KR960705881A - 열가소성 수지 조성물 및 그의 적층체(thermoplastic resin composition and laminate made therefrom) - Google Patents

열가소성 수지 조성물 및 그의 적층체(thermoplastic resin composition and laminate made therefrom)

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Publication number
KR960705881A
KR960705881A KR1019960702218A KR19960702218A KR960705881A KR 960705881 A KR960705881 A KR 960705881A KR 1019960702218 A KR1019960702218 A KR 1019960702218A KR 19960702218 A KR19960702218 A KR 19960702218A KR 960705881 A KR960705881 A KR 960705881A
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KR
South Korea
Prior art keywords
fluorine
thermoplastic resin
resin composition
ethylene
composition
Prior art date
Application number
KR1019960702218A
Other languages
English (en)
Inventor
요시히사 야마모또
다까후미 야마또
데쓰오 시미즈
다께시 하라다
Original Assignee
이노우에 노리유끼
다이낑고오교 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이노우에 노리유끼, 다이낑고오교 가부시끼가이샤 filed Critical 이노우에 노리유끼
Publication of KR960705881A publication Critical patent/KR960705881A/ko

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • B32B1/08—Tubular products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/03—3 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/12—Polyvinylhalogenides containing fluorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00—Tubular articles, e.g. hoses, pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

(i) 폴리아미드 수지5~80%, (ii) 불소 수지 15~90%, 및 (iii) 상온에서의 인장탄성율 500kg/cm2이하인 불소 고무 1~80중량%로 이루어지는 열가소성 수지 조성물, 및 이 열가소성 수지 조성물로 형성되는 층을 갖는 성형체는 우수한 내약품성을 갖는다.

Description

열가소성 수지 조성물 및 그의 젝층제(THERMOPLASTIC RESIN COMPOSITION AND SAMINATE MADE THEREFROM)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (i) 폴리아미드 수지 5~80% (ii) 불소 수지 15~90중량%, 및 (iii)상온에서의 인장 탄성율이 500kg/cm2이하인 불소 고무 1~80중량%로 이루어지는 열가소성 수지 조성물.
  2. (i) 폴리아미드 수지 5~50% (ii) 불소 수지 45~90중량%, 및 (iii)상온에서의 인장 탄성율이 500kg/cm2이하인 불소 고무 1~50중량%로 이루어지는 열가소성 수지 조성물.
  3. 제1항 또는 제2항에 있어서, 불소 고무(iii)가 라디칼 발생원 및 탄소와 결합한 요오드를 갖는 요오드화물 화합물의 존재하에서 라디칼 중합성의 불포화 결합을 갖는 단량체의 2종 이상을 라디칼 중합함에 있어서, 상기 요오드화물 화합물의 탄소-요오드 결합 사이에 2종 이상의 중합체 사슬 세그멘트를 형성시키도록 함불소 탄성체성 중합체 사슬 세그멘트(A)와 함불소 비탄성체성 중합체 사슬 세그멘트(B)을 구성한 단량체를 순차적으로 중합시켜서 얻어지는 함불소 세그멘트화 중합체인 열가소성 수지 조성물.
  4. 제1항에 내지 제3항 중 어느 한 항에 있어서, 불소 수지(ii)가 에틸렌/함불소 올레핀계 공중합체인 열가소성 수지 조성물.
  5. 제4항에 있어서, 불소 수지(ii)가 전단속도 100sec-1하의 250。C에서 용융 점도가 10~100.000포아즈의 점도를 갖는 에틸렌/함불소 올렌핀계 공중합체인 열가소성 수지 조성물.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 불소 수지(ii)가 에틸렌 대 TFE의 몰 조성비가 10/90~38/62이며, 그것들과 공중합할 수 있는 제3의 함불소 단량체가 에틸렌과 TFE 총량에 대하여 약 0.1~5몰% 함유되는 에틸렌/테트라플루오로에틸렌계 공중합체인 열가소성 수지 조성물.
  7. 제1항 내지 제6항 중 어느 한 항에 있어서, 폴리아미드 수지(i), 불소 수지(ii) 및 불소 고무(iii)가 전단속도 100sec-1하에서의 250。C에서 용융 점도가 10~100,000포아즈인 열가소성 수지 조성물.
  8. 구성층 중의 1층 이상이 제1항 내지 제7항 중 어느 한 항에 기재된 조성물로 이루어지는 성형체.
  9. 구성층 중의 1층 이상이 제1항 내지 제8항 중 어느 한 항에 기재된 조성물로 이루어지는 동시 압출로 성형하여 이루어지는 튜브상 성형체.
  10. 동시 압출로 성형하여 이루어지는 튜브상 성형체가 폴리아미드 수지층/제1항 내지 제9항 중 어느 한 항에 기재된 조성물로 이루어지는 조성물층/불소 수지층의 3층 구조를 갖는 적층체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960702218A 1993-10-29 1994-10-27 열가소성 수지 조성물 및 그의 적층체(thermoplastic resin composition and laminate made therefrom) KR960705881A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP93-272233 1993-10-29
JP27223393 1993-10-29
PCT/JP1994/001806 WO1995011940A1 (fr) 1993-10-29 1994-10-27 Composition de resine thermoplastique et stratifie a base de cette composition

Publications (1)

Publication Number Publication Date
KR960705881A true KR960705881A (ko) 1996-11-08

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ID=17510982

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KR1019960702218A KR960705881A (ko) 1993-10-29 1994-10-27 열가소성 수지 조성물 및 그의 적층체(thermoplastic resin composition and laminate made therefrom)

Country Status (7)

Country Link
US (1) US5891538A (ko)
EP (1) EP0726293B1 (ko)
JP (1) JP3324118B2 (ko)
KR (1) KR960705881A (ko)
CN (1) CN1134164A (ko)
DE (1) DE69422417T2 (ko)
WO (1) WO1995011940A1 (ko)

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Also Published As

Publication number Publication date
DE69422417D1 (de) 2000-02-03
EP0726293A4 (en) 1998-06-10
JP3324118B2 (ja) 2002-09-17
US5891538A (en) 1999-04-06
CN1134164A (zh) 1996-10-23
EP0726293B1 (en) 1999-12-29
DE69422417T2 (de) 2000-07-13
WO1995011940A1 (fr) 1995-05-04
EP0726293A1 (en) 1996-08-14

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