KR950704367A - 코흐 반응에 의해 작용화된 중합체 및 그의 유도체(polymers functionalized by koch reaction and derivatives thereof) - Google Patents
코흐 반응에 의해 작용화된 중합체 및 그의 유도체(polymers functionalized by koch reaction and derivatives thereof)Info
- Publication number
- KR950704367A KR950704367A KR1019950702453A KR19950702453A KR950704367A KR 950704367 A KR950704367 A KR 950704367A KR 1019950702453 A KR1019950702453 A KR 1019950702453A KR 19950702453 A KR19950702453 A KR 19950702453A KR 950704367 A KR950704367 A KR 950704367A
- Authority
- KR
- South Korea
- Prior art keywords
- polymer
- functionalized
- functionalized polymer
- backbone
- nucleophilic
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract 21
- 230000000269 nucleophilic effect Effects 0.000 claims abstract 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000005977 Ethylene Substances 0.000 claims abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 125000000524 functional group Chemical group 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- 229940126062 Compound A Drugs 0.000 claims 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 1
- 239000003377 acid catalyst Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000002199 base oil Substances 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 claims 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
- 239000000314 lubricant Substances 0.000 claims 1
- 239000003879 lubricant additive Substances 0.000 claims 1
- 239000010687 lubricating oil Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
- 150000003573 thiols Chemical class 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
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- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
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- B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract
본 발명은 적어도 500의 수평균 분자량과 중합체 쇄당 적어도 하나의 에틸렌 이중 결합을 갖는 적어도 하나의 중합체를 일산화 탄소와 친핵성 포획제를 반응시켜 생성된 반응 생성물인 코흐 작용화된 생성물에 관한 것이다. 본 발명은 또한 작용화된 중합체, 그의 유도체 및 그의 제조 방법을 포함한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 일반식 -CO-Y-R3기 (여기서, Y는 O 또는 S이고, R3는 H 또는 하이드로카빌이고, 작용기의 적어도 50몰%가 중합체 주쇄의 3차 탄소 원자에 결합되거나, 또는 R3는 아릴, 치환된 아릴 또는 치환된 하이드로카빌이다)에 의해 작용화된, 중합체 주쇄의 Mn이 500 이상인 작용화된 탄화수소 중합체.
- 제1항에 있어서, 중합체 쇄당 평균 2개 이하의 작용기를 갖는 작용화된 중합체.
- 제1항 또는 제2항에 있어서, 상기 중항체 주쇄의 Mn이 2800이상인 작용화된 중합체.
- 제1항 내지 제3항중 어느 한 항에 있어서, 상기 중합체 주쇄가 에틸렌-부텐 공중합체인 작용화된 중합체.
- 제1항 내지 제4항중 어느 한 항의 작용화된 중합체를 포함하는 유성 조성물.
- 상기 작용화된 중합체와 기본 오일을 포함하는 윤활유 또는 윤활유첨가제 패키쥐 형태의 제5항의 유성 조성물.
- 제1항 내지 제4항중 어느 한 항의 작용화된 중합체를 친핵성 반응물과 반응시켜 생성된 생성물인 유도된 중합체.
- 연료 또는 윤활유중에서 첨가제로서의 제1항 내지 제4항중 어느 한 항의 작용화된 중합체, 제5항 또는 제6항의 조성물, 또는 제7항의 유도된 중합체의 용도.
- (a)적어도 500의 수 평균 분자량 및 중합체 쇄당 적어도 하나의 에틸렌 이중 결합을 갖는 적어도 하나의 탄화수소 중합체; (b)일산화 탄소, (c)-7미만의 하멧트 산도(Hammett acidity)를 갖는 적어도 하나의 산 촉매, 및 (d)물, 하이드록시 함유 화합물 및 티올 함유 화합물로 구성된 군중에서 선택된 친핵성 포획제 (임의로 상기 친핵성 포획제의 pKa는 12미만이다)를 촉매로 전이 금속에 의존하지 않고 반응시키는 단계를 포함하는 제1항의 작용화된 중합체를 제조하는 방법.
- 제9항에 있어서, 상기 친핵성 포획제가 할로페놀인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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US99240392A | 1992-12-17 | 1992-12-17 | |
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PCT/US1993/012210 WO1994013709A2 (en) | 1992-12-17 | 1993-12-15 | POLYMERS FUNCTIONALIZED BY THE KOCH REACTION AND THEIR DERIVATIVES |
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- 1993-12-15 BR BR9307684-3A patent/BR9307684A/pt not_active Application Discontinuation
- 1993-12-15 WO PCT/US1993/012210 patent/WO1994013709A2/en active IP Right Grant
- 1993-12-15 JP JP6514505A patent/JP3065101B2/ja not_active Expired - Lifetime
- 1993-12-15 AT AT94905398T patent/ATE167876T1/de active
- 1993-12-16 CN CN93120132A patent/CN1057100C/zh not_active Expired - Fee Related
-
1995
- 1995-06-06 US US08/469,561 patent/US5698722A/en not_active Expired - Fee Related
- 1995-06-06 US US08/470,883 patent/US5717039A/en not_active Expired - Fee Related
- 1995-08-23 US US08/518,382 patent/US5696064A/en not_active Expired - Fee Related
- 1995-09-25 US US08/534,891 patent/US5629434A/en not_active Expired - Fee Related
-
1996
- 1996-12-16 US US08/764,918 patent/US5703256A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5698722A (en) | 1997-12-16 |
RU95118399A (ru) | 1997-06-20 |
US5717039A (en) | 1998-02-10 |
KR100253958B1 (ko) | 2000-04-15 |
US5696064A (en) | 1997-12-09 |
CA2110871C (en) | 2001-02-06 |
ZA939314B (en) | 1995-06-13 |
WO1994013709A2 (en) | 1994-06-23 |
HU9501163D0 (en) | 1996-05-28 |
MY131507A (en) | 2007-08-30 |
JP3065101B2 (ja) | 2000-07-12 |
AU5952194A (en) | 1994-07-04 |
BR9307684A (pt) | 1999-08-31 |
MX9307827A (es) | 1994-06-30 |
SG48357A1 (en) | 1998-04-17 |
ATE167876T1 (de) | 1998-07-15 |
EP0674666A1 (en) | 1995-10-04 |
HUT73198A (en) | 1996-06-28 |
IL107810A0 (en) | 1994-02-27 |
CN1090859A (zh) | 1994-08-17 |
CN1057100C (zh) | 2000-10-04 |
AU671002B2 (en) | 1996-08-08 |
ES2117783T3 (es) | 1998-08-16 |
US5629434A (en) | 1997-05-13 |
US5703256A (en) | 1997-12-30 |
DE69319447T2 (de) | 1998-12-03 |
EP0674666B1 (en) | 1998-07-01 |
JPH08505414A (ja) | 1996-06-11 |
CA2110871A1 (en) | 1994-06-18 |
DE69319447D1 (de) | 1998-08-06 |
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