KR960015156B1 - 보존조성물 및 이를 이용한 수용성물 보존방법 - Google Patents
보존조성물 및 이를 이용한 수용성물 보존방법 Download PDFInfo
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- KR960015156B1 KR960015156B1 KR1019890004998A KR890004998A KR960015156B1 KR 960015156 B1 KR960015156 B1 KR 960015156B1 KR 1019890004998 A KR1019890004998 A KR 1019890004998A KR 890004998 A KR890004998 A KR 890004998A KR 960015156 B1 KR960015156 B1 KR 960015156B1
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/32—Heterocyclic sulfur, selenium or tellurium compounds
- C10M135/36—Heterocyclic sulfur, selenium or tellurium compounds the ring containing sulfur and carbon with nitrogen or oxygen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/524—Preservatives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/102—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- Agronomy & Crop Science (AREA)
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- Biodiversity & Conservation Biology (AREA)
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Abstract
내용없음.
Description
본 발명은 미생물로 인한 퇴화에 대하여 식기세정액, 계면활성제 및 액체비누와 같은 수용성물을 보존하는 것에 관한 것이다.
보다 상세하게는, 본 발명은 미생물에 의해 퇴화되기 쉬운 물질을 보존하기 위하여 2-n-옥틸-4-이소티아졸린-3-온, 5-클로로-2-메틸-4-이소티아졸린-3-온 및 2-메틸-4-이소티아졸린-3-온을 포함하는 조성물을 사용하는 것에 관한 것이다.
수용액내에서 유기물질을 함유한 물질은 미생물의 침해를 받기 쉽다.
식기 세정액, 계면할성제, 액체비누, 접착제, 금속가공액, 손세정제, 페인트, 미네랄슬러리, 중합체에멀션 및 샴푸와 같은 물질들을 통상적으로 부패미생물의 성장을 막기 위하여 항세균제와 함께 배합된다.
물질내에서 미생물의 성장을 막기 위한 여러 물질이 문헌에 소개되어 있다.
이하, 본 발명을 설명한다.
본 발면은 이소티아졸론을 조합하여 아주 소량으로 사용할때라도 비슷한 투여률에서 어떠한 성분보다도 효과적인 것이라는 발견에 관한 것이다.
본 발명의 바람직한 구체화는, a. 성분 1 : 5-클로로-2-메틸-4-이소티아졸린-3-온 75%와 2-메틸-4-이소티아졸린-3-온 25%의 혼합물을 포함하며; 및 b. 성분 2 : 2-n-옥틸-4-이소티아졸린-3-온을 포함한다.
이들 2가지 성분은 성분 1 : 성분 2의 2 : 1-5 : 2 범위로 혼합되는 것이 좋다.
전형적인 사용수준은 활성성분으로서 성분 1 및 성분 2를 1~15ppm의 범위로, 바람직하게는 1ppm이상 4ppm미만 범위의 조성물을 사용하는 것이다.
이하, 본 발명을 실시예에 의해 설명한다.
[실시예]
상기 2가지 성분을 여러 가지 수준으로 식기세정액 배합물에 첨가하였다.
이 시험시료에 종전에 식기 세정액을 열화시킬 수 있는 것으로 알려진 박테리아를 혼입하였다.
이 시료에 4주에 걸쳐 매주 부가적으로 미생물을 투여하였다.
시료내에 존재하는 미생물 성장수준을 매주 측정하였다.
트립타카제 소이 한천배양(trypticase soy agar) 및 로즈 벤갈 크로람페니콜(rose bengal chloramphenicol)한천배양판을 이용하여 표준 플레이트 계수기술(Standard plate counting technique)을 사용하였다.
시료에 미생물설장이 없는 주(week)의 수(數)를 측정하여 시료를 평가하였다.
이들 물질내의 어떠한 성장도 수용할 수 없는 것으로 판단하고 실패(failure)라고 평가하였다.
성분 1의 MIC(최소 억제농도)
성분 1은 광범위한 항세균성을 갖는 것으로 알려져 있다.
여러 가지 종류의 미생물에 대한 성분 1의 최소억제농도(MID, minimun inhibitory concentrations)가 표 1에 나타나 있다.
성분 2의 NIC
성분 2는 진균류를 제거하는데 효과적이나 박테리아 특히 그램음성 박테리아를 제어하는데는 훨씬 덜 효과적이라고 알려져 있다.
여러 가지 종류의 미생물에 대한 최소 억제농도가 표 2에 나타나있다.
성분 2 그 자체는 전형적인 진균 및 박테리아 특히 그램음성 박테리아로써 쉽게 감염되는 물질 내에서의 미생물 성장을 막는데는 효과적이지 않다.
성분 1은 최소 4ppm의 투여량 수준에서 효과적인 것으로 알려져 있다.
그러나, 성분 1과 성분 2의 혼합물은 이 2가지 성분 각각의 활성 스펙트럼에 근거하여 추정될 수 있는 것보다 더 효과적인 것으로 발견되었다.
표 3에 액체 그릇 세정제에서 비교시험의 결과를 나타낸다(미생물 성장시작까지의 주(week)를 2성분의 농도함수로써 나타내었다).
상기 표 3에 보는 바와 같이, 본 발명에 의한 조성물은 소량 사용하더라도 이를 조성물을 이루는 각각의 성분 단독으로 사용하는 경우보다 그 활성이 뛰어남을 알 수 있다.
Claims (5)
- 5-클로로-2-메틸-4-이소티아졸린-3-온과 2-메틸-4-이소티아졸린-3-온의 혼합물(성분 1) 및 2-n-옥틸-4-이소티아졸린-3-온(성분 2)를 성분 2에 대한 성분 1의 비를 5 : 1-2 : 1로 혼합한 혼합물을 포함하는 보존성 조성물.
- 첨구범위 1의 조성물을 수용성물의 보존에 효과적인 량으로 수용성물에 첨가함을 포함하는 수용성물 보존 방법.
- 제2항에 있어서, 상기 첨가량은 1~15ppm임을 특징으로 하는 방법.
- 제3항에 있어서, 상기 첨가량은 1~4ppm임을 특징으로 하는 방법.
- 제2항에 있어서, 상기 수용성물은 식기 세정액, 계면활성제, 액체비누, 접착제, 금속가공액, 손 세정제, 페인트, 미네랄슬러리, 중합체에멀션 및 샴푸로부터 선택됨을 특징으로 하는 방법.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/190,864 US4822511A (en) | 1988-05-06 | 1988-05-06 | Preservative compositions comprising a synergistic mixture of isothiagolones |
US190,864 | 1988-05-06 | ||
US190864 | 1988-05-06 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890017351A KR890017351A (ko) | 1989-12-15 |
KR960015156B1 true KR960015156B1 (ko) | 1996-11-01 |
Family
ID=22703119
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890004998A KR960015156B1 (ko) | 1988-05-06 | 1989-04-15 | 보존조성물 및 이를 이용한 수용성물 보존방법 |
Country Status (14)
Country | Link |
---|---|
US (1) | US4822511A (ko) |
EP (1) | EP0340938A1 (ko) |
JP (1) | JP2804785B2 (ko) |
KR (1) | KR960015156B1 (ko) |
AU (1) | AU620397B2 (ko) |
CA (1) | CA1330689C (ko) |
DK (1) | DK221889A (ko) |
FI (1) | FI892175A (ko) |
HU (1) | HUT51106A (ko) |
IL (1) | IL90182A0 (ko) |
NO (1) | NO891746L (ko) |
NZ (1) | NZ228937A (ko) |
PT (1) | PT90474A (ko) |
ZA (1) | ZA893271B (ko) |
Families Citing this family (22)
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US5068338A (en) * | 1982-06-01 | 1991-11-26 | Rohm And Haas Company | Process for nitrosamine-free sabilized isothiazolones |
US4906651A (en) * | 1988-12-22 | 1990-03-06 | Rohm And Haas Company | Synergistic microbicidal combinations containing 3-isothiazolone and commercial biocides |
DE3914827C2 (de) * | 1989-05-05 | 1995-06-14 | Schuelke & Mayr Gmbh | Flüssiges Desinfektionsmittelkonzentrat |
EP0398795B1 (en) * | 1989-05-17 | 1996-03-27 | Katayama Chemical, Inc. | Aqueous isothiazolone formulation |
CA2029302A1 (en) * | 1989-11-17 | 1991-05-18 | Gary L. Willingham | Use of carbonyl stabilizers for 3-isothiazolones |
DE69102203T2 (de) * | 1990-04-27 | 1994-09-15 | Zeneca Ltd | Biozide Zusammensetzung und ihre Verwendung. |
US5142058A (en) * | 1990-12-14 | 1992-08-25 | Rohm And Haas Company | Halogen-containing organic stabilizers for 3-isothiazolones |
US5308858A (en) * | 1991-12-05 | 1994-05-03 | Electric Power Research Institute | Use of additives for preservative carrier oils to improve their efficacy against wood decay |
US5227156A (en) * | 1992-04-14 | 1993-07-13 | Amway Corporation | Use of zinc compounds to stabilize a thiazolinone preservative in an anti-dandruff shampoo |
US5342534A (en) * | 1992-12-31 | 1994-08-30 | Eastman Kodak Company | Hard surface cleaner |
US5294614A (en) * | 1993-01-13 | 1994-03-15 | Rohm And Haas Company | Synergistic microbicidal composition comprising 3-isothiazolones and 1-methyl-3,5,7-triaza-1-azoniatricyclo(3.3.1.1)decane chloride |
US5589448A (en) * | 1993-02-17 | 1996-12-31 | The Clorox Company | High water liquid enzyme prewash composition |
US5789364A (en) * | 1993-02-17 | 1998-08-04 | The Clorox Company | High water liquid enzyme prewash composition |
TW385231B (en) * | 1993-09-17 | 2000-03-21 | Chugoku Marine Paints | Anti-fouling compositions or fouling control of harmful aquatic organisms |
DE69512452T2 (de) * | 1994-04-07 | 2000-05-18 | Rohm And Haas Co., Philadelphia | Halogenfreies Biozid |
US6322778B1 (en) | 1998-02-10 | 2001-11-27 | Johnson & Johnson Consumer Companies, Inc. | Hair conditioning compositions comprising a quaternary ammonium compound |
FR2801767B1 (fr) * | 1999-12-01 | 2002-09-13 | Eastman Kodak Co | Materiau biocide ayant une activite amelioree |
DE60226840D1 (de) * | 2001-01-04 | 2008-07-10 | Byotrol Plc | Antimikrobielle zusammensetzung |
GB0713799D0 (en) | 2007-07-17 | 2007-08-22 | Byotrol Llc | Anti-microbial compositions |
US8003593B2 (en) | 2007-09-17 | 2011-08-23 | Byotrol Plc | Formulations comprising an anti-microbial composition |
JP5582714B2 (ja) * | 2009-04-07 | 2014-09-03 | 日東電工株式会社 | 粘着シートおよびその製造方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
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US4325201A (en) * | 1967-03-09 | 1982-04-20 | Rohm And Haas Company | Seed treatment with 3-isothiazolones |
US3523121A (en) * | 1967-03-09 | 1970-08-04 | Rohm & Haas | Certain 2-carbamoyl-3-isothiazolenes |
US4173643A (en) * | 1973-12-20 | 1979-11-06 | Rohm And Haas Company | Synergistic microbiocidal compositions |
US4067878A (en) * | 1976-03-05 | 1978-01-10 | Rohm And Haas Company | Stabilization of solutions of 3-isothiazolones |
US4295932A (en) * | 1980-07-14 | 1981-10-20 | Naloc Chemical Company | Synergistic blend of biocides |
US4454146A (en) * | 1982-05-14 | 1984-06-12 | Lever Brothers Company | Synergistic preservative compositions |
US4608183A (en) * | 1985-01-14 | 1986-08-26 | Board Of Governors Of Wayne State University | Synergistic antimicrobial or biocidal mixtures including isothiazolones |
US4655936A (en) * | 1985-09-19 | 1987-04-07 | Nalco Chemical Company | Microbiological control in uranium processing |
FI84421C (fi) * | 1986-03-04 | 1991-12-10 | Sutton Lab Inc | Sammansaettningar av konserveringsaemnen och anvaendningar av desamma. |
US4661503A (en) * | 1986-06-16 | 1987-04-28 | Nalco Chemical Company | Synergistic biocide of dodecyl guanidine hydrochloride and a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one |
US4725611A (en) * | 1986-08-06 | 1988-02-16 | Drew Chemical Corporation | Synergistic microbiocidal compositions containing a mixture of a bicyclicpolyoxymethyleneoxazolidine and a 4-isothiazolin-3-one |
DE3702546A1 (de) * | 1987-01-29 | 1988-08-11 | Ulrich Jordan | Desinfektionsmittel |
US4732905A (en) * | 1987-03-13 | 1988-03-22 | Betz Laboratories, Inc. | Biocidal compositions and use thereof containing a synergistic mixture of 2-bromo-2-nitropropane-1,3-diol and a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one |
-
1988
- 1988-05-06 US US07/190,864 patent/US4822511A/en not_active Expired - Lifetime
-
1989
- 1989-03-31 CA CA000595295A patent/CA1330689C/en not_active Expired - Fee Related
- 1989-04-15 KR KR1019890004998A patent/KR960015156B1/ko not_active IP Right Cessation
- 1989-04-18 EP EP89303843A patent/EP0340938A1/en not_active Ceased
- 1989-04-27 NO NO89891746A patent/NO891746L/no unknown
- 1989-05-01 NZ NZ228937A patent/NZ228937A/en unknown
- 1989-05-02 JP JP1112269A patent/JP2804785B2/ja not_active Expired - Lifetime
- 1989-05-02 AU AU33945/89A patent/AU620397B2/en not_active Ceased
- 1989-05-03 ZA ZA893271A patent/ZA893271B/xx unknown
- 1989-05-04 IL IL90182A patent/IL90182A0/xx unknown
- 1989-05-05 DK DK221889A patent/DK221889A/da not_active Application Discontinuation
- 1989-05-05 FI FI892175A patent/FI892175A/fi not_active Application Discontinuation
- 1989-05-05 PT PT90474A patent/PT90474A/pt not_active Application Discontinuation
- 1989-05-05 HU HU892175A patent/HUT51106A/hu unknown
Also Published As
Publication number | Publication date |
---|---|
ZA893271B (en) | 1990-01-31 |
EP0340938A1 (en) | 1989-11-08 |
HUT51106A (en) | 1990-04-28 |
CA1330689C (en) | 1994-07-19 |
DK221889A (da) | 1989-11-07 |
IL90182A0 (en) | 1989-12-15 |
KR890017351A (ko) | 1989-12-15 |
JP2804785B2 (ja) | 1998-09-30 |
FI892175A (fi) | 1989-11-07 |
JPH01318090A (ja) | 1989-12-22 |
DK221889D0 (da) | 1989-05-05 |
NZ228937A (en) | 1992-03-26 |
AU3394589A (en) | 1989-11-09 |
PT90474A (pt) | 1989-11-30 |
FI892175A0 (fi) | 1989-05-05 |
US4822511A (en) | 1989-04-18 |
NO891746L (no) | 1989-11-07 |
NO891746D0 (no) | 1989-04-27 |
AU620397B2 (en) | 1992-02-20 |
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