세정시에는 샴푸보다 다소 열등하고 세안시에는 비누보다 다소 열등하나 두 부류간의 제품의 단점을 상호 보완할 수 있는 즉, 모발 세정 및 세안 겸용의 기능을 가진 제품으로 나타났다.As a result of the evaluation, the human cleanser according to the present invention is somewhat inferior to shampoo when washing the hair and somewhat inferior to soap at the time of washing, but can complement the disadvantages of the two classes of products, namely, a product having a function of hair cleaning and facial cleansing. Appeared.
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KR1019940014235A KR970001234B1 (en) | 1994-06-22 | 1994-06-22 | Liquid detergent composition for body |
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KR1019940014235A KR970001234B1 (en) | 1994-06-22 | 1994-06-22 | Liquid detergent composition for body |
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KR200498014Y1 (en) | 2022-04-25 | 2024-05-21 | 안시영 | Golf glove easy to carry golf tees and ball markers |
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